CN102580709A - Amorphous anatase nano titanium dioxide material and preparation method thereof - Google Patents
Amorphous anatase nano titanium dioxide material and preparation method thereof Download PDFInfo
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- CN102580709A CN102580709A CN2012100108286A CN201210010828A CN102580709A CN 102580709 A CN102580709 A CN 102580709A CN 2012100108286 A CN2012100108286 A CN 2012100108286A CN 201210010828 A CN201210010828 A CN 201210010828A CN 102580709 A CN102580709 A CN 102580709A
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 title abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 239000010936 titanium Substances 0.000 claims abstract description 34
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 26
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 15
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007864 aqueous solution Substances 0.000 claims abstract description 12
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 12
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 5
- IUYOGGFTLHZHEG-UHFFFAOYSA-N copper titanium Chemical compound [Ti].[Cu] IUYOGGFTLHZHEG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 26
- 239000000956 alloy Substances 0.000 claims description 26
- 239000010949 copper Substances 0.000 claims description 22
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 19
- 229910052802 copper Inorganic materials 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 12
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- 230000014759 maintenance of location Effects 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 5
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 5
- 235000011151 potassium sulphates Nutrition 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 3
- 239000005300 metallic glass Substances 0.000 claims description 3
- -1 sodium sulphate Chemical compound 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 17
- 239000004408 titanium dioxide Substances 0.000 abstract description 11
- 239000007791 liquid phase Substances 0.000 abstract description 5
- 230000001699 photocatalysis Effects 0.000 abstract description 4
- 238000003837 high-temperature calcination Methods 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 238000009413 insulation Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种非晶纳米脱钛型二氧化钛材料及其制备方法，首先将非晶钛铜合金置于腐蚀液中密封容器，所述腐蚀液为质量百分数为50～68％的硝酸水溶液，其中加入硫酸盐以提供硫酸根，所述硫酸根的浓度为1～20mmol/L，然后将密封容器在50～90℃下，保温即可。本发明以非晶态钛铜合金为原料，属于液相法的范畴，提供一种能够生长出较厚的锐钛矿型的纳米多孔二氧化钛材料及其制备方法，该方法操作简单，不需要高温煅烧即可制备结晶性较好的纳米二氧化钛薄膜，具有良好的光催化性能。
The invention discloses an amorphous nano-de-titanium titanium dioxide material and a preparation method thereof. Firstly, the amorphous titanium-copper alloy is placed in an corrosive liquid to seal a container, and the corrosive liquid is an aqueous solution of nitric acid with a mass percentage of 50-68%. Sulfate is added to provide sulfate, the concentration of the sulfate is 1-20mmol/L, and then the sealed container is kept at 50-90°C to keep warm. The present invention uses amorphous titanium-copper alloy as raw material, belongs to the category of liquid phase method, and provides a nanoporous titanium dioxide material capable of growing thicker anatase type and its preparation method. The method is simple to operate and does not require high temperature Calcination can prepare nano-titanium dioxide film with good crystallinity, which has good photocatalytic performance.
Description
Technical field
The present invention relates to a kind of material and preparation method thereof, more particularly, relate to a kind of free etch synthetic nano material and method thereof utilized.
Background technology
Titanium dioxide is as a kind of semiconductor of broad stopband, and its oxidation-reduction potential is high, and light-catalyzed reaction is active strong, good stability, and fast light corrosion, and nontoxic with low cost, have the position that can not be substituted in photocatalysis field at present, be the most frequently used photochemical catalyst.With regard to crystal structure, titanium dioxide has three kinds of common crystal formations, is respectively anatase, rutile and brockite.The base unit that they form structure is TiO
6Octahedron, anatase structured by TiO
6Octahedra through being total to the limit composition, rutile and brockite structure are then by TiO
6Octahedron is total to the summit and is total to the limit to be formed.Because structure is different, with respect to other two kinds of crystal formations, the big (E of the titanium dioxide energy gap of Detitanium-ore-type
g=3.2eV), the redox ability in light induced electron hole is stronger, is more suitable for doing photochemical catalyst.The titanium dioxide of nanostructured has the distinctive skin effect of nano particle, bulk effect, quantum size effect and macro quanta tunnel effect, and oxidability is stronger under illumination, and photocatalytic activity is higher.The preparation method of nano titanium oxide generally is divided into vapor phase method and liquid phase method, and vapor phase method mainly comprises condensation of gas method, sputtering method, vacuum vapor deposition method, mixing plasma method etc.Liquid phase method mainly comprises technologies of preparing such as Hydrolyze method, the precipitation method, sol-gel process, hydro-thermal method, microemulsion method.Because the liquid phase method energy consumption is little, equipment is simple, cost is low, is that widely used preparation method is gone up with industry in the laboratory, thereby has caused extensive interest and concern.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art; With the amorphous state titanium-cuprum copper alloy is raw material; A kind of nano porous titanium dioxide material that can grow thicker Detitanium-ore-type and preparation method thereof is provided; This method is simple to operate, does not need high-temperature calcination can prepare crystallinity nano-titanium dioxide film preferably.This method belongs to the category of liquid phase method, and finished-product material has good photocatalysis performance.
The object of the invention is achieved through following technical scheme.
(be that step 1) places the corrosive liquid airtight container with the amorphous CTB alloy at first; Said corrosive liquid is that mass percent is 50～68% aqueous solution of nitric acid; Wherein add sulfate so that sulfate radical to be provided; The concentration of said sulfate radical is 1～20mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 200～600cm
2/ L.
Then (being step 2) under 50～90 ℃, temperature retention time is to get final product in 50～300 hours with airtight container.
In the said step (1), HNO
3The mass fraction of solution is preferably 55%-65%, is more preferably 65%.
In the said step (1), sulfate can make any water miscible sulfate, like sodium sulphate, and potassium sulfate, copper sulphate.
In the said step (1), the concentration of sulfate is preferably 5-15mmol/L, is more preferably 7-10mmol/L.
In the said step (1), the atomic molar of Ti and Cu is than being (2～5) in the titanium copper non-crystaline amorphous metal of use: (8～5), the atomic molar ratio of preferred Ti and Cu is 4: 6.
In the said step (1), the amorphous CTB alloy is made into ribbon, and its gross area is meant the product (ignoring beam thickness) of band length and width, and the volume ratio of itself and corrosive liquid is preferably 300-450cm
2/ L is more preferably 300-400cm
2/ L.
Holding temperature in the said step (2) is preferably 60-80 ℃, is more preferably 65-70 ℃, and temperature retention time is preferably 100-250 hour, is more preferably 120-150 hour.
Technical scheme of the present invention is easy and simple to handle, compares with the traditional preparation process method, mainly contains following advantage: (1) is raw material with the amorphous state titanium-cuprum copper alloy first; Original position synthesis of titanium dioxide film is (shown in accompanying drawing 1; SEM S4800, Hitachi, Japan); (2) do not need high-temperature calcination can prepare crystallinity nano-titanium dioxide film (shown in accompanying drawing 2, RIGAKU/DMAX2500, the XRD analysis of Japan) preferably; (3) the nano porous titanium dioxide film that grows is thicker than conventional method; Be more conducive to the absorption of reactant in the light-catalyzed reaction; The material of the present invention's preparation is used photocatalyst; Through experimental verification, organic dyestuff rhodamine B 10mmol/L shuirongye can use a small amount of this material 0.1g catalytic degradation under the irradiation of 500W xenon lamp, and degradation rate can reach 50% after one hour.Because this material belongs to thin-film material, can overcome the not re-usable shortcoming of fine catalyst.
Description of drawings
The anatase-type nanometer titanium dioxide pattern photo of Fig. 1 preparation (SEM S4800, Hitachi, Japan).
The XRD spectra of the anatase-type nanometer titanium dioxide of Fig. 2 preparation (XRD tester RIGAKU/DMAX2500, Japan).
The specific embodiment
Further specify technical scheme of the present invention below in conjunction with specific embodiment.Select for use amorphous CTB alloy band to prepare, its gross area is the product of band length and width, ignores beam thickness.
Embodiment 1
(1) with amorphous CTB alloy Ti
40Cu
60(the atomic molar ratio of titanium and copper is 4: 6) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 65% aqueous solution of nitric acid; Wherein add sodium sulphate so that sulfate radical to be provided; Concentration is 20mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 400cm
2/ L
(2) container was placed in 70 ℃ the water-bath insulation 150 hours
Embodiment 2
(1) with amorphous CTB alloy Ti
20Cu
80(the atomic molar ratio of titanium and copper is 2: 8) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 50% aqueous solution of nitric acid; Wherein add potassium sulfate so that sulfate radical to be provided; Concentration is 7mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 600cm
2/ L
(2) container was placed in 80 ℃ the water-bath insulation 120 hours
Embodiment 3
(1) with amorphous CTB alloy Ti
20Cu
80(the atomic molar ratio of titanium and copper is 2: 8) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 68% aqueous solution of nitric acid; Wherein add copper sulphate so that sulfate radical to be provided; Concentration is 1mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 200cm
2/ L
(2) container was placed in 90 ℃ the water-bath insulation 50 hours
Embodiment 4
(1) with amorphous CTB alloy Ti
30Cu
70(the atomic molar ratio of titanium and copper is 3: 7) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 55% aqueous solution of nitric acid; Wherein add sodium sulphate so that sulfate radical to be provided; Concentration is 15mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 450cm
2/ L
(2) container was placed in 65 ℃ the water-bath insulation 100 hours
Embodiment 5
(1) with amorphous CTB alloy Ti
30Cu
70(the atomic molar ratio of titanium and copper is 3: 7) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 60% aqueous solution of nitric acid; Wherein add potassium sulfate so that sulfate radical to be provided; Concentration is 10mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 300cm
2/ L
(2) container was placed in 60 ℃ the water-bath insulation 300 hours
Embodiment 6
(1) with amorphous CTB alloy Ti
20Cu
80(the atomic molar ratio of titanium and copper is 2: 8) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 60% aqueous solution of nitric acid; Wherein add sodium sulphate so that sulfate radical to be provided; Concentration is 5mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 450cm
2/ L
(2) container was placed in 50 ℃ the water-bath insulation 250 hours
Embodiment 7
(1) with amorphous CTB alloy Ti
40Cu
60(the atomic molar ratio of titanium and copper is 4: 6) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 68% aqueous solution of nitric acid; Wherein add copper sulphate so that sulfate radical to be provided; Concentration is 10mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 600cm
2/ L
(2) container was placed in 55 ℃ the water-bath insulation 50 hours
Embodiment 8
(1) with amorphous CTB alloy Ti
50Cu
50(the atomic molar ratio of titanium and copper is 5: 5) places the corrosive liquid airtight container; Said corrosive liquid is that mass percent is 55% aqueous solution of nitric acid; Wherein add copper sulphate so that sulfate radical to be provided; Concentration is 7mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 200cm
2/ L
(2) container was placed in 70 ℃ the water-bath insulation 150 hours
More than the present invention has been done exemplary description; Should be noted that; Under the situation that does not break away from core of the present invention, the replacement that is equal to that any simple distortion, modification or other those skilled in the art can not spend creative work all falls into protection scope of the present invention.
Claims (10)
1. an amorphous nano takes off titanium type titanic oxide material, is raw material with the amorphous state titanium-cuprum copper alloy, it is characterized in that, prepares according to following step:
Step 1 places the corrosive liquid airtight container with the amorphous CTB alloy; Said corrosive liquid is that mass percent is 50～68% aqueous solution of nitric acid; Wherein add sulfate so that sulfate radical to be provided; The concentration of said sulfate radical is 1～20mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 200～600cm
2/ L
Under 50～90 ℃, temperature retention time is to get final product in 50～300 hours to step 2 with airtight container.
2. a kind of amorphous nano according to claim 1 takes off titanium type titanic oxide material, it is characterized in that, and in the said step (1), HNO
3The mass fraction of solution is preferably 55%-65%, is more preferably 65%.
3. a kind of amorphous nano according to claim 1 takes off titanium type titanic oxide material, it is characterized in that, in the said step (1), sulfate can make any water miscible sulfate, like sodium sulphate, and potassium sulfate, copper sulphate; In the said step (1), the concentration of sulfate is preferably 5-15mmol/L, is more preferably 7-10mmol/L.
4. a kind of amorphous nano according to claim 1 takes off titanium type titanic oxide material; It is characterized in that; In the said step (1), the atomic molar of Ti and Cu is than being (2～5) in the titanium copper non-crystaline amorphous metal of use: (8～5), and the atomic molar ratio of preferred Ti and Cu is 4: 6; In the said step (1), the amorphous CTB alloy is made into ribbon, and its gross area is meant the product (ignoring beam thickness) of band length and width, and the volume ratio of itself and corrosive liquid is preferably 300-450cm
2/ L is more preferably 300-400cm
2/ L.
5. a kind of amorphous nano according to claim 1 takes off titanium type titanic oxide material; It is characterized in that the holding temperature in the said step (2) is preferably 60-80 ℃, be more preferably 65-70 ℃; Temperature retention time is preferably 100-250 hour, is more preferably 120-150 hour.
6. the preparation method that amorphous nano takes off titanium type titanic oxide material is characterized in that, prepares according to following step:
Step 1 places the corrosive liquid airtight container with the amorphous CTB alloy; Said corrosive liquid is that mass percent is 50～68% aqueous solution of nitric acid; Wherein add sulfate so that sulfate radical to be provided; The concentration of said sulfate radical is 1～20mmol/L, and the gross area of said amorphous CTB alloy and the volume ratio of corrosive liquid remain on 200～600cm
2/ L
Under 50～90 ℃, temperature retention time is to get final product in 50～300 hours to step 2 with airtight container.
7. a kind of amorphous nano according to claim 6 takes off the preparation method of titanium type titanic oxide material, it is characterized in that, in the said step (1), and HNO
3The mass fraction of solution is preferably 55%-65%, is more preferably 65%.
8. a kind of amorphous nano according to claim 6 takes off the preparation method of titanium type titanic oxide material, it is characterized in that, in the said step (1), sulfate can make any water miscible sulfate, like sodium sulphate, and potassium sulfate, copper sulphate; In the said step (1), the concentration of sulfate is preferably 5-15mmol/L, is more preferably 7-10mmol/L.
9. a kind of amorphous nano according to claim 6 takes off the preparation method of titanium type titanic oxide material; It is characterized in that; In the said step (1), the atomic molar of Ti and Cu is than being (2～5) in the titanium copper non-crystaline amorphous metal of use: (8～5), and the atomic molar ratio of preferred Ti and Cu is 4: 6; In the said step (1), the amorphous CTB alloy is made into ribbon, and its gross area is meant the product (ignoring beam thickness) of band length and width, and the volume ratio of itself and corrosive liquid is preferably 300-450cm
2/ L is more preferably 300-400cm
2/ L.
10. a kind of amorphous nano according to claim 6 takes off the preparation method of titanium type titanic oxide material; It is characterized in that the holding temperature in the said step (2) is preferably 60-80 ℃, be more preferably 65-70 ℃; Temperature retention time is preferably 100-250 hour, is more preferably 120-150 hour.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102928492A (en) * | 2012-11-14 | 2013-02-13 | 天津精仪博硕科技发展有限公司 | Analytical system for precise preparation and in-situ test of titanium dioxide nanotube array |
| CN104084203A (en) * | 2014-07-14 | 2014-10-08 | 东南大学 | A kind of preparation method of Cu-Ti and TiO2 composite film material |
| CN104525170A (en) * | 2015-01-16 | 2015-04-22 | 天津大学 | Preparation method of titanium-dioxide powder with exposure of high-crystalline surface energy and spindle structure |
| CN106423119A (en) * | 2016-12-12 | 2017-02-22 | 中海油天津化工研究设计院有限公司 | Preparation method of titanium dioxide photocatalyst |
| CN108686662A (en) * | 2018-05-28 | 2018-10-23 | 国网山东省电力公司电力科学研究院 | Nano TiO 2-amorphous zirconium-base alloy composite photocatalyst material and preparation method thereof and purposes |
| CN109529872A (en) * | 2018-12-19 | 2019-03-29 | 河北麦森钛白粉有限公司 | Amorphous nano titanium dioxide visible light catalyzer compound and preparation method thereof |
| CN115073070A (en) * | 2022-05-31 | 2022-09-20 | 河海大学 | Preparation method and application of antibacterial mortar coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040265041A1 (en) * | 2002-11-22 | 2004-12-30 | Mitsubishi Pencil Co., Ltd. | Ink-storing member for writing instrument |
| CN101476122A (en) * | 2009-02-06 | 2009-07-08 | 合肥工业大学 | Method for solid support of modified nano titanium dioxide by chemically plating nickel-zinc-phosphor alloy |
| CN102240550A (en) * | 2011-05-12 | 2011-11-16 | 南开大学 | Low-concentration copper-doped titanium dioxide nanotube photocatalyst and preparation method thereof |
-
2012
- 2012-01-14 CN CN2012100108286A patent/CN102580709A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040265041A1 (en) * | 2002-11-22 | 2004-12-30 | Mitsubishi Pencil Co., Ltd. | Ink-storing member for writing instrument |
| CN101476122A (en) * | 2009-02-06 | 2009-07-08 | 合肥工业大学 | Method for solid support of modified nano titanium dioxide by chemically plating nickel-zinc-phosphor alloy |
| CN102240550A (en) * | 2011-05-12 | 2011-11-16 | 南开大学 | Low-concentration copper-doped titanium dioxide nanotube photocatalyst and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《Electrochemistry Communications》 20110104 S.L.Zhu et al "Ti oxide nano-porous surface structure prepared by dealloying of Ti-Cu amorphous alloy" 第250－253页 1-10 第13卷, * |
| S.L.ZHU ET AL: ""Ti oxide nano-porous surface structure prepared by dealloying of Ti–Cu amorphous alloy"", 《ELECTROCHEMISTRY COMMUNICATIONS》 * |
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| CN102928492A (en) * | 2012-11-14 | 2013-02-13 | 天津精仪博硕科技发展有限公司 | Analytical system for precise preparation and in-situ test of titanium dioxide nanotube array |
| CN104084203A (en) * | 2014-07-14 | 2014-10-08 | 东南大学 | A kind of preparation method of Cu-Ti and TiO2 composite film material |
| CN104525170A (en) * | 2015-01-16 | 2015-04-22 | 天津大学 | Preparation method of titanium-dioxide powder with exposure of high-crystalline surface energy and spindle structure |
| CN106423119A (en) * | 2016-12-12 | 2017-02-22 | 中海油天津化工研究设计院有限公司 | Preparation method of titanium dioxide photocatalyst |
| CN108686662A (en) * | 2018-05-28 | 2018-10-23 | 国网山东省电力公司电力科学研究院 | Nano TiO 2-amorphous zirconium-base alloy composite photocatalyst material and preparation method thereof and purposes |
| CN109529872A (en) * | 2018-12-19 | 2019-03-29 | 河北麦森钛白粉有限公司 | Amorphous nano titanium dioxide visible light catalyzer compound and preparation method thereof |
| CN109529872B (en) * | 2018-12-19 | 2021-08-03 | 河北麦森钛白粉有限公司 | Amorphous nano titanium dioxide visible light catalyst compound and preparation method thereof |
| CN115073070A (en) * | 2022-05-31 | 2022-09-20 | 河海大学 | Preparation method and application of antibacterial mortar coating |
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