CN102558884A - Rock asphalt modified asphalt and preparation method thereof - Google Patents
Rock asphalt modified asphalt and preparation method thereof Download PDFInfo
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- CN102558884A CN102558884A CN2011104488877A CN201110448887A CN102558884A CN 102558884 A CN102558884 A CN 102558884A CN 2011104488877 A CN2011104488877 A CN 2011104488877A CN 201110448887 A CN201110448887 A CN 201110448887A CN 102558884 A CN102558884 A CN 102558884A
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- 239000010426 asphalt Substances 0.000 title claims abstract description 104
- 239000011435 rock Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 238000000227 grinding Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000003756 stirring Methods 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 238000007792 addition Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000011384 asphalt concrete Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种改性沥青,特别是一种新改性沥青及其制备方法。 The invention relates to a modified asphalt, in particular to a new modified asphalt and a preparation method thereof. the
背景技术 Background technique
近年来,中国社会经济的迅猛发展带来了交通动输需求的快速增长,交通量、载重量和轴重大幅增加,并有一定的超载现象。中国大部分地区夏季高温,南方地区多雨,这些不利的交通荷载特性和气候条件导致沥青路面面临严峻考验,普通沥青路面通车不久就出现严重的早期破坏,如车辙、水损害、低温开裂、坑槽等。所造成的损害无可低估。 In recent years, the rapid development of China's social economy has brought about a rapid increase in the demand for transportation and dynamic transportation. The traffic volume, load capacity and axle load have increased significantly, and there are certain overloading phenomena. Most parts of China are hot in summer and rainy in the south. These unfavorable traffic load characteristics and climatic conditions have caused the asphalt pavement to face a severe test. Ordinary asphalt pavement has serious early failures such as rutting, water damage, low temperature cracking, and potholes soon after it is opened to traffic. wait. The damage done cannot be underestimated. the
目前市场改性沥青有,SBS(苯乙烯-丁烯-苯乙烯)、SBR(丁苯橡胶)和BRA(布敦岩沥青)等。其中SBS是目前市场上用得范围最广,量最大的产品,但价格太高浮动空间有限,SBR生产成本也比较高,难以推广,BRA(CN102276187中国发明专利申请公开了一种布敦岩沥青改性沥青混合料),由于布敦岩沥青的沥青含量低(20%-30%)其中添加量最高达50%,在市场实际实施运用中未能真正达到节省成本和数据也并不理想,反而耗能,由于他沥青含量低不能湿拌,不能按传统方法添加,唯一添加方法只能在搞拌楼生产熟料时通过半机械半人工添加曾加工艺环节,添加过程烦琐,添加量大,需曾加搞拌时间损耗能源导置熟料也相对降低产量,跟据市场反映出来的数据也并不理想,所造成的问题多多运用价直不高,所以现在市场难得见到有人运用。 At present, there are modified asphalt in the market, such as SBS (styrene-butylene-styrene), SBR (styrene-butadiene rubber) and BRA (buton rock asphalt). Wherein SBS is currently the most widely used in the market, the largest product, but the price is too high floating space is limited, SBR production cost is also relatively high, difficult to promote, BRA (CN102276187 Chinese invention patent application discloses a kind of buton rock asphalt Modified asphalt mixture), due to the low asphalt content of Buton rock asphalt (20%-30%), the addition amount is up to 50%, and the cost saving and data are not really ideal in the actual implementation of the market. On the contrary, it consumes energy. Due to its low content of asphalt, it cannot be wet mixed, and it cannot be added by traditional methods. The only way to add it is to use semi-mechanical and semi-manual additions in the process of clinker production in a mixing building. The addition process is cumbersome and the amount of addition is large. The clinker needs to be added to mix time, consume energy, and reduce the output relatively. According to the data reflected by the market, it is not ideal, and the problems caused are many. The price of use is not high, so it is rare to see someone use it in the market now. the
发明内容 Contents of the invention
本发明旨在解决前述现有技术所存在的问题,提供一种新的改性沥青。 The present invention aims to solve the problems in the aforementioned prior art and provide a new modified asphalt. the
本发明提供一种改性沥青,其以重量百分比计包括85-90%的基质沥青,10-15%的天然岩沥青,其中所述天然岩沥青中沥青含量为75-80%。 The invention provides a modified asphalt, which comprises 85-90% of matrix asphalt and 10-15% of natural rock asphalt, wherein the content of asphalt in the natural rock asphalt is 75-80%. the
所述天然岩沥青粉末的平均粒径为:80-200目。 The average particle size of the natural rock asphalt powder is 80-200 mesh. the
本发明还提供所述改性沥青的制备方法,其包括如下步骤: The present invention also provides the preparation method of described modified asphalt, it comprises the steps:
1)将基质沥青加热到150-160℃; 1) Heat the base asphalt to 150-160°C;
2)在搅拌下将天然岩沥青缓缓添加入基质沥青中,其中以重量百分比计基质沥青∶天然岩沥青=85-90%∶10-15%,其中所述天然岩沥青中沥青含量为75-80%; 2) Slowly add natural rock asphalt into base asphalt under stirring, wherein base asphalt in weight percentage: natural rock asphalt=85-90%: 10-15%, wherein the bitumen content in the natural rock asphalt is 75% -80%;
3)原料混合完全后,经研磨后再混合,后得成品。 3) After the raw materials are completely mixed, they are ground and then mixed to obtain the finished product. the
如前所述的制备方法,其中步骤3)研磨后输混合沥青送到另一个研磨器,以此重复研磨两次。 The preparation method as described above, wherein step 3) after grinding, transport the mixed asphalt to another grinder, so as to repeat the grinding twice. the
具体实施方式 Detailed ways
下面以非限制性实施例对本发明进一步进行阐明。实施例中所使用的基质沥青为茂名石化AH-70重胶,所使用的天然岩沥青选自产自特立尼达和多巴哥湖沥青、美国犹他州天然岩沥青和/或中国青川岩沥青等。岩沥青含沥青量75-80%,粉末状的目数为:80-200目。 The present invention is further illustrated below with non-limiting examples. The base bitumen used in the examples is Maoming Petrochemical AH-70 heavy rubber, and the natural rock bitumen used is selected from Trinidad and Tobago lake bitumen, Utah natural rock bitumen and/or Chinese Qingchuan rock asphalt etc. Rock asphalt contains 75-80% asphalt, and the mesh number of powder is 80-200 mesh. the
以如下工艺进行生产,3批次,其中基质沥青和天然岩沥青的重量百分比分别为85%∶15%;88%∶12%;90%∶10%。 The production process is as follows, 3 batches, wherein the weight percentages of matrix asphalt and natural rock asphalt are 85%: 15%; 88%: 12%; 90%: 10%. the
a.首先将基质沥青AH-70加热到150-160度之间,输送到一个搞拌器的容器里,同时添加天然岩沥青在一边搅拌下一边缓缓添加直到两种原料按配比添加完毕; a. First, heat the base asphalt AH-70 to 150-160 degrees, transport it to a container of a mixer, and add natural rock asphalt at the same time, and slowly add it while stirring until the two raw materials are added according to the ratio;
b.继续搞拌10分钟后,两种原料达到混合,再经过过滤输送到研磨机研磨,研磨过程输送到另一个搅拌器混合,以此重复研磨两次,就可输送到储藏罐储藏起来;这两种原料通过上述简单加工研磨混合出来的产品就是新型改性沥青了。 b. After continuing to mix for 10 minutes, the two raw materials are mixed, and then filtered and transported to the grinder for grinding. The grinding process is transported to another mixer for mixing, and the grinding is repeated twice, and then it can be transported to the storage tank for storage; The product obtained by mixing these two raw materials through the above-mentioned simple processing and grinding is the new modified asphalt. the
为检验本发明改性沥青的组分相溶及存储稳定情况,基质沥青与天然岩沥青在加工罐内保温1H,2H,3H,4H及开始施工前约15H分别在加工罐内面高度上1/3和下部1/3处取样,测得软化点差并没有很大的差异,来评价天然岩沥青的稳定性,试验结果表明由于岩沥青本身软化点较高大于100以上密度较小,随着保温时间延长,岩沥青更好地与基质沥青相溶,没有出现的明显离析,可见随着保温时间延长岩沥青更好地溶解于基质沥青中。 In order to check the compatibility and storage stability of the components of the modified asphalt of the present invention, the base asphalt and the natural rock asphalt were kept warm in the processing tank for 1H, 2H, 3H, 4H and about 15H before starting construction on the height of the inner surface of the processing tank respectively. 3 and the lower 1/3 of the sample, the measured softening point difference is not very different, to evaluate the stability of natural rock asphalt, the test results show that because the rock asphalt itself has a higher softening point than 100 As the time prolongs, rock asphalt is better compatible with matrix asphalt, and there is no obvious segregation. It can be seen that rock asphalt dissolves better in matrix asphalt with the extension of holding time. the
根据矿料组成设计结果,初步选定油石比为4.2%,4.5%,4.8%,5.1%.5.5%进行标准马歇尔试验结果,最佳油石比为4.8%,此时沥青膜厚度为8.0um,马歇尔模数为5.2KN/mm,沥青饱和度为67.5%,表明沥青混合料形成了嵌挤密实的架结构,满足规范密级配沥青混合料马歇尔技术标准。 According to the design results of mineral material composition, the asphalt ratio was initially selected as 4.2%, 4.5%, 4.8%, 5.1%. 5.5% to carry out the standard Marshall test results, the optimum asphalt ratio was 4.8%, and the asphalt film thickness was 8.0um at this time. The Marshall modulus is 5.2KN/mm, and the asphalt saturation is 67.5%, which shows that the asphalt mixture has formed an embedded and compact frame structure, which meets the Marshall technical standard of the standard densely graded asphalt mixture. the
本发明所提供的改性沥青经马歇尔试验和实施数据表明,比普通沥青吸附能量在岩石材料表面高出数倍,具有良好的抗剥落性能,软化点抗车辙能力高,抗拉力,抗老化氧化性能和抗水损坏能力,可提高公路的行车舒适度,延长公路使用寿命,和环保再生的特点具有良好的推广应用价值。 Marshall test and implementation data show that the modified asphalt provided by the present invention has several times higher adsorption energy than ordinary asphalt on the surface of rock materials, has good anti-stripping performance, high anti-rutting ability at softening point, high tensile strength and anti-aging Oxidation performance and water damage resistance can improve the driving comfort of the road, prolong the service life of the road, and the characteristics of environmental protection and regeneration have good promotion and application value. the
新型改性沥青增强混合料的抗疲劳性能,改善后的沥青路面寿命大约增加30%。如果实际工程中沥青路面损坏是四车辙的拥包引起的,则道路的使用寿命通常可增加100~200%。 The new modified asphalt enhances the anti-fatigue performance of the mixture, and the life of the improved asphalt pavement increases by about 30%. If the asphalt pavement damage in actual engineering is caused by the four ruts, the service life of the road can usually be increased by 100-200%. the
新型改性沥青抗老化能力及抗微生物侵蚀作用强,耐候性好,使沥青路面经久耐用。 The new modified asphalt has strong anti-aging ability and anti-microbial erosion effect, and good weather resistance, which makes the asphalt pavement durable. the
采用新型改性沥青后的混合料的高温稳定性、水稳定性和低温性能均达到并超过《公路沥青路面施工技术规范(JTGF40-2004)相关指标的技术要求。 The high-temperature stability, water stability and low-temperature performance of the mixture after using the new modified asphalt all meet and exceed the technical requirements of the relevant indicators in the "Technical Specifications for Construction of Highway Asphalt Pavement (JTGF40-2004). the
新型改性沥青环保性能,平时的普通沥青混凝土路面和SBS改性路面(苯乙烯)在经过长时间和车辆长期磨耗下要求番修或改造,原来的路面已 老化,只能铲除丢掉,就要造成大面积的场地堆放或填埋,这样就造成环境污染,而新型改性沥青(添加天然岩沥青)是一种天然条件下生成的高分子化学物,其氮原子含量高,且氮原子以官能团的形式存在不容易老化,所以在番修或改造时可以通过铣刨可再回炉重复利用;这样保护了环境同时也降低了成本。 The environmental protection performance of new modified asphalt, the usual ordinary asphalt concrete pavement and SBS modified pavement (styrene) require repair or reconstruction after a long time and long-term wear and tear of vehicles. A large area of land is piled up or landfilled, which causes environmental pollution, and the new modified asphalt (adding natural rock asphalt) is a polymer chemical produced under natural conditions, with a high content of nitrogen atoms, and nitrogen atoms in the amount of The form of functional groups is not easy to age, so it can be re-used by milling and returning to the furnace during repair or transformation; this protects the environment and reduces costs. the
生产新型改性沥青与SBS改性沥青相比,不需要大量的设备投入和复杂的生产工艺,运输及储存方便,从搅拌楼到道路施工不用曾加任何环节,从而大大节约了施工成本和能源消耗。 Compared with SBS modified asphalt, the production of new modified asphalt does not require a large amount of equipment investment and complicated production processes, and is convenient for transportation and storage. There is no need to add any links from the mixing building to road construction, thus greatly saving construction costs and energy. consume. the
新型改性沥青采用天然岩沥青高分子(沥青含量75%-80%)矿物材料作为主要的原材料,并且由于化学结构与沥青相近,与沥青的相容性非常好,能够和基质沥青形成“互穿立构网格”,因而其改性技术性能特别优越。在添加天然岩沥青而配置出的新型改性沥青里,基质沥青只是充当一个媒介的作用,使得沥青的性能及沥青混合料的性能得到大大的改善。改性工艺简单,经济效益明显,具有可再生开发的潜在价值。 The new modified asphalt uses natural rock asphalt polymer (75%-80% asphalt content) mineral material as the main raw material, and because the chemical structure is similar to asphalt, it has very good compatibility with asphalt and can form an "interaction" with matrix asphalt. Through the three-dimensional grid", so its modified technical performance is particularly superior. In the new modified asphalt prepared by adding natural rock asphalt, the base asphalt only acts as a medium, which greatly improves the performance of asphalt and asphalt mixture. The modification process is simple, the economic benefit is obvious, and it has the potential value of renewable development. the
本发明所针对市场的主要产品SBS而产生,在目前国内市场产品只有SBS有可比性,跟据市场实施报告无论价格能耗数据本发明都占有一定的优势,在没有任何曾加环节下可节约15-20%成本。 The present invention produces for the main product SBS of the market, only SBS has comparability in the domestic market product at present, according to the market implementation report no matter price energy consumption data the present invention all occupies certain advantage, can save under any link that has been added 15-20% cost. the
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102863805A (en) * | 2012-10-11 | 2013-01-09 | 成都市第六建筑工程公司 | Modified Qingchuan rock asphalt and preparation method thereof |
CN102964852A (en) * | 2012-11-12 | 2013-03-13 | 蒋慕毅 | Method for producing modified asphalt by using Buton rock asphalt and hot method crusher |
CN102964852B (en) * | 2012-11-12 | 2014-11-12 | 蒋慕毅 | Method for producing modified asphalt by using Buton rock asphalt and hot method crusher |
CN103819913A (en) * | 2014-02-21 | 2014-05-28 | 淄博京源新材料科技有限公司 | High-performance modified asphalt, and preparation method and preparation apparatus thereof |
CN103819913B (en) * | 2014-02-21 | 2016-05-04 | 淄博京源新材料科技有限公司 | High performance modified bitumen and preparation method thereof and device |
CN105948569A (en) * | 2016-04-25 | 2016-09-21 | 东南大学 | High-modulus modified recycling bituminous mixture and preparation method and application |
CN105948569B (en) * | 2016-04-25 | 2018-05-01 | 东南大学 | A kind of high-modulus modification regeneration asphalt and preparation method and application |
CN107488353A (en) * | 2017-08-24 | 2017-12-19 | 江苏诺路桥工程检测有限公司 | One kind synthesis lake asphalt and preparation method thereof |
CN107793774A (en) * | 2017-11-10 | 2018-03-13 | 湖北正康天然沥青科技有限公司 | A kind of processes of rock asphalt modified asphalt oil abrasion method processing technology |
CN113429801A (en) * | 2021-07-12 | 2021-09-24 | 甘肃路桥建设集团养护科技有限责任公司 | Anti-rutting anti-fatigue high-modulus composite modified asphalt and preparation method thereof |
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