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CN102555659B - Method for dual surface-treatment of metal materials - Google Patents

Method for dual surface-treatment of metal materials Download PDF

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Publication number
CN102555659B
CN102555659B CN201110319043.2A CN201110319043A CN102555659B CN 102555659 B CN102555659 B CN 102555659B CN 201110319043 A CN201110319043 A CN 201110319043A CN 102555659 B CN102555659 B CN 102555659B
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Prior art keywords
metal material
processing
glossy
mask portion
mask
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CN201110319043.2A
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CN102555659A (en
Inventor
朴淳瓘
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CONNECT Co Ltd S
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CONNECT Co Ltd S
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/02Local etching
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00Electroforming
    • C25D1/10Moulds; Masks; Masterforms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F3/00Electrolytic etching or polishing
    • C25F3/02Etching
    • C25F3/14Etching locally

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Laser Beam Processing (AREA)
  • ing And Chemical Polishing (AREA)

Abstract

A surface treating method of a metallic material is provided. All kinds of pattern glossy lines are formed on the surface of metallic materials used widely in different kinds of fields. A part except the masking part is performed a abrasive blasting is performed through chemical or physical methods after a masking process is performed on the processed surface of the metallic material by one of plating, electro-deposition and dry film methods in the state that the surface of metallic materials is performed multiform surface treatment in more detail. Consequently, the part except the masking part forms a glossy surface. The invention is provided with the following effect: the method which is different from surfacing approaches before can change the masking approach and the rubbing approach to form the glossy surface. The glossy lines and the glossy surface are formed on the critical and coarse filament surface as existing mask. The other glossy lines and the other glossy surface are formed on the glossy surface by the same approaches without else machining. The method broadens field of application of tarnally-limited prior metal surfacing technology and has a mass production of products with more varying surface state.

Description

The duplex surface processing method of metal material
Technical field
The present invention relates on the surface of the widely used metal material in various field, form the technology of the light line of various pattern, in more detail, relate to technology as described below: under the state that Surface Machining process is performed to the surface of metal material, by performing the attrition process of physics or chemistry to the part beyond mask, the various decorative patterns in Surface Machining portion are made to show as gloss shape, thus on the basis of various surface tactile sensation, increase noble light line, widen the field of metal surface process technology, manufacture various product.
Background technology
In general, as the hardware that the purposes of household electrical appliances and communication equipment external shell is applied, stainless steel, aluminium or magnesium etc. is utilized to manufacture, hardware as above is firm and attractive in appearance, thus widely uses in the inside and outside decoration of building materials, exterior panel, exterior housing, the front panel of stereo set, the exterior panel of video camera, the exterior panel of mobile phone, electronic unit and automobile assembly etc.
For the hardware used with various uses as above, according to the characteristic of product or apperance and design considerations, the various processing treatment technologies of application effects on surface, thus show the more beautiful and aesthetical perception of brilliance, and under normal circumstances, as the surface treatment method for hardware as above, there are the decorative pattern formation method based on Laser Processing and the corrosion treatmentCorrosion Science method based on Wet-type etching and make use of the decorative pattern formation method etc. of printing.
Now, as above based in the surface treatment method of Laser Processing, although owing to directly applying laser to the surface of hardware, therefore there is surface can cave in or the problem of depth down, but the processing of the form making sur-face peeling can be realized, therefore can only form the unglazed line of Corrosion Types.
In addition, based on the corrosion treatmentCorrosion Science method of etching also there is the degree of depth and the mode that effects on surface directly carries out processing realizes, therefore there is following tendency: the released part caused by these surface treating part is piled up or accompanied various impurity or pollutant, cause affecting outward appearance, but also owing to implementing chemical stripping to metal surface, thus same with above-mentioned Laser Processing, only can generate the unglazed line of corrosion shape.
In addition, when printing, use the mode of effects on surface contiguity ink, have a lot of restriction to the embodiment of decorative pattern, when be applied to metal and show light face due to contiguity power, the heterogeneous sense between metal material can be produced, when existing mask, although light face can be formed, cause end bad due to the instability of mask material, enough can only be limited to specific brushing processing to carry out, therefore its application is extremely limited.
Summary of the invention
The present invention proposes to solve the problem, its object is to, there is provided a kind of duplex surface processing method of metal material as described below: under the surface-treated state that various ways is implemented to the surface of metal material, coating or plating, dry film etc. are utilized to perform mask operation to its surface treating part, then, by chemistry or physical method, attrition process is performed to the part except aforementioned mask part, make the part beyond aforementioned mask be formed with light face thus, therefore kinds of surface handling part is presented to the light line of various ways simultaneously.
To achieve these goals, the invention provides a kind of duplex surface processing method of metal material, the method performs following steps successively:
To the Surface Machining step that the exposed surface of metal material is carried out; To the masks that the finished surface of metal material carries out; To the grinding steps that the finished surface except mask portion in the finished surface of metal material carries out; And the mask removing step in removing aforementioned mask portion.
The present invention has effect as described below: different from the step of Surface Machining in the past, masks and grinding steps can be changed to be formed with light face, can light line be formed on the surface at the coarse fine rule of the limit as existing mask and have light face, can light face be formed another light line and have light face having by identical step without the need to other processing, therefore widen the range of application of extremely limited existing metal surface process technology, can produce the product of more diversified surface state in large quantities in batches.
Accompanying drawing explanation
Fig. 1 is the sequence of steps figure of surface treatment method of the present invention.
Fig. 2 is the shape machining state figure of surface treatment method of the present invention.
Fig. 3 is the Surface Machining state diagram of surface treatment method of the present invention.
Fig. 4 is the surperficial mask state diagram of surface treatment method of the present invention.
Fig. 5 is the laser lift-off block diagram of surface treatment method of the present invention.
Fig. 6 is the metal material of the laser lift-off state of surface treatment method of the present invention.
Fig. 7 is surface treatment method of the present invention, attrition process state diagram for stripping portion.
Fig. 8 is that state diagram peeled off by the mask of surface treatment method of the present invention.
Fig. 9 is the state diagram of the metal material completed of surface treatment method of the present invention.
Figure 10 is the material object example of surface treatment method of the present invention.
Figure 11 is another example in kind of surface treatment method of the present invention.
Symbol description
10: metal material 11: finished surface
12: mask portion 13: glassy surface
Detailed description of the invention
The term used in this specification and claims book or word, not limited interpretation is common or meaning in dictionary, and should from inventor in order to the invention of self is described with the method for the best, principle based on the concept suitably defining term is considered, is interpreted as meaning and the concept of technological thought according to the invention.
Below, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
Fig. 1 is the sequence of steps figure of surface treatment method of the present invention.
First, surface treatment method of the present invention be can also be applied to complete plastic working and surface of base specification product on and formed technology, it is characterized in that, can also be applied to be suitable for used in the past all surface processing specification metal material on, other surface specifications can be manufactured.
Based on this, preferred embodiment is described.
First, perform shape procedure of processing to the metal material that can use with various object, it refers to such as use rolling to equip, and is cut by the metal material of multiple material and bends to the apperance having and expect as shown in Figure 2.Now, for shape procedure of processing as above, operation can be carried out in advance as mentioned above, also can carry out operation prior to mask portion described later strip step, as long as or the problem of solution blemish, also can carry out operation after end grinding steps.In addition, above-mentioned shape procedure of processing refers to comprise the plastic working of rolling and extrusion molding and die cast, is all contained in this by the article shaped of general multiple processing method manufacture.
Just, in the preferred embodiments of the present invention and accompanying drawing, for the ease of understanding, illustrate the metal material 10 under the state processing shape.
Therefore, for the exposing surface actuating surface procedure of processing of the metal material 10 under the state completing shape processing as mentioned above.For Surface Machining step now, brushing fine rule can be utilized to process, be with fine rule processing and the existing various method of surface finish such as attrition process or sand milling processing, except the processing of above-mentioned matt surface, the light processing that has based on polishing also can be contained in this.
Thus, as shown in Figure 3, for metal material 10, carrying out under the state of Surface Machining step for obtaining finished surface 11, masks is being performed to above-mentioned finished surface 11.Masks is now realized by the various methods as being coated with or electroplating usually, through the masks of various method as above, forms diaphragm to the finished surface of metal material.Herein, the mask portion generated by masks as above as shown in Figure 4, the thickness in its mask portion 12 is preferably in the scope of 3 μm ~ 45 μm, when the thickness in mask portion 12 is thin, in the grinding steps performed afterwards, mask portion 12 can occur peel off or the phenomenon of demoulding, this is because when thickness is blocked up, the laser lift-off step for the formation of pattern becomes difficulty or the phenomenon that periphery mask portion comes off etc. occurs.
Particularly, if form the mask portion 12 for the finished surface 11 of metal material 10 by method as above, then the mask portion 12 of the finished surface 11 surrounding metal material 10 is performed to the stripping of pattern form, as shown in Figure 5, aforementioned mask portion 12 should be removed with the shape identical with the decorative pattern that will be formed and pattern by laser lift-off step.
Namely, use the laser marking machine of general type, but when considering from a large amount of equipment benchmark, the primary condition of power 60 ~ 80, speed 300 ~ 500 is best, in condition setting as above, the important point is the damage preventing the finished surface 11 to metal material 10 caused by laser marking machine.This is because, such as in the stripping process in the mask portion based on laser marking machine, when producing damage to the finished surface 11 of the metal material 10 comprising mask portion 12, can produce for the finished surface 11 of the metal material 10 generated in above-mentioned Surface Machining step corrosion or generate the mark line etc. that caused by laser, desired result thing can not be obtained.
In addition, in masks as above, when forming mask portion 12 according to the method as being coated with or electroplating, although laser lift-off step as above is necessary, but when directly forming tool figuratum mask portion 12 by the etching based on dry film to the finished surface 11 of metal material 10, do not need laser lift-off step.
Because this is by printed patterns direct on dry film, the mode of the film of this part by etching except eliminating pattern is formed, therefore on the finished surface 11 of metal material 10, direct formation has the mask portion 12 of various pattern, thus does not need the extra strip step for mask portion 12.
By laser lift-off step as above or utilize the pattern of dry film to be formed, as shown in Figure 6, the finished surface 11 of metal material 10 can intactly expose.Now, for the floral designs between the stripping area applying laser marking machine, importantly between line, spacing (line shadow spacing) is no more than 0.35mm, this is because when spacing is more than 0.35mm, the removing in mask portion can be hindered, in grinding steps, produce the slag caused by the residue in mask portion, do not have the mask portion removed directly to cause the surface of metal material 10 bad.
Then, by process as above, when the finished surface 11 of metal material 10 is formed figuratum mask portion 12, grinding steps is performed for the finished surface 11 except aforementioned mask portion 12.Grinding steps now can be divided into the Ginding process of chemistry and the Ginding process of physics.
Namely, the Ginding process of chemistry refers to the processing being called electrolytic polishing, in general be the processing making the electric current of 12V ~ 15V flow through the phosphoric acid of 55 DEG C ~ 75 DEG C and sulfuric acid liquid to carry out, if carry out the grinding of chemistry as above, then as shown in Figure 7, only on the finished surface 11 of the metal material 10 exposed in the mask portion 12 except coating or plating etc., form the fine ground of chemistry, and respective face can be formed with the glassy surface 13 of light.
In addition, physical grinding is referred to as polishing usually, by encasing grinding material and High Rotation Speed with cloth, carries out fine ground to exposed finished surface, and corresponding exposed surface is had have light face.When carrying out chemical grinding as above or physical grinding, even if under the state that the finished surface 11 of metal material 10 is the glossy surface obtained in Surface Machining step, also mutually different glossy surfaces is formed due to the difference of the cutting degree on small surface, therefore visually there is distinctiveness, can think the glassy surface 13 that can be formed and have with the diverse aesthetic feeling of finished surface 11 before.
When terminating grinding steps as above, as shown in Figure 8, as long as perform the removing step for above-mentioned mask portion 12, use the general stripping remover used on metal at present also can guarantee not damage the clean face of metallic surface, therefore, in above-mentioned mask removing step, specific description is omitted due to not special place.Just in mask removing step, the main material used is equivalent to remover, nitromethane, carrene, toluene, acetone and their mixture.In addition, the mask portion 12 based on dry film is preferably NaOH.
Then, at the end of mask removing step as above, directly can use this, also can increase rear surface treatment step to apply to metal material 10 as required, when holding corrosion-prone material or color sensation or the outstanding not metal material of texture, when wanting color sensation or the texture forming expectation, in order to carry out the surface treatment of chromium plating or deposition or coating or anodic oxidation etc., and the product of various appropriate state can be manufactured.
Therefore, as shown in Figure 9, product as described below can be manufactured: be there is the finished surface 11 obtained by various surface treatment and the glassy surface 13 having light pattern carrying out Duplex treatment to its finished surface and obtain on a metal material 10.
Illustrated by material object as shown in Figures 10 and 11, can clearer and more definite as above metal material, in case of fig. 10, unglazed process has been carried out to finished surface 11, unglazed finished surface 11 is concatenated to form to the pattern of the glassy surface 13 of light, Figure 11 illustrates under having carried out to finished surface 11 state having light process, has been concatenated to form the state having the pattern of the glassy surface 13 of light with differential glossiness.
Therefore, the duplex surface processing method of metal material of the present invention, the surface state had with restriction and its material of material has nothing to do, reasonably can form the glossiness decorative pattern of tool colorful, attractive in appearance and touch sample, therefore, having noble and multifarious while, can produce in a large number and the economic profit that maximizes.
In this description as above, described embodiment and the structure shown in accompanying drawing are only a preferred embodiment of the present invention, do not limit all technological thoughts of the present invention, should be understood to various equipollent and variation that existence replaces these.

Claims (4)

1. a duplex surface processing method for metal material, it is characterized in that, the method performs following steps successively:
To the Surface Machining step that the exposed surface of metal material is carried out;
To the masks that the finished surface of metal material carries out;
To the grinding steps that the finished surface except mask portion of the finished surface of metal material carries out; And
The mask removing step in removing aforementioned mask portion,
Surface Machining step is that a kind of processing the by selecting from fine rule processing, attrition process or sand milling processing realizes,
Masks realizes by a kind of method of selecting from coating or plating or based on the mode that the etching of dry film forms pattern, when realizing masks by the above-mentioned a kind of method selected, also perform the laser lift-off step to mask portion, thus mask portion is formed and peel off pattern
Grinding steps is that a kind of method by selecting from the chemical grinding based on electrolytic polishing or the physical grinding based on polishing realizes.
2. the duplex surface processing method of metal material according to claim 1, is characterized in that,
Before Surface Machining step, also first perform shape procedure of processing.
3. the duplex surface processing method of metal material according to claim 1, is characterized in that,
Before strip step, also first perform shape procedure of processing.
4. the duplex surface processing method of the metal material according to any one in claims 1 to 3, is characterized in that,
After end mask removing step, also perform rear surface treatment step.
CN201110319043.2A 2010-11-04 2011-10-19 Method for dual surface-treatment of metal materials Active CN102555659B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2010-0109043 2010-11-04
KR1020100109043A KR101047366B1 (en) 2010-11-04 2010-11-04 Double surface treatment method of metal material

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CN102555659B true CN102555659B (en) 2015-07-08

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KR101918983B1 (en) * 2011-08-17 2019-02-08 엘지전자 주식회사 Method for manufacturing terminal case, terminal case and mobile terminal having the same
KR101183219B1 (en) 2011-08-30 2012-09-14 (주)한국마루이 Electropolishing electrolyte to prevent the penetration of the target protective masking
KR101373677B1 (en) * 2013-07-18 2014-03-14 윤석헌 Method for processing metal material using film and metallic interior and exterior panel products made therefrom
KR102179814B1 (en) * 2013-11-08 2020-11-17 엘지전자 주식회사 Decor panel for home appliances and method for manufacturing the same
KR101551277B1 (en) * 2014-12-16 2015-09-10 곽상준 processing method of marble surface using film
KR101739173B1 (en) * 2014-12-16 2017-05-23 송묘녀 processing method of marble surface using cover
CN106827927A (en) * 2016-12-30 2017-06-13 惠州市众业科技有限公司 Metal shell of electronic product decorative pattern processing method
CN112575361A (en) * 2019-09-30 2021-03-30 S-连接株式会社 Double plating method for aluminum alloy
JP2024071311A (en) * 2022-11-14 2024-05-24 株式会社ヨコオ Method for manufacturing electroformed spring and electroformed spring

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