CN102550712A - Complex soybean oil containing conjugated linoleic acid glycerides - Google Patents
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- 229940108924 conjugated linoleic acid Drugs 0.000 title claims abstract description 40
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 title claims abstract description 40
- 235000012424 soybean oil Nutrition 0.000 title claims abstract description 39
- 239000003549 soybean oil Substances 0.000 title claims abstract description 39
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 35
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 34
- 244000269722 Thea sinensis Species 0.000 claims abstract 3
- JBYXPOFIGCOSSB-GOJKSUSPSA-N 9-cis,11-trans-octadecadienoic acid Chemical compound CCCCCC\C=C\C=C/CCCCCCCC(O)=O JBYXPOFIGCOSSB-GOJKSUSPSA-N 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 13
- 235000010692 trans-unsaturated fatty acids Nutrition 0.000 claims description 13
- 239000002199 base oil Substances 0.000 claims description 9
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 claims description 3
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 claims description 3
- 229930003427 Vitamin E Natural products 0.000 claims description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 claims description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 3
- 229940031439 squalene Drugs 0.000 claims description 3
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 claims description 3
- 235000019165 vitamin E Nutrition 0.000 claims description 3
- 229940046009 vitamin E Drugs 0.000 claims description 3
- 239000011709 vitamin E Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000194 fatty acid Substances 0.000 abstract description 6
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- 230000001603 reducing effect Effects 0.000 abstract 3
- 235000018927 edible plant Nutrition 0.000 abstract 1
- 239000010773 plant oil Substances 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 241001122767 Theaceae Species 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 239000004519 grease Substances 0.000 description 9
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- 230000004224 protection Effects 0.000 description 7
- 230000036541 health Effects 0.000 description 6
- 238000009924 canning Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
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- 150000002978 peroxides Chemical class 0.000 description 5
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
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- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- 206010006187 Breast cancer Diseases 0.000 description 1
- 208000026310 Breast neoplasm Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 102000007330 LDL Lipoproteins Human genes 0.000 description 1
- 108010007622 LDL Lipoproteins Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 102000036675 Myoglobin Human genes 0.000 description 1
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- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000000879 anti-atherosclerotic effect Effects 0.000 description 1
- 230000003178 anti-diabetic effect Effects 0.000 description 1
- 230000002058 anti-hyperglycaemic effect Effects 0.000 description 1
- 239000003472 antidiabetic agent Substances 0.000 description 1
- 238000006701 autoxidation reaction Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
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- 229950001002 cianidanol Drugs 0.000 description 1
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- 230000002708 enhancing effect Effects 0.000 description 1
- 235000004626 essential fatty acids Nutrition 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 210000003754 fetus Anatomy 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
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- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
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- Coloring Foods And Improving Nutritive Qualities (AREA)
- Medicines Containing Plant Substances (AREA)
- Edible Oils And Fats (AREA)
Abstract
The invention relates to complex soybean oil containing conjugated linoleic acid glycerides. By adding fat soluble tea polyphenols with an anti-oxidation effect and the conjugated linoleic acid glycerides wit fat reducing and anticancer effects and the like into zero trans-fatty acid soybean oil, nutrient, healthcare and edible plant oil which is healthy and nutrient and has the effects of preventing cancers, resisting arteriosclerosis, reducing blood fat, adjusting blood pressure, reducing fat, increasing muscles, resisting radiation and the like is prepared.
Description
Technical field
The present invention relates to the edible oil manufacture field.
Background technology
Trans-fatty acid is meant the aliphatic acid with two key anti-configurations, is prevalent in ruminant dairy products, the hydrogenated vegetable wet goods product.The trans-fatty acid low-density lipoprotein content that can raise increases the incidence of disease of cardiovascular and cerebrovascular disease, but also with breast cancer related.In addition, trans-fatty acid also shows reduction memory to the harm of human body, influences male fecundity, fetus or infants growth and development and the teenager aspects such as absorption to essential fatty acid.Law-making stipulation is made to trans-fatty acid by present American-European major country, and the content of trans-fatty acid has become the part of most of in the world advanced countries food standard system in the limit food product.
CLA is linoleic isomer, is a series of at 9,11 or 10,12 linoleic position and geometric isomers with two keys of carbon, is the nutriment that is prevalent in the humans and animals body.Big quantity research shows; CLA has very strong cancer-resisting ability, also has simultaneously to reduce blood lipid level, antiatherosclerosis, enhancing oxidation resistance, improve immunity, anti-diabetic, reduction body fat and increase cutability and influence many effects such as bone formation.Based on this, American-European a lot of countries have recommended CLA is carried out fortification, and CLA also is put into the new resource food list in China.
Vegetable oil contains a large amount of polyunsaturated fatty acids, is prone to oxidative rancidity and returns the look aftertaste, has a strong impact on oil quality and security.Present most enterprise protects grease through the method for adding chemical synthesis anti-oxidant (TBHQ etc.), but the security of this type anti-oxidant own is still queried.The hydrogen supply capacity that Tea Polyphenols had makes it become rare natural.In edible oil storage, add Tea Polyphenols, the autoxidation that can stop and delay unrighted acid is decomposed, thus the qualitative change Kazakhstan that prevents grease lose, the storage period prolongation that makes grease is more than one times.In addition, Tea Polyphenols delay senility, anticancer, anti arteriosclerosis, the harmful free radical of elimination, antibiotic, radioresistance, effect such as aid digestion.The Tea Polyphenols material not only in food service industry as the food adding ingredient, also bringing into play important effect in fields such as medicines and health protections gradually.
The Along with people's growth in the living standard, the consumer is increasingly high to functional requirements such as the health of edible oil, nutrition, and elaboration edible oil healthy and nutritious health care is more and more welcome and pay attention to.Be badly in need of in this respect technology and product supply.
Summary of the invention
The present invention is through adding the conjugated linoleic acid glyceride that has the fat-soluble tea polyphenol of anti-oxidation function and have effect such as antihyperglycemic, and anticancer functions in zero trans-fat acid soybean oil; Make a kind of health-nutrition that has, anticancer, anti arteriosclerosis, reduction blood fat and regulate the edible vegetable oil of nourishing healthy of effects such as blood pressure, fat-reducing, increasing flesh, radioresistance.
A kind of re-compounded soybean oil that contains conjugated linoleic acid glyceride, it is to be base oil with the soybean oil, adds conjugated linoleic acid glyceride and fat-soluble tea polyphenol.
The re-compounded soybean oil that contains conjugated linoleic acid glyceride of the present invention, wherein said base oil is preferably zero trans-fat acid soybean oil.
The re-compounded soybean oil that contains conjugated linoleic acid glyceride of the present invention, content of trans fatty acids in the wherein said base oil≤0.5 weight %; Content of vitamin E>=1200ppm; Phytosterol content>=2200ppm; Squalene content>=60ppm.
The re-compounded soybean oil that contains conjugated linoleic acid glyceride of the present invention, wherein the weight ratio of base oil, conjugated linoleic acid glyceride and fat-soluble tea polyphenol is preferably 88.29~98.31: 1.67~11.67: 0.02~0.04.Proportioning is according to being: the recommended intake of CLA is 3.5g/ people/sky, calculates according to eating the 30g edible oil for each person every day, and can add percentage is 11.67%; China's " food additives use standard " (GB2760-2011) stipulates: the maximum addition that Tea Polyphenols is added in the grease is 0.04%, and fat-soluble tea polyphenol preparation commonly used is that polyphenol content is 40%~60% preparation.The addition of fat-soluble tea polyphenol is as the criterion in the Tea Polyphenols net content among the present invention.Fat-soluble tea polyphenol is that Tea Polyphenols (mainly being the catechin molecule) molecular structure top oleophobic hydroxyl is modified to the unsaturated fat acid groups of oleophylic, makes on alcoholic extract hydroxyl group and the phenolic hydroxyl group of Tea Polyphenols molecule lipophilic group all to occur, has strengthened the lipophilic ability.
Re-compounded soybean oil of the present invention, wherein said conjugated linoleic acid glyceride is the ester that CLA and glycerine reaction obtain; Wherein CLA comprises: suitable-9, anti--the 11-CLA; Instead-9, suitable-11-CLA; Suitable-9, suitable-the 11-CLA; Instead-9, anti--11-CLA; Trans-10, suitable-the 12-CLA; Suitable-10, anti--the 12-CLA; Suitable-10, suitable-the 12-CLA; Trans-10, anti--the 12-CLA; Suitable-8, trans-10-CLA; Instead-8, suitable-10-CLA; Along 8, suitable-the 10-CLA; Instead-8, anti-10-CLA; Instead-11, along the 13-CLA; Suitable-11, anti--the 13-CLA; Suitable-11, along the 13-CLA; Instead-11, anti--13-CLA.
The preparation method who contains the re-compounded soybean oil of conjugated linoleic acid glyceride of the present invention; At first calculate each component addition according to formula rate; Through measuring pump it is transported to the grease Mixer pot, under room temperature, nitrogen protection, stirs 5-30min, filter through bag type filtering machine; Be transported to canning line and fill the nitrogen can, can obtain containing the re-compounded soybean oil of conjugated linoleic acid glyceride.
The re-compounded soybean oil that said method obtains is measured soybean oil product each item index, and the result shows; Content of trans fatty acids is 0.20%-0.46%, and color and luster (Lovibond colour comparatour, 133.4mm cell) is Y8-15; R0.5-1.2, peroxide value is 0.40-1.20meq/kg, acid value is 0.08-0.12mg/g; Conjugated linoleic acid glyceride content is 1.67-11.67%, and fat-soluble tea polyphenol content is 0.02-0.04%.
Re-compounded soybean oil that contains conjugated linoleic acid glyceride of the present invention and preparation method thereof; Through preferred zero trans-fat acid soybean oil as basic oil; Add a certain proportion of functional conjugated linoleic acid glyceride and strengthen its nutritional health function; Add the certain proportion fat-soluble tea polyphenol as anti-oxidant, thereby obtain the elaboration soybean oil of a kind of green, nutrition, health care.Also have certain synergy between conjugated linoleic acid glyceride and the fat-soluble tea polyphenol, can guarantee that conjugated linoleic acid glyceride is in soybean oil and the stability in the soybean oil storage.
Base oil that the present invention selects for use is the one-level soybean oil; For through appropriate processing gained; Its content of trans fatty acids is lower than 0.5% (according to the U.S. FDA standard, can be labeled as zero trans-fat acid), and has farthest kept nutritional labelings such as vitamin E, sterol, squalene; Compare with conventional one-level soybean oil, it is nutrient health more.Production technology is known, commercially availablely also can obtain.
That the conjugated linoleic acid glyceride that the present invention added has is anticancer, the effect of anti arteriosclerosis, increase human body cardiac muscle, skeletal muscle myoglobin content; The effect of the fat-reducing, increasing flesh of CLA is also as the big characteristic of this edible oil in addition; Can weight-reducing be provided, the novel edible oil of strong muscle for crowds such as vast women of liking to be beautiful and young mans.
The fat-soluble tea polyphenol that the present invention adds, it has effectively substituted the interpolation of chemical antioxidants as natural, green safety more, it also has detoxifcation and radiation-resistant effect simultaneously, and human body is had significant health-care treatment.
The specific embodiment
For further specifying the present invention, specify in conjunction with following examples:
Embodiment 1:
Set soybean oil addition 980kg through measuring pump, conjugated linoleic acid glyceride addition 19.75kg, fat-soluble tea polyphenol addition 0.25kg (adds with the commercial preparation form; 0.25kg be the Tea Polyphenols net content in the finished product); Through measuring pump it is transported to the grease Mixer pot, under room temperature, nitrogen protection, stirs 5-30min, filter through bag type filtering machine; Be transported to canning line and fill the nitrogen can, can obtain containing the re-compounded soybean oil of conjugated linoleic acid glyceride.
Product to the present invention's preparation carries out the index detection, and the result shows: the content of conjugated linoleic acid glyceride is 1.98%, and fat-soluble tea polyphenol content is 0.025%; Content of trans fatty acids is 0.37%; Peroxide value is 0.52meq/kg, and acid value is 0.09mg/g, color and luster (Lovibond colour comparatour; 133.4mm cell) be Y10, R0.7.
Embodiment 2:
Set soybean oil addition 1770kg through measuring pump, conjugated linoleic acid glyceride addition 229.3kg, fat-soluble tea polyphenol addition 0.7kg (adds with the commercial preparation form; 0.7kg be the Tea Polyphenols net content in the finished product); Through measuring pump it is transported to the grease Mixer pot, under room temperature, nitrogen protection, stirs 5-30min, filter through bag type filtering machine; Be transported to canning line and fill the nitrogen can, can obtain containing the re-compounded soybean oil of conjugated linoleic acid glyceride.
Product to the present invention's preparation carries out the index detection, and the result shows: the content of conjugated linoleic acid glyceride is 11.6%, and fat-soluble tea polyphenol content is 0.030%; Content of trans fatty acids is 0.41%; Peroxide value is 1.08meq/kg, and acid value is 0.11mg/g, color and luster (Lovibond colour comparatour; 133.4mm cell) be Y9, R0.6.
Embodiment 3:
Set soybean oil addition 491.3kg through measuring pump, conjugated linoleic acid glyceride addition 8.5kg, fat-soluble tea polyphenol addition 0.19kg (adds with the commercial preparation form; 0.19kg be the Tea Polyphenols net content in the finished product); Through measuring pump it is transported to the grease Mixer pot, under room temperature, nitrogen protection, stirs 5-30min, filter through bag type filtering machine; Be transported to canning line and fill the nitrogen can, can obtain containing the re-compounded soybean oil of conjugated linoleic acid glyceride.
Product to the present invention's preparation carries out the index detection, and the result shows: the content of conjugated linoleic acid glyceride is 1.7%, and fat-soluble tea polyphenol content is 0.038%; Content of trans fatty acids is 0.29%; Peroxide value is 0.58meq/kg, and acid value is 0.10mg/g, color and luster (Lovibond colour comparatour; 133.4mm cell) be Y11, R0.8.
Embodiment 4:
Set soybean oil addition 1395kg through measuring pump, conjugated linoleic acid glyceride addition 104.67kg, fat-soluble tea polyphenol addition 0.33kg (adds with the commercial preparation form; 0.33kg be the Tea Polyphenols net content in the finished product); Through measuring pump it is transported to the grease Mixer pot, under room temperature, nitrogen protection, stirs 5-30min, filter through bag type filtering machine; Be transported to canning line and fill the nitrogen can, can obtain containing the re-compounded soybean oil of conjugated linoleic acid glyceride.
Product to the present invention's preparation carries out the index detection, and the result shows: the content of conjugated linoleic acid glyceride is 6.98%, and fat-soluble tea polyphenol content is 0.022%; Content of trans fatty acids is 0.40%; Peroxide value is 0.84meq/kg, and acid value is 0.10mg/g, color and luster (Lovibond colour comparatour; 133.4mm cell) be Y9, R0.6.
The % that relates in specification of the present invention and claims all refers to percentage by weight like no specified otherwise.
Above-described embodiment describes preferred implementation of the present invention; Be not that scope of the present invention is limited; Design under the prerequisite of spirit not breaking away from the present invention; Various distortion and improvement that the common engineers and technicians in this area make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.
Claims (5)
1. a re-compounded soybean oil that contains conjugated linoleic acid glyceride is characterized in that: be base oil with the soybean oil, add conjugated linoleic acid glyceride and fat-soluble tea polyphenol.
2. the re-compounded soybean oil that contains conjugated linoleic acid glyceride according to claim 1 is characterized in that: said base oil is a zero trans-fat acid soybean oil.
3. the re-compounded soybean oil that contains conjugated linoleic acid glyceride according to claim 1 is characterized in that: content of trans fatty acids in the said base oil≤0.5 weight %; Content of vitamin E>=1200ppm; Phytosterol content>=2200ppm; Squalene content>=60ppm.
4. according to claim 2 or the 3 described re-compounded soybean oil that contain conjugated linoleic acid glyceride, it is characterized in that: the weight ratio of base oil, conjugated linoleic acid glyceride and fat-soluble tea polyphenol is 88.29~98.31: 1.67~11.67 in the said re-compounded soybean oil: 0.02~0.04.
5. the soybean oil that contains conjugated linoleic acid glyceride according to claim 1 is characterized in that: said conjugated linoleic acid glyceride is the ester that CLA and glycerine reaction obtain; Wherein CLA comprises: suitable-9, anti--the 11-CLA; Instead-9, suitable-11-CLA; Suitable-9, suitable-the 11-CLA; Instead-9, anti--11-CLA; Trans-10, suitable-the 12-CLA; Suitable-10, anti--the 12-CLA; Suitable-10, suitable-the 12-CLA; Trans-10, anti--the 12-CLA; Suitable-8, trans-10-CLA; Instead-8, suitable-10-CLA; Along 8, suitable-the 10-CLA; Instead-8, anti-10-CLA; Instead-11, along the 13-CLA; Suitable-11, anti--the 13-CLA; Suitable-11, along the 13-CLA; Instead-11, anti--13-CLA.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103704373A (en) * | 2013-12-19 | 2014-04-09 | 南京财经大学 | Edible oil and preparation method thereof |
CN105076485A (en) * | 2015-06-23 | 2015-11-25 | 海安海龙粮油有限公司 | Flavor-enhancing soybean oil and production method thereof |
CN105994695A (en) * | 2016-06-08 | 2016-10-12 | 中国热带农业科学院农产品加工研究所 | Functional oil composition |
CN106615228A (en) * | 2016-12-20 | 2017-05-10 | 乌鲁木齐上善元生物科技有限公司 | Conjugated linoleic acid-enriched diet blend oil and preparation method thereof |
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CN1445349A (en) * | 2003-02-12 | 2003-10-01 | 刘朝燊 | Oil with conjugation linoleic acid added and method for slowing up oxidation of unsaturated fatty acid and promoting its absorption |
CN1568725A (en) * | 2003-07-22 | 2005-01-26 | 南海油脂工业(赤湾)有限公司 | Edible oil containing conjugate linoleic acid and/or conjugate linoleic acid derivants |
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