CN102533465B - Low foam fabric liquid detergent and preparation method thereof - Google Patents
Low foam fabric liquid detergent and preparation method thereof Download PDFInfo
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- CN102533465B CN102533465B CN2011104538289A CN201110453828A CN102533465B CN 102533465 B CN102533465 B CN 102533465B CN 2011104538289 A CN2011104538289 A CN 2011104538289A CN 201110453828 A CN201110453828 A CN 201110453828A CN 102533465 B CN102533465 B CN 102533465B
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- lipid acid
- liquid detergent
- deionized water
- sodium
- ether
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- 239000007788 liquid Substances 0.000 title claims abstract description 49
- 239000003599 detergent Substances 0.000 title claims abstract description 46
- 239000004744 fabric Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000006260 foam Substances 0.000 title abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 81
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 58
- -1 polyoxyethylene lauryl ether sulfate sodium Polymers 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000008367 deionised water Substances 0.000 claims abstract description 33
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 33
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 29
- 239000000194 fatty acid Substances 0.000 claims abstract description 29
- 229930195729 fatty acid Natural products 0.000 claims abstract description 29
- 239000011734 sodium Substances 0.000 claims abstract description 29
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 29
- 239000003346 palm kernel oil Substances 0.000 claims abstract description 27
- 235000019865 palm kernel oil Nutrition 0.000 claims abstract description 27
- 239000001509 sodium citrate Substances 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims description 53
- 150000002632 lipids Chemical class 0.000 claims description 53
- 238000005406 washing Methods 0.000 claims description 29
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 28
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 28
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 28
- 235000011152 sodium sulphate Nutrition 0.000 claims description 28
- 239000002994 raw material Substances 0.000 claims description 27
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 26
- 229940038773 trisodium citrate Drugs 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 23
- 239000011259 mixed solution Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 abstract description 4
- 239000003240 coconut oil Substances 0.000 abstract 2
- 235000019864 coconut oil Nutrition 0.000 abstract 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000010685 fatty oil Substances 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 15
- 239000002689 soil Substances 0.000 description 10
- 239000013543 active substance Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000005187 foaming Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000012467 final product Substances 0.000 description 7
- 239000012752 auxiliary agent Substances 0.000 description 4
- 235000019633 pungent taste Nutrition 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 230000003381 solubilizing effect Effects 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011174 green composite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention provides a low foam fabric liquid detergent and a preparation method thereof. The detergent comprises fatty alcohol polyoxyethylene lauryl ether sulfate sodium, sodium alpha-olefin sulfonate, fatty alcohol polyoxyethylene (7) ether, coconut oil amide propyl betaine, fatty acid alkanolamide, palm kernel oil fatty acid, fatty oil coconut oil, sodium hydroxide, sodium citrate, 1, 2-benzisothiazoline-3-ketone, essence and deionized water. The low foam fabric liquid detergent and the preparation method of the low foam fabric liquid detergent are strong in dirt-removing power, friendly to environment, small irritation to the skin during usage, low in foam during usage and small in water consumption during rinsing.
Description
Technical field
The present invention relates to chemical field, particularly a kind of low bubble fabric liquid detergent and preparation method thereof.It is strong lowly to steep the fabric liquid detergent soil removability, and pungency is little.
Background technology
Along with the raising of expanding economy and people's income level, people are also improving the requirement of cleaning product.For cleaning supplies, people not only require high-efficiency cleaning, and require cleaning supplies little to the pungency of skin, require cleaning supplies safe, healthy.
At present the annual water that is used for the clothing rinsing of China the chances are 60 ~ 8,000,000,000 tons, if the effect of a rinsing is equivalent to the effect of three rinsings of standard washing powder, then the rinsing water amount only for 1/3rd of washing powder washing, can be saved the water about 1,500,000,000 tons so at least.China is lack of water country, therefore need to provide a kind of have the high-efficiency cleaning ability, easily rinsing, simultaneously to gentle, the low fabric liquid detergent that stimulates of skin.
Summary of the invention
The object of the present invention is to provide a kind of have the high-efficiency cleaning ability, easily rinsing, to gentle, the low low bubble fabric liquid detergent that stimulates of skin.Should select negatively charged ion and zwitterionics as the major surfaces promoting agent by low bubble fabric liquid detergent; Selected fatty acid ester class low-foaming surfactant and natural, the green composite use of lipid acid reach decontamination, fall the bubble purpose; And select solubilizing agent and sequestrant as washing assistant, improve the resistance to hard water of this washing composition.
Another object of the present invention is to provide a kind of preparation method of low bubble fabric liquid detergent.
The objective of the invention is to be realized by following technical proposals:
A kind of low bubble fabric liquid detergent, contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, BIT, essence, deionized water in the raw material of this washing composition; The ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
BIT 0.1
Essence 0.2
Deionized water 55.9～76.5.
Another object of the present invention is achieved through the following technical solutions:
This preparation method's preparation process is as follows:
(1) 20 ~ 40% of described deionized water total amount is heated to 50～60 ℃, and places the material still, then add sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to fully dissolving according to said ratio while stirring, obtain mixed solution A; This mixed solution A is formulated in the material still, need to stir successively when adding described each component;
(2) deionized water at normal temperature of adding about 20 ~ 40% in mixed solution A, then after being stirred to fully dissolving according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring, obtain mixed liquid B; When preparing this mixing solutions B, need to stir successively when adding described each component;
(3) in mixing solutions B, add Trisodium Citrate, BIT, essence, residue deionized water, stir, left standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid detergent.
The invention has the beneficial effects as follows:
The feedstock fat polyoxyethylenated alcohol sodium sulfate that 1 the present invention selects, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether all have good soil release characteristics, calcium soap dispersiveness and emulsifying property; The selected fatty acid alkylolamide carries out composite as auxiliary agent and polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, improve the solubilizing power of low bubble fabric liquid detergent of the present invention, is more conducive to dirt and removes.
The low amphoterics AMONYL 380LC that stimulates of the raw material that 2 the present invention select and other tensio-active agent synergy in decontamination, cleaning, reduce the pungency of system, can be used for the washing of underclothes.
Raw material palm kernel oil lipid acid, lipid acid Oleum Cocois and sodium hydroxide that 3 the present invention select are used, and except soil removability is provided, have more given the performance of system " low bubble ".
The material auxiliary agent Trisodium Citrate that 4 the present invention select can play sequestering action, improves the resistance to hard water of low bubble fabric liquid detergent of the present invention.
5 the present invention are environmentally friendly, and are little to skin irritation during use, improve the Ross-Miles method according to the mensuration of GB/T 7462-94 tensio-active agent foaming power, and the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
A kind of low bubble fabric liquid detergent, contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, BIT, essence, deionized water in the raw material of this washing composition; The ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
BIT 0.1
Essence 0.2
Deionized water 55.9～76.5.
The used weight unit of present embodiment is kilogram, also can be gram;
Essence described in the present embodiment is food grade essence, and all the other each components are technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each component in the described low bubble fabric liquid detergent can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Feedstock fat polyoxyethylenated alcohol sodium sulfate in the present embodiment, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether all have good soil release characteristics, calcium soap dispersiveness and emulsifying property, and the soil removability that is used each component is stronger; The selected fatty acid alkylolamide carries out composite as auxiliary agent and polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, improve the solubilizing power of low bubble fabric liquid detergent of the present invention, is more conducive to dirt and removes; The low amphoterics AMONYL 380LC that stimulates and other tensio-active agent synergy in decontamination, cleaning, reduce the pungency of washing composition, can be used for the washing of underclothes; Palm kernel oil lipid acid, lipid acid Oleum Cocois and sodium hydroxide are used, and except having soil-removing action, washing composition of the present invention has the performance of " low bubble " especially; The auxiliary agent Trisodium Citrate can play sequestering action, improves the resistance to hard water of low bubble fabric liquid detergent of the present invention.
Detersive power of the present invention reaches national sector standard QB/T1224-2007 requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, and the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
The preparation method of described a kind of low bubble fabric liquid detergent, its preparation process is as follows:
(1) with 20 ~ 40%(of described deionized water total amount preferred 30%) be heated to 50～60 ℃, and place the material still, then add sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to fully dissolving according to said ratio while stirring, obtain mixed solution A; This mixed solution A is formulated in the material still, need to stir successively when adding described each component; Heating temperature is preferably 55 ℃ in this step;
(2) deionized water at normal temperature adding about 20 ~ 40%(preferred 30% in mixed solution A), then after being stirred to fully dissolving according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring, obtain mixed liquid B; When preparing this mixing solutions B, need to stir successively when adding described each component; Described normal temperature is room temperature, is generally 20 ~ 25 ℃;
(3) in mixing solutions B, add Trisodium Citrate, BIT, essence, residue deionized water, stir, left standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid detergent.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 6
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2.5
Sodium hydroxide 0.3
Trisodium Citrate 1.5
BIT 0.1
Essence 0.2
Deionized water 70.4.
The low bubble fabric liquid detergent product that will meet industry standard is packed, vanning after the product outer packaging detects.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid detergent of the present invention reaches the industry standard requirement, mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 15
α-sodium olefin sulfonate 5
Aliphatic alcohol polyethenoxy (7) ether 4
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5
Lipid acid Oleum Cocois 3
Sodium hydroxide 0.3
Trisodium Citrate 3
BIT 0.1
Essence 0.2
Deionized water 63.9.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid detergent of the present invention reaches the industry standard requirement, mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.3
Trisodium Citrate 2.5
BIT 0.1
Essence 0.2
Deionized water 64.4.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid detergent of the present invention reaches the industry standard requirement, mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 1
Sodium hydroxide 0.2
Trisodium Citrate 2
BIT 0.1
Essence 0.2
Deionized water 68.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid detergent of the present invention reaches the industry standard requirement, mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 12
α-sodium olefin sulfonate 8
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.2
Trisodium Citrate 3.0
BIT 0.1
Essence 0.2
Deionized water 65.5.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid detergent of the present invention reaches the industry standard requirement, mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, the foam of low bubble fabric liquid detergent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 7:
Present embodiment is the preparation method of low bubble fabric liquid detergent.
A kind of preparation method of low bubble fabric liquid detergent, contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, BIT, essence, deionized water in the raw material of this washing composition; The ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
BIT 0.1
Essence 0.2
Deionized water 55.9～76.5
This preparation method's preparation process is as follows:
(1) 20 ~ 40% of described deionized water total amount is heated to 50～60 ℃, and places the material still, then add sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to fully dissolving according to said ratio while stirring, obtain mixed solution A; This mixed solution A is formulated in the material still, need to stir successively when adding described each component;
(2) deionized water at normal temperature of adding about 20 ~ 40% in mixed solution A, then after being stirred to fully dissolving according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring, obtain mixed liquid B; When preparing this mixing solutions B, need to stir successively when adding described each component;
(3) in mixing solutions B, add Trisodium Citrate, BIT, essence, residue deionized water, stir, left standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid detergent.
In above-mentioned process for preparation, should note whole clean operation environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can buy in market to obtain.
Claims (7)
1. one kind low is steeped fabric liquid detergent, it is characterized in that: the raw material of this washing composition is comprised of polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, BIT, essence, deionized water; The ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8～15
α-sodium olefin sulfonate 5～10
Aliphatic alcohol polyethenoxy (7) ether 2～4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
BIT 0.1
Essence 0.2
Deionized water 55.9～76.5.
2. low bubble fabric liquid detergent according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 6
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2.5
Sodium hydroxide 0.3
Trisodium Citrate 1.5
BIT 0.1
Essence 0.2
Deionized water 70.4.
3. low bubble fabric liquid detergent according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 15
α-sodium olefin sulfonate 5
Aliphatic alcohol polyethenoxy (7) ether 4
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5
Lipid acid Oleum Cocois 3
Sodium hydroxide 0.3
Trisodium Citrate 3
BIT 0.1
Essence 0.2
Deionized water 63.9.
4. low bubble fabric liquid detergent according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.3
Trisodium Citrate 2.5
BIT 0.1
Essence 0.2
Deionized water 64.4.
5. low bubble fabric liquid detergent according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 1
Sodium hydroxide 0.2
Trisodium Citrate 2
BIT 0.1
Essence 0.2
Deionized water 68.
6. low bubble fabric liquid detergent according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 12
α-sodium olefin sulfonate 8
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.2
Trisodium Citrate 3.0
BIT 0.1
Essence 0.2
Deionized water 65.5.
7. one kind is hanged down the preparation method who steeps fabric liquid detergent, it is characterized in that: contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, BIT, essence, deionized water in the raw material of this washing composition; The ratio of weight and number of each raw material of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
BIT 0.1
Essence 0.2
Deionized water 55.9～76.5
This preparation method's preparation process is as follows:
(1) 20 ~ 40% of described deionized water total amount is heated to 50～60 ℃, and places the material still, then add sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to fully dissolving according to said ratio, obtain mixed solution A;
(2) in mixed solution A, add 20 ~ 40% deionized water at normal temperature, then after being stirred to fully dissolving according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, obtain mixed liquid B;
(3) in mixing solutions B, add Trisodium Citrate, BIT, essence, residue deionized water, left standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid detergent.
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| CN2011104538289A CN102533465B (en) | 2011-12-30 | 2011-12-30 | Low foam fabric liquid detergent and preparation method thereof |
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| CN2011104538289A CN102533465B (en) | 2011-12-30 | 2011-12-30 | Low foam fabric liquid detergent and preparation method thereof |
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| CN103897841A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Textile washing agent |
| CN104313883B (en) * | 2014-10-20 | 2016-05-04 | 陕西科技大学 | A kind of preparation method of green multifunctional textile washing finishing agent |
| CN105602769A (en) * | 2014-11-21 | 2016-05-25 | 刘建华 | Compound laundry soap solution and preparation method thereof |
| CN106318734A (en) * | 2015-06-19 | 2017-01-11 | 镇江市润州金山包装厂 | Cloth wrapper cleaning compound |
| BR112018016451B1 (en) | 2016-02-17 | 2022-08-09 | Unilever Ip Holdings B.V. | AQUEOUS CLEANING COMPOSITION AND RIGID SURFACE CLEANING METHOD |
| CN108467803A (en) * | 2017-12-19 | 2018-08-31 | 苏州纳贝通环境科技有限公司 | A kind of environment-friendly type natural liquid detergent and preparation method thereof |
| CN108395941A (en) * | 2018-04-11 | 2018-08-14 | 岳圳 | A kind of liquid detergent and preparation method thereof of low bubble sterilization |
| CN109706002A (en) * | 2018-12-28 | 2019-05-03 | 诺而曼环保科技（江苏）有限公司 | A kind of degradable aqueous cleaning agent and preparation method thereof |
| CN110157551B (en) * | 2019-06-26 | 2021-04-30 | 广州市淳烨生物科技有限公司 | High-concentration laundry detergent |
| CN111440674A (en) * | 2020-05-13 | 2020-07-24 | 杭州炫墨生物科技有限公司 | Liquid detergent with mite removing effect |
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| CN101514306B (en) * | 2008-12-31 | 2010-10-13 | 北京绿伞化学股份有限公司 | Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof |
| CN101514314B (en) * | 2008-12-31 | 2010-12-08 | 北京绿伞化学股份有限公司 | Transparent neutral laundry detergent containing high-concentration chelating agent and preparation method thereof |
| CN101514307B (en) * | 2008-12-31 | 2011-07-20 | 北京绿伞化学股份有限公司 | Transparent and high-concentration laundry detergent and preparation method thereof |
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