CN102517982A - Water-based varnish for corrugated cartons with waterproof high gloss and preparation method thereof - Google Patents
Water-based varnish for corrugated cartons with waterproof high gloss and preparation method thereof Download PDFInfo
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002966 varnish Substances 0.000 title claims description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 54
- 239000007788 liquid Substances 0.000 claims abstract description 21
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 13
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical class OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 6
- -1 silicon modified styrene-acrylate Chemical class 0.000 claims abstract description 4
- 239000001993 wax Substances 0.000 claims description 31
- 239000013530 defoamer Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 3
- 239000004700 high-density polyethylene Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 7
- 239000002518 antifoaming agent Substances 0.000 abstract description 5
- 239000003921 oil Substances 0.000 abstract 3
- 238000005498 polishing Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 6
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
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- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
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- 238000003860 storage Methods 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
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- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
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Abstract
Description
技术领域 technical field
本发明涉及水性光油领域技术，尤其是指一种瓦楞纸箱用防水高光的水性光油及其制备方法。 The invention relates to the technology in the field of water-based varnish, in particular to a water-based varnish with waterproof and high gloss for corrugated boxes and a preparation method thereof.
背景技术 Background technique
目前，瓦楞纸箱已经成为现代包装中使用最广泛的包装容器，也是当今世界各国所采用的最重要的包装形式之一。与人民生活密切相关的食品行业、电子电器行业、饮料行业、机械行业、医药行业、日化行业等各个行业均不断推出新产品，出口数量与品种也逐日增加，这极大地带动了作为产品外包装的瓦楞纸箱生产。这些行业用户不仅对纸箱的需求量大幅增加，还对纸箱的防潮、美观、环保、抗磨等提出了很多更高的要求。比如冷冻食品行业特别注重纸箱的防潮功能，要求纸箱出冷库的时候在纸箱表面能形成水珠流走不留水痕，如果纸箱防水性不够，水会渗透到原纸里，这样就很容易把瓦楞纸箱的抗压力和挺度破坏掉，瓦楞纸箱就丧失了它的防护功能。但是，一般的水性光油很难同时达到高光泽、高防水和抗磨的要求。这是因为一般的抗磨蜡浆均会消光，增光树脂液（如松香树脂液、丙烯酸酯树脂液）由于其高酸值而影响了光油的防水性能。同时，一般的苯乙烯-丙烯酸酯乳液，仅能提供防水性能而无法提供高光泽性。 At present, corrugated boxes have become the most widely used packaging containers in modern packaging, and they are also one of the most important packaging forms used by countries all over the world today. The food industry, electronic appliance industry, beverage industry, machinery industry, pharmaceutical industry, daily chemical industry and other industries closely related to people's life have continuously launched new products, and the number and variety of exports have also increased day by day, which has greatly driven the export of products. Production of packaging in corrugated boxes. Users in these industries have not only greatly increased the demand for cartons, but also put forward many higher requirements for the moisture-proof, aesthetics, environmental protection, and wear resistance of cartons. For example, the frozen food industry pays special attention to the moisture-proof function of cartons, and requires that when the cartons leave the cold storage, water droplets will form on the surface of the cartons and flow away without leaving water marks. If the compression resistance and stiffness of the box are destroyed, the corrugated box will lose its protective function. However, it is difficult for general water-based varnish to meet the requirements of high gloss, high waterproof and anti-wear at the same time. This is because the general anti-wear wax paste will be matted, and the brightening resin liquid (such as rosin resin liquid, acrylic resin liquid) affects the waterproof performance of the varnish due to its high acid value. At the same time, general styrene-acrylate emulsions can only provide waterproof performance but cannot provide high gloss.
发明内容 Contents of the invention
本发明的目的在于提供一种瓦楞纸箱用防水高光水性光油及其制备方法，其性能同时满足高光、防潮、抗磨和环保的要求，解决了高光与防水、高光与抗磨之间的矛盾问题。 The purpose of the present invention is to provide a waterproof high-gloss water-based varnish for corrugated boxes and its preparation method, its performance can meet the requirements of high gloss, moisture-proof, wear-resistant and environmental protection at the same time, and solve the contradiction between high-gloss and waterproof, high-gloss and wear-resistant question.
为了实现上述目的，本发明的目的是通过如下的技术方案来实现的： In order to achieve the above object, the purpose of the present invention is achieved through the following technical solutions:
一种瓦楞纸箱用防水高光的水性光油，按质量百分比由以下原料制成： A water-based varnish for waterproof and high-gloss corrugated boxes is made of the following raw materials by mass percentage:
有机硅改性苯乙烯-丙烯酸酯乳液 50～69%； Silicone modified styrene-acrylate emulsion 50-69%;
苯乙烯-丙烯酸酯树脂液 16～30%； Styrene-acrylate resin liquid 16～30%;
高光蜡乳液 3～8%； High gloss wax emulsion 3～8%;
防水蜡乳液 1～3%； Waterproof wax emulsion 1～3%;
水 5～10%； Water 5～10%;
消泡剂 0.1～0.3%； Defoamer 0.1～0.3%;
以上原料的质量百分比之和等于100%。 The sum of the mass percentages of the above raw materials is equal to 100%.
所述的有机硅改性苯乙烯-丙烯酸酯乳液为一种Tg值（玻璃态转变温度）为-15～-30℃、酸值为50mgKOH/g、固含量为46～48%的成膜乳液，具有优异的防水性能。 The silicone-modified styrene-acrylate emulsion is a film-forming emulsion with a Tg value (glass transition temperature) of -15 to -30°C, an acid value of 50 mgKOH/g, and a solid content of 46 to 48%. , has excellent waterproof performance.
所述的苯乙烯-丙烯酸酯树脂液为一种Tg值（玻璃态转变温度）为100～105℃、酸值为220 mgKOH/g、固含量为35～37%的水溶性树脂，其外观为浅黄色粘稠性透明液体，具有高光泽、耐摩擦和极佳的抗水性能。相对于苯乙烯-丙烯酸酯乳液，苯乙烯-丙烯酸酯树脂液具有低分子量、低固含量、高光泽等特点。本发明采用的苯乙烯-丙烯酸酯树脂液可以在提高光泽度的同时，对防水无负面作用。（注：苯乙烯-丙烯酸酯乳液的分子量在10万以上，而苯乙烯-丙烯酸酯树脂液的分子量在数千至2万）。 The styrene-acrylate resin liquid is a water-soluble resin with a Tg value (glass transition temperature) of 100-105°C, an acid value of 220 mgKOH/g, and a solid content of 35-37%. Pale yellow viscous transparent liquid with high gloss, friction resistance and excellent water resistance. Compared with styrene-acrylate emulsion, styrene-acrylate resin liquid has the characteristics of low molecular weight, low solid content and high gloss. The styrene-acrylic ester resin solution adopted in the invention can improve the glossiness and has no negative effect on waterproofing. (Note: The molecular weight of styrene-acrylate emulsion is more than 100,000, while the molecular weight of styrene-acrylate resin liquid is from several thousand to 20,000).
所述的高光蜡乳液为高密度聚乙烯蜡（HDPE），其固含量为35～42%，粒径分布在10～500纳米的微小范围内。该类型蜡乳液可有效改善水性上光油的光泽及抗磨性能，如德国Keim-Additec公司生产的E-842N（固含量为42%）蜡乳液。 The high-gloss wax emulsion is high-density polyethylene wax (HDPE), its solid content is 35-42%, and the particle size distribution is within a small range of 10-500 nanometers. This type of wax emulsion can effectively improve the gloss and anti-wear properties of water-based varnishes, such as E-842N (42% solid content) wax emulsion produced by Keim-Additec in Germany.
所述的防水蜡乳液为石蜡乳液，其固含量为50%，如德国Keim-Additec公司生产的E-340（固含量为50%）石蜡乳液。 The waterproof wax emulsion is a paraffin wax emulsion with a solid content of 50%, such as E-340 (50% solid content) paraffin wax emulsion produced by Keim-Additec in Germany.
所述的消泡剂外观透明，组成为破泡聚硅氧烷和憎水颗粒（聚脲化合物）在聚乙二醇中的混合物，固含量为95～100%。该类型消泡剂消泡效果持久，且消光不明显，相反地，乳白外观的聚硅氧烷消泡剂消光明显。采用该类型消泡剂可以最大限度保证本发明的高光性能。符合该类型的消泡剂有毕克化学的BYK093、BYK022等。 The antifoaming agent has a transparent appearance, is composed of a mixture of foam-breaking polysiloxane and hydrophobic particles (polyurea compound) in polyethylene glycol, and has a solid content of 95-100%. This type of defoamer has a long-lasting defoaming effect, and the matting is not obvious. On the contrary, the milky white appearance of the polysiloxane defoaming agent is obvious. The use of this type of defoamer can ensure the high light performance of the present invention to the greatest extent. Defoamers that meet this type include BYK093, BYK022, etc. from BYK.
实验发现，搅拌速率过高、搅拌时间过长均会影响消泡剂的消泡效果。本发明中，消泡剂加入时，搅拌速率为400转/分、时间为5分钟，消泡效果最佳。另外，防水蜡乳液必须在较高转速（如800～900转/分钟）下加入，否则，将有析出物产生。因此，本水性光油的制备方法是：常温下，先加入有机硅改性苯乙烯-丙烯酸酯乳液，然后边搅拌（转速为800～900转/分钟）边缓慢地依次加入苯乙烯-丙烯酸酯树脂液、高光蜡乳液、防水蜡乳液和水，5分钟后调低转速至400转/分钟，加入消泡剂，再分散5分钟，使体系的各种原料分散均匀，即得一种瓦楞纸箱用水性光油。 Experiments have found that too high stirring speed and too long stirring time will affect the defoaming effect of the defoamer. In the present invention, when the defoamer is added, the stirring rate is 400 rpm and the stirring time is 5 minutes, and the defoaming effect is the best. In addition, the waterproof wax emulsion must be added at a higher speed (such as 800-900 rpm), otherwise, there will be precipitates. Therefore, the preparation method of this water-based varnish is: at room temperature, first add silicone-modified styrene-acrylate emulsion, and then slowly add styrene-acrylate Resin liquid, high-gloss wax emulsion, waterproof wax emulsion and water, reduce the speed to 400 rpm after 5 minutes, add defoamer, and disperse for another 5 minutes, so that the various raw materials of the system are evenly dispersed, and a corrugated box is obtained Water-based varnish.
采用上述方案后，本发明利用有机硅改性苯乙烯-丙烯酸酯乳液来获得高防水性能，利用苯乙烯-丙烯酸酯树脂液来提高其高光泽度，利用高光蜡乳液来改善其抗磨性能；并且其苯乙烯-丙烯酸酯树脂液不会对防水性能产生负面影响，高光蜡乳液也不会影响其光泽度，以及，采用消光不明显的消泡剂还有防水蜡乳液，通过合理的配比从而解决了高光与防水、高光与抗磨之间的矛盾问题，本发明制备的水性光油同时具备高防水、高光泽和抗磨性能，适用于各种瓦楞纸箱的上光，达到纸箱的美观、防潮、抗磨等要求。 After adopting the above scheme, the present invention utilizes silicone-modified styrene-acrylate emulsion to obtain high waterproof performance, utilizes styrene-acrylate resin liquid to improve its high gloss, and utilizes high-gloss wax emulsion to improve its anti-wear performance; And its styrene-acrylate resin liquid will not have a negative impact on the waterproof performance, and the high-gloss wax emulsion will not affect its gloss, and the anti-foaming agent and waterproof wax emulsion with inconspicuous matting are used, through a reasonable ratio Thus, the contradictory problems between high gloss and waterproof, high gloss and anti-abrasion are solved. The water-based varnish prepared by the present invention has high waterproof, high gloss and anti-abrasion properties at the same time, and is suitable for glazing various corrugated boxes to achieve the beauty of the cartons. , moisture-proof, wear-resistant and other requirements.
具体实施方式 Detailed ways
实施例1：Example 1:
(一)、水性光油配方一 (1), water-based varnish formula 1
有机硅改性苯乙烯-丙烯酸酯乳液 69%； Silicone modified styrene-acrylate emulsion 69%;
苯乙烯-丙烯酸酯树脂液 16%； Styrene-acrylate resin liquid 16%;
高光蜡乳液E-842N 8%； High gloss wax emulsion E-842N 8%;
防水蜡乳液E-340 1.8%； Waterproof wax emulsion E-340 1.8%;
水 5%； Water 5%;
消泡剂BYK093 0.2%； Defoamer BYK093 0.2%;
以上原料的质量百分比之和等于100%。 The sum of the mass percentages of the above raw materials is equal to 100%.
（二）、制备方法 (2), preparation method
常温下，先加入有机硅改性苯乙烯-丙烯酸酯乳液，然后边搅拌（速率为800～900转/分钟）边缓慢地依次加入苯乙烯-丙烯酸酯树脂液、高光蜡乳液、防水蜡乳液和水，5分钟后调低转速至400转/分钟，加入消泡剂，再分散5分钟，使体系的各种原料分散均匀，即得一种瓦楞纸箱用水性光油。 At room temperature, first add silicone-modified styrene-acrylate emulsion, then slowly add styrene-acrylate resin liquid, high-gloss wax emulsion, waterproof wax emulsion and Water, after 5 minutes, reduce the speed to 400 rpm, add defoamer, and disperse for another 5 minutes, so that the various raw materials of the system are evenly dispersed, and a water-based varnish for corrugated boxes is obtained.
实施例 2Example 2
(一)、水性光油配方二 (1), water-based varnish formula 2
有机硅改性苯乙烯-丙烯酸酯乳液 50%； Silicone modified styrene-acrylate emulsion 50%;
苯乙烯-丙烯酸酯树脂液 30%； Styrene-acrylate resin liquid 30%;
高光蜡乳液E-842N 6.9%； High gloss wax emulsion E-842N 6.9%;
防水蜡乳液E-340 3%； Waterproof wax emulsion E-340 3%;
水 10%； Water 10%;
消泡剂BYK093 0.1%； Defoamer BYK093 0.1%;
以上原料的质量百分比之和等于100%； The sum of the mass percentages of the above raw materials is equal to 100%;
（二）制备方法与实施例1相同。 (2) The preparation method is the same as in Example 1.
实施例 3Example 3
(一)、水性光油配方三 (1), water-based varnish formula three
有机硅改性苯乙烯-丙烯酸酯乳液 69%； Silicone modified styrene-acrylate emulsion 69%;
苯乙烯-丙烯酸酯树脂液 19%； Styrene-acrylate resin fluid 19%;
高光蜡乳液E-842N 3 %； High gloss wax emulsion E-842N 3%;
防水蜡乳液E-340 1 %； Waterproof wax emulsion E-340 1%;
水 7.7 %； Water 7.7%;
消泡剂BYK093 0.3 %； Defoamer BYK093 0.3%;
以上原料的质量百分比之和等于100%； The sum of the mass percentages of the above raw materials is equal to 100%;
（二）制备方法与实施例1相同。 (2) The preparation method is the same as in Example 1.
实施例 4Example 4
(一)、水性光油配方四 (1), water-based varnish formula 4
有机硅改性苯乙烯-丙烯酸乳液 57%； Silicone modified styrene-acrylic emulsion 57%;
苯乙烯-丙烯酸酯树脂液 25%； Styrene-acrylate resin liquid 25%;
高光蜡乳液E-842N 6%； High gloss wax emulsion E-842N 6%;
防水蜡乳液E-340 2%； Waterproof wax emulsion E-340 2%;
水 9.8%； Water 9.8%;
消泡剂BYK093 0.2%； Defoamer BYK093 0.2%;
以上原料的质量百分比之和等于100%； The sum of the mass percentages of the above raw materials is equal to 100%;
（二）制备方法与实施例1相同。 (2) The preparation method is the same as in Example 1.
应用实施说明Application Implementation Notes
取本方法制得的水性光油，用120LPI展色仪在未上光油的牛皮纸和白卡纸上展上很薄的一层光油，待光油涂层充分干燥后，分别进行光泽、防水性能和抗磨性能的测试。 Take the water-based varnish prepared by this method, and spread a very thin layer of varnish on the kraft paper and white cardboard without varnish with a 120LPI color development instrument. After the varnish coating is fully dried, respectively carry out gloss, Tests for water resistance and abrasion resistance.
测试结果如下表所示： The test results are shown in the table below:
测试条件： Test Conditions:
光泽：参照国标《GB/T 13217.2-2009液体油墨光泽检测方法》进行检测，采用WGG60-E3光泽度计进行测试。 Gloss: Refer to the national standard "GB/T 13217.2-2009 Liquid Ink Gloss Test Method" for testing, and use WGG60-E3 gloss meter for testing.
防水性能：防水性能包括拔水性和耐水性两个方面，其中拔水性的测试方法是1ml水滴在倾斜450的已上光的纸张表面上，能迅速形成水珠并流走，并且不留下水痕；耐水性是指滴加1ml水在上光的纸面上，观察纸面被水浸透的时间，时间越长，说明该水墨耐水性越强；重复3次取平均值，单位为秒（s）。优良的防水性能必须同时具备优良的拔水性和耐水性。 Waterproof performance: Waterproof performance includes two aspects: water-removal and water-resistance. The test method of water-removal is that 1ml of water drops on the surface of the polished paper inclined at 45 ° , and the water droplets can quickly form and flow away without leaving any water Water resistance refers to dropping 1ml of water on the glazed paper surface, and observing the time for the paper surface to be soaked by water. The longer the time, the stronger the water resistance of the ink; repeat 3 times to get the average value, the unit is second ( s). Excellent waterproof performance must have excellent water removal and water resistance at the same time.
抗磨性：SUTHERLAND 2000磨擦仪，4磅压力、Speed4,200来回由测试结果可知：本发明制备的水性光油具备高防水、高光泽和抗磨性能，适用于各种瓦楞纸箱的上光，达到纸箱的美观、防潮、抗磨等要求。 Abrasion resistance: SUTHERLAND 2000 friction instrument, 4 pounds of pressure, Speed4, 200 back and forth. From the test results, it can be seen that the water-based varnish prepared by the present invention has high waterproof, high gloss and anti-abrasion properties, and is suitable for glazing various corrugated boxes. Meet the beautiful, moisture-proof and wear-resistant requirements of the carton.
以上所述，仅是本发明的较佳实施例而已，并非对本发明的技术范围作任何限制，故凡是依据本发明的技术实质对以上实施例所作的任何细微修改、等同变化与修饰，均仍属于本发明技术方案的范围内。 The above descriptions are only preferred embodiments of the present invention, and do not limit the technical scope of the present invention in any way, so any minor modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention are still valid. It belongs to the scope of the technical solutions of the present invention.
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Address after: Chashan town Tong Kok village 523393 Guangdong city of Dongguan Province on Tong industrial area Patentee after: GUANGDONG YINGKE GROUP CO., LTD. Address before: Cha Shan Zhen Tang Jiao Cun 523000 Guangdong city in Dongguan province of Dongguan City Tong industrial area INTCO Ink Co Ltd Patentee before: Dongguan Yingke Printing Ink Co., Ltd. |