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CN102517511B - Steel for high-expansion-rate petroleum casing and method for manufacturing petroleum casing - Google Patents

Steel for high-expansion-rate petroleum casing and method for manufacturing petroleum casing Download PDF

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CN102517511B
CN102517511B CN 201210007350 CN201210007350A CN102517511B CN 102517511 B CN102517511 B CN 102517511B CN 201210007350 CN201210007350 CN 201210007350 CN 201210007350 A CN201210007350 A CN 201210007350A CN 102517511 B CN102517511 B CN 102517511B
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oil casing
steel
expansion rate
pipe
seamless
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CN102517511A (en
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何继宁
彭会芬
宋开红
姜延飞
马晓莉
李春福
阎殿然
罗平亚
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Hebei University of Technology
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Abstract

The invention discloses steel for a high-expansion-rate petroleum casing and a method for manufacturing the petroleum casing, which relates to an iron-based alloy. The petroleum casing consists of the raw material elements in percentage by mass: 0.03-0.25 percent of C, 0.3-2.5 percent of Si, 0.5-4.0 percent of Mn, 0-0.5 percent of Cr, less than or equal to 0.02 percent of S, less than or equal to 0.02 percent of P and the balance of Fe; one, two or three of 0.01-0.12 percent by mass of Nb, 0.01-0.06 percent by mass of Ti and 0.01-0.12 percent by mass of V can be added; a steel pipe blank or a steel plate is manufactured by smelting; and a high-expansion-rate seamless petroleum casing is manufacturing with the steel pipe blank by using a seamless pipe molding technology and a high-expansion-rate seamed petroleum casing is manufactured by adopting straight slit resistance welding with the steel plate. The expansion rate of the manufactured petroleum casing is more than or equal to 30 percent, and the defects of low expansion rate and high cost of the conventional expandable casing for an oil-gas well are overcome.

Description

高膨胀率石油套管用钢及其用于制作石油套管的方法Steel for high expansion rate oil casing and method for making oil casing

技术领域 technical field

本发明的技术方案涉及铁基合金,具体地说是高膨胀率石油套管用钢及其用于制作石油套管的方法。The technical solution of the invention relates to iron-based alloys, specifically steel for high-expansion oil casings and a method for making oil casings.

背景技术 Background technique

现今将石油套管下入井内是采用逐级向下的延伸技术,下一级套管从上一级套管穿过,导致套管直径越来越小。膨胀管技术是将套管下入井内预定位置,通过中间管输送泥桨液,注满套管外侧的间隙空间,然后下部扩充锥受液体压力推动,自下而上地扩张膨胀套管,使套管直径发生变形,达到紧贴井壁的一种钻井、完井和修井的新技术。应用该技术可实现深井、超深井及恶劣地质条件下的单一井径,为解决深层油气的开采提供了一个崭新途径。目前制约单一井径技术发展的关键是制备大口径和可膨胀石油套管,其关键的关键则是提供这种石油套管用的新型的合金钢材料。Nowadays, the oil casing is lowered into the well using a step-by-step downward extension technology. The next-level casing passes through the upper-level casing, resulting in a smaller and smaller casing diameter. The expansion tube technology is to run the casing into the predetermined position in the well, transport the mud fluid through the middle pipe, and fill the gap space outside the casing, and then the expansion cone at the lower part is pushed by the liquid pressure to expand and expand the casing from bottom to top, so that A new technology of drilling, completion and workover in which the diameter of the casing is deformed to be close to the well wall. Applying this technology can realize single well diameter in deep wells, ultra-deep wells and harsh geological conditions, providing a new way to solve deep oil and gas exploitation. At present, the key to restricting the development of single-caliber technology is to prepare large-diameter and expandable oil casings, and the key point is to provide new alloy steel materials for this oil casing.

现有技术中,CN101812631A公开了油井可膨胀套管用钢及其制造方法,油井可膨胀套管用钢合金材料各组分的质量百分比为:C:0.08~0.2%、Mn:1~2%、Si:0.15~0.35%、Al:0.02~0.06%、P≤0.01%、S≤0.005%、N≤0.008%、Ca:0.001~0.005%、余量为Fe,为了保证该材料的性能,制造的钢管须在730~790℃的F+A两相区进行等温处理,然后在350~450℃等温一定时间以获得F+无碳B+残余A的金相显微组织。虽然具有上述钢合金材料组分的管材可利用膨胀过程中的相变诱发塑性效应,但是该可膨胀管材的变形率只有15%。另外,该套管因尺寸长度达8~10m,在730~790℃的F+A两相区加热及350~450℃等温热处理不仅工艺复杂,大规模生产的工艺控制难度大,而且制造成本很高;CN101194038A披露了一种膨胀管用油井管及其制造方法,所述膨胀管用油井管以质量%计,含有C:0.03~0.14%、Si<0.8%、Mn:0.3~2.5%、P<0.03%、S<0.01%、Ti:0.005~0.03%、Al<0.1%、N:0.001~0.01%、B:0.0005~0.003%;根据需要,还含有Nb、Ni、Mo、Cr、Cu、V之中的1种或2种以上,进而根据需要,含有Ca、REM之中的1种或2种,而且满足A=2.7C+0.4Si+Mn+0.45Ni+0.45Cu+0.8Cr+2Mo≥1.8,余量由铁和不可避免的杂质构成,结合在Ac3+30℃以上的淬火和350~720℃的回火处理以获得回火马氏体组织,具有上述元素组分的管材的扩管率也只有20%。另外,与CN101812631A相比,该管材的合金成分中增加了Ni、Mo、Cu等合金元素,合金钢的成本又大幅度提高。In the prior art, CN101812631A discloses steel for oil well expandable casing and its manufacturing method. The mass percentages of the components of the steel alloy material for oil well expandable casing are: C: 0.08-0.2%, Mn: 1-2%, Si : 0.15~0.35%, Al: 0.02~0.06%, P≤0.01%, S≤0.005%, N≤0.008%, Ca: 0.001~0.005%, and the balance is Fe. In order to ensure the performance of this material, the manufactured steel pipe It is necessary to carry out isothermal treatment in the F+A two-phase region at 730-790°C, and then isothermally at 350-450°C for a certain period of time to obtain the metallographic microstructure of F+carbon-free B+residual A. Although the pipe with the above steel alloy material composition can utilize the phase transformation induced plastic effect during expansion, the deformation rate of the expandable pipe is only 15%. In addition, because the casing has a length of 8-10m, heating in the F+A two-phase region at 730-790°C and isothermal heat treatment at 350-450°C are not only complicated in process, but also difficult to control in large-scale production. The cost is very high; CN101194038A discloses an oil well pipe for expansion pipe and its manufacturing method. The oil well pipe for expansion pipe contains C: 0.03-0.14%, Si<0.8%, Mn: 0.3-2.5%, P <0.03%, S<0.01%, Ti: 0.005-0.03%, Al<0.1%, N: 0.001-0.01%, B: 0.0005-0.003%; Nb, Ni, Mo, Cr, Cu, One or more of V, and if necessary, contain one or two of Ca and REM, and satisfy A=2.7C+0.4Si+Mn+0.45Ni+0.45Cu+0.8Cr+2Mo ≥1.8, the balance is composed of iron and unavoidable impurities, combined with quenching above Ac3+30°C and tempering at 350-720°C to obtain tempered martensite structure, the expansion of pipes with the above element components The tube rate is only 20%. In addition, compared with CN101812631A, alloy elements such as Ni, Mo, and Cu are added to the alloy composition of the pipe, and the cost of the alloy steel is greatly increased.

总之,现有的油气井可膨胀套管还存在实际可膨胀率较低和成本高的缺点。In conclusion, the existing expandable casings for oil and gas wells still have the disadvantages of low actual expandability and high cost.

发明内容 Contents of the invention

本发明所要解决的技术问题是:提供高膨胀率石油套管用钢及其用于制作石油套管的方法,用这种钢材制作的石油套管的膨胀率≥30%,通过30~50%膨胀变形强化后,管材的屈服强度达到550~1000MPa、抗拉强度达到800~1300MPa和延伸率≥10%,克服了现有的油气井可膨胀套管还存在实际膨胀率较低和制作成本高的缺点。The technical problem to be solved by the present invention is to provide steel for high expansion rate oil casing and its method for making oil casing. The expansion rate of the oil casing made of this steel is ≥ 30%. After deformation and strengthening, the yield strength of the pipe reaches 550-1000MPa, the tensile strength reaches 800-1300MPa and the elongation rate is ≥10%, which overcomes the problems of low actual expansion rate and high production cost of the existing expandable casing for oil and gas wells. shortcoming.

本发明解决该技术问题所采用的技术方案是:高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:C:0.03~0.25%、Si:0.3~2.5%、Mn:0.5~4.0%、Cr:0~0.5%、S:≤0.02%、P:≤0.02%和Fe:余量,经冶炼并制成钢管坯或钢板。The technical solution adopted by the present invention to solve the technical problem is: steel for high expansion rate oil casing, the raw materials of which are composed of elements in terms of mass percentage: C: 0.03-0.25%, Si: 0.3-2.5%, Mn: 0.5-4.0 %, Cr: 0 to 0.5%, S: ≤0.02%, P: ≤0.02%, and Fe: the balance, which are smelted and made into steel billets or steel plates.

上述高膨胀率石油套管用钢,在其元素原料组成中再加入Nb、Ti和V之中的一种、两种或三种,加入量按质量百分数计为:Nb:0.01~0.12%、Ti:0.01~0.06%、V:0.01~0.12%。For the above-mentioned high expansion rate oil casing steel, one, two or three of Nb, Ti and V are added to the elemental raw material composition, and the addition amount is calculated by mass percentage: Nb: 0.01-0.12%, Ti : 0.01 to 0.06%, V: 0.01 to 0.12%.

上述高膨胀率石油套管用钢,其元素组成原料通过商购获得,冶炼并制成钢管坯或钢板的工艺是公知的现有技术。The above-mentioned high-expansion oil casing steel, whose elemental raw materials are commercially purchased, is smelted and made into a steel billet or steel plate, which is a well-known prior art.

上述高膨胀率石油套管用钢用于制作石油套管的方法,包括高膨胀率无缝石油套管的制作方法和高膨胀率有缝石油套管的制作方法,步骤如下:The method for making the above-mentioned high-expansion oil casing steel for oil casing includes a method for manufacturing a high-expansion seamless oil casing and a method for manufacturing a high-expansion seamed oil casing. The steps are as follows:

A.高膨胀率无缝石油套管的制作方法:将上述质量百分比的元素组成原料经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制该无缝钢管温度为800~900℃,然后采用强制空气冷却,使该无缝钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到350~450MPa,抗拉强度达到640~750MPa,延伸率≥30%;对该高膨胀率无缝石油套管管材进行扩孔变形,膨胀率≥30%,通过30~50%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为550~1000MPa、抗拉强度为800~1300MPa和延伸率≥10%。A. The production method of high expansion rate seamless oil casing pipe: the above-mentioned element composition raw materials are smelted and made into high expansion rate oil casing steel for steel pipe blanks, and seamless steel pipes are made by seamless pipe forming technology. Control the temperature of the seamless steel pipe to 800-900°C, and then use forced air cooling to rapidly cool the temperature of the seamless steel pipe to room temperature to obtain a high-expansion seamless oil with F+M or B+a small amount of residual A complex phase structure. Casing, the yield strength of the obtained high-expansion seamless oil casing pipe reaches 350-450 MPa, the tensile strength reaches 640-750 MPa, and the elongation is ≥ 30%; the high-expansion seamless oil casing pipe is subjected to hole expansion deformation , expansion rate ≥ 30%, after 30-50% expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 550-1000MPa, tensile strength is 800-1300MPa and elongation ≥ 10%.

B.高膨胀率有缝石油套管的制作方法:将上述质量百分比的元素组成原料经冶炼并制成钢板的高膨胀率石油套管用钢,采用直缝电阻焊制造技术将该钢板制成有缝钢管,再进行热处理,热处理的方法是,再利用中频感应加热器,加热至800~900℃,然后采用水冷或强制空气使该有缝钢管快速冷却到室温,获得具有F+M或B+少量残余A的复相组织的高膨胀率有缝石油套管,所得高膨胀率有缝石油套管管材的屈服强度达到350~450MPa,抗拉强度达到640~750MPa,延伸率≥30%;对该高膨胀率有缝石油套管管材进行扩孔变形,膨胀率≥30%,通过30~50%膨胀变形强化后,该高膨胀率有缝石油套管管材的屈服强度为550~1000MPa、抗拉强度800~1300MPa和延伸率≥10%。B. Manufacturing method of oil casing with high expansion rate seam: smelting the above-mentioned elements by mass percentage as raw materials and making steel plate for high expansion rate oil casing pipe, using straight seam resistance welding manufacturing technology to make the steel plate into a seam Seam steel pipe, and then conduct heat treatment. The heat treatment method is to use a medium frequency induction heater to heat to 800-900°C, and then use water cooling or forced air to quickly cool the seam steel pipe to room temperature to obtain a small amount of F+M or B+. The high-expansion slotted petroleum casing of the multi-phase structure of residual A, the yield strength of the obtained high-expansion slotted petroleum casing pipe reaches 350-450MPa, the tensile strength reaches 640-750MPa, and the elongation is ≥ 30%; The high expansion rate slotted oil casing pipe is subjected to hole expansion deformation, the expansion rate is ≥ 30%, and after being strengthened by 30-50% expansion deformation, the yield strength of the high expansion rate slotted oil casing pipe is 550-1000MPa, tensile strength Strength 800 ~ 1300MPa and elongation ≥ 10%.

上述高膨胀率石油套管用钢用于制作石油套管的方法,所制得的石油套管的外径为110mm~339mm和壁厚为6mm~14mm。The above-mentioned high-expansion oil casing steel is used in the method for manufacturing an oil casing, and the outer diameter of the prepared oil casing is 110mm-339mm and the wall thickness is 6mm-14mm.

上述高膨胀率石油套管用钢用于制作石油套管的方法,所涉及的冶金设备和工艺均为本技术领域所熟知的。The metallurgical equipment and processes involved in the method for making the oil casing with high expansion rate oil casing steel are well known in the technical field.

上述高膨胀率石油套管用钢并不限于用于石油套管的制备,也可用于制作其他器部件。The above-mentioned high-expansion oil casing steel is not limited to be used in the preparation of oil casing, and can also be used to make other machine parts.

本发明的有益效果是:与现有油井可膨胀套管用钢及其制造方法相比,本发明高膨胀率石油套管用钢及其用于制作石油套管的方法的显著进步在于:The beneficial effects of the present invention are: compared with the existing oil well expandable casing steel and its manufacturing method, the present invention's high-expansion oil casing steel and its method for making petroleum casing are significantly improved in that:

(1)用本发明高膨胀率石油套管用钢制作的石油套管的膨胀率≥30%,高于现有技术的15%~20%。该高膨胀率石油套管的管材具有F+M或B+少量残余A金相显微组织,具有屈服强度低和形变强化率高的特点,且其屈服强度为350~450MPa,抗拉强度为640~750MPa,延伸率≥30%,通过30~50%膨胀变形强化后,该高膨胀率石油套管的管材的屈服强度为550~1000MPa、抗拉强度800~1300MPa和延伸率≥10%。下文的实施例和附图对本发明的显著进步给予了具体的证明。(1) The expansion rate of the oil casing pipe made of the high expansion rate oil casing pipe steel of the present invention is ≥ 30%, which is higher than 15% to 20% of the prior art. The high expansion rate oil casing pipe has F+M or B+ a small amount of residual A metallographic microstructure, which has the characteristics of low yield strength and high deformation strengthening rate, and its yield strength is 350-450MPa, and its tensile strength is 640-750MPa , elongation ≥ 30%, after 30-50% expansion and deformation strengthening, the yield strength of the high-expansion oil casing pipe is 550-1000MPa, tensile strength 800-1300MPa and elongation ≥ 10%. The following examples and figures give concrete demonstration of the remarkable advances of the present invention.

(2)制备本发明高膨胀率石油套管用钢的原料均在市场上容易获得,且成本较低,降低了高膨胀率石油套管的总体生产成本。(2) The raw materials for preparing the high-expansion petroleum casing steel of the present invention are easily available in the market, and the cost is relatively low, which reduces the overall production cost of the high-expansion petroleum casing.

(3)用本发明高膨胀率石油套管用钢制作石油套管的方法操作简单,易于在工业上推广应用。(3) The method for producing the oil casing with the high-expansion oil casing steel of the present invention is easy to operate and easy to be popularized and applied in industry.

附图说明 Description of drawings

下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1为实施例4制作的高膨胀率无缝石油套管中经50%膨胀变形前后部分的实物照片。Fig. 1 is the physical photograph of the part before and after 50% expansion deformation in the high expansion rate seamless petroleum casing produced in Example 4.

具体实施方式 Detailed ways

实施例1Example 1

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.07%C、2.0%Si、1.2%Mn、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢板。High-expansion oil casing steel, the element composition raw materials are: 0.07%C, 2.0%Si, 1.2%Mn, ≤0.02%S, ≤0.02%P and the balance is Fe, and the raw materials are smelted and made steel plate.

将上述经冶炼并制成钢板的高膨胀率石油套管用钢,采用直缝电阻焊制造技术将该钢板制成有缝钢管,再进行热处理,热处理的方法是,利用中频感应加热器,加热至900℃,然后采用水冷或强制空气使该有缝钢管快速冷却到室温,获得具有F+M或B+少量残余A的复相组织的外径为110mm和壁厚为6mm的高膨胀率有缝石油套管,所得高膨胀率有缝石油套管管材的屈服强度达到380MPa,抗拉强度达到690MPa,延伸率32%;对该高膨胀率有缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为145mm,膨胀率32%,通过32%膨胀变形强化后,该高膨胀率有缝石油套管管材的屈服强度为650MPa、抗拉强度880MPa和延伸率19%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into a steel plate is made into a seamed steel pipe by using the straight seam resistance welding manufacturing technology, and then heat-treated. The heat treatment method is to use a medium-frequency induction heater to heat to 900°C, and then use water cooling or forced air to quickly cool the seamed steel pipe to room temperature, and obtain a high-expansion seamed oil with a multiphase structure of F+M or B+a small amount of residual A. The outer diameter is 110mm and the wall thickness is 6mm. Casing, the yield strength of the obtained high-expansion slotted petroleum casing pipe reaches 380MPa, the tensile strength reaches 690MPa, and the elongation rate is 32%; The outer diameter of the pipe is 145mm, and the expansion rate is 32%. After strengthening through 32% expansion deformation, the yield strength of the high expansion rate slotted oil casing pipe is 650MPa, the tensile strength is 880MPa and the elongation is 19%.

实施例2Example 2

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.15%C、1.5%Si、1.5%Mn、0.5%Cr、0.05%Nb、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.15%C, 1.5%Si, 1.5%Mn, 0.5%Cr, 0.05%Nb, ≤0.02%S, ≤0.02%P and the balance It is Fe, which is smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为850℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为110mm和壁厚为6mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到400MPa,抗拉强度达到700MPa,延伸率为30%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为154mm,膨胀率为40%,通过40%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为700MPa、抗拉强度为1100MPa和延伸率为16%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by using seamless pipe forming technology. Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 110 mm and a wall thickness of 6 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 400MPa, the tensile strength reaches 700MPa, and the elongation rate is 30%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 154mm, and the expansion rate is 40%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 700MPa, the tensile strength is 1100MPa and the elongation is 16%.

实施例3Example 3

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.2%C、2.5%Si、3.5%Mn、0.02%Ti、0.25%Cr、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.2%C, 2.5%Si, 3.5%Mn, 0.02%Ti, 0.25%Cr, ≤0.02%S, ≤0.02%P and the balance It is Fe, which is smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为800℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为219mm和壁厚为9mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到450MPa,抗拉强度达到750MPa,延伸率为30%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为285mm,膨胀率为30%,通过30%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为1000MPa、抗拉强度为1300MPa和延伸率为11%。The above-mentioned high-expansion oil casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by seamless pipe forming technology. The temperature of the seamless steel pipes is controlled at 800 °C, and then forced air cooling is used to make the temperature of the steel pipes rapidly Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 219 mm and a wall thickness of 9 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 450MPa, the tensile strength reaches 750MPa, and the elongation rate is 30%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 285mm, and the expansion rate is 30%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 1000 MPa, the tensile strength is 1300 MPa and the elongation is 11%.

实施例4Example 4

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.17%C、1.9%Si、3.0%Mn、0.1%Cr、0.1%V、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.17%C, 1.9%Si, 3.0%Mn, 0.1%Cr, 0.1%V, ≤0.02%S, ≤0.02%P and the balance It is Fe, which is smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为820℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为219mm和壁厚为12mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到380MPa,抗拉强度达到700MPa,延伸率为30%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为329mm,膨胀率为50%,通过50%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为850MPa、抗拉强度为1250MPa和延伸率为14%。The above-mentioned high-expansion oil casing steel that has been smelted and made into steel pipe billets is made into seamless steel pipes by seamless pipe forming technology. Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 219 mm and a wall thickness of 12 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 380MPa, the tensile strength reaches 700MPa, and the elongation rate is 30%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 329mm, and the expansion rate is 50%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 850 MPa, the tensile strength is 1250 MPa and the elongation is 14%.

图1为本实施例制作的高膨胀率无缝石油套管中经50%膨胀变形前后部分的实物照片,由图可见,利用膨胀锥对可膨胀石油套管直接进行50%扩孔变形,本实施例所制作的高膨胀率无缝石油套管的变形性能良好,管子的表面质量也很好。Fig. 1 is the physical photograph of the parts before and after 50% expansion and deformation of the high-expansion seamless oil casing pipe produced in this embodiment. The high-expansion seamless petroleum casing produced by the embodiment has good deformation performance and good surface quality.

实施例5Example 5

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.03%C、2.5%Si、0.5%Mn、0.5%Cr、0.1%V、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its element composition raw materials are calculated by mass percentage: 0.03%C, 2.5%Si, 0.5%Mn, 0.5%Cr, 0.1%V, ≤0.02%S, ≤0.02%P and the balance It is Fe, which is smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为900℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为110mm和壁厚为6mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到360MPa,抗拉强度达到650MPa,延伸率为35%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为143mm,膨胀率为30%,通过30%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为550MPa、抗拉强度为810MPa和延伸率为15%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by seamless pipe forming technology. Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 110 mm and a wall thickness of 6 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 360MPa, the tensile strength reaches 650MPa, and the elongation rate is 35%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 143mm, and the expansion rate is 30%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 550 MPa, the tensile strength is 810 MPa and the elongation is 15%.

实施例6Example 6

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.25%C、0.3%Si、4.0%Mn、0.01%Cr、0.01%Nb、0.01%Ti、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.25%C, 0.3%Si, 4.0%Mn, 0.01%Cr, 0.01%Nb, 0.01%Ti, ≤0.02%S, ≤0.02% P and the balance are Fe, which are smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为800℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为339mm和壁厚为14mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到430MPa,抗拉强度达到750MPa,延伸率为30%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为442mm,膨胀率为30%,通过30%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为900MPa、抗拉强度为1150MPa和延伸率为10%。The above-mentioned high-expansion oil casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by seamless pipe forming technology. The temperature of the seamless steel pipes is controlled at 800 °C, and then forced air cooling is used to make the temperature of the steel pipes rapidly Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 339 mm and a wall thickness of 14 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 430MPa, the tensile strength reaches 750MPa, and the elongation rate is 30%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 442mm, and the expansion rate is 30%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 900 MPa, the tensile strength is 1150 MPa and the elongation is 10%.

实施例7Example 7

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.09%C、1.5%Si、0.5%Mn、0.1%Cr、0.12%Nb、0.12%V、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its element composition raw materials are calculated by mass percentage: 0.09%C, 1.5%Si, 0.5%Mn, 0.1%Cr, 0.12%Nb, 0.12%V, ≤0.02%S, ≤0.02% P and the balance are Fe, which are smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为800℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为339mm和壁厚为14mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到420MPa,抗拉强度达到750MPa,延伸率为33%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为475mm,膨胀率为40%,通过40%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为870MPa、抗拉强度为1200MPa和延伸率为15%。The above-mentioned high-expansion oil casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by seamless pipe forming technology. The temperature of the seamless steel pipes is controlled at 800 °C, and then forced air cooling is used to make the temperature of the steel pipes rapidly Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 339 mm and a wall thickness of 14 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 420MPa, the tensile strength reaches 750MPa, and the elongation rate is 33%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 475mm, and the expansion rate is 40%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 870 MPa, the tensile strength is 1200 MPa and the elongation is 15%.

实施例8Example 8

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.07%C、2.0%Si、2.0%Mn、0.1%Cr、0.03%Ti、0.05%V、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢板。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.07%C, 2.0%Si, 2.0%Mn, 0.1%Cr, 0.03%Ti, 0.05%V, ≤0.02%S, ≤0.02% P and the balance are Fe, which are smelted and made into steel plates.

将上述经冶炼并制成钢板的高膨胀率石油套管用钢,采用直缝电阻焊制造技术将该钢板制成有缝钢管,再进行热处理,热处理的方法是,利用中频感应加热器,加热至850℃,然后采用水冷或强制空气使该有缝钢管快速冷却到室温,获得具有F+M或B+少量残余A的复相组织的外径为339mm和壁厚为14mm的高膨胀率有缝石油套管,屈服强度达到350MPa,抗拉强度达到640MPa,延伸率35%;对该有缝管材进行扩孔变形,扩孔后膨胀管的外径为442mm,膨胀率30%,通过30%膨胀变形强化后,该有缝管材的屈服强度为550MPa、抗拉强度800MPa和延伸率15%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into a steel plate is made into a seamed steel pipe by using the straight seam resistance welding manufacturing technology, and then heat-treated. The heat treatment method is to use a medium-frequency induction heater to heat to 850°C, and then use water cooling or forced air to rapidly cool the seamed steel pipe to room temperature to obtain a high-expansion seamed oil with a multiphase structure of F+M or B+a small amount of residual A. The outer diameter is 339mm and the wall thickness is 14mm. The casing has a yield strength of 350MPa, a tensile strength of 640MPa, and an elongation of 35%. The seamed pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 442mm, and the expansion rate is 30%. Through 30% expansion deformation After strengthening, the yield strength of the seamed pipe is 550MPa, the tensile strength is 800MPa and the elongation is 15%.

实施例9Example 9

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.19%C、2.5%Si、0.5%Mn、0.05%Nb、0.06%Ti、0.05%V、≤0.02%S、≤0.02%P和余量为Fe,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.19%C, 2.5%Si, 0.5%Mn, 0.05%Nb, 0.06%Ti, 0.05%V, ≤0.02%S, ≤0.02% P and the balance are Fe, which are smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为850℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为219mm和壁厚为12mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到400MPa,抗拉强度达到750MPa,延伸率为33%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为306mm,膨胀率为40%,通过40%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为900MPa、抗拉强度为1200MPa和延伸率为11%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by using seamless pipe forming technology. Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 219 mm and a wall thickness of 12 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 400MPa, the tensile strength reaches 750MPa, and the elongation rate is 33%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 306mm, and the expansion rate is 40%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 900 MPa, the tensile strength is 1200 MPa and the elongation is 11%.

实施例10Example 10

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.03%C、2.5%Si、0.5%Mn、0.5%Cr、≤0.02%S、≤0.02%P和Fe:余量,经冶炼并制成钢管坯。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.03%C, 2.5%Si, 0.5%Mn, 0.5%Cr, ≤0.02%S, ≤0.02%P and Fe: the balance, after Smelted and made into steel billets.

将上述经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制无缝钢管温度为900℃,然后采用强制空气冷却,使钢管的温度快速冷却到室温,获得具有F+M或B+少量残余A复相组织的外径为110mm和壁厚为6mm的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到360MPa,抗拉强度达到650MPa,延伸率为32%;对该高膨胀率无缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为143mm,膨胀率为30%,通过30%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为600MPa、抗拉强度为820MPa和延伸率为19%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into steel pipe blanks is made into seamless steel pipes by seamless pipe forming technology. Cool to room temperature to obtain a high expansion rate seamless oil casing with an outer diameter of 110 mm and a wall thickness of 6 mm with F+M or B+ a small amount of residual A multiphase structure, and the yield strength of the obtained high expansion rate seamless oil casing pipe The tensile strength reaches 360MPa, the tensile strength reaches 650MPa, and the elongation rate is 32%. The high expansion rate seamless oil casing pipe is reamed and deformed. After reaming, the outer diameter of the expanded pipe is 143mm, and the expansion rate is 30%. After % expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 600MPa, the tensile strength is 820MPa and the elongation is 19%.

实施例11Example 11

高膨胀率石油套管用钢,其元素组成原料按质量百分数计为:0.25%C、0.3%Si、4.0%Mn、0.25%Cr、≤0.02%S、≤0.02%P和Fe:余量,经冶炼并制成钢板。High expansion rate oil casing steel, its elemental composition raw materials are calculated by mass percentage: 0.25%C, 0.3%Si, 4.0%Mn, 0.25%Cr, ≤0.02%S, ≤0.02%P and Fe: the balance, after Smelted and made into steel plates.

将上述经冶炼并制成钢板的高膨胀率石油套管用钢,采用直缝电阻焊制造技术将该钢板制成有缝钢管,再进行热处理,热处理的方法是,利用中频感应加热器,加热至800℃,然后采用水冷或强制空气使该有缝钢管快速冷却到室温,获得具有F+M或B+少量残余A的复相组织的外径为245mm和壁厚为9mm的高膨胀率有缝石油套管,所得高膨胀率有缝石油套管管材的屈服强度达到450MPa,抗拉强度达到750MPa,延伸率30%;对该高膨胀率有缝石油套管管材进行扩孔变形,扩孔后膨胀管的外径为319mm,膨胀率30%,通过30%膨胀变形强化后,该高膨胀率有缝石油套管管材的屈服强度为900MPa、抗拉强度1100MPa和延伸率12%。The above-mentioned high-expansion petroleum casing steel that has been smelted and made into a steel plate is made into a seamed steel pipe by using the straight seam resistance welding manufacturing technology, and then heat-treated. The heat treatment method is to use a medium-frequency induction heater to heat to 800°C, and then use water cooling or forced air to quickly cool the seamed steel pipe to room temperature, and obtain a high-expansion seamed oil with a multiphase structure of F+M or B+a small amount of residual A. The outer diameter is 245mm and the wall thickness is 9mm. Casing, the yield strength of the obtained high-expansion slotted petroleum casing pipe reaches 450MPa, the tensile strength reaches 750MPa, and the elongation rate is 30%; The outer diameter of the pipe is 319mm, and the expansion rate is 30%. After strengthening through 30% expansion deformation, the yield strength of the high expansion rate slotted oil casing pipe is 900MPa, the tensile strength is 1100MPa and the elongation is 12%.

Claims (3)

1.高膨胀率石油套管用钢用于制作石油套管的方法,其特征在于:高膨胀率石油套管用钢的元素组成原料按质量百分数计为:C:0.03~0.25%、Si:0.3~2.5%、Mn:0.5~4.0%、Cr:0~0.5%、S:≤0.02%、P:≤0.02%和Fe:余量,包括高膨胀率无缝石油套管的制作方法和高膨胀率有缝石油套管的制作方法,步骤如下:1. The method for producing oil casing with steel for high expansion rate oil casing, characterized in that: the element composition raw materials of steel for high expansion rate oil casing are calculated by mass percentage: C: 0.03-0.25%, Si: 0.3- 2.5%, Mn: 0.5-4.0%, Cr: 0-0.5%, S: ≤0.02%, P: ≤0.02%, and Fe: balance, including the production method and high expansion rate of seamless oil casing with high expansion rate The manufacturing method of the seamed oil casing, the steps are as follows: A.高膨胀率无缝石油套管的制作方法:将所述质量百分比的元素组成原料经冶炼并制成钢管坯的高膨胀率石油套管用钢,采用无缝管成型技术制成无缝钢管,控制该无缝钢管温度为800~900℃,然后采用强制空气冷却,使该无缝钢管的温度快速冷却到室温,获得具有F +M或B + 少量残余A复相组织的高膨胀率无缝石油套管,所得高膨胀率无缝石油套管管材的屈服强度达到350~450MPa,抗拉强度达到640~750MPa,延伸率≥30%;对该高膨胀率无缝石油套管管材进行扩孔变形,膨胀率≥30%,通过30~50%膨胀变形强化后,该高膨胀率无缝石油套管管材的屈服强度为550~1000MPa、抗拉强度为800~1300MPa和延伸率≥10%;A. The production method of high expansion rate seamless oil casing pipe: smelting the raw materials of the above-mentioned mass percentage elements to make steel for high expansion rate oil casing pipe of steel billet, and adopting seamless pipe forming technology to make seamless steel pipe , control the temperature of the seamless steel pipe at 800-900°C, and then use forced air cooling to rapidly cool the temperature of the seamless steel pipe to room temperature, and obtain a high-expansion ratio-free structure with F + M or B + a small amount of residual A complex phase structure. The yield strength of the obtained high-expansion seamless oil casing pipe reaches 350-450MPa, the tensile strength reaches 640-750MPa, and the elongation rate is ≥ 30%. The high-expansion seamless oil casing pipe is expanded. Hole deformation, expansion rate ≥ 30%, after 30-50% expansion deformation strengthening, the yield strength of the high expansion rate seamless oil casing pipe is 550-1000MPa, tensile strength is 800-1300MPa and elongation ≥ 10% ; B.高膨胀率有缝石油套管的制作方法:将所述质量百分比的元素组成原料经冶炼并制成钢板的高膨胀率石油套管用钢,采用直缝电阻焊制造技术将该钢板制成有缝钢管,再进行热处理,热处理的方法是,再利用中频感应加热器,加热至800~900℃,然后采用水冷或强制空气使该有缝钢管快速冷却到室温,获得具有F + M或B + 少量残余A的复相组织的高膨胀率有缝石油套管,所得高膨胀率有缝石油套管管材的屈服强度达到350~450MPa,抗拉强度达到640~750MPa,延伸率≥30%;对该高膨胀率有缝石油套管管材进行扩孔变形,膨胀率≥30%,通过30~50%膨胀变形强化后,该高膨胀率有缝石油套管管材的屈服强度为550~1000MPa、抗拉强度800~1300MPa和延伸率≥10%。B. Manufacturing method of seamed oil casing with high expansion rate: smelting the raw materials of the above-mentioned elements by mass percentage and making steel plate for high expansion rate oil casing pipe, using straight seam resistance welding manufacturing technology to make the steel plate The seamed steel pipe is then subjected to heat treatment. The method of heat treatment is to use an intermediate frequency induction heater to heat it to 800-900°C, and then use water cooling or forced air to quickly cool the seamed steel pipe to room temperature to obtain F + M or B + High expansion rate slotted oil casing pipe with a small amount of residual A multiphase structure, the yield strength of the obtained high expansion rate slotted oil casing pipe reaches 350-450MPa, the tensile strength reaches 640-750MPa, and the elongation rate is ≥30%; The high expansion rate slotted oil casing pipe is subjected to hole expansion deformation, the expansion rate is ≥ 30%, and after being strengthened by 30-50% expansion deformation, the yield strength of the high expansion rate slotted oil casing pipe is 550-1000MPa, Tensile strength 800 ~ 1300MPa and elongation ≥ 10%. 2.根据权利要求1所述高膨胀率石油套管用钢用于制作石油套管的方法,其特征在于:所述高膨胀率石油套管用钢的元素组成原料中再加入Nb、Ti和V之中的一种、两种或三种,加入量按质量百分数计为:Nb:0.01~0.12%、Ti:0.01~0.06%、V:0.01~0.12%。2. The method for producing petroleum casing with the high expansion rate oil casing steel according to claim 1, characterized in that: Nb, Ti and V are added to the element composition raw materials of the high expansion rate oil casing steel. One, two or three of them are added in the following mass percentages: Nb: 0.01-0.12%, Ti: 0.01-0.06%, V: 0.01-0.12%. 3.根据权利要求1所述权利要求1高膨胀率石油套管用钢用于制作石油套管的方法,其特征在于:所制得的石油套管的外径为110mm~339mm和壁厚为6mm~14mm。3. According to claim 1, the method for making oil casing with high expansion rate steel for oil casing, characterized in that: the outer diameter of the prepared oil casing is 110mm-339mm and the wall thickness is 6mm ~14mm.
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