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CN102513520A - Method for preparing heat-fatigue-resistance wear-resistance laminated particle reinforced composite material - Google Patents

Method for preparing heat-fatigue-resistance wear-resistance laminated particle reinforced composite material Download PDF

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CN102513520A
CN102513520A CN2011104451478A CN201110445147A CN102513520A CN 102513520 A CN102513520 A CN 102513520A CN 2011104451478 A CN2011104451478 A CN 2011104451478A CN 201110445147 A CN201110445147 A CN 201110445147A CN 102513520 A CN102513520 A CN 102513520A
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resistant
wear
composite material
reinforced composite
prefabricated block
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蒋业华
李祖来
隋育栋
周荣
岑启宏
�山泉
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Kunming University of Science and Technology
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Abstract

本发明提供一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,通过将镍基自熔合金粉末与硬质陶瓷颗粒混合均匀,加入粘结剂,制成预制块,然后采用常规砂型铸造或消失模铸造,再熔炼基材金属材料至浇注温度后,将其浇注入放有所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。本发明的复合制备工艺可控性强,操作简便,成品率高,整体性能高,生产质量稳定,耐热疲劳的层状复合耐磨层与基材金属层形成良好的冶金结合,能广泛应用于矿山、电力、冶金、煤炭、建材等耐热疲劳及耐磨领域,便于工业化大规模生产。

The invention provides a method for preparing a heat-fatigue-resistant wear-resistant layered particle-reinforced composite material. By uniformly mixing nickel-based self-fluxing alloy powder and hard ceramic particles, adding a binder to make a prefabricated block, and then using conventional Sand casting or lost foam casting, after melting the base metal material to the pouring temperature, it is poured into the cavity with the obtained prefabricated block, cooled and solidified at room temperature, and after sand cleaning treatment, a layered mold with heat fatigue resistance is obtained. A wear-resistant layered particle-reinforced composite material composed of a composite wear-resistant layer, a metallurgical transition layer, and a base metal layer. The composite preparation process of the present invention has strong controllability, simple operation, high yield, high overall performance, stable production quality, good metallurgical bonding between the thermal fatigue-resistant layered composite wear-resistant layer and the base metal layer, and can be widely used In mining, electric power, metallurgy, coal, building materials and other thermal fatigue and wear resistance fields, it is convenient for industrialized large-scale production.

Description

一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法A preparation method of wear-resistant layered particle-reinforced composite material resistant to thermal fatigue

  the

技术领域 technical field

本发明属于金属基复合材料技术领域,特别涉及一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法。 The invention belongs to the technical field of metal-based composite materials, and in particular relates to a preparation method of a heat-fatigue-resistant wear-resistant layered particle-reinforced composite material.

背景技术 Background technique

现代工业的发展对材料的耐磨性能要求越来越高,冶金、矿山、建材、电力、化工、煤炭和农业等部门分别要用到矿山机械、工程机械、农业机械和各种破碎粉磨机械,这些机械设备的易损件要受到砂石、矿石、土壤等各种物料和研磨体的磨损,每年要消耗大量金属。根据不完全统计,能源的1/3~1/2消耗与摩擦和磨损有关。对材料来说,约80%的零件失效是由磨损引起的,其中因磨料磨损而失效的约占50%,据统计我国用于磨料磨损工况的耐磨铁铁件,每年要消耗200多万吨。由此,开发研制出一种能在磨损工况下,具有较长使用寿命的新材质显得极为重要。 The development of modern industry has higher and higher requirements on the wear resistance of materials. Mining machinery, engineering machinery, agricultural machinery and various crushing and grinding machinery are used in metallurgy, mining, building materials, electric power, chemical industry, coal and agriculture. , The wearing parts of these mechanical equipment are subject to the wear and tear of various materials and grinding bodies such as sand, ore, soil, etc., and consume a large amount of metal every year. According to incomplete statistics, 1/3 to 1/2 of energy consumption is related to friction and wear. For materials, about 80% of the failures of parts are caused by wear, and about 50% of them fail due to abrasive wear. According to statistics, the wear-resistant iron and iron parts used in abrasive wear conditions in my country consume more than 200 yuan per year. tons. Therefore, it is extremely important to develop a new material that can have a longer service life under wear conditions.

在工业中的许多领域存在恶劣的工作环境,要求工作零部件同时具备耐磨耐热或耐磨耐蚀综合性能,因此具有单一性能的材料已不能满足工况的需求。复合材料由于是将两种或以上具有不同特性的材料,通过物理或化学的方法将它们有机结合在一起,发挥各自优势,因此材料具有优异的综合性能。近几年来,对复合材料制备工艺的研究做了大量的工作,开发了多种工艺。这些工艺方法用于制造有色金属复合材料时,由于有色金属大多数熔点低,与很多增强颗粒间浸润性好,因此取得了很好的效果。如SiC增强铝合金复合材料制造活塞,使用寿命大幅度提高。然而对黑色金属而言,由于熔点高,相互之间冶金反应复杂,因此如何方便地使增强颗粒加入黑色金属液中,一直是一道难题,这严重影响颗粒增强铁铁基复合材料的产业化进程。多年来,对颗粒增强铁铁基复合材料的工艺研究一直是复合材料研究的重大课题之一,也取得了一些成果。专利(公开号1080221)介绍了一种制备颗粒增强耐磨复合材料的铸造方法,其工艺步骤是:先做好铸型,同时制备尺寸为负偏差的消失模,再将消失模放入铸型中,这样在消失模和铸型间就形成空隙。将空隙填满硬质颗粒,合箱抽真空浇注,从而在表面形成含硬质颗粒的耐磨材料。该方法工序复杂,不能很好的将消失模负压铸造工艺的优点利用起来,生产效率低,且复合层厚度和质量难以保证。CN1383945A公开了一种颗粒增强复合材料的制备方法,它的工序步骤是:先做好泡沫塑料模,在铸件需要制作复合材料的部位,将模制作成两部分粘结,其中之一制有沟槽,然后将混制好的增强颗粒填满沟槽,再将模的两部分粘结起来,上涂料烘干造型,最后抽真空浇注。这种方法制备较复杂,不适合实际生产的需要。CN101053898A介绍了一种制备颗粒增强金属基表面复合材料的真空实型铸渗方法,这种方法是将增强颗粒制备成与复合材料所需耐磨表面形状相适应的预制块,将其固定在需要合金化的泡沫材料模样表面,然后按铸造工艺造型并浇注。CN1128297A公布了一种局部复合材料及其制造方法,其是将陶瓷颗粒、有机粘结剂与普碳钢基、耐热钢基或镍基粉末混匀,压制成所需形状的预制块,置于需强化的铸件的铸型局部,浇注金属即可。上述两种发明与本发明类似,其中最大的区别在于上述两种方法做出的复合材料并不耐热疲劳,在激冷激热数次后,其复合层会出现致命性裂纹,从而减少其使用寿命;CN101422814A公开了一种局部复合耐磨材料的制备方法,它是选用高合金粉芯管丝,根据工件表面的形状,裁剪、卷制或叠加制成相似结构;按照铸造工艺造型,将制作好的高合金粉芯管丝预埋入砂型型腔中,冶炼基材金属材料浇注,从而得到所需复合材料。这种方法的缺点在于易形成夹渣缺陷,用于实际生产时工艺可控性较差,不适合大规模工业化生产。 There are harsh working environments in many areas of the industry, and the working parts are required to have comprehensive properties of wear and heat resistance or wear and corrosion resistance. Therefore, materials with a single performance can no longer meet the needs of working conditions. Composite materials have excellent comprehensive properties because they combine two or more materials with different properties through physical or chemical methods to give full play to their respective advantages. In recent years, a lot of work has been done on the research on the preparation process of composite materials, and a variety of processes have been developed. When these processes are used to manufacture non-ferrous metal composite materials, because most non-ferrous metals have low melting points and have good wettability with many reinforcing particles, good results have been achieved. For example, the SiC reinforced aluminum alloy composite material makes the piston, and the service life is greatly improved. However, for ferrous metals, due to the high melting point and complex metallurgical reactions between them, how to conveniently add reinforced particles to the ferrous metal liquid has always been a difficult problem, which seriously affects the industrialization process of particle-reinforced iron-iron-based composite materials . Over the years, the process research on particle reinforced iron-iron matrix composites has been one of the major topics in composites research, and some achievements have been made. The patent (publication number 1080221) introduces a casting method for preparing particle-reinforced wear-resistant composite materials. The process steps are: first make a casting mold, and at the same time prepare a lost foam with a negative size deviation, and then put the lost foam into the mold In this way, a void is formed between the lost foam and the mold. Fill the gaps with hard particles, and then vacuumize and pour the box together to form a wear-resistant material containing hard particles on the surface. The process of this method is complicated, the advantages of the lost foam negative pressure casting process cannot be well utilized, the production efficiency is low, and the thickness and quality of the composite layer are difficult to guarantee. CN1383945A discloses a method for preparing a particle-reinforced composite material. Its process steps are: firstly make a foam plastic mold, and at the position where the composite material needs to be made in the casting, the mold is made into two parts, one of which is formed with a groove Then fill the groove with the mixed reinforcing particles, then bond the two parts of the mold together, paint and dry the shape, and finally vacuum pour. This method is more complicated to prepare and is not suitable for the needs of actual production. CN101053898A has introduced a kind of method for the vacuum solid mold infiltration of preparing particle-reinforced metal-matrix surface composite material, and this method is to prepare the reinforced particle into the prefabricated block that adapts to the shape of the wear-resistant surface required by the composite material, and fix it at the required The alloyed foam pattern surface is then molded and poured in a casting process. CN1128297A discloses a kind of partial composite material and its manufacture method, it is to mix ceramic particle, organic binder and common carbon steel base, heat-resistant steel base or nickel base powder, press into the prefabricated block of required shape, set In the part of the casting mold that needs to be strengthened, it is enough to pour metal. The above two inventions are similar to the present invention, and the biggest difference is that the composite materials made by the above two methods are not resistant to thermal fatigue. Service life; CN101422814A discloses a preparation method of a local composite wear-resistant material, which uses high-alloy powder core tube wire, and cuts, rolls or superimposes a similar structure according to the shape of the workpiece surface; according to the casting process, the The prepared high-alloy powder core tube wire is pre-embedded in the sand mold cavity, and the base metal material is smelted and poured to obtain the required composite material. The disadvantage of this method is that it is easy to form slag inclusion defects, the process controllability is poor when used in actual production, and it is not suitable for large-scale industrial production.

发明内容 Contents of the invention

本发明的目的在于克服现有技术的不足,提供一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,制备能满足各种磨损、激冷激热等复杂工况下使用的高性能复合材料。 The purpose of the present invention is to overcome the deficiencies of the prior art, to provide a method for preparing a wear-resistant layered particle-reinforced composite material that is resistant to thermal fatigue, and to prepare a high performance composites.

本发明通过下列技术方案实现:一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,经过下列各步骤: The present invention is achieved through the following technical solutions: a method for preparing a heat-fatigue-resistant wear-resistant layered particle-reinforced composite material, through the following steps:

(1)将镍基自熔合金粉末与硬质陶瓷颗粒混合均匀,加入粘结剂,制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为5~25%;粘结剂占预制块的体积分数为2~4%; (1) Mix the nickel-based self-fluxing alloy powder and hard ceramic particles evenly, add a binder to make a prefabricated block, wherein the volume fraction of the nickel-based self-fluxing alloy powder accounts for 5-25% of the prefabricated block; bonding The volume fraction of the agent in the prefabricated block is 2-4%;

(2)采用常规砂型铸造或消失模铸造,再熔炼基材金属材料至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。 (2) Using conventional sand casting or lost foam casting, and then melting the base metal material to the pouring temperature, pouring it into the cavity with the prefabricated block obtained in step (1), cooling and solidifying at room temperature, and cleaning the sand. That is, a wear-resistant layered particle-reinforced composite material composed of a heat-fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained.

所述步骤(1)的硬质陶瓷颗粒是碳化硅、碳化钨、氮化硅、氮化钛中的一种或任意几种;当硬质陶瓷颗粒是两种或两种以上时,各种硬质陶瓷颗粒的粒度相同。 The hard ceramic particles in the step (1) are one or more of silicon carbide, tungsten carbide, silicon nitride, and titanium nitride; when there are two or more kinds of hard ceramic particles, various Hard ceramic particles have the same particle size.

所述步骤(1)的硬质陶瓷颗粒的粒径为-40~+80目。 The particle size of the hard ceramic particles in the step (1) is -40-+80 mesh.

所述步骤(1)的镍基自熔合金粉末是Ni25A、Ni25B、Ni35A、Ni45A、Ni55A、Ni60B、Ni60CuMo、Ni60CuMoW、Ni65、Ni25WC35、Ni6025WC、Ni6035WC或Ni6040WC。 The nickel-based self-fluxing alloy powder in the step (1) is Ni25A, Ni25B, Ni35A, Ni45A, Ni55A, Ni60B, Ni60CuMo, Ni60CuMoW, Ni65, Ni25WC35, Ni6025WC, Ni6035WC or Ni6040WC.

所述步骤(1)的镍基自熔合金粉末的粒径为-150~+200目。 The particle size of the nickel-based self-fluxing alloy powder in the step (1) is -150-+200 mesh.

所述步骤(1)的粘结剂是聚乙烯醇(PVA)或水玻璃。 The binder in the step (1) is polyvinyl alcohol (PVA) or water glass.

所述步骤(2)中的砂型铸造,是将预制块预埋入按照铸造工艺要求制作的砂型型腔中,再进行浇注。 The sand mold casting in the step (2) is to pre-embed the prefabricated block in the sand mold cavity made according to the requirements of the casting process, and then pour it.

所述砂型采用树脂砂或水玻璃砂制成,按铸造工艺制作浇冒口。 The sand mold is made of resin sand or water glass sand, and the pouring riser is made according to the casting process.

所述步骤(2)中的消失模铸造,是根据耐磨件的形状结构使用切割或发泡的方法制成可气化的泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再进行浇注。 The lost foam casting in the step (2) is to make a gasifiable foam model by cutting or foaming according to the shape and structure of the wear-resistant parts, and coat the prefabricated blocks on the wear-resistant parts to withstand thermal cycles and wear surface, and pouring.

所述消失模的泡沫模型采用聚苯乙烯(EPS)或聚甲基丙烯酸甲酯(PMMA)制成。 The foam model of the lost foam is made of polystyrene (EPS) or polymethyl methacrylate (PMMA).

所述步骤(2)中的基材金属材料是普通碳钢、合金钢或高锰钢。 The base metal material in the step (2) is ordinary carbon steel, alloy steel or high manganese steel.

和现有技术相比,本发明具有以下有益效果: Compared with the prior art, the present invention has the following beneficial effects:

1、由于碳化硅、碳化钨、氮化硅、氮化钛等陶瓷颗粒具有很高的硬度,一般是传统金属耐磨材料硬度的8~10倍,因此复合到导卫板表面后,能够成为良好的抗磨硬质相,以抵制物料在导卫板表面运动时对导卫板的切削和凿削,提高导卫板的使用寿命,比普通导卫板提高3~5倍。 1. Due to the high hardness of silicon carbide, tungsten carbide, silicon nitride, titanium nitride and other ceramic particles, which are generally 8 to 10 times the hardness of traditional metal wear-resistant materials, after being compounded on the surface of the guide plate, it can become Good anti-wear hard phase, to resist the cutting and chiseling of the guide plate when the material moves on the surface of the guide plate, and improve the service life of the guide plate, which is 3 to 5 times higher than that of the ordinary guide plate.

2、由于镍基自熔合金粉末高温性能较好,加入适量体积分数的粉末后,可以改善复合材料导板复合层中基体的组织,使其耐热疲劳性能显著提高,还可以对陶瓷颗粒提供良好的支撑作用,避免了复合材料复合层在使用时发生陶瓷颗粒脱落的现象。 2. Since the nickel-based self-fluxing alloy powder has good high-temperature performance, adding an appropriate volume fraction of the powder can improve the structure of the matrix in the composite layer of the composite material guide plate, significantly improve the thermal fatigue resistance, and provide good protection for the ceramic particles. The supporting function avoids the shedding of ceramic particles in the composite material composite layer during use.

3、复合层厚度可根据实际工况条件需要,在2~6mm范围内进行自由设计,实现对需要在激冷激热工况下使用的耐磨件的生产成本进行控制,获得很高的性价比。 3. The thickness of the composite layer can be freely designed in the range of 2-6mm according to the actual working conditions, so as to control the production cost of the wear-resistant parts that need to be used in the hot and cold working conditions, and obtain a high cost performance .

4、本发明的复合制备工艺可控性强,操作简便,成品率高,整体性能高,生产质量稳定,耐热疲劳的层状复合耐磨层与基材金属层形成良好的冶金结合,能广泛应用于矿山、电力、冶金、煤炭、建材等耐热疲劳及耐磨领域,便于工业化大规模生产。 4. The composite preparation process of the present invention is highly controllable, easy to operate, high in yield, high in overall performance, stable in production quality, and has a good metallurgical bond between the heat-fatigue-resistant layered composite wear-resistant layer and the base metal layer, which can Widely used in mining, electric power, metallurgy, coal, building materials and other thermal fatigue and wear resistance fields, it is convenient for large-scale industrial production.

附图说明 Description of drawings

图1是实施例1锤头制备过程的浇注示意图; Fig. 1 is the pouring schematic diagram of embodiment 1 hammer head preparation process;

图2是实施例1所得复合材料锤头的剖视结构示意图; Fig. 2 is the sectional structure schematic diagram of the composite material tup of gained of embodiment 1;

图3是实施例1所得复合材料锤头热循环前的金相组织图; Fig. 3 is the metallographic structure figure before embodiment 1 gained composite hammer head heat cycle;

图4是实施例1所得复合材料锤头热循环60次的金相组织图; Fig. 4 is the metallographic structure diagram of embodiment 1 gained composite material hammer thermal cycle 60 times;

图5是图2中A区域的局部放大图。 Fig. 5 is a partially enlarged view of area A in Fig. 2 .

图中1为预制块,2为造型用砂,3为型腔,4为基材金属,5为复合层。 In the figure, 1 is a prefabricated block, 2 is sand for molding, 3 is a cavity, 4 is a base metal, and 5 is a composite layer.

具体实施方式 Detailed ways

下面通过实施例并结合附图对本发明作进一步详细说明。 The present invention will be described in further detail below through the embodiments and in conjunction with the accompanying drawings.

实施例1 Example 1

(1)将粒径为150目的Ni6025WC粉末与粒径为-40~+60目的碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块(如图1中标号1),其中,镍基自熔合金粉末占预制块的体积分数为15%;粘结剂占预制块的体积分数为2%; (1) Mix Ni6025WC powder with a particle size of 150 mesh and tungsten carbide particles with a particle size of -40 to +60 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block (label 1 in Figure 1), among which, The volume fraction of nickel-based self-fluxing alloy powder in the prefabricated block is 15%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规消失模铸造,根据耐磨件的形状结构使用切割的方法采用聚苯乙烯(EPS)制成的可气化的锤头泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼合金钢Cr15高铬钢至浇注温度1580℃后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头(如图2)。 (2) Adopt conventional lost foam casting, use the cutting method according to the shape and structure of the wear-resistant parts, use a gasifiable hammer head foam model made of polystyrene (EPS), and coat the prefabricated blocks on the wear-resistant parts to withstand heat Circulation and wear on the surface, and then melting the alloy steel Cr15 high chromium steel to the pouring temperature of 1580 ° C, pouring it into the cavity with the prefabricated block obtained in step (1), cooling and solidifying at room temperature, and cleaning the sand to obtain The wear-resistant layered particle-reinforced composite material hammer head is composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer (see Figure 2).

从制成的锤头上切割出热震试样,热震前试样的金相组织如图3所示,然后将试样进行60次热循环,同一位置处的金相组织如图4所示。表明材料在激冷激热条件下,仍没有产生影响其性能的致命裂纹。 The thermal shock sample was cut from the hammer head, the metallographic structure of the sample before thermal shock is shown in Figure 3, and then the sample was subjected to 60 thermal cycles, the metallographic structure at the same position is shown in Figure 4 Show. It shows that the material has no fatal cracks affecting its performance under the conditions of severe cooling and heating.

实施例2 Example 2

(1)将粒径为180目的Ni25A粉末与粒径为40目的碳化硅和碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为10%;粘结剂占预制块的体积分数为2%; (1) Mix Ni25A powder with a particle size of 180 mesh and silicon carbide and tungsten carbide particles with a particle size of 40 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the prefabricated block The volume fraction of the binder is 10%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用树脂砂制成的锤头砂型型腔中,再熔炼高碳钢(普通碳钢)至浇注温度1580℃后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammerhead sand mold cavity made of resin sand according to the casting process requirements, and then high carbon steel (ordinary carbon steel) is smelted to a pouring temperature of 1580 °C, and then Pour into the cavity with the prefabricated block obtained in step (1), cool and solidify at room temperature, and after sand cleaning treatment, a heat-resistant fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer are obtained. Grinding layered particle reinforced composite hammer.

实施例3 Example 3

(1)将粒径为200目的Ni25B粉末与粒径为60目的碳化硅和碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为15%;粘结剂占预制块的体积分数为2%; (1) Mix Ni25B powder with a particle size of 200 mesh and silicon carbide and tungsten carbide particles with a particle size of 60 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the prefabricated block The volume fraction of the prefabricated block is 15%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用水玻璃砂制成的锤头砂型型腔中,再熔炼高碳钢(普通碳钢)至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammerhead sand mold cavity made of water glass sand according to the casting process requirements, and then the high carbon steel (ordinary carbon steel) is melted to the pouring temperature, and then poured Put it into the cavity with the prefabricated block obtained in step (1), cool and solidify at room temperature, and after sand cleaning treatment, a wear-resistant layer composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. Layered particle reinforced composite hammerhead.

实施例4 Example 4

(1)将粒径为-160目的Ni35A粉末与粒径为-60~+80目的碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为20%;粘结剂占预制块的体积分数为3%; (1) Mix Ni35A powder with a particle size of -160 mesh and tungsten carbide particles with a particle size of -60 to +80 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which nickel-based self-fluxing alloy powder accounts for The volume fraction of the prefabricated block is 20%; the volume fraction of the binder in the prefabricated block is 3%;

(2)采用消失模铸造,根据耐磨件的形状结构使用发泡的方法采用聚甲基丙烯酸甲酯(PMMA)制成的可气化的泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼合金钢Cr15高铬钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。 (2) The lost foam casting is adopted, and the foaming method is used according to the shape and structure of the wear-resistant parts. The gasifiable foam model made of polymethyl methacrylate (PMMA) is used to coat the prefabricated blocks on the wear-resistant parts. After heat cycle and worn surface, after melting alloy steel Cr15 high chromium steel to pouring temperature, it is poured into the cavity with the prefabricated block obtained in step (1), cooled and solidified at room temperature, and sand cleaning treatment is performed to obtain A wear-resistant layered particle-reinforced composite material composed of a heat-fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer.

实施例5 Example 5

(1)将粒径为-150~+170目的Ni45A粉末与粒径为80目的碳化钨、氮化硅和氮化钛颗粒混合均匀,加入水玻璃,制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为25%;粘结剂占预制块的体积分数为4%; (1) Mix Ni45A powder with a particle size of -150 to +170 mesh and tungsten carbide, silicon nitride and titanium nitride particles with a particle size of 80 mesh evenly, add water glass, and make a prefabricated block, in which the nickel-based self-fluxing The volume fraction of the alloy powder in the prefabricated block is 25%; the volume fraction of the binder in the prefabricated block is 4%;

(2)采用常规消失模铸造,根据耐磨件的形状结构使用发泡的方法采用聚苯乙烯(EPS)制成的可气化的泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼合金钢Cr15高铬钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。 (2) Conventional lost foam casting is adopted, and the foaming method is used according to the shape and structure of the wear-resistant parts. A gasifiable foam model made of polystyrene (EPS) is used to coat the prefabricated blocks on the wear-resistant parts to withstand thermal cycles. and the worn surface, after melting the alloy steel Cr15 high chromium steel to the pouring temperature, it is poured into the cavity with the prefabricated block obtained in step (1), cooled and solidified at room temperature, and the heat-resistant A wear-resistant layered particle-reinforced composite material composed of a fatigue layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer.

实施例6 Example 6

(1)将粒径为180目的Ni55A粉末与粒径为40目的氮化钛颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为5%;粘结剂占预制块的体积分数为2%; (1) Mix Ni55A powder with a particle size of 180 mesh and titanium nitride particles with a particle size of 40 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the volume of the prefabricated block The fraction is 5%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用树脂砂制成的锤头砂型型腔中,再熔炼合金钢Cr15高铬钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammerhead sand mold cavity made of resin sand according to the casting process requirements, and then the alloy steel Cr15 high chromium steel is melted to the pouring temperature, and then poured into the In the cavity of the prefabricated block obtained in step (1), cool and solidify at room temperature, and after sand cleaning treatment, wear-resistant layered particles composed of a layered composite wear-resistant layer resistant to thermal fatigue, a metallurgical transition layer, and a base metal layer are obtained Reinforced composite hammer head.

实施例7 Example 7

(1)将粒径为200目的Ni60B粉末与粒径为60目的碳化硅和碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为15%;粘结剂占预制块的体积分数为2%; (1) Mix Ni60B powder with a particle size of 200 mesh and silicon carbide and tungsten carbide particles with a particle size of 60 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the prefabricated block The volume fraction of the prefabricated block is 15%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用水玻璃砂制成的锤头砂型型腔中,再熔炼40Cr低合金钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammer head sand mold cavity made of water glass sand according to the casting process requirements, and then smelted 40Cr low alloy steel to the pouring temperature, pouring it into the step (1) In the cavity of the obtained prefabricated block, it is cooled and solidified at room temperature, and after sand cleaning treatment, a wear-resistant layered particle reinforcement composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. Composite Hammer.

实施例8 Example 8

(1)将粒径为-160目的Ni60CuMo粉末与粒径为-60~+80目的碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为22%;粘结剂占预制块的体积分数为3%; (1) Mix Ni60CuMo powder with a particle size of -160 mesh and tungsten carbide particles with a particle size of -60 to +80 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which nickel-based self-fluxing alloy powder accounts for The volume fraction of the prefabricated block is 22%; the volume fraction of the binder in the prefabricated block is 3%;

(2)采用消失模铸造,根据耐磨件的形状结构使用发泡的方法采用聚甲基丙烯酸甲酯(PMMA)制成的可气化的泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼40Cr低合金钢至浇注温度1580℃后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。 (2) The lost foam casting is adopted, and the foaming method is used according to the shape and structure of the wear-resistant parts. The gasifiable foam model made of polymethyl methacrylate (PMMA) is used to coat the prefabricated blocks on the wear-resistant parts. After heat cycle and worn surface, smelt 40Cr low-alloy steel to pouring temperature of 1580°C, then pour it into the cavity with the prefabricated block obtained in step (1), cool and solidify at room temperature, and perform sand cleaning treatment to obtain A wear-resistant layered particle-reinforced composite material composed of a heat-fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer.

实施例9 Example 9

(1)将粒径为-150~+170目的Ni60CuMoW粉末与粒径为80目的碳化钨、氮化硅和氮化钛颗粒混合均匀,加入水玻璃,制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为25%;粘结剂占预制块的体积分数为4%; (1) Mix Ni60CuMoW powder with a particle size of -150 to +170 mesh and tungsten carbide, silicon nitride and titanium nitride particles with a particle size of 80 mesh evenly, add water glass to make a prefabricated block, in which the nickel-based self-melting The volume fraction of the alloy powder in the prefabricated block is 25%; the volume fraction of the binder in the prefabricated block is 4%;

(2)采用常规消失模铸造,根据耐磨件的形状结构使用发泡的方法采用聚苯乙烯(EPS)制成的可气化的导卫板泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼高锰钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料导卫板。 (2) Adopt conventional lost foam casting, use the foaming method according to the shape and structure of the wear-resistant parts, use polystyrene (EPS) to make a gasifiable guide plate foam model, and coat the prefabricated blocks on the wear-resistant parts On the surface that is subjected to heat cycle and wear, after melting the high manganese steel to the pouring temperature, it is poured into the cavity with the prefabricated block obtained in step (1), cooled and solidified at room temperature, and after sand cleaning, the heat-resistant A wear-resistant layered particle-reinforced composite material guide plate composed of a fatigue layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer.

实施例10 Example 10

(1)将粒径为180目的Ni65粉末与粒径为40目的氮化钛颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为5%;粘结剂占预制块的体积分数为2%; (1) Mix Ni65 powder with a particle size of 180 mesh and titanium nitride particles with a particle size of 40 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the volume of the prefabricated block The fraction is 5%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用树脂砂制成的导卫板砂型型腔中,再熔炼高锰钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料导卫板。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the sand mold cavity of the guide plate made of resin sand according to the casting process requirements, and then the high manganese steel is melted to the pouring temperature, and then it is poured into the step ( 1) In the cavity of the obtained prefabricated block, it is cooled and solidified at room temperature, and after sand cleaning treatment, a wear-resistant layered particle-reinforced composite composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. Material guides.

实施例11 Example 11

(1)将粒径为200目的Ni25WC35粉末与粒径为60目的碳化硅和碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为15%;粘结剂占预制块的体积分数为2%; (1) Mix Ni25WC35 powder with a particle size of 200 mesh and silicon carbide and tungsten carbide particles with a particle size of 60 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the prefabricated block The volume fraction of the prefabricated block is 15%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用水玻璃砂制成的锤头砂型型腔中,再熔炼高碳钢(普通碳钢)至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammerhead sand mold cavity made of water glass sand according to the casting process requirements, and then the high carbon steel (ordinary carbon steel) is melted to the pouring temperature, and then poured Put it into the cavity with the prefabricated block obtained in step (1), cool and solidify at room temperature, and after sand cleaning treatment, a wear-resistant layer composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. Layered particle reinforced composite hammerhead.

实施例12 Example 12

(1)将粒径为-150~+170目的Ni6035WC粉末与粒径为80目的碳化钨、氮化硅和氮化钛颗粒混合均匀,加入水玻璃,制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为25%;粘结剂占预制块的体积分数为4%; (1) Mix Ni6035WC powder with a particle size of -150~+170 mesh and tungsten carbide, silicon nitride and titanium nitride particles with a particle size of 80 mesh evenly, add water glass to make a prefabricated block, in which the nickel-based self-melting The volume fraction of the alloy powder in the prefabricated block is 25%; the volume fraction of the binder in the prefabricated block is 4%;

(2)采用常规消失模铸造,根据耐磨件的形状结构使用发泡的方法采用聚苯乙烯(EPS)制成的可气化的导卫板泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再熔炼高碳钢(普通碳钢)至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料导卫板。 (2) Adopt conventional lost foam casting, use the foaming method according to the shape and structure of the wear-resistant parts, use polystyrene (EPS) to make a gasifiable guide plate foam model, and coat the prefabricated blocks on the wear-resistant parts The surface subjected to heat cycle and wear is smelted with high carbon steel (ordinary carbon steel) to the pouring temperature, and then poured into the cavity with the prefabricated block obtained in step (1), cooled and solidified at room temperature, and sand-cleaned. That is, a wear-resistant layered particle-reinforced composite material guide plate composed of a heat-fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained.

实施例13 Example 13

(1)将粒径为200目的Ni6040WC粉末与粒径为60目的碳化硅和碳化钨颗粒混合均匀,加入聚乙烯醇(PVA),制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为15%;粘结剂占预制块的体积分数为2%; (1) Mix Ni6040WC powder with a particle size of 200 mesh and silicon carbide and tungsten carbide particles with a particle size of 60 mesh evenly, add polyvinyl alcohol (PVA) to make a prefabricated block, in which the nickel-based self-fluxing alloy powder accounts for the prefabricated block The volume fraction of the prefabricated block is 15%; the volume fraction of the binder in the prefabricated block is 2%;

(2)采用常规砂型铸造,将预制块预埋入按照铸造工艺要求采用水玻璃砂制成的锤头砂型型腔中,再熔炼40Cr低合金钢至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料锤头。 (2) Using conventional sand casting, the prefabricated block is pre-embedded in the hammer head sand mold cavity made of water glass sand according to the casting process requirements, and then smelted 40Cr low alloy steel to the pouring temperature, pouring it into the step (1) In the cavity of the obtained prefabricated block, it is cooled and solidified at room temperature, and after sand cleaning treatment, a wear-resistant layered particle reinforcement composed of a thermal fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. Composite Hammer.

Claims (9)

1.一种耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于经过下列各步骤: 1. A preparation method of a heat-resistant wear-resistant layered particle-reinforced composite material, characterized in that through the following steps: (1)将镍基自熔合金粉末与硬质陶瓷颗粒混合均匀,加入粘结剂,制成预制块,其中,镍基自熔合金粉末占预制块的体积分数为5~25%;粘结剂占预制块的体积分数为2~4%; (1) Mix the nickel-based self-fluxing alloy powder and hard ceramic particles evenly, add a binder to make a prefabricated block, wherein the volume fraction of the nickel-based self-fluxing alloy powder accounts for 5-25% of the prefabricated block; bonding The volume fraction of the agent in the prefabricated block is 2-4%; (2)采用常规砂型铸造或消失模铸造,再熔炼基材金属材料至浇注温度后,将其浇注入放有步骤(1)所得预制块的型腔中,室温冷却凝固,经清砂处理,即得到由耐热疲劳的层状复合耐磨层、冶金过渡层、基材金属层组成的耐磨层状颗粒增强复合材料。 (2) Using conventional sand casting or lost foam casting, and then melting the base metal material to the pouring temperature, pouring it into the cavity with the prefabricated block obtained in step (1), cooling and solidifying at room temperature, and cleaning the sand. That is, a wear-resistant layered particle-reinforced composite material composed of a heat-fatigue-resistant layered composite wear-resistant layer, a metallurgical transition layer, and a base metal layer is obtained. 2.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(1)的硬质陶瓷颗粒是碳化硅、碳化钨、氮化硅、氮化钛中的一种或任意几种;当硬质陶瓷颗粒是两种或两种以上时,各种硬质陶瓷颗粒的粒度相同。 2. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the hard ceramic particles in the step (1) are silicon carbide, tungsten carbide, silicon nitride , titanium nitride or any several kinds; when there are two or more kinds of hard ceramic particles, the particle sizes of various hard ceramic particles are the same. 3.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(1)的硬质陶瓷颗粒的粒径为-40~+80目。 3. The method for preparing a thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the particle size of the hard ceramic particles in the step (1) is -40 to +80 mesh . 4.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(1)的镍基自熔合金粉末是Ni25A、Ni25B、Ni35A、Ni45A、Ni55A、Ni60B、Ni60CuMo、Ni60CuMoW、Ni65、Ni25WC35、Ni6025WC、Ni6035WC或Ni6040WC。 4. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the nickel-based self-fluxing alloy powder in the step (1) is Ni25A, Ni25B, Ni35A, Ni45A , Ni55A, Ni60B, Ni60CuMo, Ni60CuMoW, Ni65, Ni25WC35, Ni6025WC, Ni6035WC or Ni6040WC. 5.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(1)的镍基自熔合金粉末的粒径为-150~+200目。 5. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the particle size of the nickel-based self-fluxing alloy powder in the step (1) is -150~+ 200 mesh. 6.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(1)的粘结剂是聚乙烯醇或水玻璃。 6 . The method for preparing a thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1 , wherein the binder in the step (1) is polyvinyl alcohol or water glass. 7.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(2)中的砂型铸造,是将预制块预埋入按照铸造工艺要求制作的砂型型腔中,再进行浇注。 7. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the sand casting in the step (2) is to pre-embed the prefabricated blocks in accordance with the casting process It is required to make the sand mold cavity, and then pour it. 8.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(2)中的消失模铸造,是根据耐磨件的形状结构使用切割或发泡的方法制成可气化的泡沫模型,将预制块涂覆在耐磨件承受热循环及磨损的表面,再进行浇注。 8. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the lost foam casting in the step (2) is used according to the shape and structure of wear-resistant parts The method of cutting or foaming is used to make a gasifiable foam model, and the prefabricated block is coated on the surface of the wear-resistant part that is subjected to thermal cycle and wear, and then poured. 9.根据权利要求1所述的耐热疲劳的耐磨层状颗粒增强复合材料的制备方法,其特征在于:所述步骤(2)中的基材金属材料是普通碳钢、合金钢或高锰钢。 9. The preparation method of thermal fatigue-resistant wear-resistant layered particle-reinforced composite material according to claim 1, characterized in that: the base metal material in the step (2) is ordinary carbon steel, alloy steel or high-grade manganese steel.
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Application publication date: 20120627