CN102505822B - Ceramic tile with gold-plated surface and manufacturing method thereof - Google Patents
Ceramic tile with gold-plated surface and manufacturing method thereof Download PDFInfo
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- CN102505822B CN102505822B CN2011103057366A CN201110305736A CN102505822B CN 102505822 B CN102505822 B CN 102505822B CN 2011103057366 A CN2011103057366 A CN 2011103057366A CN 201110305736 A CN201110305736 A CN 201110305736A CN 102505822 B CN102505822 B CN 102505822B
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- gold
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- plated
- cream
- manufacturing
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- 239000000919 ceramic Substances 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000010931 gold Substances 0.000 claims abstract description 34
- 229910052737 gold Inorganic materials 0.000 claims abstract description 34
- 239000011449 brick Substances 0.000 claims abstract description 4
- 239000006071 cream Substances 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 239000002585 base Substances 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000006386 neutralization reaction Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000006004 Quartz sand Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007605 air drying Methods 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052637 diopside Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 3
- 238000003379 elimination reaction Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000004579 marble Substances 0.000 claims description 3
- NICDRCVJGXLKSF-UHFFFAOYSA-N nitric acid;trihydrochloride Chemical compound Cl.Cl.Cl.O[N+]([O-])=O NICDRCVJGXLKSF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims description 3
- 238000001694 spray drying Methods 0.000 claims description 3
- 239000010930 yellow gold Substances 0.000 claims description 3
- 229910001097 yellow gold Inorganic materials 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000010427 ball clay Substances 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 5
- 238000007747 plating Methods 0.000 abstract 4
- 210000003298 dental enamel Anatomy 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
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- Chemically Coating (AREA)
Abstract
The invention discloses a ceramic tile with a gold-plated surface. The ceramic tile consists of a blank body, an enamel layer and a surface plating layer, and is characterized in that the surface plating layer is a gold plating layer. The invention simultaneously discloses a manufacturing method of the ceramic tile with the gold-plated surface, wherein the manufacturing method comprises the following steps of: manufacturing a blank brick body, manufacturing molten gold, plating gold on the ceramic tile and the like. The ceramic tile with the gold-plated surface, which is manufactured by the manufacturing method disclosed by the invention, has the characteristics of excellent oxidation resistance, sudden cold and hot alternation resistance, wear resistance and the like, can be used for greatly enriching the effects and decorative effects of products and better showing luxurious, rich and honor effects in use.
Description
Technical field
The invention belongs to building material field, particularly relate to a kind of ceramic tile and manufacture method thereof of gold-plated surface.
Background technology
Along with the enhancing of china's overall national strength, the people's living standard improves constantly, and people have had higher requirement to the life class of oneself.Ceramic tile is as one of essential ornament materials of building trade, closely bound up with people's life especially.People, when decorating the family of oneself, focus on the lifting of class especially.When gold is all rich and honour, luxurious representative, very popular, and gold is incorporated to ceramic tile, has attracted especially customer's eyeball.Also really be not coated with the ceramic tile of gold in existing product.
Summary of the invention
The object of the invention is to provide a kind of surface to have ceramic tile and the manufacture method thereof of the gold-plated surface of gold color and luster sense for existing product.
The present invention for achieving the above object, adopts following technical scheme:
A kind of ceramic tile of gold-plated surface, it is by base substrate, and glaze layer and overlay coating form, and it is characterized in that: described overlay coating is gold coating.
The chief component of described base substrate, middle aluminum pyrophyllite: 10%～15%, high aluminum pyrophyllite: 20%～25%, diopside: 15%～20%, white clay soil: 15%～20%, kaolin: 15%～20%, quartz sand: 3%～5%, high-al clay: 8%～10%.
The chief component of described glaze layer glaze, zirconium white frit: 45%～50%, potassic feldspar: 15%～20%, dolomite: 5%～10%, kaolin: 20%～25%, ball clay: 10%～15%.
Described gold coating is that gold cream is plated to, its chief component, and gold: 8%～15%, chloroazotic acid: 30%～50%, thickener: 0.5%～2%, alcohol: 2%～5%, alkali: 30%～50%.
A kind of manufacture method of ceramic tile of gold-plated surface, comprise the following steps:
(1) plain adobe system is done:
Formula by each raw material, put in ball mill and ground in proportion, fineness of grind leaks into heavy rotten 24h in mud pit by mud after reaching 5.5 ± 0.5g/100ml, again by 580 ℃ of heated-air dryings of spray drying tower, form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h, carry out operations for forming through tape transport to press, be pressed into base substrate and carry out after drying glazing, printing, reentering kiln is burnt till, firing temperature is controlled at 1180 ± 10 ℃, and firing period, at 65min, is made plain brick;
(2) making of gold cream: the true yellow gold is dissolved in wang aqueous solution according to formula, carry out neutralization reaction with alkali again after fully dissolving, carry out rinsing with alcohol after neutralization reaction is complete, after standing 8h, filtered, the viscosity number that adds thickener to be adjusted to requirement after elimination impurity gets final product, and viscosity number is controlled at the 800pas left and right;
(3) ceramic tile is gold-plated:
Pattern is made to half tone, gold cream is printed on to ceramic tile surface with rubber squeegee, a kind of mode prints to gold cream on transferable paper, the marble paper that will be printed on again gold cream is plated to ceramic tile surface, the ceramic tile that is coated with gold cream is burnt till, solidified through 800 ℃ of low temperature, with the ceramic tile surface fusion, become the gold-plated ceramic tile of the present invention.
The ceramic tile of gold-plated surface of the present invention has good anti-oxidant, and the anti-characteristic such as sometimes hot and sometimes cold, wear-resisting has been enriched effect, the decoration of product greatly, uses and more can embody the effect of luxury, wealth and rank.
The accompanying drawing explanation
Fig. 1 is schematic diagram of the present invention;
1, idiosome; 2, glaze layer; 3, overlay coating.
The specific embodiment
A kind of ceramic tile of gold-plated surface as shown in Figure 1, it is by base substrate 1, and glaze layer 2 and overlay coating 3 form, and described overlay coating is gold coating.
The concrete manufacture method of the present invention is as follows:
1, the base substrate constitutive material is coordinated in following ratio: middle aluminum pyrophyllite: 10%～15%, high aluminum pyrophyllite: 20%～25%, diopside: 15%～20%, white clay soil: 15%～20%, kaolin: 15%～20%, quartz sand: 3%～5%, high-al clay: 8%～10%.Put in ball mill and ground, fineness of grind leaks into heavy rotten 24h in mud pit by mud after reaching 5.5 ± 0.5g/100ml, again by 580 ℃ of heated-air dryings of spray drying tower, form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h, carry out operations for forming through tape transport to press, be pressed into base substrate and carry out after drying glazing, printing, reenter kiln and burnt till, firing temperature is controlled at 1180 ± 10 ℃, firing period, at 65min, is made plain brick.
2, the constitutive material of gold cream is coordinated in following ratio: gold: 8%～15%, chloroazotic acid: 30%～50%, thickener: 0.5%～2%, alcohol: 2%～5%, alkali: 30%～50%.The true yellow gold is dissolved in wang aqueous solution according to formula, carry out neutralization reaction with alkali again after fully dissolving, carry out rinsing with alcohol after neutralization reaction is complete, after standing 8h, filtered, the viscosity number that adds thickener to be adjusted to requirement after elimination impurity gets final product, viscosity number is controlled at 800pas, makes gold cream.
3, glazing on base substrate, burn till rear one-tenth biscuit.
4, prepared gold cream is plated in to top layer, carry out as follows: pattern is made to half tone, gold cream is printed on to ceramic tile surface with rubber squeegee, a kind of mode prints to gold cream on transferable paper, the marble paper that will be printed on again gold cream is plated to ceramic tile surface, the ceramic tile that is coated with gold cream is burnt till, solidified through 800 ℃ of low temperature, with the ceramic tile surface fusion, become the gold-plated ceramic tile of the present invention.
Claims (4)
1. the ceramic tile of a gold-plated surface, it is by base substrate, and glaze layer and overlay coating form, and it is characterized in that: described overlay coating is gold coating; The chief component of described base substrate, middle aluminum pyrophyllite: 10%～15%, high aluminum pyrophyllite: 20%～25%, diopside: 15%～20%, white clay soil: 15%～20%, kaolin: 15%～20%, quartz sand: 3%～5%, high-al clay: 8%～10%.
2. the ceramic tile of a kind of gold-plated surface according to claim 1, is characterized in that: the chief component of described glaze layer glaze, zirconium white frit: 45%～50%, potassic feldspar: 15%～20%, dolomite: 5%～10%, kaolin: 20%～25%, ball clay: 10%～15%.
3. the ceramic tile of a kind of gold-plated surface according to claim 1, it is characterized in that: described gold coating is that gold cream is plated to, its chief component, gold: 8%～15%, chloroazotic acid: 30%～50%, thickener: 0.5%～2%, alcohol: 2%～5%, alkali: 30%～50%.
4. the manufacture method of the ceramic tile of a gold-plated surface, comprise the following steps:
(1) plain adobe system is done:
Formula by each raw material, put in ball mill and ground in proportion, fineness of grind leaks into heavy rotten 24h in mud pit by mud after reaching 5.5 ± 0.5g/100ml, again by 580 ℃ of heated-air dryings of spray drying tower, form moisture content at 5.8 ± 0.3% powder particle, reenter the powder bucket and store heavy rotten 24h, carry out operations for forming through tape transport to press, be pressed into base substrate and carry out after drying glazing, printing, reentering kiln is burnt till, firing temperature is controlled at 1180 ± 10 ℃, and firing period, at 65min, is made plain brick;
(2) making of gold cream:
The true yellow gold is dissolved in wang aqueous solution according to formula, carry out neutralization reaction with alkali again after fully dissolving, after neutralization reaction is complete, with alcohol, carry out rinsing, filtered after standing 8h, the viscosity number that adds thickener to be adjusted to requirement after elimination impurity gets final product, and viscosity number is controlled at the 800pas left and right;
(3) ceramic tile is gold-plated:
Pattern is made to half tone, gold cream is printed on to ceramic tile surface with rubber squeegee, a kind of mode prints to gold cream on transferable paper, the marble paper that will be printed on again gold cream is plated to ceramic tile surface, the ceramic tile that is coated with gold cream is burnt till, solidified through 800 ℃ of low temperature, with the ceramic tile surface fusion, become the gold-plated ceramic tile of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103057366A CN102505822B (en) | 2011-10-11 | 2011-10-11 | Ceramic tile with gold-plated surface and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103057366A CN102505822B (en) | 2011-10-11 | 2011-10-11 | Ceramic tile with gold-plated surface and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102505822A CN102505822A (en) | 2012-06-20 |
| CN102505822B true CN102505822B (en) | 2013-12-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011103057366A Active CN102505822B (en) | 2011-10-11 | 2011-10-11 | Ceramic tile with gold-plated surface and manufacturing method thereof |
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| Country | Link |
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| CN (1) | CN102505822B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104150871B (en) * | 2014-08-06 | 2016-05-18 | 朱玉华 | The Ceramic Tiles that a kind of fullerene strengthens |
| CN104193292B (en) * | 2014-08-06 | 2016-07-06 | 佛山市金环球陶瓷有限公司 | The Ceramic Tiles that a kind of CNT strengthens |
| CN104999821A (en) * | 2015-07-10 | 2015-10-28 | 祥和彩瓷制造(上海)有限公司 | Preparation method of high-temperature friction gold stained paper and high-temperature friction gold stained paper |
| CN111960672A (en) * | 2020-07-08 | 2020-11-20 | 湖南省醴陵市特种电瓷电器有限公司 | Glaze for 95 porcelain surface, 95 porcelain and manufacturing method |
| CN112405795A (en) * | 2020-11-30 | 2021-02-26 | 王金听 | Preparation method of Jun porcelain with metal patterns on surface |
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| WO1990011985A1 (en) * | 1989-04-04 | 1990-10-18 | Hatten Limited | Surface treatment method for ceramic articles |
| CN2206291Y (en) * | 1994-04-29 | 1995-08-30 | 金晖 | Multicolour ceramic tile with titanium-plating chemical compound on surface |
| CN1219521A (en) * | 1997-12-10 | 1999-06-16 | 董英助 | Method for coating precious metal on ceramic tile surface |
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| CN202299247U (en) * | 2011-10-11 | 2012-07-04 | 信益陶瓷(中国)有限公司 | Ceramic tile coated with gold |
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2011
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| CN102505822A (en) | 2012-06-20 |
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Effective date of registration: 20170629 Address after: 234000, No. three, No. 228, Jin Jiang Road, Suzhou Economic Development Zone, Anhui Patentee after: Champion building materials (Anhui) Co., Ltd. Address before: 215300, No. 8, Feng Feng Road, Yushan Town, Kunshan, Jiangsu, Suzhou Patentee before: Xinyi Ceramic (China) Co., Ltd. |
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Effective date of registration: 20200911 Address after: Building 7, No.8, Yuanfeng Road, Yushan Town, Kunshan City, Suzhou City, Jiangsu Province Patentee after: Seagull champion Limited Address before: 234000 Jin Jiang three road, Suzhou Economic Development Zone, Anhui 228 Patentee before: CHAMPION BUILDING MATERIAL (ANHUI) Co.,Ltd. |
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