CN102504663A - Color layer paint and PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) - Google Patents
Color layer paint and PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) Download PDFInfo
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- CN102504663A CN102504663A CN2011103844380A CN201110384438A CN102504663A CN 102504663 A CN102504663 A CN 102504663A CN 2011103844380 A CN2011103844380 A CN 2011103844380A CN 201110384438 A CN201110384438 A CN 201110384438A CN 102504663 A CN102504663 A CN 102504663A
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- Prior art keywords
- pet
- chromatograph
- color layer
- transfer film
- pvc
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- 238000012546 transfer Methods 0.000 title claims abstract description 20
- -1 polyethylene terephthalate Polymers 0.000 title claims abstract description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 title abstract description 27
- 239000005020 polyethylene terephthalate Substances 0.000 title abstract 8
- 229920000915 polyvinyl chloride Polymers 0.000 title abstract 5
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 5
- 239000003973 paint Substances 0.000 title abstract 4
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 238000000576 coating method Methods 0.000 claims abstract description 22
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 16
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims description 13
- 239000000975 dye Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 210000002469 basement membrane Anatomy 0.000 claims description 8
- 239000012764 mineral filler Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 235000013872 montan acid ester Nutrition 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- IAFBRPFISOTXSO-UHFFFAOYSA-N 2-[[2-chloro-4-[3-chloro-4-[[1-(2,4-dimethylanilino)-1,3-dioxobutan-2-yl]diazenyl]phenyl]phenyl]diazenyl]-n-(2,4-dimethylphenyl)-3-oxobutanamide Chemical compound C=1C=C(C)C=C(C)C=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=C(C)C=C1C IAFBRPFISOTXSO-UHFFFAOYSA-N 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 3
- LVOJOIBIVGEQBP-UHFFFAOYSA-N 4-[[2-chloro-4-[3-chloro-4-[(5-hydroxy-3-methyl-1-phenylpyrazol-4-yl)diazenyl]phenyl]phenyl]diazenyl]-5-methyl-2-phenylpyrazol-3-ol Chemical compound CC1=NN(C(O)=C1N=NC1=CC=C(C=C1Cl)C1=CC(Cl)=C(C=C1)N=NC1=C(O)N(N=C1C)C1=CC=CC=C1)C1=CC=CC=C1 LVOJOIBIVGEQBP-UHFFFAOYSA-N 0.000 claims description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000002585 base Substances 0.000 abstract 3
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 230000006750 UV protection Effects 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 239000012170 montan wax Substances 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000007774 anilox coating Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- ZODDGFAZWTZOSI-UHFFFAOYSA-N nitric acid;sulfuric acid Chemical compound O[N+]([O-])=O.OS(O)(=O)=O ZODDGFAZWTZOSI-UHFFFAOYSA-N 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
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- Laminated Bodies (AREA)
Abstract
Color layer paint comprises 50-65 parts of acrylic resin, 20-35 parts of ethyl acetate, 5-15 parts of organic pigment, 0.3-2 part of UV (ultraviolet) absorbent, and 0.5-2 parts of inorganic filler. A PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) comprises a PET base film, a release layer coated on the PET base film, and a color layer formed by coating the release layer with the color layer paint, wherein the PET base film is 10-18 micrometers in thickness, and the release layer paint is made of montan wax, butanone and cyclohexanone according to a mass ratio 10:(6-9):(0.5-3). The color layer is thermally transferred onto a PVC board through the PET heat transfer film, and a product made has high ultraviolet resistance and acid and alkali resistance.
Description
Technical field
The present invention relates to a kind of chromatograph coating and chromatograph heat is transferred to the PET thermal transfer film on the PVC.
Background technology
The PET thermal transfer film that chromatograph heat is transferred on the PVC is mainly used in the house decorative material aspect, and shifting the look film is a kind of novel technology, and the present domestic material that can reach its processing requirement is very few, therefore possesses comparatively long-range development prospect.
The PET thermal transfer film that chromatograph heat is transferred on the PVC is on the PET film, to coat parting agent, on the basis of release layer, adds to be coated with colored organic adhesion agent, is heated on the sheet materials such as being transferred to PVC; PVC sheet material is protected; Be superior to its original performance, the PVC sheet material that shifts through processing since the surface how one deck fresh colour organic materials; Not only can give its magnificent outward appearance, the more important thing is to it has increased UV resistant, important physical and chemical performance such as weather-proof, high temperature resistant.
The UV resistant of the PET thermal transfer film that prior art is produced, weather-proof, high temperature resistant often not good, and in release layer or dope layer, used more noxious solvent, bigger to the hazard ratio of environment.
Summary of the invention
The purpose of this invention is to provide and a kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC.
The technical scheme that the present invention taked is:
A kind of chromatograph coating, the ETHYLE ACETATE of its vinyl resin by 50-65 part, 20-35 part, the pigment dyestuff of 5-15 part, the UV UV light absorber of 0.3-2 part, the mineral filler of 0.5-2 part are formed.
A kind of chromatograph coating, the ETHYLE ACETATE of its vinyl resin by 50-62 part, 21-30 part, the pigment dyestuff of 5-11 part, the UV UV light absorber of 0.3-1.5 part, the mineral filler of 0.7-1.5 part are formed.
A kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC; Its by the PET basement membrane, be coated on the epilamellar release layer of PET, be coated in the chromatograph that forms on the release layer with chromatograph coating and form; Wherein, The thickness of PET basement membrane is 10-18 μ m, and releasing layer coating is formed by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10: (6-9): (0.5-3).
Described mineral filler is at least a in 200-800 purpose silicon-dioxide, 200-800 purpose water-ground limestone, the 200-800 purpose talcum powder.
Described pigment dyestuff is at least a in phthalocyanine blue, phthalein viridescent, permanent yellow, permanent bordeaux, diarylide yellow, the benzidine orange.
Described UV UV light absorber is at least a among UV-P, UV-326, UV-327, UV-328, UV-329, UV-770, UV-531, UV-292, UV-320, the UV-360.
The invention has the beneficial effects as follows: the chromatograph heat of PET thermal transfer film of the present invention is transferred on the PVC sheet material, and the product that produces has UV resistant, acid-proof alkaline preferably.
Embodiment
A kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC; Its by the PET basement membrane, be coated on the epilamellar release layer of PET and the chromatograph that is coated on the release layer is formed; Wherein, The thickness of PET basement membrane is 10-18 μ m; Releasing layer coating is formed by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10: (6-9): (0.5-3), chromatograph coating is made up of the raw material of following mass parts: the UV UV light absorber of the ETHYLE ACETATE of the vinyl resin of 50-65 part, 20-35 part, the pigment dyestuff of 5-15 part, 0.3-2 part, the mineral filler of 0.5-2 part are formed.
Preferably; The thickness of PET basement membrane is 10-17.5 μ m; Releasing layer coating is formed by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10: (6.0-8.0): (0.5-2.5), chromatograph is made up of the raw material of following mass parts: the UV UV light absorber of the ETHYLE ACETATE of the vinyl resin of 50-62 part, 21-30 part, the pigment dyestuff of 5-11 part, 0.3-1.5 part, the mineral filler of 0.7-1.5 part are formed.
The preparation method of PET thermal transfer film is: respectively releasing layer coating, chromatograph coating are mixed according to proportioning raw materials; Utilize coating machine; Through smooth roll or anilox roll through forward or reversely successively releasing layer coating, chromatograph coating are coated on the PET basement membrane, in 80-120 ℃ of oven dry down.
Below in conjunction with specific embodiment system component of the present invention is done further explanation:
Embodiment 1:
Release layer is by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10:6:0.5.
Chromatograph coating gets raw material by following mass parts and forms: 50 parts vinyl resin, 21 parts ETHYLE ACETATE, 5 parts pigment dyestuff diarylide yellow, 0.3 part UV Ultraviolet Absorber UV-P, 0.7 part 200 order SiO
2
The thickness of used PET film is 10 μ m.
Embodiment 2:
Release layer is by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10:7:1.5.
Chromatograph coating gets raw material by following mass parts and forms: 58 parts vinyl resin, 25 parts ETHYLE ACETATE, 8 parts pigment dyestuff phthalein viridescent, 1.2 parts UV UV light absorber UV-327,1 part 800 order talcum powder.
The thickness of used PET film is 13.5 μ m.
Embodiment 3:
Release layer is by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10:8:2.5.
Chromatograph coating gets raw material by following mass parts and forms: 62 parts vinyl resin, 30 parts ETHYLE ACETATE, 11 parts pigment dyestuff phthalocyanine blue, 1.5 parts UV UV light absorber UV-360,1.5 parts 500 order water-ground limestones.
The thickness of used PET film is 17.5 μ m.
Performance Detection:
Through the chromatograph heat of the PET thermal transfer film of embodiment 1 being transferred to (technology that heat shifts is known technology) on the PVC sheet material, finished product is detected.
1. acid and alkali-resistance test: get each 100ml of solution of sulfuric acid nitric acid (pH=1) respectively with beaker, respectively get small pieces PVC sheet material finished product place respectively in the sulfuric acid salpeter solution, take out the transfer coated nondiscoloration of plate surface after 3 days in the condition held of normal temperature; Get sodium hydroxide solution (pH=14) with beaker, get a small pieces PVC sheet material finished product and place taking-up after 3 days in the alkali lye, the transfer coated nondiscoloration of plate surface.
2. UV resistant test: lighttight indoor in sealing, get PVC sheet material finished product a slice (A4 size), with the high voltage mercury lamp of 1000W, fluorescent tube and sheet material is apart from being 30cm, two days (corresponding proportion is about outdoor ultraviolet 1 year) of continuously irradiating, nondiscoloration.
The product that present method produces has UV resistant, acid-proof alkaline preferably.
Claims (6)
1. chromatograph coating, it is characterized in that: the ETHYLE ACETATE of its vinyl resin by 50-65 part, 20-35 part, the pigment dyestuff of 5-15 part, the UV UV light absorber of 0.3-2 part, the mineral filler of 0.5-2 part are formed.
2. chromatograph coating, it is characterized in that: the ETHYLE ACETATE of its vinyl resin by 50-62 part, 21-30 part, the pigment dyestuff of 5-11 part, the UV UV light absorber of 0.3-1.5 part, the mineral filler of 0.7-1.5 part are formed.
3. one kind is transferred to the PET thermal transfer film on the PVC with chromatograph heat; It is characterized in that: its by the PET basement membrane, be coated on the epilamellar release layer of PET, be coated in the chromatograph that forms on the release layer with the described chromatograph coating of claim 1 and form; Wherein, The thickness of PET basement membrane is 10-18 μ m, and releasing layer coating is formed by the preparation of raw material of following mass ratio: montanic acid ester type waxes: butanone: pimelinketone=10: (6-9): (0.5-3).
4. according to claim 3ly a kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC, it is characterized in that: described mineral filler is at least a in 200-800 purpose silicon-dioxide, 200-800 purpose water-ground limestone, the 200-800 purpose talcum powder.
5. according to claim 3ly a kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC, it is characterized in that: described pigment dyestuff is at least a in phthalocyanine blue, phthalein viridescent, permanent yellow, permanent bordeaux, diarylide yellow, the benzidine orange.
6. according to claim 3ly a kind of chromatograph heat is transferred to the PET thermal transfer film on the PVC, it is characterized in that: described UV UV light absorber is at least a among UV-P, UV-326, UV-327, UV-328, UV-329, UV-770, UV-531, UV-292, UV-320, the UV-360.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103844380A CN102504663A (en) | 2011-11-28 | 2011-11-28 | Color layer paint and PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103844380A CN102504663A (en) | 2011-11-28 | 2011-11-28 | Color layer paint and PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102504663A true CN102504663A (en) | 2012-06-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103844380A Pending CN102504663A (en) | 2011-11-28 | 2011-11-28 | Color layer paint and PET (polyethylene terephthalate) heat transfer film for thermally transferring color layer onto PVC (polyvinyl chloride) |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102504663A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103351718A (en) * | 2013-07-23 | 2013-10-16 | 黎国忠 | 3D stereoscopic printing ink, and transfer film provided with 3D stereoscopic decorative layer and made by same |
| CN107629603A (en) * | 2017-10-19 | 2018-01-26 | 武汉华工图像技术开发有限公司 | Wear-resisting chromatograph coating and the wear-resisting chromatograph of formation, wear-resisting anodized aluminium and preparation method thereof |
| CN107760214A (en) * | 2017-11-08 | 2018-03-06 | 上海三恩化工有限公司 | A kind of primary coat method shifted by PET film |
| CN109484049A (en) * | 2018-10-30 | 2019-03-19 | 上海马云标识有限公司 | A kind of anti-counterfeit package integral preparation process |
| CN111971185A (en) * | 2018-12-26 | 2020-11-20 | 李龙根 | Surface transfer printing method for polyester fiber acoustic board |
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|---|---|---|---|---|
| CN1383992A (en) * | 2001-04-17 | 2002-12-11 | 韩国化学株式会社 | Hot transfer piece and its making process |
| CN1837306A (en) * | 2005-03-22 | 2006-09-27 | 韩建华 | Plastic decorative coating and corresponding diluent |
| CN101581891A (en) * | 2007-05-11 | 2009-11-18 | 株式会社理光 | Toner, image forming apparatus, image forming method, and process cartridge using the toner |
-
2011
- 2011-11-28 CN CN2011103844380A patent/CN102504663A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1383992A (en) * | 2001-04-17 | 2002-12-11 | 韩国化学株式会社 | Hot transfer piece and its making process |
| CN1837306A (en) * | 2005-03-22 | 2006-09-27 | 韩建华 | Plastic decorative coating and corresponding diluent |
| CN101581891A (en) * | 2007-05-11 | 2009-11-18 | 株式会社理光 | Toner, image forming apparatus, image forming method, and process cartridge using the toner |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103351718A (en) * | 2013-07-23 | 2013-10-16 | 黎国忠 | 3D stereoscopic printing ink, and transfer film provided with 3D stereoscopic decorative layer and made by same |
| CN107629603A (en) * | 2017-10-19 | 2018-01-26 | 武汉华工图像技术开发有限公司 | Wear-resisting chromatograph coating and the wear-resisting chromatograph of formation, wear-resisting anodized aluminium and preparation method thereof |
| CN107760214A (en) * | 2017-11-08 | 2018-03-06 | 上海三恩化工有限公司 | A kind of primary coat method shifted by PET film |
| CN109484049A (en) * | 2018-10-30 | 2019-03-19 | 上海马云标识有限公司 | A kind of anti-counterfeit package integral preparation process |
| CN111971185A (en) * | 2018-12-26 | 2020-11-20 | 李龙根 | Surface transfer printing method for polyester fiber acoustic board |
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Application publication date: 20120620 |