CN102504180B - Special low-density PU (polyurethane) board for automobile roof - Google Patents
Special low-density PU (polyurethane) board for automobile roof Download PDFInfo
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- CN102504180B CN102504180B CN 201110297375 CN201110297375A CN102504180B CN 102504180 B CN102504180 B CN 102504180B CN 201110297375 CN201110297375 CN 201110297375 CN 201110297375 A CN201110297375 A CN 201110297375A CN 102504180 B CN102504180 B CN 102504180B
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- Prior art keywords
- plate
- low density
- roof
- parts
- special use
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- 239000004814 polyurethane Substances 0.000 title abstract description 39
- 229920002635 polyurethane Polymers 0.000 title abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 51
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 25
- 229920002545 silicone oil Polymers 0.000 claims abstract description 15
- 150000001412 amines Chemical class 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 9
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 34
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 17
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 claims description 6
- 150000002334 glycols Chemical class 0.000 claims description 4
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 230000002194 synthesizing effect Effects 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 14
- 239000006260 foam Substances 0.000 abstract description 3
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 10
- 239000011496 polyurethane foam Substances 0.000 description 10
- 241000197194 Bulla Species 0.000 description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 7
- 208000002352 blister Diseases 0.000 description 7
- 238000005187 foaming Methods 0.000 description 7
- 238000009775 high-speed stirring Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a special low-density PU (polyurethane) board for an automobile roof. The special low-density PU (polyurethane) board is characterized by being prepared from the following raw materials in parts by weight: 50-70 parts of polyether polyol, 20-30 parts of phthalic anhydride polyester polyol, 10-20 parts of high-functionality polyether polyol, 1-2 parts of hard foam silicone oil, 0.1-0.5 part of amine catalyst, 5-25 parts of foaming agent and 0.5-1.0 part of hole opening agent through the following steps: uniformly mixing the raw materials to prepare an A material; reacting the A material with 140-180 parts of crude MDI (methylene diphenyl diisocyanate) (isocyanate) to generate a large foam block; and slicing, so that the density of the PU board can be up to 15-25kg/m<3>. The special low-density PU board can be used as the automobile roof, and is strong in rigidity, good in dimension stability and low in cost.
Description
Technical field
The present invention relates to automotive trim polyurethane foam production technical field, is a kind of low density PU plate of roof of the vehicle special use specifically.
Background technology
Existing internal decoration of car ceiling mostly adopts the polyurethane foam board manufacturing method, and namely polyurethane foam board and non-woven fabrics, glass fibre, tackiness agent are combined into base material, through heating and mould pressing and the compound internal decoration of car ceiling that becomes of fabric.Along with the raising of production technology and reduce the demand of cost, low density PU plate more and more comes into one's own, and present low density PU plate exists the problems such as poor rigidity, dimensional stability are general to need to solve.
Summary of the invention
Summary of the invention:
The objective of the invention is to overcome the deficiency of above-mentioned prior art, and a kind of low density PU plate of roof of the vehicle special use is provided, mainly solve the problems such as existing low density PU plate poor rigidity and dimensional stability are general.
In order to achieve the above object, the present invention is achieved in that a kind of low density PU plate of roof of the vehicle special use, its special character is that it is made by the raw material of following weight proportioning: polyether glycol 50-70 part, benzoic anhydride polyester polyol 20-30 part, high functionality polyether glycol 10-20 part, hard bubble silicone oil 1-2 part, amines catalyst 0.1-0.5 part, whipping agent 5-25 part, pore-creating agent 0.5-1.0 part, thick MDI 140-180 part, described low density PU plate density range: 15-25kg/m3.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, it is made by the raw material of following optimum weight proportioning: 60 parts of polyether glycols, 25 parts of benzoic anhydride polyester polyols, 15 parts of high functionality polyether glycols, hard bubble 1.5 parts of silicone oil, 0.3 part of amines catalyst, 20 parts of whipping agents, 0.75 part of pore-creating agent, 160 parts of thick MDI.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described polyether glycol are two or more mixing among polyethers 350, polyethers 4110, polyethers 330N, polyethers 700, polyethers 3050, the polyethers ED-28.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described polyester polyol are one or both mixing among phthalic anhydride polyester 3152, the phthalic anhydride polyester DF380.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described silicone oil that hard bubbles are one or both mixing among AK-8805, AK-8835, L580, the HP-850.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described amines catalyst are one or both the combination among AS-33, C6608, HP305, the HP115.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described whipping agent are a kind of among water, HCFC-141b, the HFC-245fa.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described thick MDI are a kind of among PM-200,44V20, M20S, the MR-200.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described pore-creating agent is 501 tensio-active agents.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its described high functionality polyether glycol is take sucrose as initiator, the functionality 6-7 of synthesizing polyether.
The low density PU plate of a kind of roof of the vehicle special use of the present invention is on the basis of existing polyurethane foamed material, the silicone oil that hard bubbles that adds optimum proportion in its proportioning raw materials makes foam aperture evenly, in order, adding pore-creating agent makes the PU cystose possess perforate raising dimensional stability, add benzoic anhydride polyester polyol, can the Effective Raise tensile strength, add the high functionality polyether glycol, so that elongation at break and compressive strength improve.
The low density PU plate of a kind of roof of the vehicle special use of the present invention, its preparation method is to be mixed by polyether glycol, benzoic anhydride polyester polyol, high functionality polyether glycol, the silicone oil that hard bubbles, amines catalyst, whipping agent, pore-creating agent to make the A material, A material and thick MDI(isocyanic ester) react, foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, is cut into slices, make the low density PU plate of roof of the vehicle special use, the low density PU plate density of the roof of the vehicle special use of making is 15-25Kg/m3.
Compared with the prior art the low density PU plate of a kind of roof of the vehicle special use of the present invention has outstanding substantive distinguishing features and marked improvement, and its rigidity is strong, good stability of the dimension, and cost is low.
Embodiment:
For Comprehension and Implementation better, describe the present invention in detail below in conjunction with embodiment.
Embodiment 1, take by weighing exactly polyethers 330N and polyethers 4,110 70 Kg, benzoic anhydride polyester polyol DF380 20 Kg, high functionality polyether glycol 10 Kg, silicone oil AK-8805 1Kg hard bubbles, amines catalyst HP115 and AS-33 0.5Kg, whipping agent water 5.0 Kg, pore-creating agent A501 0.8 Kg, it is mixed make A material, the A material mixed high-speed stirring 30 seconds with PM-200 140 Kg, and foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, is cut into slices, and makes the low density PU plate of roof of the vehicle special use.
Embodiment 2, take by weighing exactly polyethers 3050, polyethers ED28 60 Kg, phthalic anhydride polyester DF380, benzoic anhydride polyester polyol 3152 30Kg, high functionality polyether glycol 10 Kg, silicone oil L-580 hard bubbles, AK-8835 2Kg, amines catalyst HP115 and C6608 0.1Kg, blowing agent H CFC-141b 20 Kg, pore-creating agent A501 0.6 Kg, it is mixed support A material, mixed high-speed stirring 40 seconds with 44,V20 160 Kg again, foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, cut into slices, make the low density PU plate of roof of the vehicle special use.
Embodiment 3, take by weighing exactly polyethers 700, polyethers 4110 50Kg, phthalic anhydride polyester 3,152 30 Kg, high functionality polyether glycol 20Kg, silicone oil HP850 1.5Kg hard bubbles, amines catalyst HP115 and HP305 0.3Kg, whipping agent water 5.0Kg, HFC-245fa 14 Kg, pore-creating agent A501 0.5 Kg, it is mixed and made into the A material, mixed high-speed stirring 45 seconds with M20S 180 Kg again, foaming becomes urethane bulla piece, and the polyurethane foam piece that plasticizing is good is cut edge, cut into slices, and makes the low density PU plate of roof of the vehicle special use.
Embodiment 4, take by weighing exactly polyethers 330N, polyethers 700, polyethers 350 65Kg, polyester polyol DF380 22 Kg, high functionality polyether glycol 13 Kg, silicone oil AK-8805 1.3 Kg hard bubble, amines catalyst AS-33, HP305, C6608 0.4Kg, whipping agent water 5.0Kg, HCFC-141b 10 Kg, pore-creating agent A501 1.0 Kg, it is mixed make A material, mixed high-speed stirring 35 seconds with MR-200 170 Kg again, foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, cut into slices, make the low density PU plate of roof of the vehicle special use.
Embodiment 5, take by weighing exactly polyethers 330N, polyethers 700 and polyethers 4,110 60 Kg, phthalic anhydride polyester DF380 25 Kg, high functionality polyether glycol 15 Kg, silicone oil AK-8805 and HP-850 1.5 Kg hard bubble, amines catalyst AS-33, C6608t HP305 0.3Kg, whipping agent water 10.0Kg, HCFC-141b 10 Kg, pore-creating agent A501 0.75 Kg, it is mixed make A material, mixed high-speed stirring 35 seconds with 44,V20 160 Kg again, foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, cut into slices, make the low density PU plate of roof of the vehicle special use.
Embodiment 6, take by weighing exactly polyethers 330N and polyethers 4,110 70 Kg, benzoic anhydride polyester polyol DF380 20 Kg, high functionality polyether glycol 10 Kg, silicone oil AK-8805 1Kg hard bubbles, amines catalyst HP115 and AS-33 0.1Kg, whipping agent water and HCFC-141b 25Kg, pore-creating agent A501 0.5 Kg, it is mixed make A material, the A material mixed high-speed stirring 30 seconds with PM-200 160 Kg, and foaming becomes urethane bulla piece, the polyurethane foam piece that plasticizing is good is cut edge, is cut into slices, and makes the low density PU plate of roof of the vehicle special use.
The key technical indexes that the PU plate of above embodiment reaches:
| Sequence number | Project | Index |
| 1 | Density (kg/m3) | 15-25 |
| 2 | Flexural strength (Mpa) | ≥180 |
| 3 | Compressive strength (Kpa) | ≥130 |
| 4 | Tensile strength (Kpa) | ≥160 |
| 5 | Elongation at break (%) | ≥10 |
Claims (2)
1. the low density PU plate of a roof of the vehicle special use, it is characterized in that it is made by the raw material of following weight proportioning: polyether glycol 50-70 part, benzoic anhydride polyester polyol 20-30 part, high functionality polyether glycol 10-20 part, hard bubble silicone oil 1-2 part, amines catalyst 0.1-0.5 part, whipping agent 5-25 part, pore-creating agent 0.5-1.0 part, thick MDI 140-180 part, described low density PU plate density range: 15-25kg/m3; Described high functionality polyether glycol is take sucrose as initiator, the functionality 6-7 of synthesizing polyether.
2. the low density PU plate of a kind of roof of the vehicle special use according to claim 1, it is characterized in that it is made by the raw material of following weight proportioning: 60 parts of polyether glycols, 25 parts of benzoic anhydride polyester polyols, 15 parts of high functionality polyether glycols, hard bubble 1.5 parts of silicone oil, 0.3 part of amines catalyst, 20 parts of whipping agents, 0.75 part of pore-creating agent, 160 parts of thick MDI.
3, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described polyether glycol is two or more mixing among polyethers 350, polyethers 4110, polyethers 330N, polyethers 700, polyethers 3050, the polyethers ED-28.
4, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described polyester polyol is one or both mixing among phthalic anhydride polyester 3152, the phthalic anhydride polyester DF380.
5, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that the described silicone oil that hard bubbles is one or both mixing among AK-8805, AK-8835, the HP-850.
6, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described amines catalyst is the mixing of two or three among AS-33, C6608, the HP115.
7, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described whipping agent is one or both mixing among water, HCFC-141b, the HFC-245fa.
8, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described thick MDI is a kind of among PM-200,44V20, M20S, the MR-200.
9, the low density PU plate of a kind of roof of the vehicle special use according to claim 1 and 2 is characterized in that described pore-creating agent is the A501 tensio-active agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110297375 CN102504180B (en) | 2011-09-29 | 2011-09-29 | Special low-density PU (polyurethane) board for automobile roof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110297375 CN102504180B (en) | 2011-09-29 | 2011-09-29 | Special low-density PU (polyurethane) board for automobile roof |
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| Publication Number | Publication Date |
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| CN102504180A CN102504180A (en) | 2012-06-20 |
| CN102504180B true CN102504180B (en) | 2013-04-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201110297375 Active CN102504180B (en) | 2011-09-29 | 2011-09-29 | Special low-density PU (polyurethane) board for automobile roof |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898815B (en) * | 2012-10-09 | 2014-08-13 | 烟台正海汽车内饰件有限公司 | Soft and light PU foam plate for automobile engine sound insulating pad |
| CN103342797A (en) * | 2013-07-16 | 2013-10-09 | 山东泽辉高科涂层有限公司 | Polyurethane resin for superfine fiber synthetic leather |
| CN104725587B (en) * | 2013-12-18 | 2018-01-30 | 上海东大聚氨酯有限公司 | A kind of polyurethane insulation coating renovation agent and its application and application method |
| CN104004152B (en) * | 2014-04-19 | 2016-06-08 | 上海东大化学有限公司 | Combined polyether, polyurethane insulation coating renovation agent and using method thereof |
| CN104448230B (en) * | 2014-12-29 | 2017-04-19 | 上海东大化学有限公司 | Premixed polyol and polyurethane sandwich panel made of premixed polyol |
| CN104693395A (en) * | 2015-01-27 | 2015-06-10 | 瀚寅(苏州)新材料科技有限公司 | Flame-retardant polyurethane material and preparation method thereof |
| CN105315423B (en) * | 2015-11-17 | 2018-01-30 | 山东一诺威新材料有限公司 | A kind of full water low density acoustic plate material of continous way type of production and preparation method thereof |
| CN106397710B (en) * | 2016-09-30 | 2019-01-01 | 上海东大聚氨酯有限公司 | Combined polyether, polyurethane raw material composition, foam and preparation method |
| CN107474211A (en) * | 2017-08-14 | 2017-12-15 | 华信博伟（安徽）车辆部件有限公司 | A kind of roof sound panel and preparation method thereof |
| CN109627746B (en) * | 2018-11-23 | 2021-04-06 | 贵州航天天马机电科技有限公司 | Large negative pressure polyurethane front end fragile protective cover and forming method thereof |
| CN112079985A (en) * | 2020-09-21 | 2020-12-15 | 长春富晟汽车饰件有限公司 | Polyurethane plate for automobile roof and preparation method thereof |
| CN114605954B (en) * | 2022-02-25 | 2024-02-13 | 南宁珀源能源材料有限公司 | High-adhesion and quick-boiling degumming double-component polyurethane adhesive, and preparation method and application thereof |
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| CN102093527A (en) * | 2010-12-30 | 2011-06-15 | 上海东大聚氨酯有限公司 | Composite polyether, polyurethane rigid foam as well as raw material composition and usage thereof |
| CN102174166A (en) * | 2011-01-20 | 2011-09-07 | 北京科聚化工新材料有限公司 | Thermoplastic semihard polyurethane foam for automobile ceiling and preparation method thereof |
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| JPS6330240A (en) * | 1986-07-24 | 1988-02-08 | Sekisui Chem Co Ltd | Preparation of sheet-shaped molding |
| JP3959092B2 (en) * | 2004-12-27 | 2007-08-15 | 住化バイエルウレタン株式会社 | Polyurethane molded product and method for producing the same |
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- 2011-09-29 CN CN 201110297375 patent/CN102504180B/en active Active
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| CN102093527A (en) * | 2010-12-30 | 2011-06-15 | 上海东大聚氨酯有限公司 | Composite polyether, polyurethane rigid foam as well as raw material composition and usage thereof |
| CN102174166A (en) * | 2011-01-20 | 2011-09-07 | 北京科聚化工新材料有限公司 | Thermoplastic semihard polyurethane foam for automobile ceiling and preparation method thereof |
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Address after: 265500 Shandong province Yantai Fushan High-tech Zone Xiangfu Street No. 57 Patentee after: Yantai Zheng Hai He Tai Science and Technology Co., Ltd. Address before: 265500 Shandong province Yantai Fushan High-tech Zone Xiangfu Street No. 57 Patentee before: Yantai Zhenghai Automotive Interior Co., Ltd. |
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Effective date of registration: 20180104 Address after: No. 4, Huimin Road, red sand Park, Shishan town, Nanhai District, Nanhai District, Foshan, Guangdong Patentee after: Foshan Zhenghai automotive interiors Co. Ltd. Address before: 265500 Shandong province Yantai Fushan High-tech Zone Xiangfu Street No. 57 Patentee before: Yantai Zheng Hai He Tai Science and Technology Co., Ltd. |
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