CN102492245A - Formula and method for producing wood-plastic composite material by utilizing waste polyvinyl chloride cable materials - Google Patents
Formula and method for producing wood-plastic composite material by utilizing waste polyvinyl chloride cable materials Download PDFInfo
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- CN102492245A CN102492245A CN2011104268082A CN201110426808A CN102492245A CN 102492245 A CN102492245 A CN 102492245A CN 2011104268082 A CN2011104268082 A CN 2011104268082A CN 201110426808 A CN201110426808 A CN 201110426808A CN 102492245 A CN102492245 A CN 102492245A
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- Prior art keywords
- polyvinyl chloride
- chloride cable
- plastic composite
- composite material
- waste polyvinyl
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- 239000000463 material Substances 0.000 title claims abstract description 56
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 53
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 53
- 239000002699 waste material Substances 0.000 title claims abstract description 39
- 229920001587 Wood-plastic composite Polymers 0.000 title claims abstract description 25
- 239000011155 wood-plastic composite Substances 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000002023 wood Substances 0.000 claims abstract description 17
- 239000002245 particle Substances 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 239000000344 soap Substances 0.000 claims abstract description 6
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 4
- 239000004902 Softening Agent Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical group [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 8
- 239000008116 calcium stearate Substances 0.000 claims description 8
- 235000013539 calcium stearate Nutrition 0.000 claims description 8
- 244000050510 Cunninghamia lanceolata Species 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 241000219000 Populus Species 0.000 claims description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 2
- 239000006084 composite stabilizer Substances 0.000 claims description 2
- -1 titanic acid ester Chemical class 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 abstract description 7
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 239000010791 domestic waste Substances 0.000 abstract description 2
- 239000004597 plastic additive Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 238000003672 processing method Methods 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 238000005096 rolling process Methods 0.000 description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 4
- 235000017491 Bambusa tulda Nutrition 0.000 description 4
- 241001330002 Bambuseae Species 0.000 description 4
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000011425 bamboo Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- CEKJAYFBQARQNG-UHFFFAOYSA-N cadmium zinc Chemical compound [Zn].[Cd] CEKJAYFBQARQNG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011978 dissolution method Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention particularly relates to a formula and a processing method for producing a wood-plastic composite material by utilizing waste polyvinyl chloride cable materials. The method comprises the following steps: adding raw materials, namely waste polyvinyl chloride cable particles, pure polyvinyl chloride powder, wood powder, a metal soap type stabilizer, a coupling agent, a plasticizer, chlorinated polyethylene, methacrylic acid polyester and a lubricating agent, which are prepared according to the formula, into a high-speed mixing machine for mixing, and adding the well mixed raw materials into an extruding machine for extrusion forming. The polyvinyl chloride raw materials adopted by the method are outer skins of the waste and old cables, which are obtained by disassembling the domestic waste, which is low in price and conductive to environment protection. Most of plastic additives adopted in the method are non-toxic or low-toxicity products, therefore the material hardly harms human bodies and the environment during the production and the using process.
Description
Technical field
The present invention relates to a kind of recovery and utilization of waste or used plastics, particularly relate to a kind of prescription and working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material.
Background technology
In the preparation research that carries out wood plastic composite; It all is the pure material of commercial grade that the SE that is adopted is gone up basically; Some utilizes reclaimed materials, also is the leftover bits that in polrvinyl chloride product is produced, occur or some quality transparent polyvinyl chloride goods preferably, and its cost is higher.And the waste polyvinyl chloride cable material that utilizes low price is produced Wood-plastic material, does not also appear in the newspapers.
CABLE MATERIALS is as the crust of electric wire; Be exposed in the physical environment throughout the year; Stand that sunlight is exposed to the sun, the erosion of rain drop erosion, sea water immersion, acid and alkali corrosion and metal elements in soil and bacterium, oxidizing reaction and other chemical reactions never stopped, very about-face has taken place in its internal structure; If carrying out recycling as the pure material of plastics, its performance can not satisfy production requirement.Dissolution method is generally adopted in the recycling of waste polyvinyl chloride electric wire crust.Pvc sheath on waste electric wire, the cable may be dissolved in the appropriate solvent, and softening agent, pigment and other organic additive also get into polyvinyl chloride solution.After removing metal and other impurity, evaporating solvent can obtain containing the thick SE reclaimed materials of these additives, can be used for making products such as the lower floor of requirement, gardening hose, but this process is comparatively complicated, and most of optional solvent is poisonous.The another kind of method that comparatively generally adopts be with behind waste polyvinyl chloride cable crust granulation again and pure material mix and make cable sheath again.But this employing reclaimed materials is processed cable, in insulativity, weathering resistance with can not show a candle to the product of processing with pure material on work-ing life, and has very big potential safety hazard.
Summary of the invention
The object of the invention is exactly to utilize problem again for what solve the waste polyvinyl chloride cable material; A kind of prescription and working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material is provided, and the additives for plastics that in manufacturing processed, uses nontoxic or low toxicity is to reach environmental requirement.
The present invention is for realizing above-mentioned purpose, and the technical scheme that is adopted is: a kind of waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes is characterized in that: prepared by following component and parts by weight proportioning:
Waste polyvinyl chloride cable particle 70 ~ 100;
Pure polyvinyl chloride powder 0 ~ 30;
Wood powder 40 ~ 60;
Metallic soap class stablizer 0 ~ 0.75;
Coupling agent 2 ~ 3;
Softening agent 0 ~ 3;
Chlorinatedpolyethylene 5 ~ 6;
The polynary ester 5 ~ 6 of methylacrylic acid;
Lubricant 0.5 ~ 0.7.
A kind of working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material is characterized in that: comprise the steps:
1) will add high-speed mixer and mixing according to the raw material of formulated, mixing temperature is 100 ℃ ~ 110 ℃, and mixing time is 20 ~ 35 minutes;
2) mixed raw materials is added in the forcing machine extrude, the forcing machine engine speed is: 40 ~ 60 rev/mins, the feeding machine rotating speed is: 4 ~ 6 rev/mins; Carry out the press polish typing after extruding.
Extrudate is touched typing and is gone up the rolling press press polish through sheet type mouth, through cooling, section, promptly gets described wood-plastic composite panel then.
The wood plastic composite that present method is produced is to be main raw material with waste polyvinyl chloride cable material, wood powder, through adding various functional agents and a spot of pure SE, and mixing extruding in twin screw extruder.It has following characteristics:
(1) product is low to the wood fibre requirement, can adopt the waste material and the rice husk the like waste that produce in the wood working;
(2) product surface is smooth, smooth and firm, and can suppress solid pattern and other shapes;
(3) product surface need not reprocessed, and the cross-sectional structure of goods is evenly fine and close;
(4) defective of no timber-work is like: knot, diagonal lamination, rotten etc.;
(5) goods have good physical and mechanical property, and water-tolerant;
(6) the goods workability is good, can follow closely, bores, saws, dig;
(7) can add various tinting materials, process coloured prod;
(8) time limit of service is longer, and upkeep cost is cheap.
Wood Plastics Composite Product is because of having the advantage of timber and plastics concurrently, thereby is widely used in a lot of fields, like all respects of national products such as furniture, building, industry, shipping vehicle, packed and transported.
The SE raw material that present method adopted is that domestic waste and old cable is disassembled the waste and old cable sheath that enterprise is disassembled out, and is cheap, and helps environment protection.The additives for plastics that present method adopted is most of for nontoxic or low toxicity product, and is very little to human body and environmental hazard in material produce and use.
Embodiment
A kind of waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes, prepare by following component and parts by weight proportioning:
Waste polyvinyl chloride cable particle 70 ~ 100;
Pure polyvinyl chloride powder 0 ~ 30;
Wood powder 40 ~ 60;
Metallic soap class stablizer 0 ~ 0.75;
Coupling agent 2 ~ 3;
Softening agent 0 ~ 3;
Chlorinatedpolyethylene 5 ~ 6;
The polynary ester 5 ~ 6 of methylacrylic acid;
Lubricant 0.5 ~ 0.7.
The waste polyvinyl chloride cable granularity is 20 ~ 30 purpose particles.Metal soap stabilisers comprises calcium-zinc composite stabilizing agent or barium zinc composite stabilizer.Wood powder is poplar powder or China fir powder or pine powder or bamboo wood powder, and its fineness is 40 ~ 60 orders, and water cut is less than 2%.Coupling agent is titanic acid ester or aluminate coupling agent.Softening agent is a DOP.Lubricant is a calcium stearate.
A kind of working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material comprises the steps:
1) will add high-speed mixer and mixing according to the raw material of formulated, mixing temperature is 100 ℃ ~ 110 ℃, and mixing time is 20 ~ 35 minutes;
2) mixed raw materials is added in the forcing machine extrude, the forcing machine engine speed is: 40 ~ 60 rev/mins, the feeding machine rotating speed is: 4 ~ 6 rev/mins; Carry out the press polish typing after extruding.
Extrudate is touched typing and is gone up the rolling press press polish through sheet type mouth, through cooling, section, promptly gets described wood-plastic composite panel then.Forcing machine is a twin screw extruder.
Above-mentioned waste polyvinyl chloride cable material is according to the material of transparent polyvinyl chloride electricwire conduit, white PVC electric wire crust, black pvc wire outer skin pipe, and practical implementation is following:
Embodiment 1:
1. the transparent polyvinyl chloride electricwire conduit is ground into 20 purpose particles through kibbler, and cleans.Polyvinyl chloride particles after cleaning is dried down in 100 ℃ in air dry oven.
2. 40 purpose bamboo wood powders were dried 3 hours down in 100 ℃ in air dry oven, its water cut is dropped to below 2%.
3. carry out the configuration of raw material according to following table 1:
Table 1
| Material component | Parts by weight |
| Transparent polyvinyl chloride cable particle | 100 |
| The bamboo wood powder | 40 |
| Titanate coupling agent | 2 |
| Chlorinatedpolyethylene | 5 |
| The polynary ester of methylacrylic acid | 5 |
| Calcium stearate | 0.5 |
4. the waste and old transparent polyvinyl chloride CABLE MATERIALS in the above-mentioned formula material and chlorinatedpolyethylene, the polynary ester of methylacrylic acid, calcium stearate are put into the high mixer mixing simultaneously, mixing temperature is 100 ℃, mixes;
5. bamboo wood powder in the above-mentioned formula material and titanate coupling agent are added the high mixer mixing, mixing temperature is 105 ℃, mixes.
6. two groups of high mixed in the step 4 and 5 raw materials are put into high mixer and carry out height and mix, mixing temperature is 110 ℃, and mixing time is 15 minutes;
7. step 6 mixed raw materials is put into twin screw extruder and carry out mixing extruding; Barrel zone temperature is 150 ℃, and head temperature is 160 ℃, 60 rev/mins of screw extrusion press engine speeds; The feeding machine rotating speed is 6 rev/mins, and is mixing after sheet type machine head port mould extrusion sheet.
8. the sheet material in the step 7 gets in the rolling press and carries out press polish, and two roller spacings of rolling press are 5 millimeters.
9. mould sheet material through the wood of press polish in the step 8 and after overcooling, cutting, be white polyvinyl chloride based wood-plastic composite sheet.
Embodiment 2:
1, white PVC electric wire crust is ground into 25 order particles through kibbler, and cleans.Polyvinyl chloride particles after cleaning is dried down in 100 ℃ in air dry oven.
2. 50 purpose China fir powder were dried 4 hours down in 100 ℃ in air dry oven, its water cut is dropped to below 2%.
3. carry out the configuration of raw material according to following table 2:
Table 2
| Material component | Parts by weight |
| White polyvinyl chloride cable particle | 80 |
| Pure polyvinyl chloride powder | 20 |
| The China fir powder | 60 |
| Calcium-zinc composite stabilizing agent | 0.5 |
| Titanate coupling agent | 3 |
| DOP (softening agent) | 2 |
| Chlorinatedpolyethylene | 5.5 |
| The polynary ester of methylacrylic acid | 5.5 |
| Calcium stearate (lubricant) | 0.6 |
4. the waste and old white polyvinyl chloride cable material in the above-mentioned formula material and stablizer, chlorinatedpolyethylene, the polynary ester of methylacrylic acid, softening agent, calcium stearate are put into the high mixer mixing simultaneously, mixing temperature is 110 ℃, mixes;
5. China fir powder in the above-mentioned formula material and titanate coupling agent are added the high mixer mixing, mixing temperature is 105 ℃, mixes.
6. two groups of high mixed in the step 4 and 5 raw materials are put into high mixer and mix, mixing temperature is 105 ℃, and mixing time is 20 minutes;
7. step 6 mixed raw materials is put into twin screw extruder and carry out mixing extruding; Barrel zone temperature is 145 ℃, and head temperature is 155 ℃, and the screw extrusion press engine speed is 50 rev/mins; The feeding machine rotating speed is 5 rev/mins, and is mixing after sheet type machine head port mould extrusion sheet.
8. the sheet material in the step 7 gets in the rolling press and carries out press polish, and two roller spacings of rolling press are 5 millimeters.
9. mould sheet material through the wood of press polish in the step 8 and after overcooling, cutting, be the polyvinyl chloride based wood-plastic composite sheet.
Embodiment 3:
1. black pvc wire outer skin pipe is ground into 30 purpose particles through kibbler, and cleans.Polyvinyl chloride particles after cleaning is dried down in 100 ℃ in air dry oven.
2. 40 purpose poplar powder were dried 3 hours down in 100 ℃ in air dry oven, its water cut is dropped to below 2%.
3. carry out the raw material configuration according to following table 3:
Table 3
| Material component | Parts by weight |
| Black pvc cable particle | 70 |
| Pure polyvinyl chloride powder | 30 |
| The poplar powder | 50 |
| The zinc-cadmium combined stablizer of barium | 0.75 |
| Aluminate coupling agent | 2.5 |
| DOP (softening agent) | 3 |
| Chlorinatedpolyethylene | 6 |
| The polynary ester of methylacrylic acid | 6 |
| Calcium stearate (lubricant) | 0.7 |
4. the black pvc CABLE MATERIALS in the above-mentioned formula material and stablizer, chlorinatedpolyethylene, the polynary ester of methylacrylic acid, softening agent, calcium stearate are put into the high mixer mixing simultaneously, mixing temperature is 110 ℃, mixes;
5. wood powder in the above-mentioned formula material and coupling agent are added the high mixer mixing, mixing temperature is 105 ℃, mixes.
6. two groups of high mixed in the step 4 and 5 raw materials are put into high mixer and mix, mixing temperature is 110 ℃, and mixing time is 35 minutes;
7. step 6 mixed raw materials is put into twin screw extruder and carry out mixing extruding; Barrel zone temperature is 150 ℃, and head temperature is 160 ℃, and the screw extrusion press engine speed is 40 rev/mins; The feeding machine rotating speed is 4 rev/mins, and is mixing after sheet type machine head port mould extrusion sheet.
8. carry out press polish in the sheet material entering rolling press in the step 7, two roller spacings of rolling press are 8 millimeters.
9. mould sheet material through the wood of press polish in the step 8 and after overcooling, cutting, be black pvc sill plastic composite board.
A kind of prescription and working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material that the present invention proposes; Be described through embodiment; Person skilled obviously can be changed or suitably change and combination making method as herein described in not breaking away from content of the present invention, spirit and scope; Realize technology of the present invention; Special needs to be pointed out is, the replacement that all are similar and change apparent to those skilled in the artly, they are regarded as and are included in spirit of the present invention, scope and the content.
Claims (9)
1. one kind is utilized waste polyvinyl chloride cable producing wood-plastic composite material prescription, it is characterized in that: prepared by following component and parts by weight proportioning: waste polyvinyl chloride cable particle 70 ~ 100; Pure polyvinyl chloride powder 0 ~ 30; Wood powder 40 ~ 60;
Metallic soap class stablizer 0 ~ 0.75; Coupling agent 2 ~ 3; Softening agent 0 ~ 3; Chlorinatedpolyethylene 5 ~ 6; The polynary ester 5 ~ 6 of methylacrylic acid; Lubricant 0.5 ~ 0.7.
2. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1 is characterized in that: described waste polyvinyl chloride cable granularity is 20 ~ 30 purpose particles.
3. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1 is characterized in that: described metal soap stabilisers comprises calcium-zinc composite stabilizing agent or barium zinc composite stabilizer.
4. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1, it is characterized in that: described wood powder is poplar powder or China fir powder or pine powder, and its fineness is 40 ~ 60 orders, and water cut is less than 2%.
5. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1, it is characterized in that: described coupling agent is titanic acid ester or aluminate coupling agent.
6. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1, it is characterized in that: described softening agent is a DOP.
7. the waste polyvinyl chloride cable producing wood-plastic composite material prescription that utilizes according to claim 1, it is characterized in that: described lubricant is a calcium stearate.
8. a working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material is characterized in that: comprise the steps:
1) will add high-speed mixer and mixing according to the raw material of formulated, mixing temperature is 100 ℃ ~ 110 ℃, and mixing time is 20 ~ 35 minutes;
2) mixed raw materials is added in the forcing machine extrude, the forcing machine engine speed is: 40 ~ 60 rev/mins, the feeding machine rotating speed is: 4 ~ 6 rev/mins; Carry out the press polish typing after extruding.
9. the working method of utilizing the waste polyvinyl chloride cable producing wood-plastic composite material according to claim 2 is characterized in that: described forcing machine is a twin screw extruder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104268082A CN102492245A (en) | 2011-12-19 | 2011-12-19 | Formula and method for producing wood-plastic composite material by utilizing waste polyvinyl chloride cable materials |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104268082A CN102492245A (en) | 2011-12-19 | 2011-12-19 | Formula and method for producing wood-plastic composite material by utilizing waste polyvinyl chloride cable materials |
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| CN102492245A true CN102492245A (en) | 2012-06-13 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319810A (en) * | 2013-06-17 | 2013-09-25 | 内蒙古亿利塑业有限责任公司 | Salix mongolica/polyvinyl chloride wood-plastic composite material and production method thereof |
| CN105348671A (en) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | An environmental-friendly recoverable degradable building composite material |
| CN105504585A (en) * | 2015-12-29 | 2016-04-20 | 楷佳（天津）新材料科技有限公司 | a wood-plastic material |
| CN106398036A (en) * | 2016-08-31 | 2017-02-15 | 余姚市楷瑞电子有限公司 | Method for preparing wood-plastic composite material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN1500832A (en) * | 2002-11-18 | 2004-06-02 | 华昌工贸有限公司 | Polyvinyl chloride (PVC) plastic-wood panel |
| CN1948384A (en) * | 2005-10-12 | 2007-04-18 | 北京化工大学 | Wood plastic micro foaming composite material and its processing shaping method |
| CN101275003A (en) * | 2008-04-30 | 2008-10-01 | 天津大学 | Formulation and method of producing wood-plastic composite material by using waste polyvinyl chloride cable material |
-
2011
- 2011-12-19 CN CN2011104268082A patent/CN102492245A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN1500832A (en) * | 2002-11-18 | 2004-06-02 | 华昌工贸有限公司 | Polyvinyl chloride (PVC) plastic-wood panel |
| CN1948384A (en) * | 2005-10-12 | 2007-04-18 | 北京化工大学 | Wood plastic micro foaming composite material and its processing shaping method |
| CN101275003A (en) * | 2008-04-30 | 2008-10-01 | 天津大学 | Formulation and method of producing wood-plastic composite material by using waste polyvinyl chloride cable material |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319810A (en) * | 2013-06-17 | 2013-09-25 | 内蒙古亿利塑业有限责任公司 | Salix mongolica/polyvinyl chloride wood-plastic composite material and production method thereof |
| CN103319810B (en) * | 2013-06-17 | 2016-06-15 | 内蒙古亿利塑业有限责任公司 | Cortex Salicis Cheilophilae/Polyvinyl chloride wood-plastic composite material and preparation method thereof |
| CN105348671A (en) * | 2015-11-13 | 2016-02-24 | 安徽广源科技发展有限公司 | An environmental-friendly recoverable degradable building composite material |
| CN105504585A (en) * | 2015-12-29 | 2016-04-20 | 楷佳（天津）新材料科技有限公司 | a wood-plastic material |
| CN106398036A (en) * | 2016-08-31 | 2017-02-15 | 余姚市楷瑞电子有限公司 | Method for preparing wood-plastic composite material |
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