CN102491783B - Repairing method of carbon ceramic brake-disc coating - Google Patents
Repairing method of carbon ceramic brake-disc coating Download PDFInfo
- Publication number
- CN102491783B CN102491783B CN 201110372669 CN201110372669A CN102491783B CN 102491783 B CN102491783 B CN 102491783B CN 201110372669 CN201110372669 CN 201110372669 CN 201110372669 A CN201110372669 A CN 201110372669A CN 102491783 B CN102491783 B CN 102491783B
- Authority
- CN
- China
- Prior art keywords
- coating
- glass powder
- carbon
- solvent
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 63
- 239000011248 coating agent Substances 0.000 title claims abstract description 62
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000000919 ceramic Substances 0.000 title claims abstract 9
- 239000000843 powder Substances 0.000 claims abstract description 35
- 239000011521 glass Substances 0.000 claims abstract description 32
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000007787 solid Substances 0.000 claims abstract description 20
- 239000011268 mixed slurry Substances 0.000 claims abstract 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910000077 silane Inorganic materials 0.000 claims abstract 3
- 239000002002 slurry Substances 0.000 claims description 29
- 150000001282 organosilanes Chemical class 0.000 claims description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 10
- -1 polysiloxane Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920003257 polycarbosilane Polymers 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 239000005388 borosilicate glass Substances 0.000 claims description 2
- 239000005355 lead glass Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000005365 phosphate glass Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 3
- 230000003647 oxidation Effects 0.000 abstract description 21
- 238000007254 oxidation reaction Methods 0.000 abstract description 21
- 238000011049 filling Methods 0.000 abstract description 14
- 238000002360 preparation method Methods 0.000 abstract description 12
- 239000002131 composite material Substances 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000000758 substrate Substances 0.000 abstract description 6
- 229910010271 silicon carbide Inorganic materials 0.000 abstract description 4
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract 4
- 239000010410 layer Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 14
- 238000000498 ball milling Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 9
- 238000001723 curing Methods 0.000 description 9
- 229920001709 polysilazane Polymers 0.000 description 9
- 239000011159 matrix material Substances 0.000 description 7
- 229920000049 Carbon (fiber) Polymers 0.000 description 6
- 239000004917 carbon fiber Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 238000004506 ultrasonic cleaning Methods 0.000 description 5
- 230000035939 shock Effects 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- PFTIVKCRALCOLB-UHFFFAOYSA-N [SiH4].[N] Chemical compound [SiH4].[N] PFTIVKCRALCOLB-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to a repairing method of a carbon ceramic brake-disc coating. Technical characteristics of the invention comprise that: a carbon ceramic brake-disc requiring reparation is subject to ultrasonic washing; mixed slurries composed of three types of glass powders with different softening points, a solvent, organic silane and a solid filling object are prepared; the brake-disc is respectively coated by three layers, which are an inner coating layer, a middle coating layer and an outer coating layer; the coating layers are cured, such that the reparation of the carbon ceramic brake-disc is finished. With the method provided by the invention, a prepared glass coating has a high compactness; the process stability is good; a preparation period is short, and the oxidation resistance of a composite material can be effectively improved. Also, the method is a low-temperature coating preparation technology. With the method provided by the invention, a good anti-oxidative effect can be provided for a carbon-fiber-reinforced carbon substrate composite material (a C/C composite material) and a carbon-fiber-reinforced carbon and silicon carbide substrate composite material (a C/C-SiC composite material).
Description
Technical field
The present invention relates to a kind of method for repairing and mending of carbon pottery brake-disc coating, relate to a kind of carbon pottery brake-disc coating at lines mending method.
Background technology
The aircraft brake ancillary equipment is that aircraft is realized braking and ensured one of key part of flight safety, and it is to utilize between the friction surface of relative movement to produce the purpose that friction reaches braking.Aircraft need to rely on the braking devices kinetic energy that it is huge to change heat energy into and distributes in tens seconds of landing braking, and produces rapid temperature rise on the brake flange surface during braking, can make surface temperature reach 600 ℃ more than-800 ℃.
The carbon ceramic material is the widely used material of present brake flange, has that density is low, wear-resisting, characteristics such as oxidation-resistance and good thermal shock.The distinguishing feature of carbon material is to keep stable in larger temperature range, and its disadvantage is that oxidation easily occurs in air more than 400 ℃.Carbon pottery brake material surface exists exposed carbon fiber and carbon base body.These exposed carbon fiber and carbon base bodies are easily oxidized in the high temperature oxidation stability environment.The density of material reduces during mild oxidation, strength degradation, and along with temperature raises, matrix material oxidation aggravation, layering can appear in material during severe oxidation, even becomes cotton-shapedly, completely loses the mechanical property of material, causes aircraft brake to lose efficacy, even has an accident.Therefore the anti-oxidation of carbon pottery brake material mainly is the oxidation that prevents carbon fiber and the carbon base body of surface exposure.
Carbon pottery brake material production cost is high, expensive, also is great loss economically because oxidation causes the secondary premature failure of brake.Must solve the oxidation-resistance problem of material, so have great importance for the research of carbon pottery brake material inoxidzable coating for this reason.At present remarkable for the achievement in research of this respect.The coating main preparation methods has chemical Vapor deposition process, sol-gel method, and liquid phase method, solid state diffusion method etc., the prepared coating of these methods can both well be protected matrix on degree.But the problem that exists is that brake flange can cause top coat that certain destruction is arranged in the equipment process, thereby affects the provide protection of coating, affects the normal use of carbon ceramic material.In order to address this problem, the online recovery technique of research coating becomes a focus.
Present coat preparing technology is more, but all can not repair online, such as sol-gel method, needs could form coating through pyroprocessing, and this has just limited its online remedy action.
Summary of the invention
The technical problem that solves
For fear of the deficiencies in the prior art part, the present invention proposes a kind of method for repairing and mending of carbon pottery brake-disc coating, be a kind of simple effectively and the technology that can repair online, at room temperature preparation, and can under comparatively high temps, protecting material.
Technical scheme
A kind of method for repairing and mending of carbon pottery brake-disc coating is characterized in that repairing step as follows:
Step 1: adopt the carbon pottery brake flange that clear water will be to be repaired to carry out ultrasonic cleaning 20～30 minutes, then place in 100 ℃ of baking ovens through oven dry in 20～30 minutes;
Step 2: be that 650～750 ℃ glass powder, solvent, organosilane and solid filling mixes with softening temperature, the slurry that obtains mixing through ball milling; Then slurry is brushed in the damaged coating place, make its curing under 80～120 ℃ of low temperature, obtain undercoat; Described glass powder: solvent: organosilane: the mass ratio of solid filling is 3～4: 3～4: 1～1.5: 1～1.5
Step 3: be that 450～550 ℃ glass powder, solvent, organosilane mixes with softening temperature, the slurry that obtains mixing through ball milling; Then slurry is brushed on undercoat, make its curing under 80～120 ℃, obtain inter coat; Described glass powder: solvent: the mass ratio of organosilane is 3～4: 3～4: 1～1.5
Step 4: be that 350～400 ℃ glass powder, solvent, organosilane and solid filling mixes with softening temperature, the slurry that obtains mixing through ball milling; Then slurry is brushed in inter coat, make its curing under 80～120 ℃, obtain external coating (EC); The mass ratio of described glass powder, solvent, organosilane and solid filling is 3～4: 3～4: 1～1.5: 1～1.5
Described solid filling is aluminium hydroxide or aluminum oxide.
Curing in described step 2, step 3 and the step 4 adopts the infrared lamp irradiation to make its curing.
Described glass powder is: bismuth glass powder, lead glass powder, vanadium glass powder, phosphate glass powder or borosilicate glass powder.
Described organosilane tackiness agent is: polysilazane, polysiloxane, Polycarbosilane or poly-boron nitrogen silane.
Beneficial effect
The method for repairing and mending of a kind of carbon pottery brake-disc coating that the present invention proposes, problem to be solved is a kind of method for repairing and mending of carbon pottery brake-disc coating, the method can effectively solve carbon pottery brake flange at equipment process floating coat damage problem.The glass coating density that adopts the method to prepare is high, technology stability good, preparation cycle is short, the antioxidant property of energy Effective Raise matrix material.Present method also is that a kind of low temperature prepares coating technology simultaneously, can be to carbon fiber reinforced carbon matrix composite material (C/C matrix material), carbon-fiber reinforced carbon, silicon carbide-based composite material (C/C-SiC matrix material) play good oxidation protection effect.
The invention has the beneficial effects as follows: play the effect of packing hole after (1) glass powder with low melting point melts, effectively stopped entering of oxygen, prevent the oxidation of carbon fiber; (2) the preparation technology of coating process is simple, and the cycle is short, cost is low, and can repair online, and is convenient and easy.
Description of drawings
Fig. 1: coating is schemed at low-temperature curing rear surface SEM;
Fig. 2: the coating sample is coatingsurface SEM figure before 700 ℃ of oxidation experiments begin;
Fig. 3: the coating sample is coating section SEM figure before 700 ℃ of oxidation experiments begin;
Fig. 4: the coating sample is at 700 ℃, oxidation coatingsurface SEM figure after 10 hours in the air;
Fig. 5: the coating sample is at 700 ℃, oxidation coating section SEM figure after 10 hours in the air;
Fig. 6: the coating sample is at 700 ℃, coatingsurface SEM figure after the thermal shock 50 times;
Fig. 7: the coating sample is at 700 ℃, coating section SEM figure after the thermal shock 50 times;
Fig. 8: the oxidation dynamic curve of coating sample.
Embodiment
Now in conjunction with the embodiments, the invention will be further described for accompanying drawing:
Embodiment 1:
Step 1: adopt clear water to carry out ultrasonic cleaning 30 minutes for carbon pottery brake flange material to be repaired, then place in 100 ℃ of baking ovens and dried through 30 minutes, stand-by;
Step 2: the ethanol that adds 80-100% with B-Si glass powder as solvent, add 15-25% polysilazane as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 3: the slurry that mixes is brushed in substrate surface, made its curing about 120 ℃ (scenes can adopt infrared lamp irradiation) through 5-6 hour, thereby obtain undercoat;
Step 4: the ethanol that adds 80-100% with Bi glass powder as solvent, add 15-25% polysilazane as tackiness agent, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 5: the slurry that mixes is brushed on the undercoat of step 2,3 preparations, through 5-6 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), can obtain inter coat;
Step 6: the ethanol that adds 80-100% with Pb glass powder as solvent, add 15-25% polysilazane as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 7: the slurry that mixes is brushed on the inter coat of step 4,5 preparations, through 10-12 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), thereby obtain external coating (EC);
To the coating sample that prepared with without the coating sample with carry out oxidation experiment, it is about 0.19% that the result is presented at 1 hour coating sample weightlessness of 700 ℃ of insulations, and the sample weightlessness that does not add coating is 16.19%, 10 hours coating sample weightlessness of 700 ℃ of insulations is 5.10%, and the sample weightlessness that does not add coating is 41.5%, has shown that thus this scheme can play good anti-oxidation effect to matrix.Through 700 ℃ * 3min ← → 50 real thermal shock tests of room temperature * 2min (amount to oxidation 150min), oxidative mass loss is 1.60%, it is complete that coating keeps, and do not have obvious crackle and peel off, and shows that coating has preferably heat-shock resistance.
Embodiment 2:
Step 1: adopt clear water to carry out ultrasonic cleaning 30 minutes for carbon pottery brake flange material to be repaired, then place in 100 ℃ of baking ovens and dried through 30 minutes, stand-by;
Step 2: the ethanol that adds 80-100% take B-Si glass powder as solvent, the polysiloxane that adds 15-25% and polysilazane (mass ratio was as 1: 1) as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 3: the slurry that mixes is brushed in substrate surface, made its curing about 120 ℃ (scenes can adopt infrared lamp irradiation) through 5-6 hour, thereby obtain undercoat;
Step 4: add the ethanol of 80-100% as tackiness agent, ball milling is 10-15min approximately as solvent, the polysiloxane that adds 15-25% and polysilazane (mass ratio was as 1: 1) take Bi glass powder, the slurry that obtains mixing;
Step 5: the slurry that mixes is brushed on the undercoat of step 2,3 preparations, through 5-6 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), can obtain inter coat;
Step 6: the ethanol that adds 80-100% take Pb glass powder as solvent, the polysiloxane that adds 15-25% and polysilazane (mass ratio was as 1: 1) as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 7: the slurry that mixes is brushed on the inter coat of step 4,5 preparations, through 10-12 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), thereby obtain external coating (EC);
To the coating sample that prepared with without the coating sample with carry out oxidation experiment, it is about 0.40% that the result is presented at 450 ℃ of oxidations, 10 little coating sample weightlessness, and the sample weightlessness that does not add coating is 1.14%.
Embodiment 3:
Step 1: adopt clear water to carry out ultrasonic cleaning 30 minutes for carbon pottery brake flange material to be repaired, then place in 100 ℃ of baking ovens and dried through 30 minutes, stand-by;
Step 2: the ethanol that adds 80-100% with B-Si glass powder as solvent, add 20% Polycarbosilane as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 3: the slurry that mixes is brushed in substrate surface, made its curing about 120 ℃ (scenes can adopt infrared lamp irradiation) through 5-6 hour, thereby obtain undercoat;
Step 4: the ethanol that adds 80%-100% with Pb glass powder as solvent, add 20% Polycarbosilane as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 5: the slurry that mixes is brushed on the undercoat of step 2,3 preparations, through 10-12 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), thereby obtain external coating (EC);
To the coating sample that prepared with without the coating sample with carry out oxidation experiment, it is about 4.30% that the result is presented at 550 ℃ of oxidations, 10 little coating sample weightlessness, and the sample weightlessness that does not add coating is 17.26%.
Embodiment 4:
Step 1: adopt clear water to carry out ultrasonic cleaning 30 minutes for carbon pottery brake flange material to be repaired, then place in 100 ℃ of baking ovens and dried through 30 minutes, stand-by;
Step 2: the ethanol that adds 80-100% take B-Si glass powder as solvent, the polysiloxane that adds 15-25% and polysilazane (mass ratio was as 1: 1) as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 3: the slurry that mixes is brushed in substrate surface, made its curing about 120 ℃ (scenes can adopt infrared lamp irradiation) through 5-6 hour, thereby obtain undercoat;
Step 4: the ethanol that adds 80-100% take Bi glass powder as solvent, the polysiloxane that adds 15-25% and polysilazane (mass ratio was as 1: 1) as tackiness agent, add the aluminium hydroxide of 15-25% as solid filling, ball milling is 10-15min approximately, the slurry that obtains mixing;
Step 5: the slurry that mixes is brushed on the undercoat of step 2,3 preparations, through 10-12 hour it is solidified fully about 120 ℃ (the infrared lamp irradiation can be adopted in the scene), thereby obtain external coating (EC).
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110372669 CN102491783B (en) | 2011-11-21 | 2011-11-21 | Repairing method of carbon ceramic brake-disc coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110372669 CN102491783B (en) | 2011-11-21 | 2011-11-21 | Repairing method of carbon ceramic brake-disc coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102491783A CN102491783A (en) | 2012-06-13 |
| CN102491783B true CN102491783B (en) | 2013-04-17 |
Family
ID=46183653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110372669 Expired - Fee Related CN102491783B (en) | 2011-11-21 | 2011-11-21 | Repairing method of carbon ceramic brake-disc coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102491783B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746032B (en) * | 2012-06-25 | 2013-11-06 | 西北工业大学 | Method for repairing medium temperature coating (1000 to 1400 DEG C) of silicon carbide base composite material toughened by carbon fiber |
| CN103601528B (en) * | 2013-08-30 | 2015-05-27 | 航天材料及工艺研究所 | Local coating defect repairing method for carbon/carbon composite material |
| CN103804030A (en) * | 2013-12-27 | 2014-05-21 | 西北工业大学 | Method for preparing oxidation-resistant composite coating for carbon ceramic brake disc |
| CN109665866B (en) * | 2019-01-22 | 2021-09-21 | 长安大学 | Outfield repairing method for low-temperature 450-1100 ℃ coating in C/C aircraft brake material |
| CN110721881B (en) * | 2019-11-04 | 2021-10-15 | 中国人民解放军国防科技大学 | A high-temperature radar and infrared compatible stealth coating on-site repair method |
| CN112745146B (en) * | 2021-01-11 | 2022-07-12 | 上海大学 | A local defect whisker or flake-like reinforcement repair method for carbon/carbon composite coating and repair coating |
| CN113881354B (en) * | 2021-09-29 | 2022-07-22 | 湖北瑞宇空天高新技术有限公司 | Bonding repair method for carbon fiber reinforced carbon-based composite material, used bonding agent and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1280238C (en) * | 2002-09-05 | 2006-10-18 | 上海东康高热耐火制品有限公司 | Face coated carborundum heating unit |
| CN1539795A (en) * | 2003-10-29 | 2004-10-27 | 王玉震 | Self-purging ceramic tile |
| CN1277782C (en) * | 2004-08-17 | 2006-10-04 | 中国科学院合肥物质科学研究院 | compact ceramic insulating coating and preparation method thereof |
| CN1810726A (en) * | 2006-02-06 | 2006-08-02 | 霍镰泉 | Sol-gel process of preparing anti-fouling silica coating on the surface of polished ceramic tile |
| CN101054312A (en) * | 2006-04-11 | 2007-10-17 | 山东省淄博市博山长虹陶瓷装饰材料厂 | Lead-free cadmium-free ceramic pigment on glaze and preparation method thereof |
-
2011
- 2011-11-21 CN CN 201110372669 patent/CN102491783B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN102491783A (en) | 2012-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102491783B (en) | Repairing method of carbon ceramic brake-disc coating | |
| CN105237039B (en) | The inoxidzable coating material of carbon/carbon brake material and the method for prepares coating | |
| CN109968757B (en) | A kind of ablation-resistant lightweight heat-proof and heat-insulation integrated composite material and preparation method thereof | |
| CN102757260B (en) | A method for repairing a ceramic matrix composite coating with a service temperature greater than or equal to 1400°C | |
| CN103601528B (en) | Local coating defect repairing method for carbon/carbon composite material | |
| CN104261851B (en) | A high temperature resistant low ablation coating and its preparation method | |
| CN107814591A (en) | A kind of carbon material surface boride is modified the preparation method of silicon substrate antioxidant coating | |
| CN109665866B (en) | Outfield repairing method for low-temperature 450-1100 ℃ coating in C/C aircraft brake material | |
| CN103145454B (en) | A method for preparing ZrB2-SiC anti-ablation coating by in-situ reaction | |
| CN106966762B (en) | A kind of preparation method of aero-engine hot junction component Environmental Barrier Coatings on Si-based Ceramics | |
| CN111732457B (en) | A kind of anti-oxidation/infrared stealth coating on the surface of fiber-reinforced ceramic matrix composite material with temperature resistance of 1650 ° C and preparation method thereof | |
| CN105924235B (en) | A kind of anti-oxidant repair coating of the wide temperature range of carbonaceous material and repairing, preparation method | |
| CN105948819A (en) | Reparative coating and application thereof in repairing coating of silicon carbide-based composite material | |
| CN103804030A (en) | Method for preparing oxidation-resistant composite coating for carbon ceramic brake disc | |
| CN105198492A (en) | Oxidation-resistant coating and preparation method thereof | |
| CN102807394B (en) | Method for preparing high temperature oxidation resisting coating on surface of carbon material | |
| CN110387148B (en) | Anti-ablation coating material for resin-based composite material and preparation method thereof | |
| CN113248283A (en) | Repairing agent and method for repairing surface of carbon-based composite material | |
| CN105601344A (en) | Moderate-temperature antioxidation coating and preparation method thereof, and carbon/carbon composite product | |
| CN102746032B (en) | Method for repairing medium temperature coating (1000 to 1400 DEG C) of silicon carbide base composite material toughened by carbon fiber | |
| CN104193421B (en) | A kind of coating sintering preparation method of carbonaceous material high-temperature oxidation resistant coating | |
| CN112937048B (en) | Ablation-resistant gradient-distribution heat-proof composite material with surface coated with high-temperature infrared stealth coating and preparation method thereof | |
| CN1457936A (en) | Anti-oxidation composite coating of plane carbon brake disc and its preparing method | |
| CN100424375C (en) | Method for preparing anti-oxidation protective coating of C/C composite material for aircraft brake disc | |
| CN105273683B (en) | Organic high-temperature agglomerant and the method for improving the organic high temperature bond performance of ceramic material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130417 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |