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CN102464461A - Method for doping coal ash in coal gangue baked brick - Google Patents

Method for doping coal ash in coal gangue baked brick Download PDF

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Publication number
CN102464461A
CN102464461A CN2010105325054A CN201010532505A CN102464461A CN 102464461 A CN102464461 A CN 102464461A CN 2010105325054 A CN2010105325054 A CN 2010105325054A CN 201010532505 A CN201010532505 A CN 201010532505A CN 102464461 A CN102464461 A CN 102464461A
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China
Prior art keywords
coal gangue
fly ash
doping
salt
coal
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CN2010105325054A
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CN102464461B (en
Inventor
赵星
郭红彦
梁凡
张宏莲
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Huainan Tangshan No3 Building Materials Factory
Huainan Normal University
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Huainan Tangshan No3 Building Materials Factory
Huainan Normal University
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Priority to CN201010532505.4A priority Critical patent/CN102464461B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Processing Of Solid Wastes (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

本发明涉及一种墙体材料的制备方法,具体涉及一种利用煤炭废弃物制备烧结砖的方法。主要通过对煤矸石的预处理,提高煤矸石制砖过程中所掺杂的粉煤灰的含量,最大程度的利用煤炭废弃物。The present invention relates to a method for preparing wall materials, and in particular to a method for preparing sintered bricks using coal waste, which mainly increases the content of fly ash mixed in the process of making bricks from coal gangue by pre-treating the gangue, thereby making the most of the coal waste.

Description

一种在煤矸石烧结砖中掺杂粉煤灰的方法A method of doping fly ash in coal gangue sintered bricks

技术领域technical field

本发明涉及一种墙体材料的制备方法,具体涉及一种利用煤炭废弃物制备烧结砖的方法。The invention relates to a method for preparing wall materials, in particular to a method for preparing sintered bricks from coal waste.

背景技术 Background technique

多年来,我国的制砖行业一直以黏土为主要原料,但是黏土的大量使用严重的破坏了土地资源。随着国家发展改革委、建设部等四部门联合下发《关于进一步做好禁止使用实心黏土砖工作的意见》(发改环资249号),明确要求大力开展″禁实″工作,因此以煤矸石和粉煤灰为主要原料烧结的新型砖成为了黏土砖的主要替代品。目前国内对相关制备方法研究较多,也取得了一定成果并投入生产应用。但是国内目前制砖主要分为两类,一类为煤矸石烧结砖,一类为粉煤灰蒸压砖,虽然可以在煤矸石中添加少量粉煤灰,但是添加比例较低。Over the years, my country's brick industry has been using clay as the main raw material, but the extensive use of clay has seriously damaged land resources. As the National Development and Reform Commission, the Ministry of Construction and other four departments jointly issued the "Opinions on Further Improving the Work of Prohibiting the Use of Solid Clay Bricks" (Fagai Huanzi No. 249), it is clearly required to vigorously carry out the work of "banning solid clay bricks". New bricks sintered with coal gangue and fly ash as the main raw materials have become the main substitutes for clay bricks. At present, there are many researches on related preparation methods in China, and certain results have been obtained and put into production and application. However, domestic brick making is mainly divided into two categories at present, one is coal gangue sintered bricks, and the other is fly ash autoclaved bricks. Although a small amount of fly ash can be added to coal gangue, the addition ratio is relatively low.

发明内容 Contents of the invention

本发明的目的是提高煤矸石烧结砖中可掺杂粉煤灰的含量,使煤矸石和粉煤灰的比例达到1∶1,最大程度的利用废弃资源。The purpose of the present invention is to increase the content of fly ash that can be mixed in coal gangue sintered bricks, make the ratio of coal gangue and fly ash reach 1:1, and utilize waste resources to the greatest extent.

具体步骤包括:Specific steps include:

a、将煤矸石破碎至颗粒小于3毫米后,按50∶1的比例混合粗盐,放入砖窑内在高温下进行焙烧预处理。a. After the coal gangue is crushed until the particles are less than 3 mm, coarse salt is mixed in a ratio of 50:1, and put into a brick kiln for roasting pretreatment at high temperature.

b、将预处理后的煤矸石和粉煤灰按1∶1的比例混合,同时加入少量黏土和适量的水,经搅拌混合后陈化,切坯,干燥、入窑焙烧。b. Mix the pretreated coal gangue and fly ash at a ratio of 1:1, add a small amount of clay and an appropriate amount of water at the same time, mix and age after mixing, cut into billets, dry and roast in a kiln.

c、焙烧后的产品经冷却至常温后,用水喷淋,晾干后即成成品。c. After the roasted product is cooled to room temperature, it is sprayed with water and dried to become a finished product.

具体实施方式 Detailed ways

将1000公斤煤矸石破碎后,与20公斤工业盐混合均匀,在烧制其它砖坯的同时进入窑内进行焙烧预处理;将预处理后的煤矸石焙烧物与1000公斤的粉煤灰,200公斤的黏土加适量水混合后陈化24小时以上;陈化后的原料在双级真空硬塑挤砖机中,挤出压力为3.5-4MPa,真空度为0.95-0.82挤出砖坯,挤砖机的含水率控制在11-13%;挤出的砖坯要干燥以提高砖坯的强度,入窑前要预热以防止砖坯在焙烧时折裂;砖坯在机械隧道窑内焙烧烧制温度控制在1000-1100℃,焙烧24小时;砖坯出窑冷却后,需经水淋防止成品砖的爆裂。After crushing 1,000 kg of coal gangue, mix it with 20 kg of industrial salt, and enter the kiln for roasting pretreatment while firing other bricks; mix the pretreated coal gangue with 1,000 kg of fly ash, 200 kg The clay is mixed with an appropriate amount of water and aged for more than 24 hours; the aged raw materials are extruded in a two-stage vacuum rigid plastic brick extrusion machine with an extrusion pressure of 3.5-4MPa and a vacuum degree of 0.95-0.82 to extrude bricks. The moisture content of the bricks is controlled at 11-13%; the extruded bricks should be dried to increase the strength of the bricks, and preheated before entering the kiln to prevent the bricks from breaking during firing; the firing temperature of the bricks in the mechanical tunnel kiln is controlled at 1000 -1100℃, roasting for 24 hours; after the brick leaves the kiln to cool, it needs to be watered to prevent the finished brick from bursting.

Claims (5)

1.一种在煤矸石烧结砖中掺杂粉煤灰的方法,具体包括以下步骤:1. A method of doping fly ash in coal gangue sintered bricks, specifically comprising the following steps: a、将煤矸石破碎至颗粒小于3毫米后,按50∶1的比例与盐混合,放入砖窑内在高温下进行焙烧预处理。a. After the coal gangue is crushed until the particles are less than 3 mm, it is mixed with salt at a ratio of 50:1, and put into a brick kiln for roasting pretreatment at high temperature. b、将预处理后的煤矸石和粉煤灰按1∶1的比例混合,同时加入少量黏土和适量的水,经搅拌混合后陈化至少24小时,然后切坯,干燥、入窑焙烧。b. Mix the pretreated coal gangue and fly ash at a ratio of 1:1, add a small amount of clay and an appropriate amount of water at the same time, mix and age for at least 24 hours, then cut into billets, dry, and roast in a kiln. c、焙烧后的产品经冷却至常温后,用水喷淋,晾干后即成成品。c. After the roasted product is cooled to room temperature, it is sprayed with water and dried to become a finished product. 2.根据权利要求1所述的一种在煤矸石烧结砖中掺杂粉煤灰的方法,其特征在于:所述步骤a中的煤矸石应在高温下进行预处理。2. A method of doping fly ash in gangue sintered bricks according to claim 1, characterized in that: the gangue in the step a should be pretreated at high temperature. 3.根据权利要求1所述的一种在煤矸石烧结砖中掺杂粉煤灰的方法,其特征在于:所述步骤a中的煤矸石在经过预处理以后按50∶1的比例与盐混合。3. A method of doping fly ash in coal gangue sintered bricks according to claim 1, characterized in that: the coal gangue in the step a is mixed with salt in a ratio of 50:1 after pretreatment mix. 4.根据权利要求3所述的一种在煤矸石烧结砖中掺杂粉煤灰的方法,其特征在于:所述步骤a中的盐为粗盐或者工业盐。4. A method for doping fly ash in coal gangue sintered bricks according to claim 3, characterized in that: the salt in the step a is coarse salt or industrial salt. 5.根据权利要求4所述的一种在煤矸石烧结砖中掺杂粉煤灰的方法,其特征在于:粗盐或者工业盐中氯化钠的含量大于80%。5. A method of doping fly ash in coal gangue sintered bricks according to claim 4, characterized in that: the content of sodium chloride in coarse salt or industrial salt is greater than 80%.
CN201010532505.4A 2010-10-31 2010-10-31 Method of doping fly ash in gangue fired brick Expired - Fee Related CN102464461B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107098683A (en) * 2017-06-23 2017-08-29 李珠 Sintered coal gangue insulating brick and preparation method thereof
CN108624294A (en) * 2018-06-08 2018-10-09 华北电力大学 A kind of high temperature phase-change heat-storage material and preparation method based on gangue

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1246460A (en) * 1999-10-08 2000-03-08 山东省济宁鲁西实业总公司 Technology for sintering bricks containing high content of powdered coal ash and coal gangue as binder

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1246460A (en) * 1999-10-08 2000-03-08 山东省济宁鲁西实业总公司 Technology for sintering bricks containing high content of powdered coal ash and coal gangue as binder

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
蔡辉等: "高掺量粉煤灰烧结砖工艺及设备的研究", 《砖瓦》, no. 9, 31 December 2005 (2005-12-31) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107098683A (en) * 2017-06-23 2017-08-29 李珠 Sintered coal gangue insulating brick and preparation method thereof
CN107098683B (en) * 2017-06-23 2020-01-10 李珠 Sintered coal gangue heat-insulating brick and preparation method thereof
CN108624294A (en) * 2018-06-08 2018-10-09 华北电力大学 A kind of high temperature phase-change heat-storage material and preparation method based on gangue

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