CN102417772A - Environment-friendly steel structure building fireproof and anticorrosive composite coating and preparation method thereof - Google Patents
Environment-friendly steel structure building fireproof and anticorrosive composite coating and preparation method thereof Download PDFInfo
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- CN102417772A CN102417772A CN2011102984618A CN201110298461A CN102417772A CN 102417772 A CN102417772 A CN 102417772A CN 2011102984618 A CN2011102984618 A CN 2011102984618A CN 201110298461 A CN201110298461 A CN 201110298461A CN 102417772 A CN102417772 A CN 102417772A
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000002131 composite material Substances 0.000 title abstract 2
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- 239000000463 material Substances 0.000 claims abstract description 13
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- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 9
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 6
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010439 graphite Substances 0.000 claims abstract description 5
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 4
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005260 corrosion Methods 0.000 claims description 26
- 230000007797 corrosion Effects 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 18
- 239000003063 flame retardant Substances 0.000 claims description 16
- 239000003973 paint Substances 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 238000004581 coalescence Methods 0.000 claims description 13
- 239000001038 titanium pigment Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 8
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 4
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 2
- 238000013329 compounding Methods 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 241000345998 Calamus manan Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
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- LXMSZDCAJNLERA-ZHYRCANASA-N spironolactone Chemical compound C([C@@H]1[C@]2(C)CC[C@@H]3[C@@]4(C)CCC(=O)C=C4C[C@H]([C@@H]13)SC(=O)C)C[C@@]21CCC(=O)O1 LXMSZDCAJNLERA-ZHYRCANASA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
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Abstract
The invention discloses an environment-friendly steel structure building fireproof and anticorrosive composite coating, which is formed by compounding a fireproof coating and an anticorrosive coating, wherein the fireproof coating comprises the following materials in parts by weight: 200-300 parts of deionized water, 5-20 parts of dispersing agent, 10-30 parts of film forming additive, 1-5 parts of defoaming agent, 20-70 parts of titanium dioxide, 20-50 parts of chlorinated paraffin at 70 ℃, 200-350 parts of ammonium polyphosphate, 50-100 parts of melamine, 50-100 parts of dipentaerythritol, 30-100 parts of expanded graphite and 200-300 parts of acrylic emulsion. The special anticorrosive coating for the fireproof coating comprises the following materials in percentage by weight: 128 parts of deionized water, 1 part of dispersant, 48 parts of film forming additive, 7 parts of defoaming agent, 9.5 parts of propylene glycol, 5 parts of mildew preventive, 200 parts of titanium dioxide, 38 parts of sericite powder, 3.5 parts of precipitated barium sulfate and 615 parts of emulsion. Compared with the prior art, the successful implementation of the project breaks through the situation that the fire protection and the anticorrosive coating are in conflict respectively in the steel structure protection project, and the functions of the fire protection and the anticorrosive coating can be successfully integrated into a project system.
Description
Technical field
The present invention relates to the compounding technology of a kind of fire protection coating and corrosion protection coating, environment-friendly type steel building fire retardant anticorrosion compound coating specifically, and the preparation method of this compound coating; Fire protection coating and corrosion protection coating are effectively combined, neither influence fire protection coating and meet the fire expansion, performance flameproof protection function makes the antiseptic property of corrosion protection coating self reach best compounding technology again.
Background technology
Existing steel construction protection technology adopts the coating protection technology mostly.Adopt frie retardant coating to apply the steelwork of protection; Have that fire insulation performance is good, construction does not receive the restriction of steelwork geometrical body, generally need not add supplementary unit, coating quality light, plurality of advantages such as certain attractive, decorative effect is arranged, often become first-selected flameproof protection measure.
Developed country has just released steel-structure ultrathin type frie retardant coating as far back as the initial stage seventies on market.There are German Herberts company, Britain Nullifine company, U.S. Altex company, PPG company, FCC company, Caboline company, the gloomy paint company of Japanese rattan, the good company of French atropic in famous producer.
Super-thin steel structure fire-proof paint in the market mainly contains the Water Base 38320 formed steel construction frie retardant coatings (water-soluble type) of German Herberts company, and coat-thickness 2.63mm, fire endurance are 63min; 38091 formed steel construction frie retardant coatings (solvent-borne type), coat-thickness 2.42mm, fire endurance are 124min; The steel structure fire-proof paint (solvent-borne type) of Britain Nullifire company, coat-thickness 2.24mm, fire endurance 106min; China Sichuan fire-fighting scientific research institution developed super-thin steel structure fire-proof paint since 1996, product has SCB (solvent-borne type), and coat-thickness 2.69mm, fire endurance are 147min; LF (solvent-borne type) and L6 (solvent-borne type) coat-thickness are respectively 2mm and 3mm, and fire endurance is respectively 94min and 90min; The SF (solvent-borne type) of Jiangsu Lan Ling company, coat-thickness 2.07mm, ECB (water-soluble type), coat-thickness 1.6mm, fire endurance are respectively 150min and 44min.
Along with China is limiting the strictness that more becomes to organic volatile content aspect the indoor coating, limiting the quantity of among the newest standards GB18582-2008 " limits of harmful substances in the indoor decorating material interior wall coating " is 120g/L.Hence one can see that, develops high solid, water base, no-solvent type steel construction protection coating, and promptly nontoxic, free of contamination steel construction protection coating will be scientific worker's focus.
In sum, the coating that can see on the home market at present is in 3mm, and fire endurance nearly all is the solvent-borne type product greater than the steel structure fire-proof paint of 90min.Though the external existing aqueous fire-proof coating product that surpasses 90min, water tolerance is very poor, and prices are rather stiff.The great majority that present domestic engineering is used are solvent-borne type products, and the steel construction protection coating that has the fire retardant anticorrosion double effects is not simultaneously also seen product on the market at home, does not abroad appear in the newspapers yet.
Summary of the invention
The objective of the invention is to solve the problems referred to above of prior art, to fill up the market vacancy of fire retardant anticorrosion double effects steel construction protection coating for a kind of environment-friendly type steel building fire retardant anticorrosion compound coating is provided.
Another object of the present invention is for the preparation method of this compound coating is provided.
The object of the invention can be realized through following technical scheme.
A kind of environment-friendly type steel building fire retardant anticorrosion compound coating, it is composited by fire protection coating and corrosion protection coating two portions, and fire protection coating comprises the material of following weight ratio:
Deionized water 200-300, dispersion agent 5-20, film coalescence aid 10-30, skimmer 1-5; White titanium pigment 20-70,70 ℃ of clorafin 20-50, ammonium polyphosphate 200-350, trimeric cyanamide 50-100; NSC 65881 50-100, expanded graphite 30-100, ACRYLIC EMULSION 200-300.
The corrosion protection coating that is exclusively used in above-mentioned fire protection coating comprises the material of following weight ratio:
Deionized water 128, dispersion agent 1, film coalescence aid 48, skimmer 7, Ucar 35 9.5, mould inhibitor 5, white titanium pigment 200, the thin mica powder 38 of thin,tough silk, process white 3.5, emulsion 615.
In fire protection coating,
Described dispersion agent is the BYK-019 of Bi Ke company.
Described film coalescence aid is two Texnaol that reach chemical industry.
Described skimmer is the B-199 of clearization company.
Described white titanium pigment is the R706 of E.I.Du Pont Company.
Concentration is during described ACRYLIC EMULSION: 45-50%.
In corrosion protection coating,
Described dispersion agent is the BYK-019 of Bi Ke company.
The two Texnaol that reach chemical industry of described film coalescence aid.
Described skimmer is two K5 that reach chemical industry.
Described mould inhibitor is the WL-3 of following chemical industry.
Described white titanium pigment is B101.
The thin mica powder of described thin,tough silk is 1250 orders.
Described emulsion is a kind of in fluorine emulsion, organosilicon crylic acid latex and the ACRYLIC EMULSION; Its mass percent concentration is 45-55%, and wherein, concentration is during for fluorine emulsion: 50-55%; Concentration is during for organosilicon crylic acid latex: 48-52%, concentration is during for ACRYLIC EMULSION: 45-50%.
The preparation method of above-mentioned compound coating, concrete steps are:
(1) pre-dispersed process:
With water, dispersion agent, high speed dispersion (1200 ± 50 rev/mins) such as part skimmer, fire retardant, mineral filler, pigment become uniform slurry, and equipment used is the high speed dispersor of belt stirrer.
(2) grind dispersion process:
Slurry after pre-dispersed is carried out levigate dispersion through various grinding dispersing apparatus, make it reach regulation fineness (less than 100 μ m).
(3) paint process:
Levigate dispersive slurry is being stirred (700 ± 50 rev/mins) adding synthetic emulsion, PH regulator, residue skimmer, auxiliary rheological agents etc. down at a slow speed; The pH value (7-7.5) and the viscosity (120ku of adjustment coating; The Stormer rotational viscosimeter); Make it to reach the quality index requirement of regulation, generally in having the mixed cylinder of whisking appliance, carry out, last discharging.
Corrosion protection coating is certain to bring influence to fire protection coating, how to make the two effective combination, neither influences fire protection coating and meets the fire expansion, brings into play effective fire-proof function, makes the antiseptic property of corrosion protection coating self reach best again.
The present invention adopts the general in the world expanded foamed system of P-C-N.The fire endurance of fire protection coating is brought up to 90min, reach international advanced person, leading domestic level, the core technology that rational expanded foamed system is this project is crucial, is related to the foaming effect of coating, the fire endurance and the whole flameproof effect of product.That the present invention mainly adopts is fluorine-containing, silicon emulsion is as the antiseptic property of corrosion protection coating base-material with abundant raising compound coating.Fire protection coating is coated in its surperficial protective system owing to capillary difference can make and presents orange peel shape or free shape situation, so consistency between the two is particularly important.And the present invention selects good fire protection coating of consistency and protective system coupling; Make that protective system can evenly good coating on fire protection coating; Make corrosion protection coating can not influence the expanded foamed performance of fire protection coating again, make the fire retardant anticorrosion compound coating reach good overall performance.
The present invention is than prior art, and its beneficial effect is:
1, be the aqueous, environmental protective new and high technology, its fire endurance >=90min is much higher than the 60min that stipulates among the standard GB 14907-2002 " steel structure fire-proof paint ", is in advanced level in the world, fills up technological gap at home.
2, indoor ultrathin steel structure frie retardant coating, frie retardant coating special anti-corrosion finishing paint all reach environmental-protecting performance index (operative norm GB18582-2008 " limits of harmful substances in the indoor decorating material interior wall coating ")
3, the Corrosion Protection of corrosion protection coating reaches the index performance of I profile lacquer among the JG/T 224-2007 " construction steel structure protective system ".
4, the steel construction protection coating of anticorrosion double effects is not also seen product on the market at home, does not abroad appear in the newspapers yet.And the situation that flameproof protection and anticorrosive coating are fought separately in the steelwork protection works has been broken in the successful implementation of this project, with both functions can success incorporate in the engineering project system.
Embodiment
Further set forth technical characterstic of the present invention below in conjunction with specific embodiment.
1, the configuration of indoor ultrathin steel structure frie retardant coating:
Progressively slowly adding powders such as white titanium pigment, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane after pre-dispersed makes slurry fully disperseed to reach uniform state according to processes such as the deionized water in the above-mentioned raw materials prescription, dispersion agent, film coalescence aid, skimmers through grinding; Slowly add synthetic emulsion again and be in harmonious proportion, it is evenly subsequent use that evenly the back adds an amount of thickening material mediation.
Table 1: the configuration of indoor ultrathin steel structure frie retardant coating:
| Sequence number | Title material | Proportioning one | Proportioning two | Proportioning three |
| 1 | Deionized water | 250 | 220 | 200 |
| 2 | Dispersant B YK-019 | 8 | 12 | 14 |
| 3 | Film coalescence aid Texnaol | 15 | 18 | 21 |
| 4 | Skimmer B-199 | 2 | 2 | 2 |
| 5 | White titanium pigment R706 | 50 | 60 | 70 |
| 6 | 70 ℃ of clorafins | 50 | 50 | 50 |
| 7 | Ammonium polyphosphate | 240 | 220 | 200 |
| 8 | Trimeric cyanamide | 80 | 80 | 80 |
| 9 | Tetramethylolmethane | 80 | 80 | 80 |
| 10 | Expanded graphite | 50 | 60 | 70 |
| 11 | ACRYLIC EMULSION | 220 | 260 | 300 |
2, the configuration of frie retardant coating special anti-corrosion finishing paint:
Processes such as deionized water, dispersion agent, film coalescence aid, skimmer, auxiliary rheological agents progressively slowly being added powders such as white titanium pigment, mica powder, process white after pre-dispersed makes slurry fully disperseed to reach uniform state through grinding; Slowly add synthetic emulsion and be in harmonious proportion, evenly adding an amount of thickening material in back is in harmonious proportion evenly subsequent use.
Table 2: the configuration of frie retardant coating special anti-corrosion finishing paint:
| Sequence number | Title material | Proportioning one | Proportioning two | Proportioning three |
| 1 | Deionized water | 128 | 128 | 128 |
| 2 | Dispersion agent | 1(BYK-019) | 1(BYK-019) | 1(BYK-019) |
| 3 | Film coalescence aid Texnaol | 48 | 48 | 48 |
| 4 | Skimmer K5 | 7 | 7 | 7 |
| 5 | Ucar 35 | 9.5 | 9.5 | 9.5 |
| 6 | Mould inhibitor WL-3 | 5 | 5 | 5 |
| 7 | White titanium pigment (B101) | 200 | 200 | 200 |
| 8 | Thin mica powder 1250 orders of thin,tough silk | 38 | 38 | 38 |
| 9 | Process white | 3.5 | 3.5 | 3.5 |
| 10 | Emulsion | 615 (fluorine emulsions) | 615 (organosilicon crylic acid latexs) | 615 (ACRYLIC EMULSIONs) |
The frie retardant coating of embodiment 1-3 is compound according to mating at random with special-purpose anticorrosion finishing paint, do following fire retardant anticorrosion performance test:
3, the corrosion resistance nature of compound coating:
By the frie retardant coating of brushing twice again special anti-corrosion finishing paint behind brushing indoor ultrathin steel structure frie retardant coating to the specific thickness on the steel plate that is defined in 7.5cm * 15cm of I profile lacquer among the JG/T 224-2007 " construction steel structure protective system ", the condition that reaches in required time carries out carrying out the corrosion resistance nature detection after the maintenance.Its detected result is:
Acid resistance (5% sulfuric acid): 96h is no abnormal, and is qualified;
Resistance to salt water (3%NaCl): 120h is no abnormal, and is qualified.
4, the preparation of fire retardant anticorrosion compound coating:
1) successively brush the above-mentioned indoor ultrathin steel structure frie retardant coating for preparing on the 140b standard that the is defined in steel I-beam according to standard GB 14907-2002 " steel structure fire-proof paint ", thickness reaches 2 ± 0.2mm;
2) on coated fire protection coating, press the frie retardant coating of brushing twice again special anti-corrosion finishing paint of the normal maintenance application timed interval.
The total thickness of above-mentioned two kinds of coatings be up to state standards among the GB14907-2002 " steel structure fire-proof paint " regulation.Carry out maintenance according to curing time in the standard and condition.
5, the comprehensive fire endurance test of compound coating:
Fire prevention supervision inspection center of country carries out the fire endurance detection to the big girder steel that above-mentioned maintenance is good in Dujiang weir, Sichuan, and the fire endurance time of its fire retardant anticorrosion coating is 96 minutes.
In sum the fire retardant anticorrosion compound coating not only in practice of construction reality feasible, and its antiseptic property and the fire resistance requirement that all can be up to state standards.
The fire prevention of construction steel structure in the market or anticorrosion be engineering independently separately, with fire prevention and anticorrosion two functions effectively fusion be the innovation point of this project.Corrosion protection coating is certain to bring influence to fire protection coating, how to make the two effective combination, neither influences fire protection coating and meets the fire expansion, brings into play effective fire-proof function, makes the antiseptic property of corrosion protection coating self reach best again.
Exploitation aqueous environment protection steel structure fireproofing corrosion protection coating resist technology; Fire endurance is increased to 90min, reaches the performance of solvent-borne type frie retardant coating, have corrosion proof function preferably simultaneously; Realistic meaning is arranged very much; The demand for development that had both met environment protection can effectively combine flameproof protection with corrosionproof protection again, solves the difficult problem of steel structure fireproofing corrosionproof protection in the market.
Claims (5)
1. environment-friendly type steel building fire retardant anticorrosion compound coating, it is characterized in that: it is composited by fire protection coating and corrosion protection coating two portions;
Fire protection coating comprises the material of following weight ratio:
Deionized water 200-300, dispersion agent 5-20, film coalescence aid 10-30, skimmer 1-5; White titanium pigment 20-70,70 ℃ of clorafin 20-50, ammonium polyphosphate 200-350, trimeric cyanamide 50-100; NSC 65881 50-100, expanded graphite 30-100, ACRYLIC EMULSION 200-300;
The corrosion protection coating that is exclusively used in above-mentioned fire protection coating comprises the material of following weight ratio:
Deionized water 128, dispersion agent 1, film coalescence aid 48, skimmer 7, Ucar 35 9.5, mould inhibitor 5, white titanium pigment 200, the thin mica powder 38 of thin,tough silk, process white 3.5, emulsion 615.
2. a kind of environment-friendly type steel building fire retardant anticorrosion compound coating according to claim 1, it is characterized in that: in fire protection coating, described dispersion agent is BYK-019; Film coalescence aid is Texnaol; Skimmer is B-199; White titanium pigment is R706; ACRYLIC EMULSION concentration is: 45-50%.
3. a kind of environment-friendly type steel building fire retardant anticorrosion compound coating according to claim 1, it is characterized in that: in corrosion protection coating, described dispersion agent is BYK-019; Film coalescence aid is Texnaol; Skimmer is K5; Mould inhibitor is WL-3; White titanium pigment is B101; The thin mica powder of thin,tough silk is 1250 orders; Emulsion is a kind of in fluorine emulsion, organosilicon crylic acid latex and the ACRYLIC EMULSION.
4. a kind of environment-friendly type steel building fire retardant anticorrosion compound coating according to claim 1; It is characterized in that: the mass percent concentration of described emulsion is 45-55%; Wherein, Concentration is during for fluorine emulsion: 50-55%, concentration is during for organosilicon crylic acid latex: 48-52%, concentration is during for ACRYLIC EMULSION: 45-50%.
5. the preparation method of the said compound coating of claim 1 is characterized in that:
Concrete steps are:
(1) pre-dispersed process:
With deionized water, dispersant B YK-019, film coalescence aid Texnaol, skimmer B-199, white titanium pigment R706,70 ℃ of clorafins, ammonium polyphosphate, trimeric cyanamide, tetramethylolmethane, expanded graphite; Become uniform slurry through 1200 ± 50 rev/mins high speed dispersion, equipment used is the high speed dispersor of belt stirrer;
(2) grind dispersion process:
Slurry after pre-dispersed is carried out levigate dispersion through various grinding dispersing apparatus, make its fineness that reaches regulation less than 100 μ m;
(3) paint process:
The speed of levigate dispersive slurry with 700 ± 50 rev/mins is stirred at a slow speed; Add ACRYLIC EMULSION, PH regulator (AMP-95), residue skimmer B-199; The pH=7-7.5 of adjustment coating, viscosity is 120ku, makes it to reach the quality index requirement of regulation; In having the mixed cylinder of whisking appliance, carry out last discharging.
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| CN103587153A (en) * | 2012-08-13 | 2014-02-19 | 天津派尔尼尔科技发展有限公司 | Rigid polyurethane foam with fireproof function, and preparation method thereof |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
| CN104263178A (en) * | 2014-10-27 | 2015-01-07 | 徐妍玲 | Preparation method of water-based fireproof primer |
| CN105176242A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based environment-friendly expansive fireproof new material and preparing method thereof |
| CN107118644A (en) * | 2017-05-11 | 2017-09-01 | 张维秀 | A kind of building coating preparation technology |
| CN108795294A (en) * | 2018-07-04 | 2018-11-13 | 淄博旭川环保科技有限公司 | A kind of preparation process of high molecular nanometer composite coating |
| CN108864852A (en) * | 2018-06-29 | 2018-11-23 | 江苏中电科电力设计院有限公司 | Cable channel cover plate double-deck fire resistant coating and preparation method thereof |
| CN109735190A (en) * | 2019-01-15 | 2019-05-10 | 南京展拓消防设备有限公司 | A kind of the indoor ultrathin fireproof coating and its preparation process of environmental protection |
| CN111196905A (en) * | 2018-11-19 | 2020-05-26 | 上海简康新材料科技有限公司 | Fireproof coating applied to steel structure surface of building and structure and preparation method and application thereof |
| CN115305009A (en) * | 2022-08-15 | 2022-11-08 | 亚士创能科技(石家庄)有限公司 | Water-based ultrathin intumescent organic colorful fireproof coating and preparation method thereof |
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| CN103587153B (en) * | 2012-08-13 | 2015-11-11 | 天津派尔尼尔科技发展有限公司 | A kind of hard polyurethane foams with fire-proof function and preparation method thereof |
| CN102827519A (en) * | 2012-09-12 | 2012-12-19 | 山东长星集团有限公司 | Fireproof paint |
| CN102827519B (en) * | 2012-09-12 | 2015-12-09 | 山东长星集团有限公司 | A kind of flame retardant paint |
| CN104231805A (en) * | 2014-09-18 | 2014-12-24 | 江苏海晟涂料有限公司 | Water-based ultra-thin fire-retardant coating for steel structures and preparation method of fire-retardant coating |
| CN104263178A (en) * | 2014-10-27 | 2015-01-07 | 徐妍玲 | Preparation method of water-based fireproof primer |
| CN105176242A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based environment-friendly expansive fireproof new material and preparing method thereof |
| CN107118644A (en) * | 2017-05-11 | 2017-09-01 | 张维秀 | A kind of building coating preparation technology |
| CN108864852A (en) * | 2018-06-29 | 2018-11-23 | 江苏中电科电力设计院有限公司 | Cable channel cover plate double-deck fire resistant coating and preparation method thereof |
| CN108795294A (en) * | 2018-07-04 | 2018-11-13 | 淄博旭川环保科技有限公司 | A kind of preparation process of high molecular nanometer composite coating |
| CN111196905A (en) * | 2018-11-19 | 2020-05-26 | 上海简康新材料科技有限公司 | Fireproof coating applied to steel structure surface of building and structure and preparation method and application thereof |
| CN109735190A (en) * | 2019-01-15 | 2019-05-10 | 南京展拓消防设备有限公司 | A kind of the indoor ultrathin fireproof coating and its preparation process of environmental protection |
| CN115305009A (en) * | 2022-08-15 | 2022-11-08 | 亚士创能科技(石家庄)有限公司 | Water-based ultrathin intumescent organic colorful fireproof coating and preparation method thereof |
| CN115305009B (en) * | 2022-08-15 | 2023-11-07 | 亚士创能科技(石家庄)有限公司 | Water-based ultrathin intumescent organic colorful fireproof coating and preparation method thereof |
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