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CN102410990A - High-sensitivity micro-nano optical fiber refractive index sensor and preparation method thereof - Google Patents

High-sensitivity micro-nano optical fiber refractive index sensor and preparation method thereof Download PDF

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CN102410990A
CN102410990A CN2011102178664A CN201110217866A CN102410990A CN 102410990 A CN102410990 A CN 102410990A CN 2011102178664 A CN2011102178664 A CN 2011102178664A CN 201110217866 A CN201110217866 A CN 201110217866A CN 102410990 A CN102410990 A CN 102410990A
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optical fiber
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refractive index
polarization
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CN102410990B (en
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李�杰
关柏鸥
金龙
孙立朋
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Jinan University
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Abstract

The invention discloses a high-sensitivity micro-nano optical fiber refractive index sensor and a preparation method thereof, wherein the sensor comprises a broadband light source, an optical fiber annular mirror and a spectrum analyzer which are sequentially connected along an optical transmission path, wherein the optical fiber annular mirror comprises an optical fiber coupler, a birefringent micro-nano optical fiber and a polarization controller which are connected along the optical transmission path; after light emitted by the broadband light source enters the optical fiber ring mirror, the formed two light propagating in opposite directions generate polarization phase difference through the birefringent micro-nano optical fiber, form polarization interference after passing through the polarization controller, and finally are detected and output by the spectrum analyzer. The invention adopts the birefringent micro-nano optical fiber for sensing, the optical fiber has a rectangular or quasi-rectangular double symmetrical structure, and the polarization interference spectrogram obtained by utilizing the unique birefringence and the birefringence scattering effect changes along with the change of the surrounding refractive index, thereby obtaining the ultrahigh sensing sensitivity.

Description

一种高灵敏度微纳光纤折射率传感器及其制备方法A high-sensitivity micro-nano optical fiber refractive index sensor and its preparation method

技术领域 technical field

本发明涉及光纤折射率传感器技术领域,特别涉及一种高灵敏度微纳光纤折射率传感器及其制备方法。The invention relates to the technical field of optical fiber refractive index sensors, in particular to a high-sensitivity micro-nano optical fiber refractive index sensor and a preparation method thereof.

背景技术 Background technique

折射率传感用于探测外界环境的折射率的变化,由于折射率是物质的基本属性,它在物理、生物、化学等学科领域是一个重要的参数,因此折射率传感对环境监测、食品安全、医药开发、临床检验等相关领域有重要的意义和用途。光纤折射率传感器以其灵敏度高、抗电磁干扰能力强、响应速度快、抗生化腐蚀、体积小、重量轻、无毒、操控灵活方便以及低能量损耗的远距离传输能力等优点,克服了传统方法包括掠入射法、衍射光栅法、宽带吸收光谱法等不足,其发展一直受到人们的关注。许多光纤型折射率传感器应运而生,其实现原理包括表面等离子体、长周期光栅、模间干涉、微流控多孔光纤等多种类型。Refractive index sensing is used to detect changes in the refractive index of the external environment. Since the refractive index is a basic property of matter, it is an important parameter in the fields of physics, biology, chemistry and other disciplines. Therefore, the refractive index sensor is very important for environmental monitoring, food Safety, pharmaceutical development, clinical testing and other related fields have important significance and applications. The optical fiber refractive index sensor overcomes the traditional sensor with its advantages of high sensitivity, strong anti-electromagnetic interference ability, fast response speed, anti-biochemical corrosion, small size, light weight, non-toxicity, flexible and convenient operation, and long-distance transmission capability with low energy loss. The methods include grazing incidence method, diffraction grating method, broadband absorption spectroscopy and so on, and their development has always been paid attention to by people. Many fiber-optic refractive index sensors have emerged, and their realization principles include surface plasmons, long-period gratings, intermode interference, and microfluidic porous fibers.

近年来微纳光纤吸引了人们的研究兴趣,由于微纳光纤具有强消逝场效应,对折射率传感有着先天的优势,提出的实现方法包括微纳光纤环形结、布拉格光栅、长周期光栅、传输能量检测等,然而这些方法的传感灵敏度目前仍受到很大的局限,例如文献“Fei Xu,Valerio Pruneri,Vittoria Finazzi,Gilberto Brambilla.An embedded optical nanowire loop resonator refractometric sensor.Optics Express,2008,16(2):1062-1067.”提出将微纳光纤打成环形结并用聚合物封装,这种方法制作工艺较复杂,理论获得灵敏度为700nm/RIU(单位折射率)。又如文献“X.Fang,C.R.Liao,D.N.Wang.Femtosecond laser fabricated fiber Bragg grating inmicrofiber for refractive index sensing.Optics Letters,2010,35(7):1007-1009.”利用飞秒激光器在微纳光纤上刻写布拉格光栅制作折射率传感器,测量获得的灵敏度最大为234.1nm/RIU。再如文献“Haifeng Xuan,Wei Jin,and Shujing Liu.Long-period gratings in wavelength-scale microfibers.Optics Letters,2010,35(1):85-87.”利用飞秒激光刻写技术在微纳光纤中写入长周期光栅,测量的灵敏度达到1900nm/RIU,灵敏度稍低且飞秒激光昂贵,另外飞秒激光刻写技术对光纤结构有破坏作用。In recent years, micro-nano fiber has attracted people's research interest. Due to the strong evanescent field effect of micro-nano fiber, it has inherent advantages in refractive index sensing. The proposed implementation methods include micro-nano fiber ring junction, Bragg grating, long-period grating, Transmission energy detection, etc., but the sensing sensitivity of these methods is still greatly limited, for example, the literature "Fei Xu, Valerio Pruneri, Vittoria Finazzi, Gilberto Brambilla.An embedded optical nanowire loop resonator refractometric sensor. Optics Express, 2008, 16 (2): 1062-1067." It is proposed to tie the micro-nano optical fiber into a ring junction and encapsulate it with a polymer. This method has a complicated manufacturing process, and the theoretically obtained sensitivity is 700nm/RIU (refractive index unit). Another example is the document "X.Fang, C.R.Liao, D.N.Wang. Femtosecond laser fabricated fiber Bragg grating inmicrofiber for reactive index sensing. Optics Letters, 2010, 35(7): 1007-1009." Write the Bragg grating to make the refractive index sensor, and the measured sensitivity is up to 234.1nm/RIU. Another example is the document "Haifeng Xuan, Wei Jin, and Shujing Liu. Long-period gratings in wavelength-scale microfibers. Optics Letters, 2010, 35(1): 85-87." Using femtosecond laser writing technology in micro-nano fibers Writing long-period gratings, the measurement sensitivity reaches 1900nm/RIU, the sensitivity is slightly lower and the femtosecond laser is expensive. In addition, the femtosecond laser writing technology has a destructive effect on the fiber structure.

发明内容 Contents of the invention

本发明的目的在于克服现有技术的缺点与不足,提供一种高灵敏度微纳光纤折射率传感器,利用双折射微纳光纤的独特的双折射及其色散效应,获得现有方法中所无法达到的超高灵敏度。The purpose of the present invention is to overcome the shortcomings and deficiencies of the prior art, to provide a high-sensitivity micro-nano optical fiber refractive index sensor, which utilizes the unique birefringence and dispersion effect of the birefringent micro-nano optical fiber to obtain ultra-high sensitivity.

本发明的另一目的在于,提供一种高灵敏度微纳光纤折射率传感器的制备方法,使之具有更高的折射率传感灵敏度,可以实现对外界环境折射率微变量的实时传感和快速检测。Another object of the present invention is to provide a method for preparing a high-sensitivity micro-nano optical fiber refractive index sensor, so that it has higher refractive index sensing sensitivity, and can realize real-time sensing and rapid detection of micro-variable refractive index in the external environment. detection.

为了达到上述目的,本发明采用以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:

本发明高灵敏度微纳光纤折射率传感器,包括沿光传输路径顺序连接的宽带光源、光纤环形镜和光谱分析仪,其中光纤环形镜包括沿光传输路径连接的光纤耦合器、双折射微纳光纤和第一偏振控制器;由宽带光源发出的光经光纤耦合器进入光纤环形镜后,形成两个相反方向传播的光束,其中一束依次经过第一偏振控制器和双折射微纳光纤,另一束则依次经过双折射微纳光纤和第一偏振控制器,这两束光产生偏振相位差,经光纤耦合器合波后形成偏振干涉光谱,最后由光谱分析仪检测输出。The high-sensitivity micro-nano optical fiber refractive index sensor of the present invention includes a broadband light source, an optical fiber loop mirror and a spectrum analyzer sequentially connected along the optical transmission path, wherein the optical fiber loop mirror includes an optical fiber coupler connected along the optical transmission path, a birefringent micro-nano optical fiber and the first polarization controller; after the light emitted by the broadband light source enters the fiber optic loop mirror through the fiber coupler, two beams propagating in opposite directions are formed, one of which passes through the first polarization controller and the birefringent micro-nano fiber in turn, and the other One beam passes through the birefringent micro-nano fiber and the first polarization controller in turn. The two beams produce a polarization phase difference, and after being combined by a fiber coupler, a polarization interference spectrum is formed, and finally the output is detected by a spectrum analyzer.

所述双折射微纳光纤通常在具有矩形或类矩形的二重对称结构包层的光纤上,采用传统光纤熔拉技术,对光纤进行高温加热和熔融拉锥,使横截面的最长边尺寸小于10μm,两端熔接标准光纤,连接各种光纤仪器。The birefringent micro-nano optical fiber is usually on an optical fiber with a rectangular or quasi-rectangular double symmetrical structure cladding, using traditional optical fiber melting and drawing technology to heat and melt the optical fiber at high temperature, so that the longest side dimension of the cross section Less than 10μm, the two ends of the standard optical fiber are fused to connect various optical fiber instruments.

优选的,所述光纤环形镜还包括第二偏振控制器和保偏光纤,所述光纤耦合器、第一偏振控制器、双折射微纳光纤、第二偏振控制器及保偏光纤沿光传输路径顺序连接,所述第二偏振控制器用于调节干涉光谱的疏密程度,所述保偏光纤作为参考光纤,可以提高传感器的灵敏度。Preferably, the fiber optic loop mirror also includes a second polarization controller and a polarization-maintaining fiber, and the fiber coupler, the first polarization controller, the birefringent micro-nano fiber, the second polarization controller and the polarization-maintaining fiber are along the light transmission The paths are connected in sequence, the second polarization controller is used to adjust the density of the interference spectrum, and the polarization-maintaining fiber is used as a reference fiber to improve the sensitivity of the sensor.

优选的,所述保偏光纤是双折射微纳光纤、熊猫型保偏光纤、领结型保偏光纤、椭圆型保偏光纤或保偏光子晶体光纤。Preferably, the polarization-maintaining fiber is a birefringent micro-nano fiber, a panda-type polarization-maintaining fiber, a bow-tie-type polarization-maintaining fiber, an elliptical-type polarization-maintaining fiber or a polarization-maintaining photonic crystal fiber.

优选的,所述光纤耦合器分光比通常为50%∶50%。Preferably, the light splitting ratio of the fiber coupler is usually 50%:50%.

优选的,所述双折射微纳光纤的横截面为矩形或类矩形的二重对称结构。Preferably, the cross-section of the birefringent micro-nano optical fiber is a rectangle or a double-symmetric structure similar to a rectangle.

所述双折射微纳光纤包括光纤纤芯和将所述光纤纤芯包围的光纤包层。The birefringent micro-nano optical fiber includes an optical fiber core and an optical fiber cladding surrounding the optical fiber core.

所述光纤纤芯折射率高于光纤包层折射率。The refractive index of the optical fiber core is higher than that of the optical fiber cladding.

为了达到上述另一目的,本发明采用以下技术方案:一种高灵敏度微纳光纤折射率传感器的制备方法,包括以下步骤:In order to achieve the above another purpose, the present invention adopts the following technical solutions: a method for preparing a high-sensitivity micro-nano optical fiber refractive index sensor, comprising the following steps:

(1)、选取双折射微纳光纤,所述双折射微纳光纤的横截面结构为矩形或类矩形的二重对称结构;(1), select the birefringent micro-nano fiber, the cross-sectional structure of the birefringent micro-nano fiber is a double symmetric structure of a rectangle or a rectangle;

(2)、采用光纤耦合器,将光纤耦合器同侧的两个端口分别连接宽带光源和光谱分析仪;(2), using a fiber coupler, connect the two ports on the same side of the fiber coupler to the broadband light source and the spectrum analyzer respectively;

(3)、所述光纤耦合器另一侧的两个端口间连接双折射微纳光纤和偏振控制器后组成闭合光路,从而构成包含微纳光纤的光纤环形镜。(3) Two ports on the other side of the fiber coupler are connected to a birefringent micro-nano fiber and a polarization controller to form a closed optical path, thereby forming a fiber loop mirror including a micro-nano fiber.

本发明相对于现有技术具有如下的优点及效果:Compared with the prior art, the present invention has the following advantages and effects:

1、本发明提出了一种高灵敏度微纳光纤折射率传感器,采用二重对称结构的双折射微纳光纤,利用其独特的双折射及双折射色散特性,实现了超高灵敏度的折射率传感,本发明突破了现有方案对灵敏性的限制,其灵敏度可达5000~100000nm/RIU。1. The present invention proposes a high-sensitivity micro-nano optical fiber refractive index sensor, which adopts a birefringent micro-nano optical fiber with a double symmetrical structure, and utilizes its unique birefringence and birefringence dispersion characteristics to realize ultra-high sensitivity refractive index transmission. Sensitivity, the present invention breaks through the sensitivity limitation of the existing scheme, and its sensitivity can reach 5000-100000nm/RIU.

2、本发明与传统光学折射率传感方法相比,具有体积小、重量轻、可与光纤系统兼容、可远距离监测等优点。2. Compared with the traditional optical refractive index sensing method, the present invention has the advantages of small size, light weight, compatibility with optical fiber systems, and remote monitoring.

3、本发明与其它光纤型折射率传感方法相比,具有尺寸更小、结构简单、便于集成、反应速度快等优点。3. Compared with other optical fiber-type refractive index sensing methods, the present invention has the advantages of smaller size, simple structure, easy integration, fast response speed and the like.

4、本发明与现有微纳光纤型折射率传感技术相比,具有更高的灵敏度(灵敏度可提高一个数量级以上),且测量稳定性好。4. Compared with the existing micro-nano optical fiber refractive index sensing technology, the present invention has higher sensitivity (the sensitivity can be increased by more than one order of magnitude), and the measurement stability is good.

5、本发明避免了将待测物质装进光纤微孔结构之中,而直接将传感光纤置于待测物质之中传感,实现了快速、准确传感,因此具有巨大的应用潜力。5. The present invention avoids loading the substance to be measured into the micropore structure of the optical fiber, and directly places the sensing fiber in the substance to be measured for sensing, thereby realizing fast and accurate sensing, so it has great application potential.

附图说明 Description of drawings

图1是基于偏振干涉的微纳光纤折射率传感器;Figure 1 is a micro-nano fiber optic refractive index sensor based on polarization interference;

图2是双折射微纳光纤横截面示意图;Fig. 2 is a cross-sectional schematic diagram of a birefringent micro-nano fiber;

图3是传感光纤与待测物质分界面的示意图;Fig. 3 is a schematic diagram of the interface between the sensing fiber and the substance to be measured;

图4是应用本发明的传感器进行折射率溶液的测量数据与理论计算曲线;Fig. 4 is the measurement data and the theoretical calculation curve of the refractive index solution using the sensor of the present invention;

图5是改进后的微纳光纤折射率传感器;Fig. 5 is the improved micro-nano fiber optic refractive index sensor;

图6是不同参考光纤长度的透射谱对应的波长与折射率的关系。Fig. 6 is the relationship between the wavelength and the refractive index corresponding to the transmission spectra of different reference fiber lengths.

具体实施方式 Detailed ways

下面结合实施例及附图对本发明作进一步详细的描述,但本发明的实施方式不限于此。The present invention will be further described in detail below in conjunction with the embodiments and the accompanying drawings, but the embodiments of the present invention are not limited thereto.

实施例1Example 1

如图1所示,一种高灵敏度微纳光纤折射率传感器包括沿光传输路径顺序相连的宽带光源1、分光比为50%∶50%的光纤耦合器2、双折射微纳光纤3、第一偏振控制器4和光谱分析仪5,其中光纤耦合器2、双折射微纳光纤3和第一偏振控制器4构成光纤环形镜;由宽带光源1发出的光经光纤耦合器2进入光纤环形镜后,形成两个相反方向传播的光束,其中一束依次经过第一偏振控制器4和双折射微纳光纤3,另一束则依次经过双折射微纳光纤3和第一偏振控制器4,这两束光产生偏振相位差,通过调节第一偏振控制器4,经光纤耦合器2合波后形成偏振干涉光谱,出射光谱经光谱分析仪5检测输出,改变双折射微纳光纤3周围待测物质的折射率,计算干涉光谱的波长漂移量,进而推断出待测物质折射率的变化。As shown in Figure 1, a high-sensitivity micro-nano optical fiber refractive index sensor includes a broadband light source 1 sequentially connected along the optical transmission path, an optical fiber coupler 2 with a splitting ratio of 50%:50%, a birefringent micro-nano optical fiber 3, and A polarization controller 4 and a spectrum analyzer 5, wherein the fiber coupler 2, the birefringent micro-nano fiber 3 and the first polarization controller 4 form a fiber optic ring mirror; the light emitted by the broadband light source 1 enters the fiber ring through the fiber coupler 2 After the mirror, two light beams propagating in opposite directions are formed, one of which passes through the first polarization controller 4 and the birefringent micro-nano fiber 3 in sequence, and the other passes through the birefringent micro-nano fiber 3 and the first polarization controller 4 in sequence , the two beams of light produce a polarization phase difference. By adjusting the first polarization controller 4, the polarization interference spectrum is formed after the optical fiber coupler 2 is combined. Calculate the refractive index of the substance to be measured, calculate the wavelength shift of the interference spectrum, and then deduce the change of the refractive index of the substance to be measured.

图2是本发明的双折射微纳光纤3的横截面示意图,它包括掺锗光纤纤芯6和由二氧化硅材料制成的光纤包层7,光纤纤芯6为圆形结构,光纤包层7为矩形结构,它设置在光纤纤芯6的四周,将光纤纤芯6包围;典型光纤包层的最长边尺寸不超过10μm。光纤纤芯折射率高于光纤包层折射率。Fig. 2 is the schematic cross-sectional view of birefringent micro-nano optical fiber 3 of the present invention, and it comprises germanium-doped optical fiber core 6 and the optical fiber cladding 7 that is made of silica material, and optical fiber core 6 is circular structure, and optical fiber cladding The layer 7 is a rectangular structure, which is arranged around the fiber core 6 and surrounds the fiber core 6; the longest side dimension of a typical fiber cladding is not more than 10 μm. The refractive index of the fiber core is higher than that of the fiber cladding.

在图3中,示意了传感光纤与待测物质的分界面,8表示微纳光纤传感段,9表示待测物质,10表示待测物质与外界环境的分界面,11表示光纤封装位置。In Figure 3, the interface between the sensing fiber and the substance to be measured is shown, 8 represents the micro-nano optical fiber sensing section, 9 represents the substance to be measured, 10 represents the interface between the substance to be measured and the external environment, and 11 represents the optical fiber packaging position .

图4表示实验测量得到出射光谱的波谷位置对应的波长与折射率的关系,在本实例中,将微纳光纤置于蔗糖溶液当中,通过调整蔗糖浓度以改变溶液的折射率,在图4中,圆圈表示实例测量数据点,实线表示由下述方程(1)得到的数值拟合曲线,可见测量值能很好地与理论值相符合;在测量中,波长随着折射率增大而增大,在水溶液附近即折射率1.333左右,实验获得的灵敏度分别为12511nm/RIU,13441nm/RIU,18987nm/RIU,18677nm/RIU,最大灵敏度达到18987nm/RIU。Figure 4 shows the relationship between the wavelength and the refractive index corresponding to the trough position of the outgoing spectrum obtained from experimental measurements. In this example, the micro-nano optical fiber is placed in a sucrose solution, and the refractive index of the solution is changed by adjusting the sucrose concentration. In Figure 4 , the circle represents the example measurement data points, the solid line represents the numerical fitting curve obtained by the following equation (1), it can be seen that the measured value can be well consistent with the theoretical value; in the measurement, the wavelength increases with the refractive index In the vicinity of the aqueous solution, the refractive index is about 1.333. The experimentally obtained sensitivities are 12511nm/RIU, 13441nm/RIU, 18987nm/RIU, 18677nm/RIU, and the maximum sensitivity reaches 18987nm/RIU.

实施例2Example 2

上述实施例1的高灵敏度微纳光纤折射率传感器可做如下改进,如图5所示为改进后的折射率传感器,与图1不同的是,在微纳光纤的一侧通过标准光纤依次连接一个第二偏振控制器12和保偏光纤13,该保偏光纤13作为参考光纤,在本实例中为领结型保偏光纤,通过调节第二偏振控制器12可调节干涉光谱的疏密程度,我们将干涉光谱调成疏的状态,对应两个双折射光纤引起偏振相位差相减的情况,如下文方程(3)所示,同时调节第一偏振控制器4以增强干涉谱图的消光比便于测量。The high-sensitivity micro-nano optical fiber refractive index sensor of the above-mentioned embodiment 1 can be improved as follows, as shown in Figure 5, the improved refractive index sensor is different from Figure 1 in that one side of the micro-nano optical fiber is sequentially connected through a standard optical fiber A second polarization controller 12 and polarization-maintaining fiber 13, this polarization-maintaining fiber 13 is as a reference fiber, in this example is a bow-tie type polarization-maintaining fiber, by adjusting the second polarization controller 12 can adjust the degree of density of the interference spectrum, We adjust the interference spectrum to a sparse state, corresponding to the situation where two birefringent fibers cause polarization phase difference subtraction, as shown in equation (3) below, and at the same time adjust the first polarization controller 4 to enhance the extinction ratio of the interference spectrum Easy to measure.

图6给出了不同领结光纤长度测得的出射谱波谷位置对应的波长与折射率的关系,其中离散点表示测量的结果,实线则表示采用二次方程拟合的结果,图中分别给出了有参考光纤和无参考光纤时的数据测量和理论拟合,结果表明:在波长1550附近,无参考光纤时传感器的折射率灵敏度为7151nm/RIU,而在保偏光纤长度为4.7cm和10.8cm时,对应折射率灵敏度分别为26065nm/RIU和-16196nm/RIU,可见加入参考光纤后其绝对灵敏度得到大幅提高,与理论预测相符。Figure 6 shows the relationship between the wavelength and the refractive index corresponding to the position of the trough of the exit spectrum measured with different bow-tie fiber lengths, where the discrete points represent the measurement results, and the solid line represents the result of the quadratic equation fitting. The data measurement and theoretical fitting with reference fiber and without reference fiber are shown. The results show that: near the wavelength of 1550, the refractive index sensitivity of the sensor without reference fiber is 7151nm/RIU, while the length of polarization-maintaining fiber is 4.7cm and At 10.8cm, the corresponding refractive index sensitivities are 26065nm/RIU and -16196nm/RIU, respectively. It can be seen that the absolute sensitivity is greatly improved after adding the reference fiber, which is consistent with the theoretical prediction.

本发明高灵敏度微纳光纤折射率传感器的制备方法,包括下述步骤:The preparation method of the high-sensitivity micro-nano optical fiber refractive index sensor of the present invention comprises the following steps:

(一)、选取微纳光纤,所述微纳光纤横截面结构为矩形或类矩形的二重对称结构的双折射微纳光纤,经过光纤横截面中心的最长边和最短边的长度比值为1.05~5.0,它们的尺寸为10nm~10μm;该微纳光纤是在具有矩形或类矩形的二重对称结构包层的光纤上,利用常规光纤熔拉技术,对光纤进行高温加热和熔融拉锥制作而成;所述微纳光纤的两端熔接标准光纤,连接各种光纤仪器。(1), select the micro-nano optical fiber, the cross-sectional structure of the micro-nano optical fiber is a birefringent micro-nano optical fiber with a rectangular or rectangular double symmetric structure, and the length ratio of the longest side and the shortest side passing through the center of the optical fiber cross section is 1.05~5.0, their size is 10nm~10μm; the micro-nano fiber is on the optical fiber with rectangular or quasi-rectangular double symmetrical structure cladding, using conventional optical fiber melting and drawing technology to heat and melt the optical fiber at high temperature Manufactured; the two ends of the micro-nano optical fiber are fused with standard optical fibers to connect various optical fiber instruments.

(二)、将步骤(一)的双折射微纳光纤熔接到光纤环形镜上,具体是:采用光纤耦合器(分光比通常为50%∶50%),光纤耦合器同侧的两个端口分别连接宽带光源和光谱分析仪,另一侧的两个端口之间依次连接双折射微纳光纤和偏振控制器后组成闭合光路,从而构成包含微纳光纤的光纤环形镜,即为微纳光纤折射率传感器,由于双折射微纳光纤的双折射效应,在光纤中传输光波的两个偏振态产生光程差,调整偏振控制器的状态,即可在光谱分析仪得到偏振干涉谱图。(2), the birefringent micro-nano fiber of step (1) is fused to the fiber optic loop mirror, specifically: using a fiber coupler (the splitting ratio is usually 50%: 50%), two ports on the same side of the fiber coupler The broadband light source and the spectrum analyzer are respectively connected, and the birefringent micro-nano fiber and the polarization controller are connected in sequence between the two ports on the other side to form a closed optical path, thus forming a fiber loop mirror containing the micro-nano fiber, which is the micro-nano fiber Refractive index sensor, due to the birefringence effect of the birefringent micro-nano fiber, the two polarization states of the light wave transmitted in the fiber produce an optical path difference, adjust the state of the polarization controller, and the polarization interference spectrum can be obtained in the spectrum analyzer.

在上述光纤环形镜中,由于双折射效应引起偏振干涉的透射谱表示为T=sin2(Φ/2),其中Φ是偏振相位差,表示为:In the above-mentioned fiber optic loop mirror, the transmission spectrum of the polarization interference due to the birefringence effect is expressed as T=sin 2 (Φ/2), where Φ is the polarization phase difference, expressed as:

Φ=(2π/λ)BL        (1)Φ=(2π/λ)BL (1)

其中,λ是光波长,B=ni-nj是微纳光纤双折射,ni、nj分别是波导两个偏振模式的有效折射率,L是微纳光纤的长度。为理论计算波长随折射率的变化率,在方程(1)中,假设相位差Φ不变,折射率的微变量Δn将引起双折射改变,从而波长发生漂移,同时考虑光纤的双折射色散效应对方程(1)进行微分操作,得到灵敏度公式为:Among them, λ is the wavelength of light, B=n i -n j is the birefringence of the micro-nano fiber, n i and n j are the effective refractive indices of the two polarization modes of the waveguide respectively, and L is the length of the micro-nano fiber. In order to theoretically calculate the change rate of wavelength with the refractive index, in equation (1), assuming that the phase difference Φ is constant, the microvariable Δn of the refractive index will cause the birefringence to change, so that the wavelength will drift, and the birefringence dispersion effect of the fiber is considered at the same time Differentiate the equation (1), and the sensitivity formula is obtained as:

SS == ΔλΔλ ΔnΔ n == λλ ·&Center Dot; ∂∂ BB // ∂∂ nno BB -- λλ ∂∂ BB // ∂∂ λλ == λλ GG ∂∂ BB ∂∂ nno -- -- -- (( 22 ))

其中,

Figure BDA0000080261420000062
是折射率导致的双折射变化率,G是光纤的群双折射,由方程(2)可知灵敏度的大小除了与波长λ和双折射变化率
Figure BDA0000080261420000063
相关外,还与群双折射G的大小相关,而G的大小与双折射色散值
Figure BDA0000080261420000064
相关,当G趋近于零时,器件灵敏度将变得非常大。in,
Figure BDA0000080261420000062
is the birefringence change rate caused by the refractive index, and G is the group birefringence of the fiber. From equation (2), it can be known that the sensitivity is not related to the wavelength λ and the birefringence change rate
Figure BDA0000080261420000063
In addition to correlation, it is also related to the size of the group birefringence G, and the size of G is related to the birefringence dispersion value
Figure BDA0000080261420000064
Related, when G approaches zero, the device sensitivity will become very large.

(三)、将上述传感器的双折射微纳光纤置于待测物质中,由于物质的折射率变化引起器件的干涉谱图发生漂移,测量其波长漂移量从而可探知物质折射率的变化。(3) Place the birefringent micro-nano optical fiber of the above sensor in the substance to be measured, the interference spectrum of the device will drift due to the change of the refractive index of the substance, and the change of the refractive index of the substance can be detected by measuring the amount of wavelength shift.

在上述方案的基础上,为进一步提高传感灵敏度,可对微纳光纤折射率传感器做如下改进,在双折射微纳光纤的一侧通过标准光纤依次连接一个偏振控制器和一段普通保偏光纤作为参考光纤,该参考光纤本身不参与传感,它起的作用是调制器件的折射率传感灵敏度,参考光纤可以是高双折射微纳光纤,或是传统的熊猫型保偏光纤、领结型保偏光纤或椭圆型保偏光纤等,也可以是保偏光子晶体光纤。由于干涉系统中有两个双折射光纤,其相位差表达式(1)变为:On the basis of the above scheme, in order to further improve the sensing sensitivity, the following improvements can be made to the micro-nano optical fiber refractive index sensor. A polarization controller and a section of ordinary polarization-maintaining optical fiber are sequentially connected to one side of the birefringent micro-nano optical fiber through a standard optical fiber As a reference fiber, the reference fiber itself does not participate in sensing, it plays a role in modulating the refractive index sensing sensitivity of the device. The reference fiber can be a high-birefringence micro-nano fiber, or a traditional panda-type polarization-maintaining fiber, bow-tie type Polarization-maintaining optical fiber or elliptical polarization-maintaining optical fiber, etc., may also be polarization-maintaining photonic crystal optical fiber. Since there are two birefringent fibers in the interference system, the phase difference expression (1) becomes:

Φ=(2π/λ)(B1L1±B2L2)        (3)Φ=(2π/λ)(B 1 L 1 ±B 2 L 2 ) (3)

其中,“+”和“-”分别表示两个双折射光纤引起偏振相位差相增和相减两个状态,可通过调节光纤间的偏振控制器实现,B1和L1对应第一个双折射微纳光纤,B2和L2对应第二个保偏光纤。由于外界折射率变化引起第一个光纤的B1发生变化,从而由方程(3)可知波长发生改变,波长的改变又引起第二个光纤的B2发生改变,同样地,对方程(3)进行微分操作,可得到折射率灵敏度公式为:Among them, "+" and "-" represent two birefringent fibers causing polarization phase difference phase increase and phase subtraction respectively, which can be realized by adjusting the polarization controller between the fibers, B 1 and L 1 correspond to the first birefringent fiber Refractive micro-nano fiber, B 2 and L 2 correspond to the second polarization-maintaining fiber. Due to the change of B1 of the first optical fiber due to the change of the external refractive index, it can be seen from the equation (3) that the wavelength changes, and the change of the wavelength causes the B2 of the second optical fiber to change. Similarly, the equation (3) is Differential operation, the refractive index sensitivity formula can be obtained as:

SS == ΔλΔλ ΔnΔn == λLλL 11 ·&Center Dot; ∂∂ BB 11 // ∂∂ nno GG 11 LL 11 ±± GG 22 LL 22 -- -- -- (( 44 ))

其中,G1和G2分别表示第一个双折射微纳光纤和第二个保偏光纤的群双折射,只要通过选择两个光纤的双折射参数和调节光纤长度使|G1L1±G2L2|趋近于零,可大幅提高器件的传感灵敏度。Among them, G 1 and G 2 represent the group birefringence of the first birefringent micro-nano fiber and the second polarization-maintaining fiber, as long as |G 1 L 1 ± G 2 L 2 | tends to zero, which can greatly improve the sensing sensitivity of the device.

上述实施例为本发明较佳的实施方式,但本发明的实施方式并不受上述实施例的限制,其他的任何未背离本发明的精神实质与原理下所作的改变、修饰、替代、组合、简化,均应为等效的置换方式,都包含在本发明的保护范围之内。The above-mentioned embodiment is a preferred embodiment of the present invention, but the embodiment of the present invention is not limited by the above-mentioned embodiment, and any other changes, modifications, substitutions, combinations, Simplifications should be equivalent replacement methods, and all are included in the protection scope of the present invention.

Claims (8)

1. A high-sensitivity micro-nano optical fiber refractive index sensor is characterized by comprising a broadband light source, an optical fiber ring mirror and a spectrum analyzer which are sequentially connected along an optical transmission path, wherein the optical fiber ring mirror comprises an optical fiber coupler, a first polarization controller and a birefringent micro-nano optical fiber which are sequentially connected along the optical transmission path; light emitted by a broadband light source enters the optical fiber ring mirror through the optical fiber coupler to form two light beams which are transmitted in opposite directions, one light beam sequentially passes through the first polarization controller and the birefringent micro-nano optical fiber, the other light beam sequentially passes through the birefringent micro-nano optical fiber and the first polarization controller, the two light beams generate polarization phase differences, the polarization interference spectrum is formed after wave combination through the optical fiber coupler, and finally the polarization interference spectrum is detected and output by the optical spectrum analyzer.
2. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 1, wherein the optical fiber ring mirror further comprises a second polarization controller and a polarization maintaining optical fiber, the optical fiber coupler, the first polarization controller, the birefringence micro-nano optical fiber, the second polarization controller and the polarization maintaining optical fiber are sequentially connected along an optical transmission path, the second polarization controller is used for adjusting the density degree of an interference spectrum, and the polarization maintaining optical fiber is used as a reference optical fiber.
3. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 2, wherein the polarization maintaining optical fiber is a birefringent micro-nano optical fiber, a panda type polarization maintaining optical fiber, a bow-tie type polarization maintaining optical fiber, an elliptical type polarization maintaining optical fiber or a polarization maintaining photonic crystal optical fiber.
4. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 1, wherein the fiber coupler splitting ratio is 50% to 50%.
5. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 1, wherein the birefringent micro-nano optical fiber comprises an optical fiber core and an optical fiber cladding surrounding the optical fiber core.
6. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 5, wherein the cross section of the optical fiber cladding is a rectangular or rectangular-like double symmetrical structure.
7. The high-sensitivity micro-nano optical fiber refractive index sensor according to claim 5, wherein the refractive index of the fiber core is higher than that of the fiber cladding.
8. The preparation method of the high-sensitivity micro-nano optical fiber refractive index sensor according to any one of claims 1 to 7, which is characterized by comprising the following steps of:
(1) selecting a birefringent micro-nano optical fiber, wherein the cross section structure of the birefringent micro-nano optical fiber is a rectangular or quasi-rectangular double symmetrical structure;
(2) connecting two ports on the same side of the optical fiber coupler with a broadband light source and a spectrum analyzer respectively by adopting the optical fiber coupler;
(3) and the birefringence micro-nano optical fiber and the first polarization controller are sequentially connected between the two ports on the other side of the optical fiber coupler to form a closed optical path, so that the optical fiber annular mirror containing the birefringence micro-nano optical fiber is formed.
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CN113740587A (en) * 2021-08-30 2021-12-03 国网陕西省电力公司电力科学研究院 VFTO sensor and preparation method and application thereof
CN114460044A (en) * 2022-02-18 2022-05-10 北京航空航天大学 Reflective all-fiber hydrogen concentration and humidity sensor

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