CN102391836B - Capillary crystalline type waterproofing agent - Google Patents
Capillary crystalline type waterproofing agent Download PDFInfo
- Publication number
- CN102391836B CN102391836B CN 201110191320 CN201110191320A CN102391836B CN 102391836 B CN102391836 B CN 102391836B CN 201110191320 CN201110191320 CN 201110191320 CN 201110191320 A CN201110191320 A CN 201110191320A CN 102391836 B CN102391836 B CN 102391836B
- Authority
- CN
- China
- Prior art keywords
- water
- waterproofing agent
- terpolymer
- capillary crystalline
- capillary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004078 waterproofing Methods 0.000 title claims abstract description 17
- 229920001897 terpolymer Polymers 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 239000002178 crystalline material Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012153 distilled water Substances 0.000 claims abstract description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 5
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 5
- 239000000920 calcium hydroxide Substances 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- -1 titanic acid ester Chemical class 0.000 claims description 5
- XEPHLVLFTHOHGU-UHFFFAOYSA-L dipotassium sulfate dihydrate Chemical compound O.O.[K+].[K+].[O-]S([O-])(=O)=O XEPHLVLFTHOHGU-UHFFFAOYSA-L 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 4
- 241000894006 Bacteria Species 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004568 cement Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention discloses a capillary crystalline type waterproofing agent, which consists of terpolymer, L type water-soluble capillary crystalline materials and distilled water, and the weight ratio of the three materials is 25 to 50:2 to 8:50 to 250. The capillary crystalline type waterproofing agent has the characteristics of transparency, zero formaldehyde and high permeability and the effectsof effective water proofing and air permeation, bacteria resistance, mould proofing and the like. The capillary crystalline type waterproofing agent is convenient to use, can be sprayed, rolled and brushed, cannot be formed into a film, and is uniform and smooth, time and materials are saved, the power is high, the cost is low, and the service life is long.
Description
Technical field
The present invention relates to a kind of water-resisting agent, relate in particular to a kind of capillary crystalline waterproofing agent.
Background technology
The conventional waterproof materials such as common vinylformic acid, alcohol third, poly-propylhomoserin, silane in the market; usually can be because containing formaldehyde; after using human body and environment are impacted, simultaneously, after wall face uses; easily variable color, skinning; affect the aesthetics of buildings, and only have 3-12 month work-ing life, easily season cracking; this just needs again brushing, thus waste of manpower, material resources.
Summary of the invention
Technical problem to be solved by this invention is: the capillary crystalline waterproofing agent that a kind of free from extraneous odour, zero formaldehyde, long service life are provided.
For addressing the above problem, the technical solution used in the present invention is: capillary crystalline waterproofing agent, formed by terpolymer part, water-soluble penetrant crystalline material L-type and distilled water, and three's mass ratio is 25-50:2-8:50-250;
Described water-soluble penetrant crystalline material L-type consists of by mass fraction: the 12 current acid potassium of 3-20 part, the silicone emulsion of 6-20 part (solid content), the calcium hydroxide of 6-30 part, 2.5-16 the water glass of part, the silicone surfactant of 0.7-3 part, the titanic acid ester tensio-active agent of 0.6-3 part;
Described terpolymer is that vinylchlorid, ethene, vinyl acetate are polymerized for 2-2.6:1-1.2:5-6 in molar ratio.
The number-average molecular weight of described terpolymer is 3000-4500.
Terpolymer, water-soluble penetrant crystalline material L-type are 40-45:5-6:180-210 with distilled water three preferred mass ratio.
The invention has the beneficial effects as follows:
1) has superior penetrating quality, reinforcement: can directly infiltrate through the 5-10mm of basic unit, make matrix can obtain reinforcement more than two times;
2) permeable watertight: repair liquid inner forms active xln at matrix, under drying regime, and xln shrinks and discharges steam, and when meeting the water moisture, the xln sealing is fine and close, stops that matrix is subjected to the moisture vapor transmission of water head-on or back side water;
3) water white transparency: can keep the original style and features of buildings fully, and the tool self-cleaning function, the infiltration of chlorion in the salt that prevents from thawing;
4) mildew-resistant, anticorrosion, anti-accumulation of salt in the surface soil function: prevent that effectively the objectionable impuritiess such as grease, soda acid, mould, ultraviolet ray are to the erosion of matrix;
5) construction is convenient, flexible, can spray, rolls, brush; Film forming is evenly not smooth.
Embodiment
Embodiment 1
Press mass fraction, with terpolymer 250Kg, water-soluble penetrant crystalline material L-type 80Kg, distilled water 2500Kg mixes, and namely makes capillary crystalline waterproofing agent.
Described water-soluble penetrant crystalline material L-type consists of by mass fraction: 20 parts 12 current acid potassium, 18 parts silicone emulsion (solid content), 6 parts calcium hydroxide, 5 parts water glass, 3 parts silicone surfactant, 1 part titanic acid ester tensio-active agent.
Wherein terpolymer is that vinylchlorid, ethene, vinyl acetate are polymerized for 2.1:1:5.3 in molar ratio, and the number-average molecular weight of terpolymer is 3000-4500.
Embodiment 2
Press mass fraction, with terpolymer 500Kg, water-soluble penetrant crystalline material L-type 20Kg, distilled water 500kg mixes, and namely makes capillary crystalline waterproofing agent.
Described water-soluble penetrant crystalline material L-type consists of by mass fraction: 5 parts 12 current acid potassium, 10 parts silicone emulsion (solid content), 23 parts calcium hydroxide, 40 parts water glass, 1.5 parts silicone surfactant, 2 parts titanic acid ester tensio-active agent;
Wherein terpolymer is that vinylchlorid, ethene, vinyl acetate are polymerized for 2.5:1.2:6 in molar ratio, and the number-average molecular weight of terpolymer is 3000-4500.
Embodiment 3
Press mass fraction, with terpolymer 400Kg, water-soluble penetrant crystalline material L-type 50Kg, distilled water 1800 Kg mix, and namely make capillary crystalline waterproofing agent.
Described water-soluble penetrant crystalline material L-type consists of by mass fraction: 13 parts 12 current acid potassium, 15 parts silicone emulsion (solid content), 24 parts calcium hydroxide, 9 parts water glass, 1.7 parts silicone surfactant, 2.3 parts titanic acid ester tensio-active agent;
Wherein terpolymer is that vinylchlorid, ethene, vinyl acetate are polymerized for 2.3:1.1:5.7 in molar ratio, and the number-average molecular weight of terpolymer is 3000-4500.
The use range of capillary crystalline waterproofing agent of the present invention:
1) is applicable to the waterproof, impervious of the wall facing of various buildingss;
2) be used for the waterproof, mildew-resistant, protection against the tide of concrete, sand-cement slurry and woodwork, the protection such as anticorrosion;
3) be used for the cement basal plane, to be coated with charge level, ceramic tile, mosaic, marble, granite etc. self-cleaning and repair.
The using method of capillary crystalline waterproofing agent of the present invention and precaution:
1) base treatment
Check that carefully wall, floor tile basal plane have zero defect, dust, greasy dirt, algae or liver moss, discrete particle, hollowing etc., if any, need clean out, must with sand-cement slurry the crack be filled up complete in advance if any crack and cavity, make basal plane keep firm, dustless, clean state.Require simultaneously basal plane to keep dry.
2) constructional method
Need not to add water and any additive during use, product of the present invention is stirred after (the xln throw out that produces when leaving standstill is evenly decomposed), can be painted on basal plane.Apply at least twice, the interval is about more than 5 minutes.
3) precaution
Use temperature 0-40 ℃, must not construct in rain, snow and strong wind sky, and the greasy weather must construct after the dew receipts are done again, meets rain during construction and should take rainproof measure; Guarantee to brush again behind basal plane leakless and the hole.
The above only is preferred implementation of the present invention; be noted that for those skilled in the art; under the prerequisite that does not break away from the principle of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (3)
1. capillary crystalline waterproofing agent is comprised of terpolymer, water-soluble penetrant crystalline material L-type and distilled water, and three's mass ratio is 25-50:2-8:50-250;
Described water-soluble penetrant crystalline material L-type consists of by mass fraction: the ten sulfate dihydrate potassium of 3-20 part, the silicone emulsion of 6-20 part, the calcium hydroxide of 6-30 part, 2.5-16 the water glass of part, the silicone surfactant of 0.7-3 part, the titanic acid ester tensio-active agent of 0. 6-3 part;
Described terpolymer is that vinylchlorid, ethene, vinyl acetate are 2-2. 6: 1-1. 2 in molar ratio: 5-6 is polymerized.
2. capillary crystalline waterproofing agent according to claim 1, it is characterized in that: the number-average molecular weight of described terpolymer is 3000-4500.
3. capillary crystalline waterproofing agent according to claim 1, it is characterized in that: terpolymer, water-soluble penetrant crystalline material L-type and distilled water three mass ratio are 40-45:5-6:180-210.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110191320 CN102391836B (en) | 2011-07-08 | 2011-07-08 | Capillary crystalline type waterproofing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110191320 CN102391836B (en) | 2011-07-08 | 2011-07-08 | Capillary crystalline type waterproofing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102391836A CN102391836A (en) | 2012-03-28 |
| CN102391836B true CN102391836B (en) | 2013-03-13 |
Family
ID=45859222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110191320 Expired - Fee Related CN102391836B (en) | 2011-07-08 | 2011-07-08 | Capillary crystalline type waterproofing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391836B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701635B (en) * | 2012-06-13 | 2013-06-19 | 天津泰克建筑科技有限公司青岛分公司 | Nanometer composite type expansion anti-cracking waterproofing agent |
| CN104212385B (en) * | 2014-08-27 | 2016-06-15 | 辽宁省建设科学研究院 | Concrete surface permeable waterproof adhesive and preparation method thereof |
| CN106049892A (en) * | 2016-05-31 | 2016-10-26 | 宝葫历史建筑科技（上海）有限公司 | Repairing method for damp-proof course of historical building |
| CN109020464A (en) * | 2018-09-20 | 2018-12-18 | 翟琳 | A kind of inorganic infiltration waterproofing agent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099364A (en) * | 1994-07-30 | 1995-03-01 | 阮庆生 | Organosilicon cement waterproof powder and its producing method |
| CN1218081A (en) * | 1998-10-29 | 1999-06-02 | 化学工业部星火化工厂 | Organic silicone waterproofing agent and application thereof |
| US20050107514A1 (en) * | 2003-11-14 | 2005-05-19 | Wall-Guard Corporation | Non-flammable waterproofing composition |
| CN101580355A (en) * | 2009-06-26 | 2009-11-18 | 郭元华 | Water-based organic silicon waterproof agent |
| KR20100132405A (en) * | 2009-06-09 | 2010-12-17 | 케이에스피주식회사 | New exposed liquid waterproof material composition and construction method using the material |
-
2011
- 2011-07-08 CN CN 201110191320 patent/CN102391836B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099364A (en) * | 1994-07-30 | 1995-03-01 | 阮庆生 | Organosilicon cement waterproof powder and its producing method |
| CN1218081A (en) * | 1998-10-29 | 1999-06-02 | 化学工业部星火化工厂 | Organic silicone waterproofing agent and application thereof |
| US20050107514A1 (en) * | 2003-11-14 | 2005-05-19 | Wall-Guard Corporation | Non-flammable waterproofing composition |
| KR20100132405A (en) * | 2009-06-09 | 2010-12-17 | 케이에스피주식회사 | New exposed liquid waterproof material composition and construction method using the material |
| CN101580355A (en) * | 2009-06-26 | 2009-11-18 | 郭元华 | Water-based organic silicon waterproof agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102391836A (en) | 2012-03-28 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGSU DEONE ENERGY SAVING TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: JIANGSU DEYI NEW BUILDING MATERIAL TECHNOLOGY CO., LTD. Effective date: 20150703 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20150703 Address after: Suzhou City, Jiangsu province 215600 Zhangjiagang City Tangqiao town Miao Bridge Mall Road Patentee after: Jiangsu Deyi Energy Saving Technology Co., Ltd. Address before: Suzhou City, Jiangsu province 215600 Zhangjiagang City Tangqiao town Mall Road Patentee before: Jiangsu Deyi Novel Building Material Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130313 Termination date: 20160708 |