CN102391795A - Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method - Google Patents
Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method Download PDFInfo
- Publication number
- CN102391795A CN102391795A CN2011102872345A CN201110287234A CN102391795A CN 102391795 A CN102391795 A CN 102391795A CN 2011102872345 A CN2011102872345 A CN 2011102872345A CN 201110287234 A CN201110287234 A CN 201110287234A CN 102391795 A CN102391795 A CN 102391795A
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- CN
- China
- Prior art keywords
- cigarette
- acid
- flame
- application method
- fire retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 96
- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000000853 adhesive Substances 0.000 title claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 14
- 230000002378 acidificating effect Effects 0.000 title abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 238000000576 coating method Methods 0.000 claims abstract description 20
- 239000003292 glue Substances 0.000 claims description 35
- 239000002253 acid Substances 0.000 claims description 26
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229920000881 Modified starch Polymers 0.000 claims description 6
- 239000004368 Modified starch Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 235000019426 modified starch Nutrition 0.000 claims description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- -1 Z 150PH Substances 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- CUXQLKLUPGTTKL-UHFFFAOYSA-M microcosmic salt Chemical compound [NH4+].[Na+].OP([O-])([O-])=O CUXQLKLUPGTTKL-UHFFFAOYSA-M 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000003017 phosphorus Chemical class 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000004026 adhesive bonding Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229920005601 base polymer Polymers 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- VWDWKYIASSYTQR-YTBWXGASSA-N sodium;dioxido(oxo)azanium Chemical compound [Na+].[O-][15N+]([O-])=O VWDWKYIASSYTQR-YTBWXGASSA-N 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Paper (AREA)
Abstract
The invention discloses an acidic flame-retardant adhesive for automatically extinguishing cigarettes and an application method. The acidic flame-retardant adhesive is obtained by adding a halogen-free nitrogen and phosphorus series flame retardant into an acidic adhesive for cigarettes. The acidic flame-retardant adhesive can be coated on a piece of cigarette paper to form a flame-retardant tape of certain width to prepare low-ignition cigarette paper, and can also be used as a connection adhesive for connecting a piece of tipping paper, a filter stick and the cigarette paper together. The coating thickness of the acidic flame-retardant adhesive on the cigarette paper and the tipping paper is 0.02 to 1 millimeter. When the cigarettes prepared by using the acidic flame-retardant adhesive are burnt to the flame-retardant tapes or the tipping paper, the cigarettes are automatically extinguished, so that the ignition tendency of the cigarettes can be simply and effectively reduced.
Description
Technical field
The invention belongs to cigarette producing field, be specifically related to a kind of fire retardant glue and application method that makes the cigarette auto extinguishing.
Background technology
The cigarette of lighting drops on initiation fire on the inflammable substance, causes great loss at home and abroad, proposes the cigarette of low ignition tendency in the world, and its purpose is to reduce loss, reduces harm.At present, U.S. some areas have been set up decree, implement the low standard of igniting of cigarette by force, and states such as European Union, Australia have also set about legistration work, and the associated mechanisms of China has also been carried out this research, and various reports are visible successively.The low ignition tendency cigarette of CN101781867A preparation is through inhibiting tape is set on cigarette tissue; Can be when cigarette burning to inhibiting tape from horizontal blanking; The method of using is successively to use the internal layer and outer coating fire retardant matter of two rubber rolls at the same position of cigarette tissue; And be not at single spreading, so location difficulty is difficult to carry out.
On the other hand, customer response, many regular-size cigarettes can burn away when burning to the tipping paper place; The danger of initiation fire strengthens, and distributes unpleasant mouth rod smell of burning, more can injure finger because of carelessness during suction; At present, on market, do not have the maturation method head it off.CN101798779A has prepared the flame-retardant tipping body paper, but what adopt is that phosphoric melamine salt and verivate thereof are coated on the paper, does not obviously meet the food safety requirement.
Summary of the invention
The object of the invention provides a kind of acid fire retardant glue and application method that makes the cigarette auto extinguishing, uses the cigarette of this acidity fire retardant glue preparation, but props up auto extinguishing in the combustion processes at cigarette, but need not dinch also auto extinguishing of cigarette end after the burning, and security obviously improves.
A kind of acid fire retardant glue that makes the cigarette auto extinguishing is to add the Halogen nitrogen phosphorus flame retardant that mass percent accounts for 0.5-5% (preferred 1-3%) in the Aci-Jel stick at cigarette to obtain; Described Halogen nitrogen phosphorus flame retardant comprises: one or more in ammonium phosphate, primary ammonium phosphate, Secondary ammonium phosphate, sodium ammonium phosphate, AMS, the ammonium polyphosphate.
Described Halogen nitrogen phosphorus flame retardant adds one or more its pH values of adjustment in sulfuric acid, hydrochloric acid, phosphoric acid, the acetate earlier before interpolation, make it consistent with the pH value of Aci-Jel stick with cigarette.Described sulfuric acid, hydrochloric acid, phosphoric acid, the acetate concentration indefinite in the Aci-Jel stick.
Described cigarette uses the Aci-Jel stick to be modified starch adhesive, Z 150PH, acid polyacrylic ester, acid Yodo Sol VC 400, acid vinyl-acetic ester-ethylene copolymer or other Aci-Jel class.
Described modified starch adhesive, Z 150PH product are acidic substance; Glue base polymers such as described polyacrylic ester, Yodo Sol VC 400, vinyl-acetic ester-ethylene copolymer are owing to production technique and requirement is different, and the pH value of each manufacturer's final product has than big-difference, and pH value scope is at 3.0-10.0.The pH value of glue base polymers such as modified starch adhesive of the present invention, Z 150PH, polyacrylic ester, Yodo Sol VC 400, vinyl-acetic ester-ethylene copolymer is less than 7.0.
Described acid fire retardant glue is used to prepare the cigarette that can extinguish automatically; Specifically be after described acid fire retardant glue is coated on cigarette tissue internal surface or outside surface; Be used for cigarette cigarette; Perhaps as connect mouth glue link together tipping paper, filter stick and cigarette tissue (connecing the form coating of mouth glue, the width indefinite, can prop up filter tip and cigarette to link together get final product).
The coating thickness of described acid fire retardant glue on cigarette tissue and tipping paper is the 0.02-1 millimeter; With the 0.04-0.08 millimeter is good.
Can described acid fire retardant glue be coated with into endless belt on cigarette tissue, the endless belt at least one on every cigarette; The wide 6-8 millimeter of endless belt.
Cigarette of the present invention has stronger cohesiveness and film-forming properties with acid fire retardant glue; Can satisfy the bonding requirement of cigarette on the one hand; On the other hand can be on cigarette tissue and tipping paper film forming, significantly reduce the permeability of paper, stop air to participate in burning; After adding flame-retardant composition, fire retardation is more obvious.
Compared with present technology the present invention has remarkable advantage:
A. compare with other common colloidality material, cigarette of the present invention can satisfy the bonding requirement with acid fire retardant glue, can significantly improve flame retardant effect again;
B. the present invention can use on cigarette tissue and tipping paper, does not receive any condition restriction during use.
Embodiment
The fire retardant glue that adopts above technology to produce is used for production of cigarettes and can stops cigarette burning, combines embodiment to further specify at present, and can not limit the present invention.
Embodiment 1
The acid fire retardant glue of preparation the present invention:
Ammonium dihydrogen phosphate 50 grams of preparation 30% add phosphatase 11 0 gram, and after stirring, system pH is 4.7, join in modified starch adhesive modified starch adhesive (132-2123 of Henkel KGaA company) 1000 grams, fully stir.
Using coating thickness is that 0.05 millimeter, width are 6 millimeters rubber roll, with above-mentioned glue coating cigarette tissue, is coated with 1 inhibiting tape on every cigarette.
Using coating thickness is 0.05 millimeter, the rubber roll of full width gluing, is coated with tipping paper to above-mentioned glue as connecing mouth glue, and the cigarette cigarette props up on rolling up and connecting machine.
Light each 20 of the cigarette of the cigarette that on cigarette tissue, is coated with inhibiting tape and coating, observe combustion position at the tipping paper place, add up at the inhibiting tape place flame-out cigarette amount respectively and at the tipping paper place flame-out cigarette amount, test-results is following:
Table 1
| Flame-out cigarette amount (propping up) | Flame-out rate (%) | |
| Light 20 of inhibiting tape cigarette amounts are arranged on the cigarette tissue | 20 | 100 |
| Light 20 of tipping paper place coating cigarette amounts | 20 | 100 |
Embodiment 2
Use the inventive method and prepare fire retardant glue:
Ammonium dibasic phosphate solution 30 grams of preparation 30%; Add ammonium polyphosphate 10 grams, acetate 10 grams, after stirring, system pH is 5.3; Join in acid vinyl-acetic ester-ethylene copolymer (Korea S becomes the T300-1 of Co., Ltd. C again) 1000 grams, fully stir.
Using coating thickness is that 0.06 millimeter, width are 6 millimeters rubber roll, with above-mentioned glue coating cigarette tissue, is coated with 1 inhibiting tape on every cigarette.
Using coating thickness is 0.04 millimeter, the rubber roll of full width gluing, is coated with tipping paper to above-mentioned glue as connecing mouth glue, and the cigarette cigarette props up on rolling up and connecting machine.
Light each 20 of the cigarette of the cigarette that on cigarette tissue, is coated with inhibiting tape and coating, observe combustion position at the tipping paper place, add up at the inhibiting tape place flame-out cigarette amount respectively and at the tipping paper place flame-out cigarette amount, test-results is following:
Table 2
| Flame-out cigarette amount (propping up) | Flame-out rate (%) | |
| Light 20 of inhibiting tape cigarette amounts are arranged on the cigarette tissue | 20 | 100 |
| Light 20 of tipping paper place coating cigarette amounts | 20 | 100 |
Embodiment 3
Use the inventive method and prepare fire retardant glue:
Thionamic acid ammonium solution 60 grams of preparation 10% add phosphoric acid 5 grams, and after stirring, system pH is 4.5, join in acid Yodo Sol VC 400 (Korea S becomes the T30000 of Co., Ltd. C again) 1000 grams, fully stir.
Using coating thickness is that 0.05 millimeter, width are 6 millimeters rubber roll, with above-mentioned glue coating cigarette tissue, is coated with 1 inhibiting tape on every cigarette.
Using coating thickness is 0.04 millimeter, the rubber roll of full width gluing, is coated with tipping paper to above-mentioned glue as connecing mouth glue, and the cigarette cigarette props up on rolling up and connecting machine.
Light each 20 of the cigarette of the cigarette that on cigarette tissue, is coated with inhibiting tape and coating, observe combustion position at the tipping paper place, add up at the inhibiting tape place flame-out cigarette amount respectively and at the tipping paper place flame-out cigarette amount, test-results is following:
Table 3
| Flame-out cigarette amount (propping up) | Flame-out rate (%) | |
| Light 20 of inhibiting tape cigarette amounts are arranged on the cigarette tissue | 20 | 100 |
| Light 20 of tipping paper place coating cigarette amounts | 20 | 100 |
Claims (9)
1. an acid fire retardant glue that makes the cigarette auto extinguishing is characterized in that, is to add the Halogen nitrogen phosphorus flame retardant that mass percent accounts for 0.5-5% in the Aci-Jel stick at cigarette to obtain; Described Halogen nitrogen phosphorus flame retardant comprises: one or more in ammonium phosphate, primary ammonium phosphate, Secondary ammonium phosphate, sodium ammonium phosphate, AMS, the ammonium polyphosphate.
2. acid fire retardant glue according to claim 1 is characterized in that, Halogen nitrogen phosphorus flame retardant adds one or more its pH values of adjustment in sulfuric acid, hydrochloric acid, phosphoric acid, the acetate earlier before interpolation, make it consistent with the pH value of Aci-Jel stick with cigarette.
3. acid fire retardant according to claim 1 is characterized in that: described cigarette uses the Aci-Jel stick to be modified starch adhesive, Z 150PH, acid polyacrylic ester, acid Yodo Sol VC 400, acid vinyl-acetic ester-ethylene copolymer or other Aci-Jel class.
4. the application method of claim 1 or 2 or 3 described acid fire retardant glue is characterized in that, is used to prepare the cigarette that can extinguish automatically.
5. application method according to claim 4 is characterized in that, described acid fire retardant glue is coated on cigarette tissue internal surface or outside surface after, be used for cigarette cigarette, perhaps bond together tipping paper, filter stick and cigarette tissue as connecing mouth glue.
6. application method according to claim 5 is characterized in that, the coating thickness of described acid fire retardant glue on cigarette tissue and tipping paper is the 0.02-1 millimeter.
7. according to the described application method of right claim 6, it is characterized in that, described acid fire retardant glue is coated with into endless belt on cigarette tissue.
8. according to the described application method of right claim 7, it is characterized in that described endless belt has one at least on every cigarette.
9. according to the described application method of right claim 8, it is characterized in that the wide 6-8 millimeter of described endless belt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102872345A CN102391795A (en) | 2011-09-26 | 2011-09-26 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102872345A CN102391795A (en) | 2011-09-26 | 2011-09-26 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102391795A true CN102391795A (en) | 2012-03-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102872345A Pending CN102391795A (en) | 2011-09-26 | 2011-09-26 | Acidic flame-retardant adhesive for automatically extinguishing cigarettes and application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391795A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173162A (en) * | 2013-04-03 | 2013-06-26 | 湖南中烟工业有限责任公司 | Acidic flame-retardant holder adhesive for cigarettes |
| CN103233391A (en) * | 2013-04-03 | 2013-08-07 | 湖南中烟工业有限责任公司 | Acidic flame-retardant additive for cigarette and application thereof |
| CN108531112A (en) * | 2018-04-19 | 2018-09-14 | 滁州君越高分子新材料有限公司 | A kind of fire retardant glue making cigarette auto extinguishing |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2259769Y (en) * | 1996-05-22 | 1997-08-20 | 张骐纬 | Fireproof Cigarettes |
| CN1795770A (en) * | 2004-12-24 | 2006-07-05 | 长沙卷烟厂 | Fireproof self-extinguishing cigarette, preparation device and preparation method |
| CN101018834A (en) * | 2004-07-13 | 2007-08-15 | 亨斯迈先进材料（瑞士）有限公司 | Fire retardant composition |
| CN101126002A (en) * | 2007-08-17 | 2008-02-20 | 北京双成木科技有限公司 | Wood-based plate fire retardant mixed into adhesive and preparation method thereof |
| CN102040790A (en) * | 2009-08-18 | 2011-05-04 | 中国科学院成都有机化学有限公司 | Fireproof polyvinyl acetate emulsion and preparation method thereof |
| CN102174779A (en) * | 2011-03-18 | 2011-09-07 | 云南烟草科学研究院 | Method for reducing viscosity of flame retardant glue for low ignition propensity (LIP) cigarette paper |
-
2011
- 2011-09-26 CN CN2011102872345A patent/CN102391795A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2259769Y (en) * | 1996-05-22 | 1997-08-20 | 张骐纬 | Fireproof Cigarettes |
| CN101018834A (en) * | 2004-07-13 | 2007-08-15 | 亨斯迈先进材料（瑞士）有限公司 | Fire retardant composition |
| CN1795770A (en) * | 2004-12-24 | 2006-07-05 | 长沙卷烟厂 | Fireproof self-extinguishing cigarette, preparation device and preparation method |
| CN101126002A (en) * | 2007-08-17 | 2008-02-20 | 北京双成木科技有限公司 | Wood-based plate fire retardant mixed into adhesive and preparation method thereof |
| CN102040790A (en) * | 2009-08-18 | 2011-05-04 | 中国科学院成都有机化学有限公司 | Fireproof polyvinyl acetate emulsion and preparation method thereof |
| CN102174779A (en) * | 2011-03-18 | 2011-09-07 | 云南烟草科学研究院 | Method for reducing viscosity of flame retardant glue for low ignition propensity (LIP) cigarette paper |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173162A (en) * | 2013-04-03 | 2013-06-26 | 湖南中烟工业有限责任公司 | Acidic flame-retardant holder adhesive for cigarettes |
| CN103233391A (en) * | 2013-04-03 | 2013-08-07 | 湖南中烟工业有限责任公司 | Acidic flame-retardant additive for cigarette and application thereof |
| CN103173162B (en) * | 2013-04-03 | 2015-07-15 | 湖南中烟工业有限责任公司 | Acidic flame-retardant holder adhesive for cigarettes |
| CN108531112A (en) * | 2018-04-19 | 2018-09-14 | 滁州君越高分子新材料有限公司 | A kind of fire retardant glue making cigarette auto extinguishing |
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Application publication date: 20120328 |