CN102372891B - Special acrylonitile-styrene-acrylate color masterbatch - Google Patents
Special acrylonitile-styrene-acrylate color masterbatch Download PDFInfo
- Publication number
- CN102372891B CN102372891B CN 201010262806 CN201010262806A CN102372891B CN 102372891 B CN102372891 B CN 102372891B CN 201010262806 CN201010262806 CN 201010262806 CN 201010262806 A CN201010262806 A CN 201010262806A CN 102372891 B CN102372891 B CN 102372891B
- Authority
- CN
- China
- Prior art keywords
- asa
- styrene
- parts
- master batch
- special
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004595 color masterbatch Substances 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- -1 styrene-ethylene-butylene-styrene Chemical class 0.000 claims abstract 2
- 239000000049 pigment Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 8
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- IMJPDWLPOLPEAY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;propanoic acid Chemical class CCC(O)=O.OCC(CO)(CO)CO IMJPDWLPOLPEAY-UHFFFAOYSA-N 0.000 claims description 6
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 235000019359 magnesium stearate Nutrition 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- 238000004040 coloring Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- HIPSYHMDLMDYNX-UHFFFAOYSA-N CCC(O)=O.CCC(O)=O.CCC(O)=O.CCC(O)=O.OCC(CO)(CO)CO Chemical compound CCC(O)=O.CCC(O)=O.CCC(O)=O.CCC(O)=O.OCC(CO)(CO)CO HIPSYHMDLMDYNX-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 238000001816 cooling Methods 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 238000005453 pelletization Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the production technical field of the acrylonitile-styrene-acrylate (ASA) material and particularly relates to a special ASA color masterbatch. The masterbatch is characterized by comprising the following components in parts by weight: 10-30 parts of ASA resin, 15-20 parts of dispersant, 30-50 parts of colourant, 5-10 parts of ethylene-octene copolymer or styrene-ethylene-butylene-styrene (SEBS), 0.1-0.3 part of tetra(propionic acid) pentaerythritol and 0.1-0.3 part of titanate coupling agent. The special ASA color masterbatch has the advantages of stable color, uniform coloring, convenient color-changing operation, convenient storage and transportation operations no influence on the mechanical properties of the material, and is environmentally-friendly.
Description
Technical field: the invention belongs to ASA material produce technical field, be specifically related to a kind of ASA Special colored master batch.
Background technology: at present, the ASA resin also claims AAS resin, by vinyl cyanide (A), the ternary graft copolymer that vinylbenzene (S) and acrylate (A) form, compare with ABS, replace divinyl rubber owing to having introduced not double bond containing acrylic elastomer, weathering resistance has had essential improvement, has excellent mechanical property, processing characteristics, electrical insulating property, the characteristics such as chemical-resistant are a kind of thermoplastic engineering plastics of high comprehensive performance, are widely used in automobile, the electronic apparatus production, in the fields such as building and gardening, the painted main employing toner dyeing of existing ASA material, not only the pigment dust is large in the operation, contaminate environment, and the product colour changing is loaded down with trivial details, color is unstable, and tinting material improper use meeting directly affects the mechanical property of material, and product is frangible, affects quality product.
Summary of the invention: the purpose of this invention is to provide a kind of colour stable, uniform coloring, colour changing is convenient, is convenient to accumulating, does not affect the mechanical property of material, the ASA Special colored master batch of environmental protection.
Technical scheme of the present invention is: a kind of ASA Special colored master batch is characterized in that it is made of by weight following component: the multipolymer of ASA resin 10-30, dispersion agent 15-20, tinting material 30-50, ethylene-octene or SEBS 5-10, four propionic acid tetramethylolmethane 0.1-0.3, titanate coupling agent 0.1-0.3; Wherein, described dispersion agent is EVA wax or stearic acid or Magnesium Stearate or their composition; Described tinting material is pigment dyestuff of all kinds.
Working method is: first above-mentioned various raw materials are dry mixed 3-5 minute in super mixer, place again twin screw extruder through melt extrude, cooling, pelletizing, packaging final prod get final product; Wherein, twin screw extruder one district's temperature is 90-100 ℃, and two districts are 150-180 ℃, and three districts are 200-220 ℃, and four districts are 205-215 ℃; Five districts are 200-210 ℃, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Its best-of-breed technology scheme is: a kind of ASA Special colored master batch is characterized in that it is made of by weight following component: the multipolymer of ASA resin 20, dispersion agent 17.5, tinting material 40, ethylene-octene or SEBS 7.5, four propionic acid pentaerythritol esters 0.2, titanate coupling agent 0.2; Wherein, described dispersion agent is EVA wax or stearic acid or Magnesium Stearate or their composition; Described tinting material is pigment of all kinds.
Working method is: first above-mentioned various raw materials are dry mixed 3-5 minute in super mixer, place again twin screw extruder through melt extrude, cooling, pelletizing, packaging final prod get final product; Wherein, twin screw extruder one district's temperature is 90-100 ℃, and two districts are 150-180 ℃, and three districts are 200-220 ℃, and four districts are 205-215 ℃; Five districts are 200-210 ℃, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
The invention has the beneficial effects as follows, owing to adopt technique scheme, as required, the pigment of the high density of the different colours method by the twin screw extruder blend is scattered among the ASA, avoid the reunion of pigment, improved the dispersion of pigment, reduced consumption, the master batch that makes has colour stable, uniform coloring, colour changing is convenient, is convenient to accumulating, do not affect the mechanical property of material, environment friendly and pollution-free advantage.
Embodiment: further specify technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1: a kind of ASA Special colored master batch is made of by weight following component: the multipolymer 5 of ASA resin 30, EVA wax 15, tinting material 30, ethylene-octene, four propionic acid pentaerythritol esters 0.1, titanate coupling agent 0.3; Described tinting material is pigment of all kinds.Working method is: first above-mentioned various raw materials are dry mixed 3-5 minute in super mixer, place again twin screw extruder through melt extrude, cooling, pelletizing, packaging final prod get final product; Wherein, twin screw extruder one district's temperature is 90-100 ℃, and two districts are 150-180 ℃, and three districts are 200-220 ℃, and four districts are 205-215 ℃; Five districts are 200-210 ℃, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Embodiment 2: a kind of ASA Special colored master batch is made of by weight following component: ASA resin 10, stearic acid 20, tinting material 50, SEBS 10, four propionic acid pentaerythritol esters 0.3, titanate coupling agent 0.1, described tinting material is pigment of all kinds.
Working method is: first above-mentioned various raw materials are dry mixed 3-5 minute in super mixer, place again twin screw extruder through melt extrude, cooling, pelletizing, packaging final prod get final product; Wherein, twin screw extruder one district's temperature is 90-100 ℃, and two districts are 150-180 ℃, and three districts are 200-220 ℃, and four districts are 205-215 ℃; Five districts are 200-210 ℃, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Embodiment 3: a kind of ASA Special colored master batch, be comprised of by weight following component: the multipolymer 7.5 of ASA resin 20, Magnesium Stearate 17.5, tinting material 40, ethylene-octene, four propionic acid pentaerythritol esters 0.2, titanate coupling agent 0.2, described tinting material is pigment of all kinds.
Working method is: first above-mentioned various raw materials are dry mixed 3-5 minute in super mixer, place again twin screw extruder through melt extrude, cooling, pelletizing, packaging final prod get final product; Wherein, twin screw extruder one district's temperature is 90-100 ℃, and two districts are 150-180 ℃, and three districts are 200-220 ℃, and four districts are 205-215 ℃; Five districts are 200-210 ℃, and the residence time is 1-2 minute, and pressure is 10-15Mpa.
Claims (4)
1. an ASA Special colored master batch is characterized in that it is made of by weight following component: the multipolymer of acrylonitrile-styrene-acrylic ester terpolymer ASA resin 10-30, dispersion agent 15-20, tinting material 30-50, ethylene-octene or SEBS 5-10, four propionic acid pentaerythritol ester 0.1-0.3, titanate coupling agent 0.1-0.3.
2. by a kind of ASA Special colored master batch claimed in claim 1, it is characterized in that it is made of by weight following component: the multipolymer of ASA resin 20, dispersion agent 17.5, tinting material 40, ethylene-octene or SEBS 7.5, four propionic acid pentaerythritol esters 0.2, titanate coupling agent 0.2.
3. a kind of ASA Special colored master batch according to claim 1 and 2, it is characterized in that: described dispersion agent is EVA wax or stearic acid or Magnesium Stearate or their composition.
4. a kind of ASA Special colored master batch according to claim 1 and 2, it is characterized in that: described tinting material is pigment of all kinds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010262806 CN102372891B (en) | 2010-08-22 | 2010-08-22 | Special acrylonitile-styrene-acrylate color masterbatch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010262806 CN102372891B (en) | 2010-08-22 | 2010-08-22 | Special acrylonitile-styrene-acrylate color masterbatch |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102372891A CN102372891A (en) | 2012-03-14 |
| CN102372891B true CN102372891B (en) | 2013-01-16 |
Family
ID=45792146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010262806 Active CN102372891B (en) | 2010-08-22 | 2010-08-22 | Special acrylonitile-styrene-acrylate color masterbatch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102372891B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571179A (en) * | 2012-08-01 | 2014-02-12 | 山东道恩高分子材料股份有限公司 | Environment-friendly red color masterbatch for nylon |
| CN107417938A (en) * | 2016-05-24 | 2017-12-01 | 上海羽迪新材料科技有限公司 | A kind of method that color correct rate is reduced in Color master batch production process |
| CN107974021A (en) * | 2016-10-25 | 2018-05-01 | 中国石油化工股份有限公司 | A kind of high durable ASA film PP Pipe Compounds and preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0450485A2 (en) * | 1990-04-06 | 1991-10-09 | BASF Aktiengesellschaft | Thermoplastic moulding compound |
| CN101225211A (en) * | 2007-12-17 | 2008-07-23 | 胡大忠 | ASA modified material |
-
2010
- 2010-08-22 CN CN 201010262806 patent/CN102372891B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0450485A2 (en) * | 1990-04-06 | 1991-10-09 | BASF Aktiengesellschaft | Thermoplastic moulding compound |
| CN101225211A (en) * | 2007-12-17 | 2008-07-23 | 胡大忠 | ASA modified material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102372891A (en) | 2012-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102040764B (en) | Black master batch and preparation method thereof | |
| CN103360670B (en) | A kind of general high light black masterbatch | |
| CN100475900C (en) | Modified super-fine cool-ash composite plastic | |
| CN101392077B (en) | Polypropylene color master-batch with pearlescent interference effect and preparation method thereof | |
| CN102181094B (en) | Antistatic and anti-aging white master batch of polypropylene resin and preparation method thereof | |
| CN103709497A (en) | Color master batch for plastic cement and preparation method thereof | |
| CN101985506B (en) | White master batch for high impact polystyrene (HIPS) and preparation method thereof | |
| CN102161808B (en) | ASA (acrylonitrile-styrene-acrylate) resin with favorable appearance performance and preparation method thereof | |
| CN102140197B (en) | Antistatic agent, antistatic flame-retarding plastics and production methods thereof | |
| CN101885885A (en) | Color master batch for hard PVC and preparation method thereof | |
| CN103172939A (en) | Macromolecule color masterbatch and preparation method thereof | |
| CN101392078A (en) | Universal white master batch and preparation method thereof | |
| CN102367320A (en) | General white master batch and its preparation method | |
| CN103254546A (en) | ABS color master batch and preparation process thereof | |
| CN102617974B (en) | Acrylonitrile butadiene styrene (ABS)/nerchinskite composite material and preparation method thereof | |
| CN102372891B (en) | Special acrylonitile-styrene-acrylate color masterbatch | |
| CN103571179A (en) | Environment-friendly red color masterbatch for nylon | |
| CN103012902B (en) | Black master-batch and preparation method thereof | |
| CN103881315A (en) | Smooth color master batch used for PET and preparation method thereof | |
| CN103709488A (en) | Plastic color master batch and preparation method thereof | |
| CN102372908A (en) | Glass fiber reinforced PBT masterbatch | |
| CN109096777A (en) | A kind of Masterbatch and production method | |
| CN104672758A (en) | ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof | |
| CN111849108B (en) | Highlight spraying-free polymer alloy and preparation method thereof | |
| CN104861435A (en) | Smooth color master batch for PTT film |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |