CN102367362A - Polyamide resin capacitor aluminium shell film mulching paint and its preparation method - Google Patents
Polyamide resin capacitor aluminium shell film mulching paint and its preparation method Download PDFInfo
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- CN102367362A CN102367362A CN2011103297105A CN201110329710A CN102367362A CN 102367362 A CN102367362 A CN 102367362A CN 2011103297105 A CN2011103297105 A CN 2011103297105A CN 201110329710 A CN201110329710 A CN 201110329710A CN 102367362 A CN102367362 A CN 102367362A
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Abstract
The invention discloses a polyamide resin capacitor aluminium shell film mulching paint and its preparation method. The polyamide resin capacitor aluminium shell film mulching paint is mainly prepared by mixing raw materials of a composition A and a composition B, wherein the composition A is composed of polyamide resin, ketone, polyethylene wax, nanometer powdered carbon, ethanol, glycerol and attapulgite; and the composition B is composed of an acrylic acid ester copolymer modifier, a silane coupling agent, graphite and tetramethylsilane. The formulation provided by the invention is reasonable and the preparation method is simple. The film mulching paint has a good curing effect on the capacitor aluminium shell and has heat-resistant and wear-resistant performance, and can be used to effectively protect the capacitor and increase the service life of the capacitor.
Description
Technical field
The present invention relates to capacitor case and chemical compsn, be specifically related to a kind of polyamide resin capacitor aluminum housing coating paint and preparation method thereof.
Background technology
Along with the electron trade development of technology; The manufacturing technology of electronic circuit board also has greatly improved; For the volume that dwindles electronic product consumes with reducing; Electrolytic condenser is as one of universal component on the electronic circuit board, and it is increasingly high not only its heatproof, anti-puncture being required, and to require its footprints also be more little good more.The electrolytic condenser footprints is little, at first is that aluminium shell of capacitor will have high length-to-diameter ratio, and electrical condenser diameter reduced dimension area is just little; Next is that capacitor case will have high air heat resistance; Otherwise, damages and reduction of service life easily in the sky of compactness in asking; Traditional aluminium shell of capacitor is that subpunch is processed shape, and one deck insulating material is sealed up in back pyrocondensation, and insulating material tightly is rolled on the capacitor case after heating.This its shortcoming of red shortness's plastic film electrical condenser is that the anti-AT of insulating material of heat-sealing is not high enough, in the process of heat-seal process, also can produce a lot of plastic film waste materials.The coating method that the disclosed a kind of insulation film on aluminum body of electrolytic capacitor of TaiWan, China Yabo Company is also arranged; Chinese invention patent application publication number CNl944704; This method mainly is to take 1000～20000 volts high potential gradient; Make gaseous ion bump ZX 21 tetrafluoroethylene (polytetrafluoroethylene), clash into fluorine atom, simultaneous oxidation generates fluorine oxide; Fluorine oxide promptly can produce powerful tackiness under high temperature action, and is deposited on the aluminum enclosure surface glutinous covering and forms the insulated hull rete of fluorine oxide.This method in fact only is the chloride secondary pollution of covering material that has reduced, and temperature tolerance is poor, the production cost problem of higher but exist.
Summary of the invention
For deficiency and the defective of alleviating prior art; The object of the present invention is to provide a kind of polyamide resin capacitor aluminum housing coating paint and preparation method thereof; The present invention fills a prescription rationally, and the preparation method is simple, and solidification effect is good on aluminium shell of capacitor; Effectively carry out protective condenser, the coating paint that makes has the heat-resistant antifriction performance, has increased the work-ing life of electrical condenser.
The present invention adopts following technical scheme to achieve these goals:
The polyamide resin capacitor aluminum housing coating paint; The weight part that it is characterized in that its constitutive material is: comprise compsn A and compsn B, described compsn A: polyamide resin 60-70 part, ketone 20-30 part, polyethylene wax 5-10 part, nano-carbon powder 15-25 part, ethanol 5-15 part, USP Kosher 15-25 part and attapulgite 10-15 part; Described compsn B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, silane coupling agent 5-10 part, Graphite Powder 99 5-10 part and TMS 5-10 part.
The preparation method of described polyamide resin capacitor aluminum housing coating paint is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; Polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, USP Kosher and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and TMS was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
Beneficial effect of the present invention:
The present invention fills a prescription rationally, and the preparation method is simple, and solidification effect is good on aluminium shell of capacitor, effectively carries out protective condenser, and the coating paint that makes has the heat-resistant antifriction performance, increased the work-ing life of electrical condenser.
Embodiment
Embodiment 1:The polyamide resin capacitor aluminum housing coating paint; The weight part of its constitutive material is: comprise compsn A and compsn B, described compsn A: 10 parts of 60 parts of polyamide resins, 20 parts of ketones, 5 parts of polyethylene waxs, 15 parts of nano-carbon powders, 5 parts of ethanol, 15 parts of USP Kosher and attapulgites; Described compsn B: 5 parts of 20 parts of acrylic acid esters co-polymer properties-correcting agent, 5 parts of silane coupling agents, 5 parts of Graphite Powder 99s and TMSs.
The preparation method of polyamide resin capacitor aluminum housing coating paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; Polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, USP Kosher and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and TMS was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull; Aluminum hull need use the hot water that adds NaOH to clean; NaOH concentration is 4-6%, clean the back place 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned polyamide resin capacitor aluminum housing coating paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate; Then aluminium sheet is placed 210-220 ℃ environment curing down, solidified at least 1 minute.
Embodiment 2:The polyamide resin capacitor aluminum housing coating paint; The weight part of its constitutive material is: comprise compsn A and compsn B, described compsn A: 15 parts of 70 parts of polyamide resins, 30 parts of ketones, 10 parts of polyethylene waxs, 25 parts of nano-carbon powders, 15 parts of ethanol, 25 parts of USP Kosher and attapulgites; Described compsn B: 10 parts of 30 parts of acrylic acid esters co-polymer properties-correcting agent, 10 parts of silane coupling agents, 10 parts of Graphite Powder 99s and TMSs.
The preparation method of polyamide resin capacitor aluminum housing coating paint may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; Polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, USP Kosher and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and TMS was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
During the coating aluminum hull; Aluminum hull need use the hot water that adds NaOH to clean; NaOH concentration is 4-6%, clean the back place 160-180 ℃ dry oxidation 1-2 minute, then the above-mentioned polyamide resin capacitor aluminum housing coating paint that makes evenly is being applied under the environment of room temperature on the pretreated surface of aluminum plate; Then aluminium sheet is placed 210-220 ℃ environment curing down, solidified at least 1 minute.
Embodiment 3:Scribble the polyamide resin capacitor aluminum housing coating paint of embodiment 1 and embodiment 2, the electrical condenser overlay film aluminum hull technical indicator that solidification value wherein, time and gained overlay film aluminum hull are processed is:
| ? | Embodiment 1 | Embodiment 2 |
| Solidification value (℃) | 198 | 216 |
| Set time (s) | 60 | 60 |
| Require index | Meet | Meet |
| Length-to-diameter ratio | 2.6:1 | 3.2:1 |
Claims (2)
1. polyamide resin capacitor aluminum housing coating paint; The weight part that it is characterized in that its constitutive material is: comprise compsn A and compsn B, described compsn A: polyamide resin 60-70 part, ketone 20-30 part, polyethylene wax 5-10 part, nano-carbon powder 15-25 part, ethanol 5-15 part, USP Kosher 15-25 part and attapulgite 10-15 part; Described compsn B: acrylic acid esters co-polymer properties-correcting agent 20-30 part, silane coupling agent 5-10 part, Graphite Powder 99 5-10 part and TMS 5-10 part.
2. the preparation method of a polyamide resin capacitor aluminum housing coating paint as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material; Polyamide resin, ketone, polyethylene wax, nano-carbon powder, ethanol, USP Kosher and attapulgite are added in the stirrer; Normal temperature stirred 30-45 minute down, mixed and obtained compsn A, acrylic acid esters co-polymer properties-correcting agent, silane coupling agent, Graphite Powder 99 and TMS was added in the stirrer again; Normal temperature stirred 30-45 minute down, mixed and obtained compsn B;
(2) compsn A and compsn B are added in the stirrer, mix, solution stirring is to clear solution in the stirrer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103297105A CN102367362B (en) | 2011-10-27 | 2011-10-27 | Polyamide resin capacitor aluminium shell film mulching paint and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103297105A CN102367362B (en) | 2011-10-27 | 2011-10-27 | Polyamide resin capacitor aluminium shell film mulching paint and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102367362A true CN102367362A (en) | 2012-03-07 |
| CN102367362B CN102367362B (en) | 2013-03-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011103297105A Expired - Fee Related CN102367362B (en) | 2011-10-27 | 2011-10-27 | Polyamide resin capacitor aluminium shell film mulching paint and its preparation method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543857A (en) * | 2016-10-26 | 2017-03-29 | 安徽飞达电气科技有限公司 | A kind of aluminium shell of capacitor heatproof coating paint |
| CN106634112A (en) * | 2016-12-13 | 2017-05-10 | 宁国市大荣电器有限公司 | Capacitor aluminum shell heat-resisting coating paint |
| CN108165068A (en) * | 2017-11-24 | 2018-06-15 | 安徽江南泵阀有限公司 | A kind of preparation process of the filler of chemical pump coating |
| CN113121770A (en) * | 2019-12-31 | 2021-07-16 | 都江堰市天兴硅业有限责任公司 | Polyamide 1.1, preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6162568A (en) * | 1984-09-03 | 1986-03-31 | Nippon Paint Co Ltd | Method of preventing steel material corrosion |
| GB2242430A (en) * | 1990-03-27 | 1991-10-02 | Intevep Sa | Anticorrosive coating composition |
| CN101358106A (en) * | 2008-09-25 | 2009-02-04 | 武汉工程大学 | Anti-icing nanocomposite coating and its application |
-
2011
- 2011-10-27 CN CN2011103297105A patent/CN102367362B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6162568A (en) * | 1984-09-03 | 1986-03-31 | Nippon Paint Co Ltd | Method of preventing steel material corrosion |
| GB2242430A (en) * | 1990-03-27 | 1991-10-02 | Intevep Sa | Anticorrosive coating composition |
| CN101358106A (en) * | 2008-09-25 | 2009-02-04 | 武汉工程大学 | Anti-icing nanocomposite coating and its application |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106543857A (en) * | 2016-10-26 | 2017-03-29 | 安徽飞达电气科技有限公司 | A kind of aluminium shell of capacitor heatproof coating paint |
| CN106634112A (en) * | 2016-12-13 | 2017-05-10 | 宁国市大荣电器有限公司 | Capacitor aluminum shell heat-resisting coating paint |
| CN108165068A (en) * | 2017-11-24 | 2018-06-15 | 安徽江南泵阀有限公司 | A kind of preparation process of the filler of chemical pump coating |
| CN113121770A (en) * | 2019-12-31 | 2021-07-16 | 都江堰市天兴硅业有限责任公司 | Polyamide 1.1, preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102367362B (en) | 2013-03-20 |
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