[go: up one dir, main page]

CN102348743A - Methods of preparing masterbatches and compounds - Google Patents

Methods of preparing masterbatches and compounds Download PDF

Info

Publication number
CN102348743A
CN102348743A CN2010800167245A CN201080016724A CN102348743A CN 102348743 A CN102348743 A CN 102348743A CN 2010800167245 A CN2010800167245 A CN 2010800167245A CN 201080016724 A CN201080016724 A CN 201080016724A CN 102348743 A CN102348743 A CN 102348743A
Authority
CN
China
Prior art keywords
colorants
solid
masterbatches
liquid
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2010800167245A
Other languages
Chinese (zh)
Inventor
安德斯·弗伦伯格
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Building Chemical Innovation Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610771387.XA priority Critical patent/CN106317428A/en
Publication of CN102348743A publication Critical patent/CN102348743A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/203—Solid polymers with solid and/or liquid additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a process for preparing a masterbatch for use in plastics manufacture by converting a colorant into a solid substance, such as pellets. The compound to be mixed comprises a carrier polymer (SBS-elastomer), a colorant and an oil (ABTC or Citrofol B2). A mechanism is used that causes the polymer to swell. The colorant may be solid, liquid or gel-like.

Description

The method for preparing masterbatch and mixture
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a kind of method for preparing masterbatch and mixture, and the masterbatch of the pointed type of preparation claim 1 preamble and the preparation method of mixture.
The background technology of invention
WO02/42042A1 discloses a kind of method for preparing polymeric aggregate, and this polymeric aggregate has the pigment and/or the additive of high density, and its form is for based on the single component of wax or contain the masterbatch of one or more pigment and/or additive.The low viscosity polymer carrier mixes with one or more pigment and/or additive, also can be with assistant carrier, and the content that is concentrated into pigment/additive is processed into pellet up to 75-90% with this mixture fusion and through extruding.
WO2007/059767A1 discloses a kind of preparation in new ways that does not influence the molecular structure of related polymer materials and has had the method for the polymer beads of particular color and certain capabilities; Wherein through using the soluble polymeric material preparation to contain the lacquer or the glue of tinting material and/or additive; Said lacquer is applied to the surface of particulate polymer material, with said drying of materials until the surface film or the coating that obtain said tinting material and/or additive.Through suitably control the amount of tinting material and/or additive according to the amount of polymer beads, can realize in view of the above covering required tinting material and/or additive on each independent particle, to obtain the pre-determined characteristics of related polymer beads.Last said tinting material and additive are fixed on the surface of polymer beads through drying or evaporating solvent.
Goal of the invention
The purpose of this invention is to provide a kind of method of making masterbatch and mixture,, can partially or completely avoid expressing technique through this method according to required product.
Description of the invention
The method that the present invention prepares masterbatch and mixture is transformed into solid matter through for example liquid or solid tinting material with other enriched materials; For example be used for the pellet that plastics are made; Wherein through utilizing swelling mechanism; Binding property bead-type substrate, pigment, filler and additive swelling are become still specific (trickable) the finished product together, and make the finished product in the finished product, combine the advantage of liquid or solid tinting material and solid concentrates.
Through utilizing swelling mechanism, binding property carrier, pigment, filler and additive keep together with simple mode, and this processes material more easily, need be through not using expressing technique to form particle.
The present invention prepares the method for masterbatch and mixture can use liquid colourant and other enriched materials, maybe can use solid tinting material and other enriched materials.
In the instance that first is mentioned, the method that the present invention prepares masterbatch and mixture be characterised in that in super mixer, add between mixing period based on oil (for example ATBC or Citrofol TMB2) liquid colourant becomes solid on the surface on the base material (for example SBS elastomerics or similar polymkeric substance).
Alternatively, second instance that the present invention prepares the method for masterbatch and mixture is characterised in that carrier (for example SBS elastomerics) and pigment and the dry blending of additive, further slowly adding liquid for example ATBC or Citrofol between mixing period then TMB2.
Possibly, the present invention prepares masterbatch and method for compositions and can be changed into it and use the intermediate type tinting material of definition between liquid and solid tinting material, example gel shape tinting material.
Advantageously, the present invention prepares masterbatch and method for compositions can be changed into the additive that it uses tinting material, additive and various particle sizes, comprises the particle size of nano-sized particles scope.
Detailed description of the present invention
Method of the present invention can two kinds of patterns be implemented.
Use liquid:
The invention describes how for example liquid colourant and other enriched materials are transformed into solid matter, for example plastics are made used polymeric aggregate, and these the finished product combine the advantage of liquid colourant and solid concentrates.
The present invention utilizes swelling mechanism, and wherein swelling agent, carrier, pigment, filler and additive are integrated in the finished product or the material, and this makes this product and material process more easily for the user.
This technology or method can be described below simply:
A kind of based on oil (for example ATBC or Citrofol TMWhen carrying out adding between mixing period, liquid colourant B2) can on the surface on the base material (for example SBS-elastomerics or similar polymkeric substance), form solid in super mixer.What taken place is the power owing to swelling mechanism, and carrier oil will swell in the polymeric matrix, and all non-solubility materials are incorporated in the final material or product.At first, described oil as solvent, makes swelling agent, pigment, filler and additive be incorporated in base material or the product on generation swollen base material thus.
Through different techniques, this technology may be controlled to the perfect solid phase prod of preparation, for example is used for the polymeric aggregate of plastics-production, and it can match in excellence or beauty with solid and the liquid phase that standard is extruded.This control comprises particle or the particulate size of selecting base material, makes can to hold swelling agent, pigment, filler and additive formation the finished product more or less fully in the specific surface of swollen.
Use solid:
The invention describes how to prepare enriched material, for example masterbatch, composition or mixture utilize swelling mechanism, and the assistance through the swelling component with different solid adhesion together.
This means that for example single component enriched material, masterbatch etc. can prepare through simple " dry mixed ", and according to desired product, expressing technique can partly or completely be avoided.
This method or technology can be described below simply:
Carrier, SBS-elastomerics for example is with pigment and the dry blending of additive.After the mixing, under further mixing, add liquid for example ATBC or Citrofol TMB2.When pigment and additive swelling entering generation, the swelling behavior of ATBC in Styrenics will be incorporated into pigment and additive in the carrier.
The finished product of said solid method are the drying products identical with liquid processes.But the reason of two kinds of possibility methods is to make flexible method ground adapt to the top condition about material and application.

Claims (7)

1.制备母料和组合物的方法，其通过将例如液体或固体着色剂和其他浓缩物转变成固体物质，例如用于塑料制造的粒料，所述方法的特征在于通过利用溶胀机理将粘合性溶胀剂、载体、颜料、填料及添加剂整合到仍有特效的最终产品中，而在最终产品中结合液体或固体着色剂和固体浓缩物的优点。1. Process for the preparation of masterbatches and compositions by converting, for example, liquid or solid colorants and other concentrates into solid substances, such as pellets for plastics manufacture, characterized in that the viscous Composite swelling agents, carriers, pigments, fillers and additives can be integrated into final products that still have specific effects, and the advantages of liquid or solid colorants and solid concentrates can be combined in the final product. 2.根据权利要求1所述的制备母料和复合物的方法，其特征在于使用液体着色剂和其他浓缩物。2. Process for the preparation of masterbatches and compounds according to claim 1, characterized by the use of liquid colorants and other concentrates. 3.根据权利要求1所述的制备母料和组合物的方法，其特征在于使用固体着色剂和其他浓缩物。3. Process for the preparation of masterbatches and compositions according to claim 1, characterized by the use of solid colorants and other concentrates. 4.根据权利要求1所述的制备母料和组合物的方法，其特征在于在高速混合器中混合期间添加的基于油，例如ATBC或CitrofolTMB2，的液体着色剂在基材例如SBS-弹性体或类似聚合物上的表面上形成固体。4. Process for the preparation of masterbatches and compositions according to claim 1, characterized in that liquid colorants based on oils, such as ATBC or Citrofol TM B2, added during mixing in a high speed mixer, are added on substrates such as SBS- A solid formed on a surface of an elastomer or similar polymer. 5.根据权利要求2所述的制备母料和组合物的方法，其特征在于载体，例如SBS-弹性体，与颜料和添加剂干燥掺混，然后在进一步的混合期间加入液体例如ATBC或CitrofolTMB2。5. Process for the preparation of masterbatches and compositions according to claim 2, characterized in that the carrier, e.g. SBS-elastomer, is dry blended with pigments and additives, and then a liquid, e.g. ATBC or Citrofol ™, is added during further mixing B2. 6.根据权利要求1所述的制备母料和组合物的方法，其特征在于使用定义介于液体和固体着色剂之间的中间类型着色剂，例如凝胶状的着色剂。6. Process for the preparation of masterbatches and compositions according to claim 1, characterized by using colorants of an intermediate type defined between liquid and solid colorants, such as gel-like colorants. 7.根据权利要求1所述的制备母料和组合物的方法，其特征在于使用着色剂、添加剂和各种颗粒尺寸的添加剂，包括纳米尺寸颗粒范围的颗粒尺寸。7. Process for the preparation of masterbatches and compositions according to claim 1, characterized by the use of colorants, additives and additives of various particle sizes, including particle sizes in the nano-sized particle range.
CN2010800167245A 2009-03-09 2010-03-02 Methods of preparing masterbatches and compounds Pending CN102348743A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610771387.XA CN106317428A (en) 2009-03-09 2010-03-02 Method for manufacturing of masterbatches and compounds

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA200900309 2009-03-09
DKPA200900309 2009-03-09
PCT/DK2010/050052 WO2010102631A1 (en) 2009-03-09 2010-03-02 Method for manufacturing of masterbatches and compounds

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201610771387.XA Division CN106317428A (en) 2009-03-09 2010-03-02 Method for manufacturing of masterbatches and compounds

Publications (1)

Publication Number Publication Date
CN102348743A true CN102348743A (en) 2012-02-08

Family

ID=42727809

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201610771387.XA Pending CN106317428A (en) 2009-03-09 2010-03-02 Method for manufacturing of masterbatches and compounds
CN2010800167245A Pending CN102348743A (en) 2009-03-09 2010-03-02 Methods of preparing masterbatches and compounds

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201610771387.XA Pending CN106317428A (en) 2009-03-09 2010-03-02 Method for manufacturing of masterbatches and compounds

Country Status (3)

Country Link
EP (1) EP2406305A4 (en)
CN (2) CN106317428A (en)
WO (1) WO2010102631A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4271211A (en) * 1978-03-18 1981-06-02 Karl Finke Ohg Process for making plastic resin-dyestuff concentrates for use in the dyeing of plastic resins
CN1030925A (en) * 1987-04-03 1989-02-08 孙绍宣 High concentration universal chromogen and preparation method thereof
CN1110975A (en) * 1994-03-15 1995-11-01 赫彻斯特股份公司 Coloring agent adapted for preparation master agent of color
CN1161703A (en) * 1994-08-29 1997-10-08 卡伯特公司 Universal masterbatch
US5843524A (en) * 1993-12-20 1998-12-01 Ferro Corporation Vinyl halide polymer color concentrate

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2359354A (en) * 1940-09-06 1944-10-03 Charles H Campbell Milling rubber
US2793195A (en) * 1953-06-02 1957-05-21 Goodrich Co B F Process for preparing pigmented organic plastics
NL272812A (en) * 1960-12-27
US3394101A (en) * 1963-08-14 1968-07-23 Columbian Carbon Method of masterbatching reinforcing pigments with elastomeric polymers
US3770692A (en) * 1971-10-29 1973-11-06 Electroprint Inc Colored polymeric microsphere toners
CH662356A5 (en) * 1985-04-04 1987-09-30 Firmenich & Cie ARTICLE FOR THE DISSEMINATION OF SENSITIZING VAPORS BASED ON POLYAMIDE AND POLYETHER RESIN.
CA1303770C (en) * 1985-10-21 1992-06-16 Goodrich(B.F.) Company (The) Process for incorporating an additive into a polymer and product produced thereby
HU199885B (en) * 1986-11-05 1990-03-28 Pest Megyei Mueanyagipari Process for producing master-batch for dyeing sbs-type thermoplastic caoutchouc suitable for injection moulding
IT1237195B (en) * 1989-11-16 1993-05-26 Giuseppe Moltrasio WIDE MASTERBATCH FIELD OF USE.
JPH0693201A (en) * 1992-09-09 1994-04-05 Tokyo Ink Kk Color masterbatch and processed pigment
US5929132A (en) * 1992-11-19 1999-07-27 Arch Chemicals, Inc. Process for incorporating biocides into a liquid dispersion
EP1345742A1 (en) 2000-11-27 2003-09-24 Anders Flensburg High pigment/additive concentration polymer granulate
EP1266739A1 (en) * 2001-06-11 2002-12-18 R & D Technology, Inc. Method and apparatus for introducing colorant or the like to resinous materials
PL1969040T3 (en) 2005-11-23 2012-12-31 Controlled Polymers As Method for producing coloured polymer granulate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4271211A (en) * 1978-03-18 1981-06-02 Karl Finke Ohg Process for making plastic resin-dyestuff concentrates for use in the dyeing of plastic resins
CN1030925A (en) * 1987-04-03 1989-02-08 孙绍宣 High concentration universal chromogen and preparation method thereof
US5843524A (en) * 1993-12-20 1998-12-01 Ferro Corporation Vinyl halide polymer color concentrate
CN1110975A (en) * 1994-03-15 1995-11-01 赫彻斯特股份公司 Coloring agent adapted for preparation master agent of color
CN1161703A (en) * 1994-08-29 1997-10-08 卡伯特公司 Universal masterbatch

Also Published As

Publication number Publication date
WO2010102631A1 (en) 2010-09-16
CN106317428A (en) 2017-01-11
EP2406305A4 (en) 2014-05-28
EP2406305A1 (en) 2012-01-18

Similar Documents

Publication Publication Date Title
KR102017363B1 (en) Biodegradable material made of biological components
CN100500764C (en) A kind of preparation method of polyamide/nanometer montmorillonite masterbatch
CN101289599A (en) Process for dispersing hot-melt adhesive fillers
CN104877419B (en) Gouache and acrylic painting pigment and method for manufacturing same
CN103102814A (en) EVA (ethylene-vinyl acetate) hot-melting adhesive and preparation method thereof
CN104085139B (en) Easily released film with smooth silicone oil surface and production process thereof
CN103819959A (en) Light stone-imitating particulate matter and water-based stone-imitating coating prepared by adopting same
CN101319068A (en) White master batch applied for polyolefin film and preparation method thereof
CN102167941A (en) Aqueous plastic coating paint
WO2018115729A1 (en) Binder that is solid at room temperature
CN102002338A (en) Preparation method of waterproof soyabean protein adhesive
CN102408700A (en) Preparation method of long-afterglow luminescent plastic
CN102061113B (en) Alcohol-soluble polyurethane gravure plastic ink and preparation method thereof
CN102337035A (en) Waste plastic modified asphalt and preparation method thereof
CN108276914B (en) Water-based litchi surface stone-like sand-containing color coating and preparation method thereof
CN107446336A (en) A kind of low smell exempts to spray PC/ABS materials and preparation method thereof
CN106543805B (en) A kind of high solid content polyvinyl chloride film gravure white ink and preparation method thereof
CN103275545A (en) Isocyanate derivative microcapsule and preparation method thereof
CN103819918A (en) Composite high-viscosity modified asphalt and preparation method thereof
Lv et al. A latened catalytic strategy for low cure thermoset powder coating by post-dry-blending technique
CN106833112A (en) A kind of offset lithographic ink and preparation method thereof
CN102348743A (en) Methods of preparing masterbatches and compounds
CN106147525A (en) A kind of antimicrobial form montmorillonite intercalation polymeric modification epoxy resin based powder coating and preparation method thereof
CN108977123A (en) A kind of low temperature resistant books and periodicals glue and preparation method thereof
CN104151498A (en) Preparation method for multi-component composite grafting modification resins used for hot melt adhesive

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: CONSTRUCTION CHEMICAL INNOVATIONS LTD.

Free format text: FORMER OWNER: ANDERS FLENSBURG

Effective date: 20150907

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20150907

Address after: Dane Lieb

Applicant after: Building chemical innovation Co Ltd

Address before: Dane Lieb

Applicant before: Flensburg Anders

C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20120208