CN102344838A - Preparation method for emulsified diesel oil - Google Patents
Preparation method for emulsified diesel oil Download PDFInfo
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- CN102344838A CN102344838A CN2011102587242A CN201110258724A CN102344838A CN 102344838 A CN102344838 A CN 102344838A CN 2011102587242 A CN2011102587242 A CN 2011102587242A CN 201110258724 A CN201110258724 A CN 201110258724A CN 102344838 A CN102344838 A CN 102344838A
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- Prior art keywords
- diesel oil
- biomass
- mixed solution
- preparation
- additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000002028 Biomass Substances 0.000 claims abstract description 52
- 239000000654 additive Substances 0.000 claims abstract description 36
- 230000000996 additive effect Effects 0.000 claims abstract description 36
- 239000011259 mixed solution Substances 0.000 claims abstract description 35
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 238000004945 emulsification Methods 0.000 claims description 18
- 238000005303 weighing Methods 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 9
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 9
- 229920000768 polyamine Polymers 0.000 claims description 9
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 8
- -1 Polyoxyethylene nonylphenol Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 150000002632 lipids Chemical class 0.000 claims description 8
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical group [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 239000002803 fossil fuel Substances 0.000 abstract description 4
- 239000000295 fuel oil Substances 0.000 abstract description 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002551 biofuel Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- NBLKSVZGIFWHQH-UHFFFAOYSA-N [O].C(CCCCCCCC)C1=C(C=CC=C1)O Chemical compound [O].C(CCCCCCCC)C1=C(C=CC=C1)O NBLKSVZGIFWHQH-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention relates to a preparation method for emulsified diesel oil, and belongs to the technical field of clean energy sources. The method comprises the following steps of: adding a biomass additive and water into the diesel oil; mixing the weighed biomass additive and diesel oil in proportion; stirring mixture with a stirrer at normal temperature; adding weighed water after uniform mixing and stirring; and keeping mixed solution clear and transparent after stirring to obtain the emulsified diesel oil. All the chromaticity, ash content, corrosion and solidification point of the biomass additive-containing emulsified diesel oil prepared by the method meet the national GB252-2000 light diesel oil standard, and the heat value is equivalent to that of the diesel oil. Sulfur content is 40 percent lower than that of the market available diesel oil. By using the biomass additive, the emulsified diesel oil with high stability, low sulfur content, less ash content, no mechanical corrosion and high combustion performance can be prepared; fossil fuel resources are greatly saved; and the pollution caused to environment by fuel oil is reduced.
Description
Technical field
The present invention relates to a kind of preparation method of diesel oil emulsification, belong to the clean energy technology field.
Background technology
Diesel oil is as a kind of important refining of petroleum article; Occupy the higher market share at home in the fuel; Become important power fuel; Along with domestic vehicle diesel oil trend is accelerated; The demand of following diesel oil can be more and more big; And petroleum resources is exhausted day by day; International Crude Oil rises steadily; People's environment protection health consciousness improves constantly; The exploitation paces of diesel oil alternative fuel have been promoted to accelerate greatly; Last century, the nineties can be used processing extraction biofuel and biomass fuels such as regenerated plant, and is low with sulphur content; The discharging of sulfurous gas and sulfide is reduced, and oxygen level is high; Smoke evacuation reduces during burning, and the advantages such as fossil fuel resource and renewable circulation of can saving receive the attention and the support of countries in the world government.
For many years, biofuel has outside the above-mentioned advantage, also faces various challenges simultaneously.1, strives grain with human, livestock.2, partly grain price and feed price rise have been raised.3, output is influenced by weather, the market factor easily.4, quality control is difficult, and product chance high temperature is prone to produce oxidation, and chance low temperature is prone to generation and condenses.5, standard disunity, designing and manufacturing technique does not have complete scheme.
Summary of the invention
The objective of the invention is to propose a kind of preparation method of diesel oil emulsification; To solve problem the present invention described in the present biofuel a kind of biomass additive is provided; After this biomass additive can fully fuse with commercially available diesel oil and water; Stability is strong; Sulphur content is low, ash is few, no mechanical burn into has good burning performance; Save fossil fuel resource, reduce environmental pollution.
The preparation method of the diesel oil emulsification that the present invention proposes may further comprise the steps:
(1) in diesel oil, add biomass additive and water, the ratio of adding is:
Biomass additive 5～10%
Water 15～20%
Diesel oil 70～85;
(2) the biomass additive with weighing mixes with diesel oil mutually; Mixture stirs with stirrer at normal temperatures; The stirrer rotating speed is 800～1200 rev/mins; The water that adds weighing after the mixing and stirring; The stirrer rotating speed is 800～1200 rev/mins; Stirred 10～20 minutes, and made mixed solution limpid thorough, obtain diesel oil emulsification.
Among the above-mentioned preparation method, the preparation method of described biomass additive comprises following each step:
(1) by each component in the following weight percent weighing biomass additive:
Biomass mixed solution 90～92%,
High molecular polymer 1.5～2%,
Polyamines 2～3%,
Primary isoamyl alcohol 1～2%,
Toluene 1.5～2%,
Encircle luxuriant iron 0.2～1.5%,
Polyoxyethylene nonylphenol ether 0.3～1.5%;
(2) the biomass mixed solution of weighing is heated to 35～45 ℃ in proportion; High molecular polymer, polyamines and the primary isoamyl alcohol of weighing in proportion whenever were separated by 7～15 minutes successively, join in the biomass mixed solution of intensification, after the stirring and dissolving; Be cooled to normal temperature, obtain first mixed solution;
(3) will be in proportion toluene, the luxuriant iron of ring and the polyoxyethylene nonylphenol ether of weighing whenever be separated by successively and mixed successively in 3～7 minutes, stirring and dissolving under the normal temperature obtains second mixed solution;
(4) above-mentioned first mixed solution is joined in second mixed solution, be heated to 35～45 ℃, mix and stirred 30 minutes, obtain the biomass additive.
With the diesel oil emulsification that contains the biomass additive that obtains of the inventive method preparation, its colourity, ash, corrosion and condensation point all meet national GB252-2000 LIGHT DIESEL OIL standard, and caloic and diesel oil are suitable.Sulphur content is than commercially available diesel oil low 40%.Use biomass additive of the present invention, it is strong to prepare stability, and the diesel oil emulsification that sulphur content is low, ash is few, no mechanical burn into has good burning performance is saved the fossil fuel resource greatly, and reduces the pollution of fuel oil to environment.
The practical implementation method
The preparation method of the diesel oil emulsification that the present invention proposes may further comprise the steps:
(1) in diesel oil, add biomass additive and water, the ratio of adding is:
Biomass additive 5～10%
Water 15～20%
Diesel oil 70～85;
(2) the biomass additive with weighing mixes with diesel oil mutually; Mixture stirs with stirrer at normal temperatures; The stirrer rotating speed is 800～1200 rev/mins; The water that adds weighing after the mixing and stirring; The stirrer rotating speed is 800～1200 rev/mins; Stirred 10～20 minutes, and made mixed solution limpid thorough, obtain diesel oil emulsification.
Among the preparation method of the present invention, the preparation method of described biomass additive comprises following each step:
(1) by each component in the following weight percent weighing biomass additive:
Biomass mixed solution 90～92%,
High molecular polymer 1.5～2%,
Polyamines 2～3%,
Primary isoamyl alcohol 1～2%,
Toluene 1.5～2%,
Encircle luxuriant iron 0.2～1.5%,
Polyoxyethylene nonylphenol ether 0.3～1.5%;
(2) the biomass mixed solution of weighing is heated to 35～45 ℃ in proportion; High molecular polymer, polyamines and the primary isoamyl alcohol of weighing in proportion whenever were separated by 7～15 minutes successively, join in the biomass mixed solution of intensification, after the stirring and dissolving; Be cooled to normal temperature, obtain first mixed solution;
(3) will be in proportion toluene, the luxuriant iron of ring and the polyoxyethylene nonylphenol ether of weighing whenever be separated by successively and mixed successively in 3～7 minutes, stirring and dissolving under the normal temperature obtains second mixed solution;
(4) above-mentioned first mixed solution is joined in second mixed solution, be heated to 35～45 ℃, mix and stirred 30 minutes, obtain the biomass additive.
Among the preparation method of above-mentioned biomass additive, described biomass mixed solution is mixed by lipid acid, acidifying oil and oleic acid, and lipid acid, acidifying oil and oleic weight percent are:
Lipid acid 10～15%
Acidifying oil 15～30%
Oleic acid 55～75%
Among the preparation method of above-mentioned biomass additive, used lipid acid, acidifying oil and oleic acid are produced by blue sky, Shandong grease factory.Described high molecular polymer is a triton x-100, is produced by Hai'an, Jiangsu petroleum chemical plant.
The polyamines that uses among the preparation method of the present invention, primary isoamyl alcohol, toluene, the luxuriant iron of ring and nonyl phenol oxygen Vinyl Ether all are the general chemical raw materials, can buy from Chemical market.
Below introduce the embodiment of the inventive method:
Embodiment one
Prepare diesel oil emulsification of the present invention, form by following compositions in weight percentage:
Commercially available diesel oil 75%; Biomass additive 10% and 15% water; Elder generation stirs the mixture of biomass additive and diesel oil at normal temperatures in proportion; The stirrer rotating speed is 1000 rev/mins; After the mixing and stirring, add entry in proportion and stir, mixed 15 minutes; Treating limpidly when thorough, both had been the diesel oil emulsification finished product.
Embodiment two
Prepare diesel oil emulsification of the present invention; Form by following compositions in weight percentage: commercially available diesel oil 80%; Biomass additive 10% (pressing the preparation of embodiment two methods) and 10% water; Elder generation stirs the mixture of biomass additive and diesel oil at normal temperatures in proportion, and the stirrer rotating speed is 1000 rev/mins, after the mixing and stirring; Add entry and mix stirring 20 minutes; Treating limpidly when thorough, both had been the diesel oil emulsification finished product
The foregoing description is to prepare according to different service requirementss, and each item physical and chemical index of the diesel oil emulsification of embodiment one, embodiment two preparations is detected, and its leading indicator all meets national solar oil GB252-2000 standard.Colourity 3.5, ash 0.0029, condensation point-6,1 grade of copper corrosion, kinematic viscosity 7.6, flash-point 55, calorific value 41.06/MJ/kg, sulphur content 0.074.
Embodiment three
Used biomass additive when preparing diesel oil emulsification of the present invention, form by following compositions in weight percentage:
Biomass mixed solution 90% is heated to 40 ℃, high molecular polymer 1.5%, polyamines 3%; Primary isoamyl alcohol 1.5% is sequentially added in the biomass mixed solution, after mixing, is cooled to normal temperature; Obtain first mixed solution; Toluene 2% is dissolved in luxuriant iron 0.5% of ring and the polyoxyethylene nonylphenol ether 1.5%, obtains second mixed solution, first mixed solution is joined in second mixed solution; Be heated to 35 ℃; Stirring at low speed dissolving 30 minutes obtains the biomass additive, and products obtained therefrom is a brown liquid.
Used biomass mixed solution is by lipid acid in the present embodiment: 13%, and acidifying oil: 20% and oleic acid: 67% mixes.
Embodiment four
Used biomass additive when preparing diesel oil emulsification of the present invention, form by following compositions in weight percentage:
Biomass mixed solution 92%, high molecular polymer 1.6%, polyamines 2%, primary isoamyl alcohol 1.6%; Toluene 1.5% encircles luxuriant iron 1%, polyoxyethylene nonylphenol ether 0.3%; Technological process is identical with embodiment one, prepares the biomass additive product, and products obtained therefrom is a brown liquid.
Claims (4)
1. the preparation method of a diesel oil emulsification is characterized in that this preparation method may further comprise the steps:
(1-1) in diesel oil, add biomass additive and water, the ratio of adding is:
Biomass additive 5～10%
Water 15～20%
Diesel oil 70～85;
(1-2) the biomass additive with weighing mixes with diesel oil mutually; Mixture stirs with stirrer at normal temperatures; The stirrer rotating speed is 800～1200 rev/mins; The water that adds weighing after the mixing and stirring; The stirrer rotating speed is 800～1200 rev/mins; Stirred 10～20 minutes, and made mixed solution limpid thorough, obtain diesel oil emulsification.
2. preparation method as claimed in claim 1 is characterized in that the preparation method of wherein said biomass additive comprising following each step:
(2-1) by each component in the following weight percent weighing biomass additive:
Biomass mixed solution 90～92%,
High molecular polymer 1.5～2%,
Polyamines 2～3%,
Primary isoamyl alcohol 1～2%,
Toluene 1.5～2%,
Encircle luxuriant iron 0.2～1.5%,
Polyoxyethylene nonylphenol ether 0.3～1.5%;
(2-2) the biomass mixed solution of weighing is heated to 35～45 ℃ in proportion; High molecular polymer, polyamines and the primary isoamyl alcohol of weighing in proportion whenever were separated by 7～15 minutes successively, join in the biomass mixed solution of intensification, after the stirring and dissolving; Be cooled to normal temperature, obtain first mixed solution;
(2-3) will be in proportion toluene, the luxuriant iron of ring and the polyoxyethylene nonylphenol ether of weighing whenever be separated by successively and mixed successively in 3～7 minutes, stirring and dissolving under the normal temperature obtains second mixed solution;
(2-4) above-mentioned first mixed solution is joined in second mixed solution, be heated to 35～45 ℃, mix and stirred 30 minutes, obtain the biomass additive.
3. preparation method as claimed in claim 2 is characterized in that wherein said biomass mixed solution is mixed by lipid acid, acidifying oil and oleic acid, and lipid acid, acidifying oil and oleic weight percent are:
Lipid acid 10～15%
Acidifying oil 15～30%
Oleic acid 55～75%
4. preparation method as claimed in claim 2 is characterized in that wherein said high molecular polymer is a triton x-100.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102587242A CN102344838B (en) | 2011-09-02 | 2011-09-02 | Preparation method for emulsified diesel oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102587242A CN102344838B (en) | 2011-09-02 | 2011-09-02 | Preparation method for emulsified diesel oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102344838A true CN102344838A (en) | 2012-02-08 |
| CN102344838B CN102344838B (en) | 2013-12-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102587242A Expired - Fee Related CN102344838B (en) | 2011-09-02 | 2011-09-02 | Preparation method for emulsified diesel oil |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1958745A (en) * | 2006-10-09 | 2007-05-09 | 陈志红 | Environmental protective diesel oil, and preparation method |
| CN101020842A (en) * | 2007-03-13 | 2007-08-22 | 广东工业大学 | Recipe and prepn process of diesel oil additive |
| CN101067094A (en) * | 2007-06-12 | 2007-11-07 | 广东工业大学 | Preparation method of microemulsion diesel oil |
| EP1900796A1 (en) * | 2005-06-24 | 2008-03-19 | Xianlun Wang | A modified emulsified fuel oil and its preparation method |
| CN101824343A (en) * | 2010-05-27 | 2010-09-08 | 熊道陵 | Clean and energy-saving micro-emulsified diesel oil with high flash point and preparation method thereof |
| CN101940981A (en) * | 2010-08-07 | 2011-01-12 | 武贵丙 | Highly watered micro-emulsified diesel oil additive, preparation method and application thereof |
-
2011
- 2011-09-02 CN CN2011102587242A patent/CN102344838B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1900796A1 (en) * | 2005-06-24 | 2008-03-19 | Xianlun Wang | A modified emulsified fuel oil and its preparation method |
| CN1958745A (en) * | 2006-10-09 | 2007-05-09 | 陈志红 | Environmental protective diesel oil, and preparation method |
| CN101020842A (en) * | 2007-03-13 | 2007-08-22 | 广东工业大学 | Recipe and prepn process of diesel oil additive |
| CN101067094A (en) * | 2007-06-12 | 2007-11-07 | 广东工业大学 | Preparation method of microemulsion diesel oil |
| CN101824343A (en) * | 2010-05-27 | 2010-09-08 | 熊道陵 | Clean and energy-saving micro-emulsified diesel oil with high flash point and preparation method thereof |
| CN101940981A (en) * | 2010-08-07 | 2011-01-12 | 武贵丙 | Highly watered micro-emulsified diesel oil additive, preparation method and application thereof |
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| CN102344838B (en) | 2013-12-11 |
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