CN102321357A - Environment-friendly heat-resistant antistatic insulating material - Google Patents
Environment-friendly heat-resistant antistatic insulating material Download PDFInfo
- Publication number
- CN102321357A CN102321357A CN201110208702A CN201110208702A CN102321357A CN 102321357 A CN102321357 A CN 102321357A CN 201110208702 A CN201110208702 A CN 201110208702A CN 201110208702 A CN201110208702 A CN 201110208702A CN 102321357 A CN102321357 A CN 102321357A
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- CN
- China
- Prior art keywords
- insulating material
- environment
- antistatic
- insulating
- resistanceheat resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011810 insulating material Substances 0.000 title claims abstract description 35
- 239000002216 antistatic agent Substances 0.000 claims abstract description 14
- 239000003063 flame retardant Substances 0.000 claims abstract description 12
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 8
- 239000004417 polycarbonate Substances 0.000 claims abstract description 8
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- -1 ester alkyl acid amide Chemical class 0.000 claims description 8
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 6
- 238000007046 ethoxylation reaction Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 abstract description 7
- 238000005452 bending Methods 0.000 abstract description 6
- 238000004080 punching Methods 0.000 abstract description 3
- 230000003068 static effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an environment-friendly heat-resistant antistatic insulating material which is characterized by comprising the following components in percentage by mass: 80% of polycarbonate, 3% of halogen-free flame retardant, 10% of carbon black, 5% of calcium carbonate and 2% of antistatic agent. The insulating material or insulating piece made of the insulating material has new components and proportioning, and the chemical molecular structure is improved; and thus, the insulating material or insulating piece has better bending resistance (1.2-1.5 times of the product made of the traditional insulating material), higher heat resistance and better heat-resistant effect, and can effectively prolong the punching service life of the finished product by 1.5-2 times. Since the antistatic agent is added in the formula, the static electricity produced by friction is effectively reduced in the manufacturing process of insulating products, and the insulating material has good antistatic effect.
Description
Technical field
The present invention relates to a kind of insulating material, especially relate to a kind of insulating material that is used on the electronic product, belong to material chemistry technical field.
Background technology
Along with the development of society and improving constantly of secondary industry level. product demand amounts such as communication cable and optical cable, household electrical appliances, aviation, mobile phone constantly increase; And complicated, the functionalization of product is also in continuous intensification; Especially the high quality of product is required also in continuous enhancing, especially to demands for higher performance such as environmental protection, heat resistanceheat resistant, anti-electrostatic and the insulation of product, planarizations.And traditional technology way has also fundamentally satisfied not present demand, and technical requirements do not reach customer requirement yet, in this case, must will pass through the functional performance of improved products, enhancing product, could satisfy to show demand.And the insulating material that performance of products is played a crucial role, the insulating trip on the electronic product has more very important effect; Traditional insulating material is owing to the restriction on component, the proportioning; At the insulating trip that cuts through itemize, board, forms after a series of procedure of processings such as gum, punch press are die-cut, packing perforation, torn edges, cleaning, it is after attaching on the casing, because not anti-bending; Be easy to produce the situation of alice; And through the baking oven baking of 150 degree after 4 hours, the situation that product can bend, shrink has had a strong impact on the quality of product.
Summary of the invention
Be to solve the deficiency of prior art, the object of the present invention is to provide and a kind ofly can effectively improve the heat resistanceheat resistant performance of product, the environment-friendly type heat resistanceheat resistant antistatic insulating material of antistatic performance.
For achieving the above object, the present invention realizes through following technical scheme:
A kind of environment-friendly type heat resistanceheat resistant antistatic insulating material is characterized in that, comprise following component, and the quality percentage composition of each component is respectively:
Polycarbonate 80%;
Halogen-free flame retardants 3 ± 0.2%;
Carbon black 10 ± 0.2%;
Lime carbonate 5 ± 0.1%;
Antistatic agent 2 ± 0.1%.
Above-mentioned halogen-free flame retardants is 95% triphenylphosphate, i.e. MCA.
Above-mentioned antistatic agent is 100% ethoxylation ester alkyl acid amide, i.e. ASA.
A kind of insulating trip of above-mentioned environment-friendly type heat resistanceheat resistant antistatic insulating material prepn.
The invention has the beneficial effects as follows: insulating material of the present invention or the insulating trip that especially prepares; Because it has new component and proportioning, has improved the chemical molecular structure, has better resistance to bend(ing); It is 1.2-1.5 times that traditional insulating material prepares product; And have better heat resistanceheat resistant performance and heat resistanceheat resistant effect, can effectively prolong the finished product punching press work-ing life 1.5-2 doubly, and owing in prescription, increased antistatic agent; Effectively reduced insulating products fricative static in making processes, anti-static effect is very good.
Embodiment
Below in conjunction with specific embodiment the present invention is done concrete introduction.
Embodiment 1:
Environment-friendly type heat resistanceheat resistant antistatic insulating material comprises following component, and the quality percentage composition of each component is respectively: polycarbonate 79%; Halogen-free flame retardants 2.8%; Carbon black 10.2%; Lime carbonate 5.1%; Antistatic agent 1.9% wherein, halogen-free flame retardants is 95% triphenylphosphate, i.e. MCA, antistatic agent then is 100% ethoxylation ester alkyl acid amide, i.e. ASA.
Embodiment 2:
Environment-friendly type heat resistanceheat resistant antistatic insulating material comprises following component, and the quality percentage composition of each component is respectively: polycarbonate 80%; Halogen-free flame retardants 3%; Carbon black 10%; Lime carbonate 5%; Antistatic agent 2% wherein, halogen-free flame retardants is 95% triphenylphosphate, i.e. MCA, antistatic agent then is 100% ethoxylation ester alkyl acid amide, i.e. ASA.
Embodiment 3:
Environment-friendly type heat resistanceheat resistant antistatic insulating material comprises following component, and the quality percentage composition of each component is respectively: polycarbonate 80%; Halogen-free flame retardants 3.1%; Carbon black 9.9%; Lime carbonate 4.9%; Antistatic agent 2.1% wherein, halogen-free flame retardants is 95% triphenylphosphate, i.e. MCA, antistatic agent then is 100% ethoxylation ester alkyl acid amide, i.e. ASA.
The above embodiments are most preferred embodiment with embodiment 2.
The insulating trip that utilizes above-mentioned environment-friendly type heat resistanceheat resistant antistatic insulating material to cut, prepare after a series of procedure of processings such as gum, punch press are die-cut, packing perforation, torn edges, cleaning through injection moulding, itemize, board.
The component of traditional insulating material and each components contents are respectively: polycarbonate 70%; Halogen-free flame retardants 2%; Carbon black 20% and lime carbonate 8%.
The clinging power performance comparison of the insulating products of traditional insulating material preparation and the insulating products of insulating material of the present invention preparation is as shown in table 1 below; Wherein, laminated material is: PET#25, and the condition that overlays is: the 2kg cylinder is back and forth once; Storage period: 30 minutes; Draw speed: 300mm/min, the stretching angle: 180 degree, measure temperature: 23 degree * 50%RH.
Table 1: unit: N/20mm
| Clung body | Insulating products according to the invention | The tradition insulating products |
| Stainless steel plate | 11.0 | 11.0 |
| The ABS plate | 10.0 | 8.0 |
| Polyester film | 9.5 | 8.0 |
| Polycarbonate plate | 12.5 | 10.5 |
| Foam (ML24) | 9.0 | 8.5 |
The bending resistance of traditional insulating material is 90mpa, and the bending resistance of insulating material of the present invention can reach 100mpa, and aspect heat impedance, traditional insulating material is 90 ℃, and the bending resistance of insulating material of the present invention can reach 110 ℃.
Can know through above-mentioned testing experiment: insulating material of the present invention or by the insulating trip of its preparation; Because it has new component and proportioning, has improved the chemical molecular structure, has better resistance to bend(ing); It is 1.2-1.5 times that traditional insulating material prepares product; And have better heat resistanceheat resistant performance and heat resistanceheat resistant effect, can effectively prolong the finished product punching press work-ing life 1.5-2 doubly, and owing in prescription, increased antistatic agent; Effectively reduced insulating products fricative static in making processes, anti-static effect is very good.
And at insulating material in the process of fitting with product, anti-bending, not alice.And advanced 200 degree baking ovens bakings 4 as a child, product is smooth, do not shrink.
The present invention forms and content through improving component, makes the multifunction that has of product, and the more stable quality of product, uses convenient.
The foregoing description does not limit the present invention in any form, and all employings are equal to the technical scheme that mode obtained of replacement or equivalent transformation, all drop in protection scope of the present invention.
Claims (4)
1. an environment-friendly type heat resistanceheat resistant antistatic insulating material is characterized in that, comprise following component, and the quality percentage composition of each component is respectively:
Polycarbonate 80%;
Halogen-free flame retardants 3 ± 0.2%;
Carbon black 10 ± 0.2%;
Lime carbonate 5 ± 0.1%;
Antistatic agent 2 ± 0.1%.
2. environment-friendly type heat resistanceheat resistant antistatic insulating material according to claim 1 is characterized in that described halogen-free flame retardants is 95% triphenylphosphate.
3. environment-friendly type heat resistanceheat resistant antistatic insulating material according to claim 1 is characterized in that, described antistatic agent is 100% ethoxylation ester alkyl acid amide.
4. insulating trip that utilizes the described environment-friendly type heat resistanceheat resistant of each claim antistatic insulating material prepn among the claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110208702A CN102321357A (en) | 2011-07-25 | 2011-07-25 | Environment-friendly heat-resistant antistatic insulating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110208702A CN102321357A (en) | 2011-07-25 | 2011-07-25 | Environment-friendly heat-resistant antistatic insulating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102321357A true CN102321357A (en) | 2012-01-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110208702A Pending CN102321357A (en) | 2011-07-25 | 2011-07-25 | Environment-friendly heat-resistant antistatic insulating material |
Country Status (1)
| Country | Link |
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| CN (1) | CN102321357A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105513726A (en) * | 2015-11-23 | 2016-04-20 | 安徽恒利机电科技有限公司 | Production technology for automobile battery insulation sheets |
| CN106893158A (en) * | 2017-04-20 | 2017-06-27 | 马鞍山市润启新材料科技有限公司 | A kind of environmental protection type antistatic insulating materials |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1336945A (en) * | 1999-01-11 | 2002-02-20 | 西巴特殊化学品控股有限公司 | Synthetic polymers comprising additive blends with enhanced effect |
| US20040011999A1 (en) * | 2002-07-22 | 2004-01-22 | Murray Michael C. | Antistatic flame retardant resin composition and methods for manufacture thereof |
| WO2008108983A1 (en) * | 2007-03-07 | 2008-09-12 | E. I. Du Pont De Nemours And Company | Flame retardant polycarbonate compositions |
| CN101508835A (en) * | 2009-03-12 | 2009-08-19 | 华南理工大学 | Halogen-free flame-proof static resistant polycarbonate composition and method for producing the same |
| CN101627079A (en) * | 2007-03-07 | 2010-01-13 | 纳幕尔杜邦公司 | Flame retardant polycarbonate compositions |
-
2011
- 2011-07-25 CN CN201110208702A patent/CN102321357A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1336945A (en) * | 1999-01-11 | 2002-02-20 | 西巴特殊化学品控股有限公司 | Synthetic polymers comprising additive blends with enhanced effect |
| US20040011999A1 (en) * | 2002-07-22 | 2004-01-22 | Murray Michael C. | Antistatic flame retardant resin composition and methods for manufacture thereof |
| CN1681885A (en) * | 2002-07-22 | 2005-10-12 | 通用电气公司 | Antistatic flame retardant resin composition and methods for manufacture thereof |
| WO2008108983A1 (en) * | 2007-03-07 | 2008-09-12 | E. I. Du Pont De Nemours And Company | Flame retardant polycarbonate compositions |
| CN101627079A (en) * | 2007-03-07 | 2010-01-13 | 纳幕尔杜邦公司 | Flame retardant polycarbonate compositions |
| CN101508835A (en) * | 2009-03-12 | 2009-08-19 | 华南理工大学 | Halogen-free flame-proof static resistant polycarbonate composition and method for producing the same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105513726A (en) * | 2015-11-23 | 2016-04-20 | 安徽恒利机电科技有限公司 | Production technology for automobile battery insulation sheets |
| CN106893158A (en) * | 2017-04-20 | 2017-06-27 | 马鞍山市润启新材料科技有限公司 | A kind of environmental protection type antistatic insulating materials |
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Application publication date: 20120118 |