CN102295879A - Vacuum tin plating or indium plating photocurable coating and preparation method thereof - Google Patents
Vacuum tin plating or indium plating photocurable coating and preparation method thereof Download PDFInfo
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- CN102295879A CN102295879A CN2010102101371A CN201010210137A CN102295879A CN 102295879 A CN102295879 A CN 102295879A CN 2010102101371 A CN2010102101371 A CN 2010102101371A CN 201010210137 A CN201010210137 A CN 201010210137A CN 102295879 A CN102295879 A CN 102295879A
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- photo
- cured coating
- vacuum
- acrylate
- plated
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- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000000576 coating method Methods 0.000 title claims abstract description 44
- 238000007747 plating Methods 0.000 title claims abstract description 33
- 229910052738 indium Inorganic materials 0.000 title claims abstract description 27
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 title claims abstract description 27
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title abstract description 6
- 238000002360 preparation method Methods 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 44
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229920000728 polyester Polymers 0.000 claims abstract description 30
- 239000003504 photosensitizing agent Substances 0.000 claims abstract description 25
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 39
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 18
- 230000001588 bifunctional effect Effects 0.000 claims description 18
- 229940043232 butyl acetate Drugs 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 18
- 239000011737 fluorine Substances 0.000 claims description 18
- 238000012986 modification Methods 0.000 claims description 18
- 230000004048 modification Effects 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 13
- 239000000049 pigment Substances 0.000 claims description 12
- -1 titanic acid ester Chemical class 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 125000000524 functional group Chemical group 0.000 claims description 9
- 239000012895 dilution Substances 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 6
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 5
- 150000008103 phosphatidic acids Chemical class 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 230000006378 damage Effects 0.000 abstract description 3
- 208000027418 Wounds and injury Diseases 0.000 abstract description 2
- 208000014674 injury Diseases 0.000 abstract description 2
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 238000003912 environmental pollution Methods 0.000 abstract 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000005034 decoration Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004500 asepsis Methods 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 231100000739 chronic poisoning Toxicity 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Chemically Coating (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a vacuum tin plating or indium plating photocurable coating and preparation method thereof. A formula of the vacuum tin plating or indium plating photocurable coating comprises the following components in percentage by weight: 10-15 percent of double-functional group aliphatic urethane acrylate, 12-19 percent of six-functional group polyester acrylate, 11-18 percent of four-functional group polyester acrylate, 8-13 percent of double-functional group acrylate monomer, 0.5-2 percent of acidic coupling agent, 0.1-0.5 percent of fluorine-modified leveling agent, 2-7 percent of photosensitizer, 15-30 percent of butyl acetate, 4-10 percent of ethyl acetate and 1-5 percent of ethylene glycol monoethyl ether acetate. The vacuum tin plating or indium plating photocurable coating has excellent leveling property, high hardness and stable performance; and the problems of environmental pollution caused by an organic solvent in a vacuum process of the conventional coating and injury caused to bodies of operators can be avoided.
Description
Technical field
The present invention relates to a kind of coating and manufacture method thereof, particularly relate to a kind of vacuum zinc-plated or plating indium photo-cured coating and manufacture method thereof, can be applicable to the surface protection and the decoration of the vacuum plating spare of electronic products such as mobile phone, digital camera.
Background technology
In the prior art; be used for mobile phone; in the surface protection of the vacuum plating spare of electronic products such as digital camera and the process of decoration; the Reflow Soldering of surface mount production process is arranged usually and be coated with operations such as tin; and the manual welding operation of maintenance and checkout can produce plumbous indium; resin-coated oven dry; also there are organic solvents such as toluene in the wiping operation; spectrometer in the physical detection operation can produce radio-frequency radiation in addition; and the roentgen machine that checkout is used also can produce ionizing rays; the toluene that exists in these vacuum production processes; Virahol; organic solvents such as isopropyl ether can pollute environment; can cause chronic poisoning to operative employee's health, even can be because of the residual health of damaging the human consumer of solvent.
Summary of the invention
The present invention is directed to the defective of prior art, a kind of vacuum zinc-plated or plating indium photo-cured coating and manufacture method thereof of environment-protecting asepsis is provided.
Technical scheme of the present invention is as follows:
Zinc-plated or the plating indium photo-cured coating of a kind of vacuum, by weight, each component and content comprise in its prescription: bifunctional fat adoption ammonia ester acrylate 10%～15%, six functional groups polyester acrylate 12%～19%, four-functional group polyester acrylate 11%～18%, bifunctional acrylate's monomer 8%～13%, acid coupling agent 0.5%～2%, fluorine modification flow agent 0.1%～0.5%, photosensitizers 2%～7%, butylacetate 15%～30%, ethyl acetate 4%～10%, ethylene glycol ether acetate 1%～5%.
Described fluorine modification flow agent adopts fluorine-carbon modified acrylate copolymer.
Described acid coupling agent adopts two (the two hot phosphatidic acids) titanic acid ester of tetra isopropyl.
Described photosensitizers adopts the a-hydroxy cyclohexyl phenylketone.
Zinc-plated or the plating indium photo-cured coating of another kind of vacuum of the present invention, comprise photo-cured coating and tinting pigment, by weight, the prescription of described photo-cured coating comprises: bifunctional fat adoption ammonia ester acrylate 10%～15%, six functional groups polyester acrylate 12%～19%, four-functional group polyester acrylate 11%～18%, bifunctional acrylate's monomer 8%～13%, acid coupling agent 0.5%～2%, fluorine modification flow agent 0.1%～0.5%, photosensitizers 2%～7%, butylacetate 15%～30%, ethyl acetate 4%～10%, ethylene glycol ether acetate 1%～5%.
By weight, described photo-cured coating accounts for 90%～94%, and described tinting pigment accounts for 6%～10%.
Described fluorine modification flow agent adopts fluorine-carbon modified acrylate copolymer, and described acid coupling agent adopts two (the two hot phosphatidic acids) titanic acid ester of tetra isopropyl, and described photosensitizers adopts the a-hydroxy cyclohexyl phenylketone.
Vacuum of the present invention manufacture method zinc-plated or plating indium photo-cured coating comprises the steps:
A1. in producing container, add double methacrylate monomer and stirring earlier;
B1. add two official's aliphatic urethane acrylates again in the production container successively, four functional polyester acrylate, six official's polyester acrylates and fluorine modification flow agent also stir down to 800-1200 rev/min rotating speed continuation;
C1. get the butylacetate that 2-4 doubly measures and be used to dilute photosensitizers;
D1. in producing container, slowly add remaining butylacetate, ethyl acetate and ethylene glycol ether acetate, stirred 25-35 minute with 500-700 rev/min rotating speed;
E1. the last good photosensitizers solution of dilution that adds promptly stopped with 600-800 rev/min of stirring in 8-12 minute.
Another kind of vacuum of the present invention manufacture method zinc-plated or plating indium photo-cured coating comprises the steps:.
A2. in producing container, add double methacrylate monomer and stirring earlier;
B2. add two official's aliphatic urethane acrylates again in the production container successively, four functional polyester acrylate, six official's polyester acrylates and fluorine modification flow agent also stir down to 800-1200 rev/min rotating speed continuation;
C2. get the butylacetate that 2-4 doubly measures and be used to dilute photosensitizers;
D2. in producing container, slowly add remaining butylacetate, ethyl acetate and ethylene glycol ether acetate, stirred 25-35 minute with 500-700 rev/min rotating speed;
E2. the last good photosensitizers solution of dilution that adds promptly stopped with 600-800 rev/min of stirring in 8-12 minute;
F2. after the coating that obtains in the above-mentioned E2 step and tinting pigment being dropped into stirrer in proportion and disperseing 20-40 minute, drop into three-roller and grind 4-6 time, but the test fineness reaches just discharging after the requirement, packing.
Compared with prior art; zinc-plated or the plating indium photo-cured coating of vacuum of the present invention has been issued to the curing of film (layer) in the irradiation of the moment of high pressure mercury vapour lamp and halogenide mercuryvapour lamp; avoided the traditional mode of production mobile phone; during electronic products such as digital camera at vacuum plating (tin; the surface protection of indium spare and decoration construction) toluene in the process; Virahol; the pollution on the environment during volatilization of organic solvents such as isopropyl ether; the harm that the operative employee is caused and cause injury because of dissolvent residual to the human consumer; and has fabulous levelling property; the hardness height; stable performance requires constant to execution conditions.
Embodiment
The present invention is described in further detail below in conjunction with embodiment.
Zinc-plated or the plating indium photo-cured coating of vacuum of the present invention, (following identical) by weight, each component and content comprise in its prescription: bifunctional fat adoption ammonia ester acrylate 10%～15%, six functional groups polyester acrylate 12%～19%, four-functional group polyester acrylate 11%～18%, bifunctional acrylate's monomer 8%～13%, acid coupling agent 0.5%～2%, fluorine modification flow agent 0.1%～0.5%, photosensitizers 2%～7%, butylacetate 15%～30%, ethyl acetate 4%～10%, ethylene glycol ether acetate 1%～5%.
When needs are done colo(u)r coating, also can increase tinting pigment, described tinting pigment can be selected pigment commonly used for use, as (organic) phthalocyanine blue pigment or (chromium metal mould assembly) dyestuff.At this moment, by weight, above-mentioned photo-cured coating accounts for 90%～94%, and described tinting pigment accounts for 6%～10%.
In the said components, described bifunctional fat adoption ammonia ester acrylate, six functional groups polyester acrylate, four-functional group polyester acrylate and bifunctional acrylate's monomer are the reactive thinner in the UV photo-cured coating system.Described fluorine modification flow agent can adopt fluorine-carbon modified acrylate copolymer, and described acid coupling agent can adopt two (the two hot phosphatidic acids) titanic acid ester of tetra isopropyl, and described photosensitizers can adopt the 184D photosensitizers, i.e. the a-hydroxy cyclohexyl phenylketone.
Below be several embodiment that vacuum of the present invention is zinc-plated or plating indium photo-cured coating is filled a prescription:
Embodiment one, each component and content are: bifunctional fat adoption ammonia ester acrylate 12.2%, six functional groups polyester acrylate 19%, four-functional group polyester acrylate 16%, bifunctional acrylate's monomer 13%, acid coupling agent 0.8%, fluorine modification flow agent 0.5%, photosensitizers 7%, butylacetate 19.5%, ethyl acetate 10%, ethylene glycol ether acetate 2%.
Embodiment two, each component and content are: bifunctional fat adoption ammonia ester acrylate 13%, six functional groups polyester acrylate 15.5%, four-functional group polyester acrylate 15%, bifunctional acrylate's monomer 11.2%, acid coupling agent 1.5%, fluorine modification flow agent 0.3%, photosensitizers 5%, butylacetate 27.5%, ethyl acetate 8%, ethylene glycol ether acetate 3%.
Embodiment three, each component and content are: bifunctional fat adoption ammonia ester acrylate 15%, six functional groups polyester acrylate 14%, four-functional group polyester acrylate 18%, bifunctional acrylate's monomer 9.8%, acid coupling agent 2%, fluorine modification flow agent 0.2%, photosensitizers 4%, butylacetate 26%, ethyl acetate 6%, ethylene glycol ether acetate 5%.
Vacuum of the present invention manufacture method zinc-plated or plating indium photo-cured coating comprises the steps:
A. add the double methacrylate monomer earlier in producing container, the unlatching stirrer stirs with 700 rev/mins rotating speed;
B. add two official's aliphatic urethane acrylates again in the production container successively, four functional polyester acrylate, six official's polyester acrylates and fluorine modification flow agent also stir down to 1000 rev/mins rotating speed continuation;
C. get the butylacetate that 2-4 doubly measures and be used to dilute photosensitizers;
D. in producing container, slowly add remaining butylacetate, ethyl acetate and ethylene glycol ether acetate, stirred 30 minutes with 600 rev/mins rotating speeds;
E. the last good photosensitizers solution of dilution that adds, 700 rev/mins of stirrings promptly stopped in 10 minutes, discharging, packing promptly obtains photo-cured coating product of the present invention.
If it is coating material solidified to make colorama, behind above-mentioned steps E, also add following steps:
F. the coating that obtains in the above-mentioned E step and tinting pigment are dropped in proportion stirrer and disperse 20-40 minute after evenly, drop into three-roller and grind 4-6 time, but the test fineness reaches just discharging after the requirement, packing.
Below be that vacuum is zinc-plated. plating indium photo-cured coating (containing colo(u)r coating) test item and technical parameter:
Annotate: testing method is the method for inspection of coating of the present invention according to the relevant photo-cured coating of existing country.
1. Dilution ratio: working fluid, directly spraying;
2. spraying method: spray gun bore 1.0～1.5mm;
Air pressure 3～5KG/cm
2
Spray gun distance 15～20cm;
3. construction environment: dustless, air themperature＜70%, 20～30 ℃ of temperature;
4. baking levelling: 60 ± 5 ℃ in vacuum plating (chromium) faceization, infrared rays levelling 10～15mm;
5.UV solidify: lamp type: high pressure mercury vapour lamp and halogenide mercuryvapour lamp;
Output energy: 80～120W/cm
2
Accumulative total UV energy: 800～1500mj/cm
2, add color and use 900mj/cm
2Add the pigment suggestion and use 1200mj/cm
2
Claims (9)
1. the zinc-plated or plating indium photo-cured coating of a vacuum, it is characterized in that: by weight, each component and content comprise in its prescription: bifunctional fat adoption ammonia ester acrylate 10%～15%, six functional groups polyester acrylate 12%～19%, four-functional group polyester acrylate 11%～18%, bifunctional acrylate's monomer 8%～13%, acid coupling agent 0.5%～2%, fluorine modification flow agent 0.1%～0.5%, photosensitizers 2%～7%, butylacetate 15%～30%, ethyl acetate 4%～10%, ethylene glycol ether acetate 1%～5%.
2. the zinc-plated or plating indium photo-cured coating of vacuum according to claim 1, it is characterized in that: described fluorine modification flow agent adopts fluorine-carbon modified acrylate copolymer.
3. the zinc-plated or plating indium photo-cured coating of vacuum according to claim 1 and 2, it is characterized in that: described acid coupling agent adopts two (the two hot phosphatidic acids) titanic acid ester of tetra isopropyl.
4. the zinc-plated or plating indium photo-cured coating of vacuum according to claim 1 and 2, it is characterized in that: described photosensitizers adopts the a-hydroxy cyclohexyl phenylketone.
5. the zinc-plated or plating indium photo-cured coating of a vacuum, comprise photo-cured coating and tinting pigment, it is characterized in that: by weight, the prescription of described photo-cured coating comprises: bifunctional fat adoption ammonia ester acrylate 10%～15%, six functional groups polyester acrylate 12%～19%, four-functional group polyester acrylate 11%～18%, bifunctional acrylate's monomer 8%～13%, acid coupling agent 0.5%～2%, fluorine modification flow agent 0.1%～0.5%, photosensitizers 2%～7%, butylacetate 15%～30%, ethyl acetate 4%～10%, ethylene glycol ether acetate 1%～5%.
6. the zinc-plated or plating indium photo-cured coating of vacuum according to claim 5, it is characterized in that: by weight, described photo-cured coating accounts for 90%～94%, and described tinting pigment accounts for 6%～10%.
7. according to claim 5 or 6 described vacuum are zinc-plated or plating indium photo-cured coating, it is characterized in that: described fluorine modification flow agent adopts fluorine-carbon modified acrylate copolymer, described acid coupling agent adopts two (the two hot phosphatidic acids) titanic acid ester of tetra isopropyl, and described photosensitizers adopts the a-hydroxy cyclohexyl phenylketone.
8. the manufacture method of the zinc-plated or plating indium photo-cured coating of a vacuum as claimed in claim 1 is characterized in that this method comprises the steps:
A1. in producing container, add double methacrylate monomer and stirring earlier;
B1. add two official's aliphatic urethane acrylates again in the production container successively, four functional polyester acrylate, six official's polyester acrylates and fluorine modification flow agent also stir down to 800-1200 rev/min rotating speed continuation;
C1. get the butylacetate that 2-4 doubly measures and be used to dilute photosensitizers;
D1. in producing container, slowly add remaining butylacetate, ethyl acetate and ethylene glycol ether acetate, stirred 25-35 minute with 500-700 rev/min rotating speed;
E1. the last good photosensitizers solution of dilution that adds promptly stopped with 600-800 rev/min of stirring in 8-12 minute.
9. the manufacture method of the zinc-plated or plating indium photo-cured coating of a vacuum as claimed in claim 5 is characterized in that this method comprises the steps:.
A2. in producing container, add double methacrylate monomer and stirring earlier;
B2. add two official's aliphatic urethane acrylates again in the production container successively, four functional polyester acrylate, six official's polyester acrylates and fluorine modification flow agent also stir down to 800-1200 rev/min rotating speed continuation;
C2. get the butylacetate that 2-4 doubly measures and be used to dilute photosensitizers;
D2. in producing container, slowly add remaining butylacetate, ethyl acetate and ethylene glycol ether acetate, stirred 25-35 minute with 500-700 rev/min rotating speed;
E2. the last good photosensitizers solution of dilution that adds promptly stopped with 600-800 rev/min of stirring in 8-12 minute;
F2. after the coating that obtains in the above-mentioned E2 step and tinting pigment being dropped into stirrer in proportion and disperseing 20-40 minute, drop into three-roller and grind 4-6 time, but the test fineness reaches just discharging after the requirement, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102101371A CN102295879A (en) | 2010-06-25 | 2010-06-25 | Vacuum tin plating or indium plating photocurable coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102101371A CN102295879A (en) | 2010-06-25 | 2010-06-25 | Vacuum tin plating or indium plating photocurable coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102295879A true CN102295879A (en) | 2011-12-28 |
Family
ID=45356564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102101371A Pending CN102295879A (en) | 2010-06-25 | 2010-06-25 | Vacuum tin plating or indium plating photocurable coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102295879A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602255A (en) * | 2013-11-14 | 2014-02-26 | 惠州市长润发涂料有限公司 | Anti-sinking roller coating primer |
| CN108624221A (en) * | 2018-05-25 | 2018-10-09 | 深圳市深赛尔股份有限公司 | Painted in a kind of high-performance vacuum plating UV dope and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526771A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured metal paint |
| CN1557882A (en) * | 2004-01-14 | 2004-12-29 | 惠州市华阳化工有限公司 | Ultraviolet cured paint |
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
-
2010
- 2010-06-25 CN CN2010102101371A patent/CN102295879A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526771A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured metal paint |
| CN1557882A (en) * | 2004-01-14 | 2004-12-29 | 惠州市华阳化工有限公司 | Ultraviolet cured paint |
| CN101407651A (en) * | 2008-11-27 | 2009-04-15 | 中国乐凯胶片集团公司 | UV curing color decorative coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602255A (en) * | 2013-11-14 | 2014-02-26 | 惠州市长润发涂料有限公司 | Anti-sinking roller coating primer |
| CN108624221A (en) * | 2018-05-25 | 2018-10-09 | 深圳市深赛尔股份有限公司 | Painted in a kind of high-performance vacuum plating UV dope and preparation method thereof |
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Application publication date: 20111228 |