CN102295326B - Water electrolysis device - Google Patents
Water electrolysis device Download PDFInfo
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- CN102295326B CN102295326B CN2010102071535A CN201010207153A CN102295326B CN 102295326 B CN102295326 B CN 102295326B CN 2010102071535 A CN2010102071535 A CN 2010102071535A CN 201010207153 A CN201010207153 A CN 201010207153A CN 102295326 B CN102295326 B CN 102295326B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 152
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 42
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 103
- 239000001257 hydrogen Substances 0.000 claims abstract description 54
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 54
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 49
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000012528 membrane Substances 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- 238000006555 catalytic reaction Methods 0.000 claims description 16
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- 239000001301 oxygen Substances 0.000 claims description 7
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The invention discloses a water electrolysis device, comprising an electrolysis unit, a water tank, a gas-liquid mixer, a gas-liquid separator and a power supply. The electrolysis unit comprises a shell, top of the shell is provided with a water intake, and an anode titanium electrifying pore plate, a beta-PbO2 anode catalytic plate, a solid polymer electrolyte membrane, a Pt/C cathode catalytic plate and a cathode titanium electrifying pore plate are arranged under the water intake; the bottom of the water tank is provided with an engaging interface while the top thereof is movably provided with a top cover, the top cover is provided with an ozone outlet pipe and a water supply port, and the water tank is provided with an ozone outlet; the gas-liquid mixer comprises a mixer container on which an ozone inlet, the water intake and an ozone water outlet are arranged; the gas-liquid separator comprises a separator container on which a hydrogen water intake, a hydrogen outlet pipe and a water outlet are arranged; an anode of the power supply is connected with the anode of the electrolysis unit, and the cathode of the power supply is connected with the cathode of the electrolysis unit. The water electrolysis device can electrolyze water into ozone, ozone water, hydrogen and hydrogen-contained water, is simple in structure, less in energy consumption and lower in cost, and can be widely used.
Description
Technical field
The present invention relates to a kind of apparatus for electrolyzing.
Background technology
Ozone is a kind of strong oxidizer, has very strong instantaneous sterilization, sterilization, sterilization, deodorizing, decolouring, function such as fresh-keeping, can also decompose the organism that is difficult to decompose.At transmissible disease, virus popular public health and medical field without restraint; The disaggregating treatment field of the clean field of industrial circles such as the environmental area of control atmosphere pollution, water pollution, food and pharmacy, electronic industry, the highly difficult chemical substances such as sterilization, trade effluent and nuke rubbish of tap water tap water, its application is extremely important.
The application of ozone has two aspects: the one, and the application of ozone body, it is mainly used in sterilization and the purification of air, the decomposition of medium-gas, decomposition discharging of industrial tail gas etc.Ultrapure clean ozone body is used widely at aspects such as medicine industry, foodstuffs industry and medical treatment; The 2nd, the application of ozone water, present technology is ozone to be sneaked in the water obtain mostly, and blending means is a lot, and the consistency of ozone water that different modes obtains is different, but will reach application purpose, and the slave unit cost of investment still is that energy consumption is all than higher.
At present, have the ozone system access method of the value utilized that following several kinds of modes are arranged:
1. be the ultraviolet low-pressure mercury fluorescent tube method of raw material with the natural air: the ozone concn that this method is produced out is very low, is used for sterilizing air more, and it is not high to produce the utility value of ozone water.
2. be the high frequency discharge method of raw material with the purity oxygen: the ozone concn that this method is produced out is higher than ultraviolet low-pressure mercury fluorescent tube method, no matter is the utilization of ozone or the utilization of ozone water, all is the method for relatively popularizing at present.Yet because this method produces oxynitride simultaneously, and oxynitride is a carcinogenic substance, therefore causes this method to receive great restriction in the application in pure field and tap water field.
3. be the electrolytic process of raw material with the pure water: this method is raw material with water, with β-PbO
2For anode catalyst be under the electrolytic catalysis effect of cathod catalyst hydrogen to be separated with oxygen with platinum (Pt/c), anode generates O
2And O
3, negative electrode generates H.The ozone concn that this method is produced out is very high very pure, however since energy consumption big, cost an arm and a leg, and product is difficult to control, and causes being difficult to being popularized adopting.
It is documented that the research of water electrolysis formula ozonizer is since 1886,, come out in SPE formula electrolysis ozone generator in 1985 through the long term studies progress.The ozonizer substruction of this form is with β-PbO
2Be anode catalyst layer; With platinum (Pt/c) is the cathode catalysis layer of catalyzer; Clip solid polyelectrolyte membrane (SPE) wherein; Press from both sides porous matter titanium plate or the spumescence titanium material that has the electrical conductor effect and play the air-and water-permeable effect in the outside of anode and negative electrode, on its outside folder separately, accept the anode and cathode titanium plate that positive-negative power is given electricity again.During work; Be provided with pure water to anode; Pass to the direct current of 2～3.5V, water is under the katalysis of anodic-cathodic, and Wasserstoffatoms moves generation hydrogen through solid polyelectrolyte membrane (SPE) to negative electrode; The Sauerstoffatom that remains generates ozone at anode discharge, and platinum Catalytic Layer (the Pt 1mg/cm of negative electrode
2) play the effect that redox reaction generates hydrogen.The technology of this form is still the main flow of current Japanese market electrolysis ozone generator.
The substruction of this ozonizer is: solid polyelectrolyte membrane (SPE) is placed on central authorities; Anode (+electrode) and negative electrode (electrode) are placed on its both sides; Anode ultrapure water raw material electrolyzer and negative electrode water storage tank are placed on the both sides of anode electrode and cathode electrode more respectively; The oxygen ozone body that contains that anode generates enters anode gas-liquid separation chamber (generally being called the anode water tank) together with the ozone water that contains ozone by anode electrolytic tank; The different specific weight that utilizes ozone and water is after this process is separated, and the ozone body that contains oxygen is discharged by the top of gas-liquid separation chamber; Water gets into anode electrolytic tank through vacuum breaker again; The hydrogen G&W that negative electrode generates enters negative electrode gas-liquid separation chamber (generally being called the negative electrode water tank) by the negative electrode water storage tank; The different specific weight that utilizes the hydrogen G&W is after this is through separation, and hydrogen is by the top discharge of gas-liquid separation chamber and through being discharged in the atmosphere after the air dilution process; Water is discharged by negative electrode gas-liquid separation chamber.The electrolysis structure that this vertical arrangement is put equals electrode and electrolysis also is vertical storing with raw water; Electrode and water are contacts side surfaces; The gravity of water is downward; And contacts side surfaces causes the wiping of electrode and water in the electrolytic process, and the ozone body of generation flows in the friction waters up, forms fluidity sinuous flow and loss.And this structure electrolysis groove volume is difficult for excessive, has caused the raw material water yield very little.In addition, the loss that friction causes with sinuous flow has caused the intensification of liquid, so for the rising of controlled temperature, the means such as in addition externally cooled water cycle cooling of having to again.The defective that this structure exists is:
(1) because ozone is strong oxidizer; So all overcurrent parts all must adopt the very strong material of erosion resistance, how with titanium alloy, stainless steel 316 with resin materials such as first-class metallic substance or polytetrafluoroethylene PTFE, PFA, component are many; Connecting link is many; Be difficult to connect between the material, cause cost quite expensive, complicated structure can cause the complicated of water supply, liquid level, temperature dispatch control system; Also cause the user to increase in aspect difficulty such as management, operation, maintenances, these all cause the limitation in the application;
(2) limit by its technology, in case interruption of power supply, the β-PbO of anode catalyst layer
2Very easily reduce deterioration, will arrive certain current efficiency and used time of concentration when restarting needs the time long, for this reason in case promptly can not cut off the power supply after passing to electric current, needs to be equipped with store battery or emergency power supply in the device, therefore is difficult to use and popularizes;
(3) ozone concn of ozonizer self is unadjustable, when not needing too high ozone concn, need reduce concentration through the air-pump inflating dilution, outside the high ozonizer of power consumption, has increased the exhaustion point and the consumable accessory hidden danger point of air pump again;
(4) its anode needs 10
6The ultrapure water that Ω cm is above, this condition restriction the application of ozonizer, and the environment that can't obtain ultrapure water just can't be used down;
(5) ozonizer is running stores, just need when using certain life-span to change, yet complicated syndeton makes the user can not carry out simple and safe dismounting and change, and must accomplish replacing down in certain operation condition and technology.This also causes difficulty to application.
Hydrogen just is realized as far back as eighties of last century the validity of human body oxidation-resisting and caducity and various diseases; In recent years; The medical expert of Japan has successfully resolved it theoretically the mechanism of HUMAN HEALTH effect has been caused a sensation, and inquires into hydrogen from all angles and is quickening to launch in the research of the medical effect of daily health caring, disease prevention and clinical treatment.The approach that human body is accepted hydrogen is mainly breathing hydrogen and quotes hydrogeneous water, and the report of injection hydrogen water is also arranged.Though hydrogen is the materials of a large amount of existence of nature, people but can't obtain it in daily life, have a lot of hydrogen and hydrogen water commodity to pour into market suddenly one after another at present, but its confidence level and price are kept someone at a respectful distance the people.
Summary of the invention
The purpose of this invention is to provide a kind of apparatus for electrolyzing, can be ozone, ozone water, hydrogen and hydrogeneous water with water decomposition, and simple in structure, energy consumption is less, and cost is lower, but widespread use.
For realizing above-mentioned purpose, technical scheme of the present invention is:
A kind of apparatus for electrolyzing, it comprises electrolysis cells, water tank, gas liquid mixer, gas-liquid separator, power supply;
Described electrolysis cells comprises housing, and the top of said housing offers water-in, and the below of said water-in is provided with the anode titanium of the arranged transversely that links to each other successively from top to bottom and gives electric orifice plate, β-PbO
2Anode-catalyzed plate, solid polyelectrolyte membrane, Pt/C cathode catalysis plate, cathode titanium are given electric orifice plate, negative electrode water leg, described β-PbO
2Anode-catalyzed plate, Pt/C cathode catalysis plate are respectively by β-PbO
2Anode-catalyzed electrode and POROUS TITANIUM PLATE, Pt/C cathode catalysis electrode and POROUS TITANIUM PLATE are compressed to one, and said anode titanium is given electric orifice plate, β-PbO
2Anode-catalyzed plate, solid polyelectrolyte membrane, Pt/C cathode catalysis plate, cathode titanium are given electric orifice plate, the negative electrode water leg is fastening through holding bolt is whole electrolytic module, and described negative electrode water leg is provided with the hydrogen water discharge pipe;
The bottom of said water tank is provided with the interlock interface that matches and be connected with the water-in of said housing, and the top of said water tank is provided with ozone vent pipe, water supplement port, and the casing of said water tank is provided with the ozone water relief outlet;
Said gas liquid mixer comprises the mixing tank container that is used to mix ozone and water; Said mixing tank container is provided with ozone inlet, water-in, ozone water outlet; Said ozone inlet is connected with the ozone vent pipe of said water tank, and said water-in is connected in outside application water source;
Said gas-liquid separator comprises the separator vessel that is used for the separation of hydrogen G&W, and said separator vessel is provided with hydrogen water inlet, water port, hydrogen discharge pipe, and said hydrogen water inlet is connected with the hydrogen water discharge pipe of said electrolysis cells;
The positive pole of said power supply is connected for electric orifice plate with the anode titanium, and the negative pole of said power supply is connected for electric orifice plate with cathode titanium.
As a kind of preferred construction, the top of water tank according to the invention also is movably equipped with top cover, and described ozone vent pipe, water supplement port are arranged on the top cover; Also be provided with ozone on the described ozone vent pipe and utilize mouth, ozone splitter, ozone leak protection valve, it is oxygen that said ozone splitter is used for ozone reduction; Also be provided with liquidometer, TP on the top cover of said water tank; The ozone inlet and the water-in of said gas liquid mixer are respectively equipped with nozzle; Also be provided with hydrogen utilization mouth and hydrogen gas leakage protective valve on the said hydrogen discharge pipe.
As a kind of preferred improvement structure, power supply according to the invention comprises adjustment module, override protection module, overheating protection module and the abnormal protection module that is used for controlling concn.
Alternatively, through being threaded, the water-in of said electrolysis cells is provided with IT between electrolysis cells according to the invention and the water tank, and correspondence is provided with outside screw on the interlock interface of said water tank bottom; Also can be to be connected between said electrolysis cells and the water tank through the bayonet socket make-up.
Preferably; It is the direct puncture orifice plate that is evenly distributed that anode titanium according to the invention gives electric orifice plate for electric orifice plate, cathode titanium; The area in said hole and give electric orifice plate/cathode titanium for the anode titanium and give more than 40% of the electric orifice plate total area, it is more than the 0.5mm that said anode titanium gives the thickness of electric orifice plate for electric orifice plate/cathode titanium.
Therefore compared with prior art, the present invention has following beneficial effect:
(1) each plate arranged transversely in the electrolysis cells of the present invention, the water during work in the water tank falls to acting directly on the anode electrode naturally, and the ozone body that generates through electrolysis directly rises; The loss that does not cause because of frictional force and back flow of gas in the electrolysis cells has reduced the consumption of electric energy, has improved the speed of ozone concn rising; In addition, the size of water tank can be changeable as required, and the water yield is sufficient; Can effectively take away the heat that produces in the electrode catalyst process, play favorable cooling effect, simple in structure; Energy consumption is less, and cost is lower, but widespread use;
(2) the mutual interlock of electrolysis cells and water tank among the present invention, electrolysis cells can remove and install as changing the bulb, and does not need the instrument of specialty, and is very easy to use;
(3) the present invention can generate 4 kinds of materials that utility value is high and be difficult to obtain simultaneously; That is: ozone gas, ozone water, hydrogen and hydrogeneous air water; The high cleanliness concentration of ozone gas that makes can be up to 250mg/L; Consistency of ozone water can be up to 64ppm, and every 1A electric current can obtain high-concentrated ozone body and the saturated hydrogen of 8ml/min about 4ml/min.
Description of drawings
Accompanying drawing described herein is used to provide further understanding of the present invention, constitutes the application's a part, does not constitute to improper qualification of the present invention, in the accompanying drawings:
Fig. 1 is the structural representation of the embodiment of the invention;
Fig. 2 is the structural representation of electrolysis cells in the embodiment of the invention;
Fig. 3 is the structural representation of water tank in the embodiment of the invention;
Fig. 4 is the structural representation of gas liquid mixer in the embodiment of the invention;
Fig. 5 is the structural representation of gas-liquid separator in the embodiment of the invention;
Fig. 6 is a structural representation of giving electroplax in the embodiment of the invention.
Embodiment
To combine accompanying drawing and specific embodiment to specify the present invention below, be used for explaining the present invention in this illustrative examples of the present invention and explanation, but not as to qualification of the present invention.
Extremely shown in Figure 6 like Fig. 1 is the embodiment of a kind of apparatus for electrolyzing of the present invention; It comprises electrolysis cells 1, water tank 2, gas liquid mixer 3, gas-liquid separator 4, power supply 5; Electrolysis cells 1 comprises housing 10; The top of housing 10 offers water-in, and the anode titanium that the below of water-in is provided with from top to bottom the arranged transversely that links to each other is successively given electric orifice plate 11, β-PbO
2Anode-catalyzed plate 12, solid polyelectrolyte membrane 13, Pt/C cathode catalysis plate 14, cathode titanium are given electric orifice plate 15, negative electrode water leg 17, β-PbO
2Anode-catalyzed plate 12, Pt/C cathode catalysis plate 14 are respectively by β-PbO
2Anode-catalyzed electrode and POROUS TITANIUM PLATE, Pt/C cathode catalysis electrode and POROUS TITANIUM PLATE are compressed to one, and the anode titanium is given electric orifice plate 11, β-PbO
2It is whole electrolytic module that anode-catalyzed plate 12, solid polyelectrolyte membrane 13, Pt/C cathode catalysis plate 14, cathode titanium give electric orifice plate 15, negative electrode water leg 17 fastening through holding bolt 18, and negative electrode water leg 17 is provided with hydrogen water discharge pipe 19; The bottom of water tank 2 is provided with the interlock interface 21 that matches and be connected with the water-in of housing 10, and the top of water tank 2 is provided with ozone vent pipe 23, water supplement port 24, and the casing of water tank 2 is provided with ozone water relief outlet 25; Gas liquid mixer 3 comprises the mixing tank container 31 that is used to mix ozone and water; Mixing tank container 31 is provided with ozone inlet 32, water-in 33, ozone water outlet 34; Ozone inlet 32 is connected with the ozone vent pipe 23 of water tank 2, and water-in 33 is connected in the application water source of outside; Gas-liquid separator 4 comprises the separator vessel 41 that is used for the separation of hydrogen G&W, and separator vessel 41 is provided with hydrogen water inlet 42, water port 44, hydrogen discharge pipe 43, and hydrogen water inlet 42 is connected with the hydrogen water discharge pipe 19 of electrolysis cells 1; The positive pole 51 of power supply 5 is connected for electric orifice plate 11 with the anode titanium, and the negative pole 52 of power supply 5 is connected for the negative electrode of electric orifice plate 15 with cathode titanium.
During work; Water in the water tank 2 falls in the electrolysis cells 1 through interlock interface 21 naturally, and water is electrolyzed to produce ozone and hydrogen, and wherein ozone rises in the water tank 2; Water in the water tank 2 becomes the saturated ozone water of high density gradually; Ozone overflows the water surface and gets in the gas liquid mixer 3 through ozone vent pipe 23 and ozone inlet 32, mixes the ozone water of lower concentration from ozone water outlet 34 can obtain continuously with answering water; It is hydrogen water that the hydrogen that electrolysis produces is assembled in negative electrode water leg 17; And flow into gas-liquid separator 4 through vent pipe 19 and hydrogen water inlet 42 successively; The hydrogen G&W constantly separates therein; Hydrogen is discharged from hydrogen discharge pipe 43, and the water that contains the not separated hydrogen that falls is discharged from water port 44 and can directly be utilized; β-PbO
2Anode-catalyzed plate 12, Pt/C cathode catalysis plate 14 are respectively by β-PbO
2Anode-catalyzed electrode and POROUS TITANIUM PLATE, Pt/C cathode catalysis electrode and POROUS TITANIUM PLATE are compressed to one, can not have the gap of loose contact, have reduced the impedance of conduction, have improved current work efficient; β-PbO
2Anode-catalyzed plate 12 is processed by chemical method, degradation phenomena can not occur, recovers works better within a short period of time but restart after the outage, need not be equipped with store battery or emergency power supply.
In the present embodiment, the top of water tank 2 also is movably equipped with top cover 22, and ozone vent pipe 23, water supplement port 24 are arranged on the top cover 22, and the movable top cover 22 that is provided with detachably gets off during use, is convenient to install and repairs; Also be provided with ozone on the ozone vent pipe 23 and utilize mouth 26, ozone splitter 27, ozone leak protection valve 28; It is oxygen that ozone splitter 27 is used for ozone reduction; Ozone leak protection valve 28 can stop its leakage when ozone is not utilized; Ozone gets into ozone splitter 27, just is thrown in the air after thoroughly being reduced into oxygen; Also be provided with liquidometer 29, TP 20 on the top cover 22 of water tank 2, the liquid level in the liquidometer 29 adjustable control water tank 2; The ozone inlet 32 of gas liquid mixer 3 and the meet of water-in 33 are provided with nozzle 34; Also be provided with hydrogen utilization mouth 45 and hydrogen gas leakage protective valve 46 on the hydrogen discharge pipe 43, when hydrogen was not utilized, hydrogen gas leakage protective valve 46 can stop the hydrogen leak outflow; Power supply 5 comprises adjustment module, override protection module, overheating protection module and the abnormal protection module that is used for controlling concn; The serviceability of power supply 5 and anodic-cathodic characteristic are coincide each other; Can be through improving or reduce the size adjustment that its output services power is realized ozone output; And then reach the purpose of regulating the using ozone water concentration; The effect of the overheating protection module of power supply 5 is when electrolysis cells work is overheated, to cut off the electricity supply automatically, and the effect of override protection module is that electric current and voltage can be regulated automatically when the service rating superelevation, and the effect of abnormal protection module is aging or extraneously can cut off the electricity supply when unusual when electrolysis cells; And can freely restart behind the power dump, need not be equipped with store battery or emergency use protection power supply.
In the present embodiment; Adopt between electrolysis cells 1 and the water tank 2 and be threaded; The water-in of electrolysis cells 1 is provided with IT 16, and correspondence is provided with outside screw on the interlock interface 21 of water tank 2 bottoms, and electrolysis cells 1 can remove and install as changing the bulb like this; Do not need the instrument of specialty, very easy to use; During real work, also can be to be connected between electrolysis cells 1 and the water tank 2 through the bayonet socket make-up.
In order to improve resistance to overturning; In the present embodiment; The anode titanium gives the direct puncture orifice plate of electric orifice plate 15 for being evenly distributed for electric orifice plate 11, cathode titanium, the area in hole and give electric orifice plate 11/ cathode titanium for the anode titanium and give more than 40% of electric orifice plate 15 total areas, and it is more than the 0.5mm to the thickness of electric orifice plate 15 that the anode titanium is given electric orifice plate 11/ cathode titanium; Can improve the stability of whole device like this, also the rising of controlled temperature more easily.
The present invention can be according to the consumption and the concentration of demand; Be made into the device of various different sizes; As long as can realize to obtain the single-phase DC electricity and drink the pure water of grade; Just can plug and play, not only can be widely used in industry, also for extensively popularizing of family, cause institute, office, school, dentistry, medical treatment and public place provides maybe.As utilize technological development of the present invention to be used for the small-sized machine of family, and then its current consumption is merely about 25W, and the consumption in operation raw material water yield is about 25cc/h.Mix with tap water and the concentration ozone about up to 250mg/L; Can obtain flow continuously and be about 1.5L/min, concentration is the ozone water about 4ppm; Except that can be used for the cleaning of fruit and vegetable, fishery products, chopping board, cutter, tableware, towel etc.; Also can the soaked in water fruit vegetable and aquatic products raw meat etc. with the dirt settling of eliminating the surface to reach fresh-keeping and the effect that prolongs staging life, can also be used to wash one's hands, gargle, foot bath, hair washing etc.In the high-concentration ozone water spray chamber that directly takes a morsel, refuse container, sewage draining exit etc., can also play purify air, effect such as deodoring and disinfecting.Directly utilize the ozone body of trace, more can be when bacteriophage be popular family, office, school and public place etc. keep off infection and spread, hydrogen of producing simultaneously and hydrogeneous water are also capable of using, prevent human senescence and daily health caring.
More than the technical scheme that the embodiment of the invention provided is described in detail; Used specific case herein the principle and the embodiment of the embodiment of the invention are set forth, the explanation of above embodiment only is applicable to the principle that helps to understand the embodiment of the invention; Simultaneously, for one of ordinary skill in the art, according to the embodiment of the invention, the part that on the specific embodiment and range of application, all can change, in sum, this description should not be construed as limitation of the present invention.
Claims (10)
1. apparatus for electrolyzing is characterized in that:
It comprises electrolysis cells, water tank, gas liquid mixer, gas-liquid separator, power supply;
Described electrolysis cells comprises housing, and the top of said housing offers water-in, and the below of said water-in is provided with the anode titanium of the arranged transversely that links to each other successively from top to bottom and gives electric orifice plate, β-PbO
2Anode-catalyzed plate, solid polyelectrolyte membrane, Pt/C cathode catalysis plate, cathode titanium are given electric orifice plate, negative electrode water leg, described β-PbO
2Anode-catalyzed plate, Pt/C cathode catalysis plate are respectively by β-PbO
2Anode-catalyzed electrode and POROUS TITANIUM PLATE, Pt/C cathode catalysis electrode and POROUS TITANIUM PLATE are compressed to one, and said anode titanium is given electric orifice plate, β-PbO
2Anode-catalyzed plate, solid polyelectrolyte membrane, Pt/C cathode catalysis plate, cathode titanium are given electric orifice plate, the negative electrode water leg is fastening through holding bolt is whole electrolytic module, and described negative electrode water leg is provided with the hydrogen water discharge pipe;
The bottom of said water tank is provided with the interlock interface that matches and be connected with the water-in of said housing, and the top of said water tank is provided with ozone vent pipe, water supplement port, and the casing of said water tank is provided with the ozone water relief outlet,
Said gas liquid mixer comprises the mixing tank container that is used to mix ozone and water; Said mixing tank container is provided with ozone inlet, water-in, ozone water outlet; Said ozone inlet is connected with the ozone vent pipe of said water tank, and said water-in is connected in outside application water source
Said gas-liquid separator comprises the separator vessel that is used for the separation of hydrogen G&W, and said separator vessel is provided with hydrogen water inlet, water port, hydrogen discharge pipe, and said hydrogen water inlet is connected with the hydrogen water discharge pipe of said electrolysis cells,
The positive pole of said power supply is connected for electric orifice plate with the anode titanium, and the negative pole of said power supply is connected for electric orifice plate with cathode titanium.
2. apparatus for electrolyzing according to claim 1 is characterized in that: the top of said water tank also is movably equipped with top cover, and described ozone vent pipe, water supplement port are arranged on the top cover.
3. apparatus for electrolyzing according to claim 1 is characterized in that: also be provided with ozone on the described ozone vent pipe and utilize mouth, ozone splitter, ozone leak protection valve, it is oxygen that said ozone splitter is used for ozone reduction.
4. apparatus for electrolyzing according to claim 2 is characterized in that: also be provided with liquidometer, TP on the top cover of said water tank.
5. apparatus for electrolyzing according to claim 1 is characterized in that: the ozone inlet and the water-in of said gas liquid mixer are respectively equipped with nozzle.
6. apparatus for electrolyzing according to claim 1 is characterized in that: also be provided with hydrogen utilization mouth and hydrogen gas leakage protective valve on the described hydrogen discharge pipe.
7. apparatus for electrolyzing according to claim 1 is characterized in that: described power supply is provided with adjustment module, override protection module, overheating protection module and the abnormal protection module that is used for controlling concn.
8. apparatus for electrolyzing according to claim 1 is characterized in that: through being threaded, the water-in of said electrolysis cells is provided with IT between said electrolysis cells and the water tank, and correspondence is provided with outside screw on the interlock interface of said water tank bottom.
9. apparatus for electrolyzing according to claim 1 is characterized in that: be connected through the bayonet socket make-up between said electrolysis cells and the water tank.
10. apparatus for electrolyzing according to claim 1; It is characterized in that: it is the direct puncture orifice plate that is evenly distributed that said anode titanium gives electric orifice plate for electric orifice plate, cathode titanium; The area in said hole and give electric orifice plate/cathode titanium for the anode titanium and give more than 40% of the electric orifice plate total area, it is more than the 0.5mm that said anode titanium gives the thickness of electric orifice plate for electric orifice plate/cathode titanium.
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| CN2010102071535A CN102295326B (en) | 2010-06-22 | 2010-06-22 | Water electrolysis device |
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| CN2010102071535A CN102295326B (en) | 2010-06-22 | 2010-06-22 | Water electrolysis device |
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| CN110639137B (en) * | 2019-09-23 | 2021-05-11 | 宁波市欣宁信息科技有限公司 | Oxygen supply device and method based on electrolyzed water |
| CN112744903A (en) * | 2019-10-30 | 2021-05-04 | 无锡维邦工业设备成套技术有限公司 | Electrolyzed water ozone-making type purified water sterilization system |
| CN113388855A (en) * | 2020-03-11 | 2021-09-14 | 上海喜运环保科技有限公司 | Improved method and structure of ozone mouth wash instant generation device |
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| CN112535625A (en) * | 2020-12-10 | 2021-03-23 | 百特环保科技（烟台）有限公司 | Portable hydrogen water and ozone water bathing machine |
| CN112981440A (en) * | 2021-04-25 | 2021-06-18 | 爱可依科技(上海)有限公司 | Ozone generator |
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| CN2431290Y (en) * | 2000-07-04 | 2001-05-23 | 胡柏 | Generator for producing ozone by electrolyzing process |
| CN2431291Y (en) * | 2000-07-11 | 2001-05-23 | 上海奥赛科技有限公司 | Generator for producing large flow of ozone water |
| CN201746592U (en) * | 2010-06-22 | 2011-02-16 | 刘迅 | Water electrolysis device |
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