CN102277068A - Primer used for building curtain wall aluminum veneer and preparation method thereof - Google Patents
Primer used for building curtain wall aluminum veneer and preparation method thereof Download PDFInfo
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- CN102277068A CN102277068A CN2011102079067A CN201110207906A CN102277068A CN 102277068 A CN102277068 A CN 102277068A CN 2011102079067 A CN2011102079067 A CN 2011102079067A CN 201110207906 A CN201110207906 A CN 201110207906A CN 102277068 A CN102277068 A CN 102277068A
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- formula ratio
- curtain wall
- agent
- aluminum veneer
- building curtain
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 48
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 57
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000004593 Epoxy Substances 0.000 claims abstract description 26
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 17
- 239000010452 phosphate Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 229920001225 polyester resin Polymers 0.000 claims abstract description 11
- 239000004645 polyester resin Substances 0.000 claims abstract description 11
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 11
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920003180 amino resin Polymers 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims description 50
- -1 phosphate ester Chemical class 0.000 claims description 23
- 239000011259 mixed solution Substances 0.000 claims description 21
- 230000037452 priming Effects 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 21
- 229920005989 resin Polymers 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 17
- 239000004408 titanium dioxide Substances 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 239000000706 filtrate Substances 0.000 claims description 7
- UVGLBOPDEUYYCS-UHFFFAOYSA-N silicon zirconium Chemical compound [Si].[Zr] UVGLBOPDEUYYCS-UHFFFAOYSA-N 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000002270 dispersing agent Substances 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 150000002736 metal compounds Chemical class 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract 4
- 239000010703 silicon Substances 0.000 abstract 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- 229910001424 calcium ion Inorganic materials 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 30
- 239000011248 coating agent Substances 0.000 description 29
- 238000004519 manufacturing process Methods 0.000 description 21
- 229910000838 Al alloy Inorganic materials 0.000 description 19
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000010276 construction Methods 0.000 description 11
- 239000012046 mixed solvent Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000011056 performance test Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
- 239000012964 benzotriazole Substances 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 239000004611 light stabiliser Substances 0.000 description 5
- 229920002050 silicone resin Polymers 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 3
- 229920003270 Cymel® Polymers 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- 238000003916 acid precipitation Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241001600132 Streptomyces cyanogenus Species 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- POCFBDFTJMJWLG-UHFFFAOYSA-N dihydrosinapic acid methyl ester Natural products COC(=O)CCC1=CC(OC)=C(O)C(OC)=C1 POCFBDFTJMJWLG-UHFFFAOYSA-N 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to a primer used for building curtain wall aluminum veneers and a preparation method thereof. The primer comprises the following components in percentage by weight: 45-55% of saturated polyester resin, 4-6% of amino resin, 1-1.5% of epoxy phosphate, 5-10% of calcium ion exchange type anticorrosive pigment, 10-15% of titanium white, 5-10% of kaolin, 0.5-1% of dispersing agent, 0.5-2% of silicon and titanium or silicon and zirconium type coupling agent, 0.1-0.3% of antisettling agent, 5-10% of S-150 aromatic hydrocarbons solvent and 5-10% of butyl cellosolve, wherein the dispersing agent is a polyamine-acyl-amine type dispersing agent, and the antisettling agent is aerosol. The primer does not contain heavy metal compounds, such as strontium chromate and the like in the traditional formula, thus heavy metal pollution can be avoided, and the primer is more environmentally-friendly; and the silicon and titanium or silicon and zirconium type coupling agent is adopted, the adhesive force of the surface of the aluminum veneer is greatly enhanced, and the durability is better. The primer disclosed by the invention has the advantages of reasonable formula, simple preparation method and good protection performance for nonferrous metal materials, such as the aluminum veneers, galvanized plates and the like.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of building curtain wall aluminum veneer priming paint and preparation method thereof
Background technology
As time goes on, the phenomenon that the top coat of building curtain wall loss of gloss, variable color, efflorescence can occur and come off under atmospheric environment, cause the curtain wall base material exposed, chemistry or electrochemical reaction take place when corrosive medium in the environment contacts and by corrosion in the curtain wall base material, performance is degenerated, even destroy, so the aseptic technic of curtain wall base material plays a part very important for the safety performance and the weather resistance of curtain wall base material.In addition, acid rain, various dust dirts etc. stick to the curtain wall surface easily in the atmospheric environment, acid rain is corrosive to the curtain wall top coat, the dust dirt forms ugly stain at the curtain wall outside surface, need artificial routine cleaning, if dirt be penetrated into film in, then stain can not be removed clean, piebald appears in film coated surface, has a strong impact on sight.Change this present situation, can take following measure: the one, the corrosion-resistant and strong coating of weather resistance in the curtain wall surface-coated is isolated base material and corrosive medium; The 2nd, at curtain wall surface-coated self-cleaning coat (refer to the hydrophobic or hydrophilic physical property that relies on coating itself to be had, play the coating of antifouling and easy clean effect), this kind method cost is lower, and effect is better, applied range.
The building curtain wall aluminum veneer comprises with coating and directly is coated in the aluminum veneer surface with the priming paint that forms undercoat and be coated in outermost layer with the finish paint that forms finishing coat etc. that the coating of each layer all plays crucial effect to the protection of structure.There are some following problems in traditional building curtain wall aluminum veneer with priming paint: contain strontium yellow in the coating usually, thereby can cause heavy metal contamination, not environmental protection; Coating is limited to poor adhesive force, the weather resistance of aluminum veneer
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, and a kind of more environmental protection, sticking power and the better building curtain wall aluminum veneer of weather resistance priming paint are provided.
The present invention also will provide the preparation method of a kind of above-mentioned building curtain wall aluminum veneer with priming paint simultaneously.
For solving above technical problem, the present invention takes following technical scheme:
A kind of building curtain wall aluminum veneer priming paint, by weight percentage, this priming paint is mixed by following component: saturated polyester resin 45% ~ 55%, aminoresin 4% ~ 6%, epoxy phosphate ester 1% ~ 1.5%, calcium ion-exchanged type rust-stabilising pigment 5% ~ 10%, titanium dioxide 10% ~ 15%, kaolin 5% ~ 10%, dispersion agent 0.5% ~ 1%, silicon titanium or silicon zirconium type coupling agent 0.5% ~ 2%, anti-settling agent 0.1% ~ 0.3%, S-150 aromatic hydrocarbon solvent 5% ~ 10%, butyl glycol ether 5% ~ 10%; Wherein, described dispersion agent is polyamine-acyl-amine type dispersion agent; Described anti-settling agent is an aerosil.
Above-mentioned building curtain wall aluminum veneer comprises the steps: with the preparation method of priming paint
(1), gets the saturated polyester resin of 40% formula ratio, under 500 ~ 700 rev/mins of stirrings, add the S-150 aromatic hydrocarbon solvent of 30% formula ratio, the butyl glycol ether of formula ratio, the dispersion agent of formula ratio, the anti-settling agent of formula ratio, the titanium dioxide of formula ratio, the kaolin of formula ratio and the calcium ion-exchanged type rust-stabilising pigment of formula ratio successively, high-speed stirring 20 ~ 30 minutes under 1800 ~ 2200 rev/mins condition then, premix;
(2), step (1) gained premix is transferred in the shredder, this premix is ground, to the mixed solution that obtains solid particulate fineness≤20 micron;
(3), stir with 600 rev/mins rotating speed mixed solution step (2) gained, and in this mixed solution, add remaining saturated polyester resin, the aminoresin of formula ratio, the epoxy phosphate ester of formula ratio, the silicon titanium or the silicon zirconium type coupling agent of formula ratio successively, adjust viscosity of mixed liquid to 120 second/25 ℃/FORD#4 cup with remaining S-150 aromatic hydrocarbon solvent, and under 300 ~ 400 rev/mins rotating speed, continue stirring 8 ~ 12 minutes;
(4), be that 50 microns filter bag filters the mixed solution through step (3) with the aperture, filtrate is described building curtain wall aluminum veneer priming paint.
Because the enforcement of above technical scheme, the present invention compared with prior art has following advantage:
Building curtain wall aluminum veneer of the present invention has been abandoned heavy metal compounds such as strontium yellow with priming paint, therefore can not cause heavy metal contamination, more environmental protection; Adopt silicon titanium or silicon zirconium coupling agent, the silicon chain is formed centrally chelate structure in can being with hydrophilic inorganic metal titanium ion or zirconium ion, makes priming paint greatly increase at the sticking power on aluminum veneer surface, and weather resistance is also better; In addition, base paint formulation of the present invention is reasonable, and the preparation method is simple, all has the favorable protection performance for non-ferrous metal materials such as aluminum veneer and galvanized sheets.
Embodiment
Priming paint of the present invention as the building curtain wall aluminum veneer with first component of chalking paint and usefulness forms undercoat directly to be coated in the aluminum veneer surface; This chalking paint comprises that also being used to be coated in described undercoat surface is coated in described inter coat surface to form the 3rd component (being finish paint) of finishing coat with second component that forms inter coat with being used to.Below the application with priming paint is elaborated to building curtain wall aluminum veneer of the present invention:
Building curtain wall aluminum veneer of the present invention is (by weight percentage) with the prescription of first component of chalking paint:
Saturated polyester resin 45% ~ 55%
Aminoresin 4% ~ 6%
Epoxy phosphate ester 1% ~ 1.5%
Calcium ion-exchanged type rust-stabilising pigment 5% ~ 10%
Titanium dioxide 10% ~ 15%
Kaolin 5% ~ 10%
Dispersion agent 0.5% ~ 1%
Silicon titanium or silicon zirconium type coupling agent 0.5% ~ 2%
Anti-settling agent 0.1% ~ 0.3%
S-150 aromatic hydrocarbon solvent 5% ~ 10%
Butyl glycol ether 5% ~ 10%.
In the above-mentioned prescription, saturated polyester resin is optional uses that sea wind is marked vibrin that the trade mark of chemical Science and Technology Ltd. production and selling is FB8131 or the trade mark of Shanghai, Shanghai clean worker raw material company limited production and selling is the vibrin of K668A; Aminoresin can be selected the CYMEL 303 of U.S. cyanogen secret service industry company limited production and selling for use; Described calcium ion-exchanged type rust-stabilising pigment can be selected the SHIELDEX C 303 of W. R. Grace ﹠ Co's production and selling for use; Described titanium dioxide can be selected the R-960 Rutile type Titanium Dioxide of E.I.Du Pont Company's production and selling for use; Described dispersion agent can be selected the ANTI-TERRA U of German BYK company production and selling for use, its chemical constitution is the mixed solution of unsaturated polyamine-acyl-amine salt and lower molecular weight acid esters, can improve the wettability of pigment, reduce the process of lapping required time and colo(u)rant dispersion is got more stable; Described coupling agent optional MOAP 1306, the Tyzor AA or the Tyzor NPZ of E.I.Du Pont Company's production and selling with Shanghai More's chemical industry company limited production and selling; It is the aerosil of Aerosil 200 that described anti-settling agent can be selected the trade mark of German Degussa Corporation production and selling for use; Described epoxy phosphate ester can be selected the ETERKYD 490P-B-72 or the homemade epoxy phosphate ester of Taiwan Changxing Chemical Industry Co Ltd production and selling for use;
The method of self-control epoxy phosphate ester is as follows:
Taking by weighing Resins, epoxy, propyl carbinol and massfraction respectively by weight 1:0.84:0.41 is 85% phosphoric acid, earlier Resins, epoxy, propyl carbinol is added and has in the reactor of whipping appts and temperature control unit, causes Resins, epoxy under stirring and dissolves fully; Under 300 ~ 400 rev/mins agitation condition, phosphoric acid is slowly added in the above-mentioned reaction system, and the temperature of control reaction system is 40 ℃ ~ 50 ℃; Stir after 1 hour, mixing speed is risen to 700 ~ 800 rev/mins, continue to stir 20 minutes; Then, make reaction system be cooled to normal temperature naturally, obtain solid content and be about 60% self-control epoxy phosphate ester.
Building curtain wall aluminum veneer of the present invention prepares as follows with first component of chalking paint:
(1), gets the saturated polyester resin of 40% formula ratio, under 500 ~ 700 rev/mins of stirrings, add the S-150 aromatic hydrocarbon solvent of 30% formula ratio, the butyl glycol ether of formula ratio, the dispersion agent of formula ratio, the anti-settling agent of formula ratio, the titanium dioxide of formula ratio, the kaolin of formula ratio and the calcium ion-exchanged type rust-stabilising pigment of formula ratio successively, high-speed stirring 20 ~ 30 minutes under 1800 ~ 2200 rev/mins condition then, premix;
(2), step (1) gained premix is transferred in the shredder, this premix is ground, to the mixed solution that obtains solid particulate fineness≤20 micron;
(3), stir with 600 rev/mins rotating speed mixed solution step (2) gained, and in this mixed solution, add remaining saturated polyester resin, the aminoresin of formula ratio, the epoxy phosphate ester of formula ratio, the silicon titanium or the silicon zirconium coupling agent of formula ratio successively, adjust viscosity of mixed liquid to 120 second/25 ℃/FORD#4 cup with remaining S-150 aromatic hydrocarbon solvent, and under 300 ~ 400 rev/mins rotating speed, continue stirring 8 ~ 12 minutes;
(4), be that 50 microns filter bag filters the mixed solution through step (3) with the aperture, filtrate is first component of described building curtain wall aluminum veneer with chalking paint;
Building curtain wall aluminum veneer of the present invention constitutes (by weight percentage) with second component of chalking paint by following component:
FEVE fluorocarbon resin 45% ~ 55%
Titanium dioxide 15% ~ 25%
Cobalt black 2% ~ 5%
Anti-settling agent 0.1% ~ 0.6%
Dispersion agent 0.2% ~ 0.5%
Toluene 5% ~ 10%
Dimethylbenzene 2% ~ 5%
N-BUTYL ACETATE 8% ~ 10%
Vinylformic acid levelling agent 0.05% ~ 0.15%
Organotin catalysts 0.1% ~ 0.3%
Aliphatic isocyanates solidifying agent 7% ~ 10%
Wherein, toluene, dimethylbenzene and N-BUTYL ACETATE constitute mixed solvent, this mixed solvent of aliphatic isocyanates solidifying agent and 3/10 formula ratio constitutes the B component of independent packaging, the mixed solvent of other materials and remaining 7/10 formula ratio constitutes the A component of independent packaging, A component and the supporting use of B component, both deposit separately, both are mixed before the construction again.
In the above-mentioned prescription, the FEVE fluorocarbon resin be a kind of in aromatic hydrocarbons, ester class or ketones solvent the copolymer resins of soluble fluoroolefin and vinyl ether, greater than 15% for well, specifically can select the Lumiflon series fluorocarbon resin (as LF-552 or LF-600X) of Japan AGC company production and selling, the ZEFFLE GK-570 of Daikin company production and selling or the JF-3X of Shanghai Sanaifu New Material Co., Ltd's production and selling with the mass content of fluorine for use; It is the wilkinite of SD-2 that described anti-settling agent can be selected the trade mark of U.S. Ying Geerhade company (Engelhard) production and selling for use; Described dispersion agent can select for use the BYK-110 of German BYK company production and selling or Japanese nanmu to change into the DISPARLON 2150 that company limited produces; The agent of described vinylformic acid levelling can be selected the BYK350 or the BYK355 of German BYK company production and selling for use; Described aliphatic isocyanates solidifying agent can be selected the N-3390 solidifying agent of Bayer A.G's production and selling for use.
Building curtain wall aluminum veneer of the present invention is divided into the preparation of A component and preparation two portions of B component with the preparation of second component of chalking paint, and the preparation method of A component is as follows:
(1), gets the FEVE fluorocarbon resin of 40% formula ratio, under 500 ~ 700 rev/mins of stirrings, add the mixed solvent of 7/10 formula ratio, the dispersion agent of formula ratio, the anti-settling agent of formula ratio, the titanium dioxide of formula ratio and the cobalt black pigment of formula ratio successively, get premix;
(2), the premix of step (1) gained is transferred in the shredder, this premix is ground, to the mixed solution that obtains solid particulate fineness≤20 micron;
(3), stir with 600 rev/mins rotating speed mixed solution step (2) gained, and in this mixed solution, add remaining FEVE fluorocarbon resin, the vinylformic acid levelling agent of formula ratio, the organotin catalysts of formula ratio successively, adjust viscosity of mixed liquid to 70 ± 25 ℃/stormer viscosity of 5KU/ meter with the rest parts mixed solvent, and under 300 ~ 400 rev/mins rotating speed, continue to stir 8 ~ 12 minutes;
(4), be that 50 microns filter bag filters the mixed solution through step (3) with the aperture, filtrate is described building curtain wall aluminum veneer with the A component in chalking paint second component;
The preparation method of the B component in described second component is as follows:
Getting the aliphatic isocyanates solidifying agent of formula ratio and the mixed solvent of about 3/10 formula ratio of remainder mixes, the gained mixed solution is that 10 microns filter bag filters with the aperture, and filtrate is described building curtain wall aluminum veneer with the B component in chalking paint second component.
Building curtain wall aluminum veneer of the present invention constitutes (by weight percentage) with the 3rd component of chalking paint by following component:
FEVE fluorocarbon resin 60% ~ 70%
Silicone resin 5% ~ 10%
Vinylformic acid levelling agent 0.05% ~ 0.1%
Organosilicon flow agent 0.1% ~ 0.3%
Benzotriazole category ultraviolet absorbers 0.3% ~ 0.8%
Hindered amine light stabilizer 0.3% ~ 0.8%
Organotin catalysts 0.1% ~ 0.3%
N-BUTYL ACETATE 10% ~ 15%
Dimethylbenzene 10% ~ 15%
Aliphatic isocyanates solidifying agent 9% ~ 13%;
Wherein, N-BUTYL ACETATE and dimethylbenzene constitute mixed solvent, this mixed solvent of aliphatic isocyanates solidifying agent and 1/5 formula ratio constitutes the Y component of independent packaging, the mixed solvent of other materials and remaining 4/5 formula ratio constitutes the X component of independent packaging, X component and the supporting use of Y component, both deposit separately, both are mixed before the construction again.
In the above-mentioned prescription, silicone resin is selected the Protect 5001 of German Di Gao chemical company (TEGO) production and selling for use; Described organosilicon flow agent can be selected the BYK310 or the BYK306 of German BYK company production and selling for use; Described benzotriazole category ultraviolet absorbers can be selected the Tinuvin 1130 of vapour crust (China) company limited production and selling for use; Described hindered amine light stabilizer can be selected the Tinuvin 292 of vapour crust (China) company limited production and selling for use.The manufacturer that all the other components are specifically selected for use and the trade mark can be referring to the prescription introductions of second component.
Building curtain wall aluminum veneer of the present invention is divided into the preparation of X component and preparation two portions of Y component with the preparation of the 3rd component of chalking paint, and the preparation method of X component is as follows:
(1), gets the FEVE fluorocarbon resin of formula ratio, under 500 ~ 700 rev/mins agitation condition, add the silicone resin of formula ratio, the vinylformic acid levelling agent of formula ratio, the organosilicon flow agent of formula ratio, the benzotriazole category ultraviolet absorbers of formula ratio, the hindered amine light stabilizer of formula ratio, the organotin catalysts of formula ratio, the mixed solvent of 4/5 formula ratio successively, adjust viscosity to 65 ± 25 ℃/stormer viscosity of the 5KU/ meter of mixed solution, and under 300 ~ 400 rev/mins rotating speed, continue to stir 8 ~ 12 minutes;
(2), be that 10 microns filter bag filters the mixed solution through step (1) with the aperture, filtrate is described building curtain wall aluminum veneer with the X component in chalking paint the 3rd component;
The preparation method of the Y component in described the 3rd component is as follows:
Get the aliphatic isocyanates solidifying agent of formula ratio and the mixed solvent of about 1/5 formula ratio and mix, the gained mixed solution is that 10 microns filter bag filters with the aperture, and filtrate is described building curtain wall aluminum veneer with the Y component in chalking paint the 3rd component.
Building curtain wall aluminum veneer of the present invention is coated in the surface of aluminium alloy plate with first component of chalking paint, and the preparation condition of filming is as follows:
Ground: chromium is handled aluminium alloy plate
Application viscosity: 90 ± 5 seconds/FORD#4 cup/normal temperature
Primary coat bed thickness: 8 ± 2 μ m
Time of repose: 30-50 second/normal temperature
Drying conditions: 234 ℃ * 100 seconds (plate temperature)
Application mode: roller coating application
Thinner: S-150 aromatic hydrocarbon solvent/butyl glycol ether=1:1
The formed undercoat of first component is carried out performance test, and test result is shown in table 1:
The performance of table 1 undercoat
* hardness test standard: GB/T6739-96
* sticking power testing standard: GB/T 9286-98
* Impact Test standard: GB/T 1732-93
* solvent resistance test standard: GB/T 23989-2009
* anti-boiling water testing standard: GB/T 1733-93
* buckling test testing standard: GB/T13448-2006
The preparation condition of filming of second, third component of the present invention is as follows:
Substrate: the aluminium alloy base plate that has been coated with undercoat
Application viscosity: 20 ± 3 seconds/be coated with #4 cup/normal temperature
Inter coat is thick: 35 ± 5 μ m, finishing coat is thick: 20 ± 5 μ m
Time of repose: 5-10 minute/normal temperature
Drying conditions: 80 ℃ * 30 minutes
Application mode: aerial spraying
Thinner: N-BUTYL ACETATE
The construction pitch time of finishing coat and inter coat: the inter coat baking is cooled to normal temperature or seasoning sprays the 3rd component coating after 24 hours.
The formed compound coating of three components is carried out performance test, and test result is shown in table 2:
The performance of table 2 compound coating
* chemical resistant properties testing standard: GB/T 1763-1979
* solvent resistance test standard: GB/T 23989-2009
* QUV artificial weathering testing standard: GB/T 1706
Building curtain wall aluminum veneer of the present invention is specially adapted to roll up aluminum screen wall field with chalking paint.
The present invention will be further described in detail below in conjunction with specific embodiment, but be not limited to these embodiment.
Embodiment 1
Using the prescription of first component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
FB8131 vibrin 520
CYMEL 303 aminoresin 44
ETERKYD 490P-B-72 epoxy phosphate ester 12
SHIELDEX C 303 calcium ion-exchanged rust-stabilising pigments 80
Titanium dioxide R-960 130
Kaolin ASP170 70
Dispersant B YK ANTI-TERRA U 10
Coupling agent MOAP 1,306 10
Coupling agent TYZOL AA-75 7
AEROSIL 200 aerosils 2
S-150 aromatic hydrocarbon solvent 60
Butyl glycol ether 60
The first component coating is coated in chromium handles on the aluminium alloy plate, step is as follows:
(1), the chromium of getting 1mm * 200mm * 300mm handles aluminium alloy plate, with Virahol (IPA) with its surperficial wiped clean;
(2), adopt the line rod preparing device of filming that the first component coating is coated in the aluminium alloy plate surface of handling through step (1), make build and be 5 ~ 10 microns undercoat (drying conditions PMT=234 ℃ * 100 seconds);
Prepared undercoat is carried out performance test, and the result is as follows:
Pencil hardness: H
Sticking power (GB/T 9286-98): 0 grade
T bends characteristic: 0T;
MEK wiping: 100 times;
Using the prescription of second component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
FEVE fluorocarbon resin (GK-570) 520
Titanium dioxide R-960 200
Cobalt black 5
Modified alta-mud SD-2(Elementies) 3
BYK-110 dispersion agent 11
Vinylformic acid levelling agent BYK-350 1
Organotin catalysts 2
Dimethylbenzene 30
Toluene 57
N-BUTYL ACETATE 88
Solidifying agent N-3390 83
In proportion second component is prepared into A component and B component respectively, during construction A, the mixing of B two components is stirred evenly;
Using the prescription of the 3rd component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
FEVE fluoro-resin (GK-570) 625
Silicone resin TEGO PROTECT 5,001 60
Vinylformic acid levelling agent BYK-355 0.5
Organosilicon flow agent BYK-310 2
Benzotriazole category ultraviolet absorbers Tinuvin 1,130 5
Hindered amine light stabilizer Tinuvin 292 5
Organotin catalysts (DBTDL) 2
N-BUTYL ACETATE 100
Dimethylbenzene 100.5
Solidifying agent N-3390 100
In proportion the 3rd component is prepared into X component and Y component respectively, during construction X, the mixing of Y two components is stirred evenly.
The coating of above-mentioned prepared second component and the 3rd component is coated on the aluminium alloy plate of surperficial coating base coat, and step is as follows:
(1), get the aluminium alloy plate of the coating base coat of 1mm * 200mm * 300mm, with Virahol (IPA) with its surperficial wiped clean;
(2), adopt the aerial spraying construction, on the surface of step (1) gained aluminium alloy plate, normal temperature was placed 24 hours, made to form the inter coat of build between 25 ~ 35 microns with the paint spay-coating of second component;
(3), adopt the aerial spraying construction, on the surface of step (2) gained aluminium alloy plate, Air drying made to form the finishing coat of build between 15 ~ 30 microns more than 7 days with the paint spay-coating of the 3rd component; So far, aluminum alloy surface has formed trilaminar compound coating.
Prepared compound coating is carried out performance test, the results are shown in table 3:
The performance of table 3 embodiment 1 gained compound coating
Embodiment 2
Using the prescription of first component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
K668A vibrin 520
CYMEL 303 aminoresin 44
Epoxy phosphate ester 13
SHIELDEX C 303 calcium ion-exchanged type rust-stabilising pigments 80
Titanium dioxide R-960 130
Kaolin ASP170 70
Dispersant B YK ANTI-TERRA U 10
Coupling agent MOAP 1,306 10
Coupling agent TYZOL NPZ 8
Aerosil anti-settling agent AEROSIL 200 2
S-150 aromatic hydrocarbon solvent 56
Butyl glycol ether 60
In the present embodiment, epoxy phosphate ester is (units by weight) for self-control epoxy phosphate ester, its prescription:
Propyl carbinol 5.6
E-51 Resins, epoxy 6.7
Phosphoric acid (massfraction 85%) 2.7
Its preparation method is as follows:
Get one 200 liters plastic tank, the propyl carbinol, the Resins, epoxy that add formula ratio successively, under 300 ~ 400 rev/mins agitation condition, stir and dissolved fully to Resins, epoxy in 20 minutes, slowly add phosphoric acid, control interpolation speed, controlled temperature is not higher than 50 ° of C, treats that phosphoric acid adds the back that finishes and continues to stir 1 hour, naturally cool to normal temperature, add a cover placement and spend the night standby.
The prepared first component coating of present embodiment is coated in chromium handles on the aluminium alloy plate, step is as follows:
(1), the chromium of getting 1mm * 200mm * 300mm handles aluminium alloy plate, with Virahol (IPA) with its surperficial wiped clean;
(2), adopt the line rod preparing device of filming that the first component coating is coated in the aluminium alloy plate surface of handling through step (1), make build and be 5 ~ 10 microns undercoat (drying conditions PMT=234 ℃ * 100 seconds);
Prepared undercoat is carried out performance test, and the result is as follows:
Pencil hardness: H
Sticking power (GB/T 9286-98): 0 grade
T bends characteristic: 0T;
MEK wiping: 100 times;
Using the prescription of second component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
FEVE fluorocarbon resin JF-3X 530
Titanium dioxide R-960 200
Cobalt black 3
Modified alta-mud SD-2(Elementies) 3
DISPARLON 2150 dispersion agents 12
Vinylformic acid levelling agent BYK-350 2
Dimethylbenzene 32
Toluene 55
N-BUTYL ACETATE 80
Organotin catalysts (DBTDL) 3
Solidifying agent N-3390 80
In proportion second component is prepared into A component and B component respectively, during construction A, the mixing of B two components is stirred evenly;
Using the prescription of the 3rd component of chalking paint according to the building curtain wall aluminum veneer of present embodiment is (units by weight):
FEVE fluorocarbon resin (GK-570) 625
Silicone resin TEGO PROTECT 5,001 60
Vinylformic acid levelling agent BYK-355 0.5
Organosilicon flow agent BYK-310 2
Benzotriazole category ultraviolet absorbers Tinuvin 1,130 5
Hindered amine light stabilizer Tinuvin 292 5
Organotin catalysts (DBTDL) 2
N-BUTYL ACETATE 100
Dimethylbenzene 100.5
Solidifying agent N-3390 100
In proportion the 3rd component is prepared into X component and Y component respectively, during construction X, the mixing of Y two components is stirred evenly.
The coating of above-mentioned prepared second component and the 3rd component is coated on the aluminium alloy plate of coating base coat, step is as follows:
(1), get the aluminium alloy plate of the coating base coat of 1mm * 200mm * 300mm, with Virahol (IPA) with its surperficial wiped clean;
(2), adopt the aerial spraying construction, on the surface of step (1) gained aluminium alloy plate, normal temperature was placed 24 hours, made to form the inter coat of build between 25 ~ 35 microns with the paint spay-coating of second component;
(3), adopt the aerial spraying construction, on the surface of step (2) gained aluminium alloy plate, Air drying made to form the finishing coat of build between 15 ~ 30 microns more than 7 days with the paint spay-coating of the 3rd component; So far, aluminum alloy surface has formed trilaminar compound coating.
Prepared compound coating is carried out performance test, the results are shown in table 4:
The performance of table 4 embodiment 2 gained compound coatings
More than the present invention has been done detailed description; its purpose is to allow the personage that is familiar with this art can understand content of the present invention and is implemented; can not limit protection scope of the present invention with this; all equivalences of doing according to spirit of the present invention change or modify, and all should be encompassed in protection scope of the present invention
Claims (5)
1. building curtain wall aluminum veneer priming paint, it is characterized in that: by weight percentage, described priming paint is mixed by following component: saturated polyester resin 45% ~ 55%, aminoresin 4% ~ 6%, epoxy phosphate ester 1% ~ 1.5%, calcium ion-exchanged type rust-stabilising pigment 5% ~ 10%, titanium dioxide 10% ~ 15%, kaolin 5% ~ 10%, dispersion agent 0.5% ~ 1%, silicon titanium or silicon zirconium type coupling agent 0.5% ~ 2%, anti-settling agent 0.1% ~ 0.3%, S-150 aromatic hydrocarbon solvent 5% ~ 10%, butyl glycol ether 5% ~ 10%; Wherein, described dispersion agent is polyamine-acyl-amine type dispersion agent; Described anti-settling agent is an aerosil.
2. building curtain wall aluminum veneer priming paint according to claim 1 is characterized in that: described epoxy phosphate ester is got by following method preparation:
Taking by weighing Resins, epoxy, propyl carbinol and massfraction respectively by weight 1:0.84:0.41 is 85% phosphoric acid, earlier Resins, epoxy, propyl carbinol is added and has in the reactor of whipping appts and temperature control unit, causes Resins, epoxy under stirring and dissolves fully; Under 300 ~ 400 rev/mins agitation condition, phosphoric acid is slowly added in the above-mentioned reaction system, and the temperature of control reaction system is 40 ℃ ~ 50 ℃; Stir after 1 hour, mixing speed is risen to 700 ~ 800 rev/mins, continue to stir 20 minutes; Then, make reaction system be cooled to normal temperature naturally, obtain the epoxy phosphate ester of solid content between 55% ~ 65%.
3. building curtain wall aluminum veneer priming paint according to claim 1 is characterized in that: described titanium dioxide is a Rutile type Titanium Dioxide.
4. the preparation method of a building curtain wall aluminum veneer usefulness priming paint as claimed in claim 1 is characterized in that: comprise the steps:
(1), gets the saturated polyester resin of 40% formula ratio, under 500 ~ 700 rev/mins of stirrings, add the S-150 aromatic hydrocarbon solvent of 30% formula ratio, the butyl glycol ether of formula ratio, the dispersion agent of formula ratio, the anti-settling agent of formula ratio, the titanium dioxide of formula ratio, the kaolin of formula ratio and the calcium ion-exchanged type rust-stabilising pigment of formula ratio successively, high-speed stirring 20 ~ 30 minutes under 1800 ~ 2200 rev/mins condition then, premix;
(2), step (1) gained premix is transferred in the shredder, this premix is ground, to the mixed solution that obtains solid particulate fineness≤20 micron;
(3), stir with 600 rev/mins rotating speed mixed solution step (2) gained, and in this mixed solution, add remaining saturated polyester resin, the aminoresin of formula ratio, the epoxy phosphate ester of formula ratio, the silicon titanium or the silicon zirconium type coupling agent of formula ratio successively, adjust viscosity of mixed liquid to 120 second/25 ℃/FORD#4 cup with remaining S-150 aromatic hydrocarbon solvent, and under 300 ~ 400 rev/mins rotating speed, continue stirring 8 ~ 12 minutes;
(4), be that 50 microns filter bag filters the mixed solution through step (3) with the aperture, filtrate is described building curtain wall aluminum veneer priming paint.
5. the described building curtain wall aluminum veneer of each claim application of priming paint in volume aluminum screen wall in the claim 1 to 3.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087604A (en) * | 2013-01-23 | 2013-05-08 | 浙江德尚化工科技有限公司 | Functional additive for amino baking varnishes and preparation method thereof |
| CN103087603A (en) * | 2013-01-23 | 2013-05-08 | 浙江德尚化工科技有限公司 | Amino stoving varnish capable of being cured quickly at low temperature |
| CN103382356A (en) * | 2013-07-01 | 2013-11-06 | 吴江市物华五金制品有限公司 | Anti-corrosion and wear-resistance coating for metal pipes and preparation method thereof |
| CN114958155A (en) * | 2022-05-10 | 2022-08-30 | 浙江华普环保材料有限公司 | Silane-containing chromium-free roll priming paint |
| CN115322659A (en) * | 2022-09-11 | 2022-11-11 | 房辉 | Preparation method of water-based paint |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906264A (en) * | 2010-08-13 | 2010-12-08 | 华南理工大学 | A kind of thermal insulation coil coating and preparation method thereof |
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2011
- 2011-07-25 CN CN2011102079067A patent/CN102277068A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101906264A (en) * | 2010-08-13 | 2010-12-08 | 华南理工大学 | A kind of thermal insulation coil coating and preparation method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087604A (en) * | 2013-01-23 | 2013-05-08 | 浙江德尚化工科技有限公司 | Functional additive for amino baking varnishes and preparation method thereof |
| CN103087603A (en) * | 2013-01-23 | 2013-05-08 | 浙江德尚化工科技有限公司 | Amino stoving varnish capable of being cured quickly at low temperature |
| CN103087604B (en) * | 2013-01-23 | 2015-04-15 | 浙江德尚化工科技有限公司 | Functional additive for amino baking varnishes and preparation method thereof |
| CN103087603B (en) * | 2013-01-23 | 2015-04-15 | 浙江德尚化工科技有限公司 | Amino stoving varnish capable of being cured quickly at low temperature |
| CN103382356A (en) * | 2013-07-01 | 2013-11-06 | 吴江市物华五金制品有限公司 | Anti-corrosion and wear-resistance coating for metal pipes and preparation method thereof |
| CN103382356B (en) * | 2013-07-01 | 2015-10-21 | 韦少荣 | Metallic conduit corrosion-resistant abrasion coating and preparation method thereof |
| CN114958155A (en) * | 2022-05-10 | 2022-08-30 | 浙江华普环保材料有限公司 | Silane-containing chromium-free roll priming paint |
| CN115322659A (en) * | 2022-09-11 | 2022-11-11 | 房辉 | Preparation method of water-based paint |
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