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CN102259365B - Method for producing environment-friendly imitation solid wood color bamboo floor - Google Patents

Method for producing environment-friendly imitation solid wood color bamboo floor Download PDF

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CN102259365B
CN102259365B CN 201110170858 CN201110170858A CN102259365B CN 102259365 B CN102259365 B CN 102259365B CN 201110170858 CN201110170858 CN 201110170858 CN 201110170858 A CN201110170858 A CN 201110170858A CN 102259365 B CN102259365 B CN 102259365B
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CN102259365A (en
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李琴
胡波
袁少飞
张建
汪奎宏
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Zhejiang Academy of Forestry
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Abstract

一种环保型仿实木彩色竹地板的生产方法,包括以下步骤:①建立竹材仿实木染色配色数据库:选取酸性染料的三原色,酸性黄、酸性红、酸性蓝进行配色、染色、测色,列出三原色酸性染料采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色的配色数据库;②竹材循环染色,2.1)配方选取;2.2)建立三原色拼色染液浓度计算方法;2.3)配制染液;2.4)首次染色;2.5)测定残液中染料的吸光值;2.6)补加染料和染色助剂;2.7)重复步骤4)到6)进行循环染色;③制取仿实木彩色竹地板:依次通过浸胶干燥、组坯和胶合成型,制成仿实木彩色竹地板。本发明能提升染色效果、仿真度高、染料消耗较少、环保性良好。A kind of production method of environment-friendly type imitation solid wood color bamboo floor, comprises the following steps: 1. establish bamboo imitation solid wood dyeing color matching database: choose the three primary colors of acid dyestuff, acid yellow, acid red, acid blue carry out color matching, dyeing, color measurement, list The dyeing conditions adopted by the three primary color acid dyes, as well as the imitation solid wood bamboo dyeing color sample information, establish the color matching database of bamboo imitation solid wood dyeing; 2. Bamboo cycle dyeing, 2.1) formula selection; 2.2) establish the calculation method of the concentration of the three primary colors color matching dye solution; 2.3) 2.4) dyeing for the first time; 2.5) measuring the absorbance of the dye in the raffinate; 2.6) adding dyes and dyeing auxiliaries; 2.7) repeating steps 4) to 6) for cyclic dyeing; ③ producing imitation solid wood colored bamboo Floor: through dipping and drying, billet formation and gluing in sequence to make imitation solid wood colored bamboo flooring. The invention can improve the dyeing effect, has high imitation degree, less dye consumption and good environmental protection.

Description

一种仿实木彩色竹地板生产方法A kind of imitation solid wood color bamboo floor production method

技术领域technical field

本发明属竹材加工制造技术,涉及一种仿实木彩色竹地板生产方法。The invention belongs to bamboo material processing and manufacturing technology, and relates to a production method of imitation solid wood colored bamboo floor.

背景技术Background technique

竹地板具有强度高、韧性好、耐磨、色泽淡雅柔和、外表美观精致等优点,极受外商喜爱,产品远销国内外,目前我国已成为最大的竹地板出口国。但是一直以来竹地板只有本色和炭化两个系列产品,产品颜色单一,附加值低,生产企业经济效益差,急需开发一种高附加值的彩色竹地板。但是竹材染色存在着二个亟待解决的技术难题:一是由于竹材结构致密,润湿性差,染色色牢度和均匀度差,仿真度低;二是在染色过程中染液重复使用次数少(5-6次),废液(含有70%~80%的染料)排放带来的环境污染严重。因此在环保意识日益深入人心的今天,研发一种节能减排的环保型仿实木彩色竹地板生产方法就成了当务之急。发明专利CN101579880A中公开了一种染色竹丝板生产工艺,发明专利CN101579871A中公开了一种彩色薄竹生产工艺,发明专利CN101439530A公开了一种能对木材和竹材通透染色的染色液及其染色方法,以上3个专利都是采用常规的染色方法。发明专利CN101574825A中公开了一种彩色竹集成材的加工方法,染色方法是加压染色。发明专利CN1740772A公开了木材单板染色的配色方法,配色选取的染料不是三原色。上述技术中圴没有从建立竹材仿实木染色配色数据库和循环染色节能减排的角度考虑。现有仿实木彩色竹地板生产工艺存在的技术缺陷是:染色效果差、仿真度低、染料消耗大、污染严重。Bamboo flooring has the advantages of high strength, good toughness, wear resistance, elegant and soft color, beautiful and exquisite appearance, etc. It is very popular with foreign businessmen, and its products are sold at home and abroad. At present, my country has become the largest exporter of bamboo flooring. But all the time bamboo flooring only has two series products of natural color and carbonization, and the product color is single, and added value is low, and the economic benefit of production enterprise is poor, urgently needs to develop a kind of high value-added colored bamboo flooring. However, there are two technical problems to be solved urgently in bamboo dyeing: one is due to the dense structure of bamboo, poor wettability, poor color fastness and uniformity, and low degree of simulation; the other is that the number of times the dyeing solution is reused in the dyeing process is small ( 5-6 times), the discharge of waste liquid (containing 70% to 80% of dyes) causes serious environmental pollution. Therefore in today that environmental protection awareness is increasingly rooted in the hearts of the people, it has become a top priority to develop a kind of energy-saving and emission-reducing environmental-friendly imitation solid wood color bamboo floor production method. Invention patent CN101579880A discloses a kind of production process of dyed bamboo silk board, invention patent CN101579871A discloses a kind of color thin bamboo production process, invention patent CN101439530A discloses a kind of dyeing liquid and its dyeing solution which can dye wood and bamboo transparently Method, above 3 patents all are to adopt conventional dyeing method. Invention patent CN101574825A discloses a kind of processing method of colored bamboo glulam, and the dyeing method is pressure dyeing. Invention patent CN1740772A discloses a color matching method for wood veneer dyeing, and the dyes selected for color matching are not the three primary colors. Above-mentioned technology does not consider from the angle of setting up bamboo imitation solid wood dyeing and color matching database and circular dyeing energy saving and emission reduction. The technical defects in the existing production process of imitation solid wood colored bamboo flooring are: poor dyeing effect, low simulation degree, large dye consumption and serious pollution.

发明内容Contents of the invention

为了克服已有仿实木彩色竹地板生产工艺存在的染色效果差、仿真度低、染料消耗大、污染严重的不足,本发明提供一种提升染色效果、仿真度高、染料消耗较少、环保性良好的仿实木彩色竹地板生产方法。In order to overcome the shortcomings of poor dyeing effect, low simulation degree, large dye consumption and serious pollution existing in the existing imitation solid wood colored bamboo flooring production process, the present invention provides a kind of improved dyeing effect, high simulation degree, less dye consumption, and environmental protection. Good imitation solid wood color bamboo floor production method.

本发明解决其技术问题所采用的技术方案是:The technical solution adopted by the present invention to solve its technical problems is:

一种仿实木彩色竹地板生产方法,所述生产方法包括以下步骤:A kind of imitation solid wood color bamboo floor production method, described production method comprises the following steps:

①建立竹材仿实木染色配色数据库:选取酸性染料的三原色,酸性黄、酸性红、酸性蓝进行配色、染色、测色,列出三原色酸性染料及采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色的配色数据库;①Establish a database of color matching for imitation solid wood dyeing of bamboo: select the three primary colors of acid dyes, acid yellow, acid red, and acid blue for color matching, dyeing, and color measurement, list the three primary color acid dyes and the dyeing conditions used, and imitate solid wood bamboo dyeing color samples information , establish a database of color matching for bamboo imitation solid wood dyeing;

②竹材循环染色,具体包括以下过程:② Circular dyeing of bamboo, specifically including the following processes:

2.1)配方选取:根据配色数据库,选取竹材仿实木染色的配方。2.1) Formula selection: According to the color matching database, select the formula for imitating solid wood dyeing of bamboo.

2.2)建立三原色拼色染液浓度计算方法:配制三种酸性染料的标准溶液,并确定三种染料的峰值和波长,然后确定染料比例常数,最后建立三原色拼色染液浓度计算公式:CY=1.85A369-0.422A506-0.498A600,CR=-0.160A369+1.78A506-0.340A600,CB=-0.0266A369-0.229A506+2.42A6002.2) Establish the calculation method of the concentration of the three primary colors color matching dye solution: prepare the standard solutions of three kinds of acid dyes, and determine the peak value and wavelength of the three dyes, then determine the dye proportional constant, and finally establish the calculation formula of the concentration of the three primary colors color matching dye solution: C Y =1.85A 369 -0.422A 506 -0.498A 600 , C R =-0.160A 369 +1.78A 506 -0.340A 600 , C B =-0.0266A 369 -0.229A 506 +2.42A 600 ;

其中,CY为酸性黄的染液浓度,CR为酸性红的染液浓度,CB为酸性蓝的染液浓度,A369为酸性黄最大吸收波长处的吸光度值,A506为酸性红最大吸收波长处的吸光度值,A600为酸性蓝最大吸收波长处的吸光度值;Among them, C Y is the dye solution concentration of acid yellow, C R is the dye solution concentration of acid red, C B is the dye solution concentration of acid blue, A 369 is the absorbance value at the maximum absorption wavelength of acid yellow, A 506 is acid red The absorbance value at the maximum absorption wavelength, A 600 is the absorbance value at the maximum absorption wavelength of acid blue;

2.3)配制染液:按照配方和染色条件,称取三种酸性染料,先在80-100℃的水中溶解30min-100min后,把溶解好的染液倒入染槽中,根据浴比,加水到设定的体积,再加入染色助剂,调节pH值为4.5~6.0,最后量取1~20ml染液待测其三个最大波长处的吸光值;2.3) Preparation of dye solution: According to the formula and dyeing conditions, weigh three kinds of acid dyes, dissolve them in water at 80-100°C for 30min-100min, pour the dissolved dye solution into the dye tank, add water according to the bath ratio To the set volume, add dyeing auxiliaries, adjust the pH value to 4.5-6.0, and finally measure 1-20ml dyeing solution to measure the absorbance value at the three maximum wavelengths;

2.4)首次染色:将碾压竹片放入配制好的染液中,在75℃~100℃的环境下染色3~23小时后取出,再对染色竹片水洗,并干燥到含水率为5%~15%,用分光测色仪测量其颜色;2.4) First dyeing: Put the rolled bamboo slices into the prepared dye solution, take them out after dyeing at 75°C-100°C for 3-23 hours, then wash the dyed bamboo slices with water, and dry them until the moisture content is 5 %~15%, measure its color with a spectrophotometer;

2.5)测定残液中染料的吸光值:取出染色竹片后,在染槽中加水补充到染色之前的体积,再量取1~20ml染色残液,当其温度达到室温后,待测其三个最大波长处的吸光值;2.5) Determination of the absorbance value of the dye in the residual liquid: after taking out the dyed bamboo slices, add water to the dyeing tank to replenish the volume before dyeing, and then measure 1-20ml of the dyed residual liquid. When the temperature reaches room temperature, the third The absorbance value at the maximum wavelength;

2.6)补加染料和助剂:根据所述的浓度计算公式,由吸光值得出染色后染液的浓度,根据染液前后的浓度差值,得出需要补加的染料量,并加入染色助剂,保证补加后的染液和首次染液相当;2.6) Adding dyes and auxiliaries: According to the concentration calculation formula, the concentration of the dyeing solution after dyeing is obtained from the light absorption value, and the amount of dye that needs to be added is obtained according to the concentration difference before and after the dyeing solution, and dyeing auxiliaries are added. agent, to ensure that the added dye solution is equivalent to the first dye solution;

2.7)重复步骤4)到6)进行循环染色;2.7) repeat steps 4) to 6) to carry out cycle dyeing;

③制取仿实木彩色竹地板:依次通过浸胶干燥、组坯和胶合成型,制成仿实木彩色竹地板。③ Manufacture of imitation solid wood colored bamboo floor: through dipping and drying, forming blanks and gluing in sequence to make imitation solid wood colored bamboo floor.

本发明中的染色助剂为均染剂、渗透剂中的一种或两种混合,其中,均染剂为NaCl、烷基酚聚氧乙烯醚、聚乙二醇或十二烷基苯磺酸等,渗透剂为JFC、平平加O或(C12H25-O-C2HO)n系等。 The dyeing auxiliaries in the present invention are one or a combination of leveling agent and penetrating agent, wherein the leveling agent is NaCl, alkylphenol polyoxyethylene ether, polyethylene glycol or dodecylbenzenesulfonate Acid, etc., the penetrating agent is JFC, Pingping plus O or (C12H25-O-C2HO)n series, etc.

进一步,所述步骤①中,建立竹材仿实木染色配色数据库的过程如下:Further, in the step 1., the process of setting up the bamboo imitation solid wood dyeing and color matching database is as follows:

1.1)备料:选取酸性染料的三原色,酸性黄、酸性红、酸性蓝;1.1) Material preparation: select the three primary colors of acid dyes, acid yellow, acid red, and acid blue;

1.2)配色:根据三种酸性染料成分比例的变化,建立染料三原色拼色的三色图;1.2) Color matching: according to the change of the composition ratio of the three acid dyes, a three-color map of the three primary colors of the dyes is established;

1.3)染色:根据三色图和预设的分档浓度,对碾压竹片进行依次染色,然后对其水洗,并干燥到含水率为5%~15%;所述的分档浓度就是对每个色样配方最大染色饱和浓度1%分为12档,分别是0.01%、0.05%、0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1%;1.3) Dyeing: According to the three-color map and the preset concentration of grades, the rolled bamboo chips are dyed sequentially, then washed with water, and dried to a moisture content of 5% to 15%; The maximum dyeing saturation concentration of each color sample formula is divided into 12 levels, which are 0.01%, 0.05%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9% ,1%;

1.4)测色:对染色竹片使用分光测色仪逐个测量,每种染色竹片测量多次,以平均值作为其颜色值;1.4) Color measurement: measure one by one with a spectrophotometer to the dyed bamboo chips, each kind of dyed bamboo chips is measured many times, and the average value is used as its color value;

1.5)建立配色数据库:运用数据库建立方法,详细列出三原色酸性染料及采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色专用的配色数据库。1.5) Establish a color matching database: use the database building method to list in detail the three primary color acid dyes and the dyeing conditions used, as well as the color sample information of imitation solid wood bamboo dyeing, and establish a special color matching database for bamboo imitation solid wood dyeing.

再进一步,所述步骤1.2)中,确定每种染料实际用于拼色时可能使用的最大浓度,范围在0.01%~8%,然后每种配方从最低浓度到最大浓度进行分档,分为6~15档。Further, in the step 1.2), determine the maximum possible concentration of each dye that may be used for color matching, ranging from 0.01% to 8%, and then classify each formula from the lowest concentration to the maximum concentration, divided into 6 to 15 gears.

更进一步,所述步骤③中,制取仿实木彩色竹地板的过程如下:Further, in said step 3., the process of making imitation solid wood colored bamboo floor is as follows:

3.1)浸胶干燥:将染色竹片干燥至含水率为5%-15%后再浸渍改性酚醛树脂胶,胶液固含量为15%~32%,浸胶时间为8~15min,然后将其干燥到含水率为5%~15%;3.1) Dipping and drying: Dried the dyed bamboo slices until the water content was 5%-15%, then impregnated the modified phenolic resin glue, the solid content of the glue was 15%-32%, the dipping time was 8-15min, and then It is dried to a moisture content of 5% to 15%;

3.2)组坯:将染色竹材在模具内纵向组坯;3.2) Blank assembly: vertically assemble the dyed bamboo in the mould;

3.3)胶合成型:采用冷压热固化或热压工艺,将组好的板坯胶合成型制成竹方或竹坯板;3.3) Gluing and molding: using cold pressing and heat curing or hot pressing technology, the assembled slabs are glued and formed into bamboo squares or bamboo blanks;

3.4)后续加工:经锯切、修边、开榫槽、砂光、涂饰、干燥工序制成仿实木彩色竹地板。3.4) Subsequent processing: After sawing, trimming, grooving, sanding, painting, and drying processes, it is made into imitation solid wood colored bamboo flooring.

所述步骤3.2)中,采用单一染色竹材组坯,或者采用两种或两种以上不同染色竹材组坯。In the step 3.2), a single dyed bamboo material is used to form a blank, or two or more different dyed bamboo materials are used to form a blank.

本发明的有益效果主要表现在:具有染色效果好、仿真度高、染色成本低(降低40%左右)、节能减排(节约水电汽等能源消耗30%,减少染色污水排放量30%以上)等优势。采用本技术生产的竹地板和现有竹地板产品相比,具有产品种类丰富、外表美观、附加值高的优势。The beneficial effects of the present invention are mainly manifested in: good dyeing effect, high simulation degree, low dyeing cost (about 40% reduction), energy saving and emission reduction (saving water, electricity, steam and other energy consumption by 30%, and reducing dyeing sewage discharge by more than 30%) and other advantages. Compared with the existing bamboo floor products, the bamboo floor produced by the technology has the advantages of rich product types, beautiful appearance and high added value.

具体实施方式Detailed ways

下面对本发明作进一步描述。The present invention will be further described below.

一种环保型仿实木彩色竹地板生产方法,所述生产方法包括以下步骤:A kind of environmental protection type imitation solid wood color bamboo floor production method, described production method comprises the following steps:

①建立竹材仿实木染色配色数据库:选取酸性染料的三原色,酸性黄、酸性红、酸性蓝进行配色、染色、测色,列出三原色酸性染料的生产厂家、生产批次和型号及采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色的配色数据库;①Establish a color matching database for bamboo imitation solid wood dyeing: select the three primary colors of acid dyes, acid yellow, acid red, and acid blue for color matching, dyeing, and color measurement, and list the manufacturers, production batches, models and dyeing conditions of the three primary color acid dyes , as well as imitation solid wood bamboo dyeing color sample information, to establish a color matching database for bamboo imitation solid wood dyeing;

②竹材循环染色,具体包括以下过程:② Circular dyeing of bamboo, specifically including the following processes:

2.1)配方选取:根据配色数据库,选取竹材仿实木染色的配方。2.1) Formula selection: According to the color matching database, select the formula for imitating solid wood dyeing of bamboo.

2.2)建立三原色拼色染液浓度计算方法:配制三种酸性染料的标准溶液,并确定三种染料的峰值和波长,然后确定染料比例常数,最后建立三原色拼色染液浓度计算公式:CY=1.85A369-0.422A506-0.498A600,CR=-0.160A369+1.78A506-0.340A600,CB=-0.0266A369-0.229A506+2.42A6002.2) Establish the calculation method of the concentration of the three primary colors color matching dye solution: prepare the standard solutions of three kinds of acid dyes, and determine the peak value and wavelength of the three dyes, then determine the dye proportional constant, and finally establish the calculation formula of the concentration of the three primary colors color matching dye solution: C Y =1.85A 369 -0.422A 506 -0.498A 600 , C R =-0.160A 369 +1.78A 506 -0.340A 600 , C B =-0.0266A 369 -0.229A 506 +2.42A 600 ;

其中,CY为酸性黄的染液浓度,CR为酸性红的染液浓度,CB为酸性蓝的染液浓度,A369为酸性黄最大吸收波长处的吸光度值,A506为酸性红最大吸收波长处的吸光度值,A600为酸性蓝最大吸收波长处的吸光度值;Among them, C Y is the dye solution concentration of acid yellow, C R is the dye solution concentration of acid red, C B is the dye solution concentration of acid blue, A 369 is the absorbance value at the maximum absorption wavelength of acid yellow, A 506 is acid red The absorbance value at the maximum absorption wavelength, A 600 is the absorbance value at the maximum absorption wavelength of acid blue;

2.3)配制染液:按照配方和染色条件,称取三种酸性染料,先在80-100℃的水中溶解30min-100min后,把溶解好的染液倒入染槽中,再加入染色助剂,根据浴比,加水到设定的体积,最后量取1~20ml染液待测其三个最大波长处的吸光值;2.3) Preparation of dye solution: According to the formula and dyeing conditions, weigh three kinds of acid dyes, first dissolve in water at 80-100°C for 30min-100min, pour the dissolved dye solution into the dye tank, and then add dyeing auxiliaries , according to the bath ratio, add water to the set volume, and finally measure 1-20ml of the dye solution to measure the absorbance at the three maximum wavelengths;

2.4)首次染色:将碾压竹片放入吊笼,然后浸入配制好的染液中,在75℃~100℃的环境下染色3~23小时后取出,再对染色竹片水洗,并干燥到含水率为5%~15%,用分光测色仪测量其颜色。2.4) First dyeing: Put the rolled bamboo slices into a hanging cage, then immerse them in the prepared dye solution, take them out after dyeing at 75°C-100°C for 3-23 hours, then wash the dyed bamboo slices with water, and dry them When the water content is 5% to 15%, measure its color with a spectrophotometer.

2.5)测定残液中染料的吸光值:取出染色竹片后,在染槽中加水补充到染色之前的体积,再量取1~20ml染色残液,当其温度达到室温后,待测其三个最大波长处的吸光值。2.5) Determination of the absorbance value of the dye in the residual liquid: after taking out the dyed bamboo slices, add water to the dyeing tank to replenish the volume before dyeing, and then measure 1-20ml of the dyed residual liquid. When the temperature reaches room temperature, the third The absorbance value at the maximum wavelength.

2.6)补加染料和助剂:根据所述的浓度计算公式,由吸光值得出染色后染液的浓度,根据染液前后的浓度差值,得出需要补加的染料量,并加入染色助剂,保证补加后的染液和首次染液相当;2.6) Adding dyes and auxiliaries: According to the concentration calculation formula, the concentration of the dyeing solution after dyeing is obtained from the light absorption value, and the amount of dye that needs to be added is obtained according to the concentration difference before and after the dyeing solution, and dyeing auxiliaries are added. agent, to ensure that the added dye solution is equivalent to the first dye solution;

2.7)重复步骤4)到6)进行循环染色;2.7) repeat steps 4) to 6) to carry out cycle dyeing;

③制取仿实木彩色竹地板:依次通过浸胶干燥、组坯和胶合成型,制成仿实木彩色竹地板。③ Manufacture of imitation solid wood colored bamboo floor: through dipping and drying, forming blanks and gluing in sequence to make imitation solid wood colored bamboo floor.

所述步骤①中,建立竹材仿实木染色配色数据库的过程如下:In described step 1., the process of setting up bamboo imitation solid wood dyeing and matching database is as follows:

1.1)备料:选取酸性染料的三原色,酸性黄、酸性红、酸性蓝;1.1) Material preparation: select the three primary colors of acid dyes, acid yellow, acid red, and acid blue;

1.2)配色:根据三种酸性染料成分比例的变化,建立染料三原色拼色的三色图;1.2) Color matching: according to the change of the composition ratio of the three acid dyes, a three-color map of the three primary colors of the dyes is established;

1.3)染色:根据三色图和分档浓度,对碾压竹片进行依次染色,然后对其水洗,并干燥到含水率为5%~15%;1.3) Dyeing: According to the three-color map and graded concentration, the rolled bamboo chips are dyed sequentially, then washed with water, and dried to a moisture content of 5% to 15%;

1.4)测色:对染色竹片使用分光测色仪逐个测量,每种染色竹片测量多次,以平均值作为其颜色值;1.4) Color measurement: measure one by one with a spectrophotometer to the dyed bamboo chips, each kind of dyed bamboo chips is measured many times, and the average value is used as its color value;

1.5)建立配色数据库:运用数据库建立方法,详细列出三原色酸性染料的生产厂家、生产批次和型号及采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色专用的配色数据库。1.5) Establish a color matching database: use the database building method to list in detail the manufacturers, production batches and models of acid dyes of the three primary colors and the dyeing conditions used, as well as the dyeing color sample information of imitation solid wood bamboo, and establish a special color matching database for bamboo imitation solid wood dyeing .

所述步骤1.2)中,确定每种染料实际用于拼色时可能使用的最大浓度,范围在0.01%~8%,然后每种配方从最低浓度到最大浓度进行分档,分为6~15档。In the step 1.2), determine the maximum possible concentration of each dye that may be used for color matching, ranging from 0.01% to 8%, and then classify each formula from the lowest concentration to the maximum concentration, divided into 6 to 15 files.

所述步骤③中,制取仿实木彩色竹地板的过程如下:In described step 3., the process of making imitation solid wood color bamboo floor is as follows:

3.1)浸胶干燥:将染色竹片干燥至含水率为5%-15%后再浸渍改性酚醛树脂胶,胶液固含量为15%~32%,浸胶时间为8~15min,然后将其干燥到含水率为5%~15%;3.1) Dipping and drying: Dried the dyed bamboo slices until the water content was 5%-15%, then impregnated the modified phenolic resin glue, the solid content of the glue was 15%-32%, the dipping time was 8-15min, and then It is dried to a moisture content of 5% to 15%;

3.2)组坯:将染色竹材在模具内纵向组坯;3.2) Blank assembly: vertically assemble the dyed bamboo in the mould;

3.3)胶合成型:采用冷压热固化或热压工艺,将组好的板坯胶合成型制成竹方或竹坯板;3.3) Gluing and molding: using cold pressing and heat curing or hot pressing technology, the assembled slabs are glued and formed into bamboo squares or bamboo blanks;

3.4)后续加工:经锯切、修边、开榫槽、砂光、涂饰、干燥工序制成仿实木彩色竹地板。3.4) Subsequent processing: After sawing, trimming, grooving, sanding, painting, and drying processes, it is made into imitation solid wood colored bamboo flooring.

所述步骤3.2)中,采用单一染色竹材组坯,或者采用两种或两种以上不同染色竹材组坯。In the step 3.2), a single dyed bamboo material is used to form a blank, or two or more different dyed bamboo materials are used to form a blank.

本实施例的染色助剂为均染剂、渗透剂中的一种或两种混合,其中,均染剂为NaCl、烷基酚聚氧乙烯醚、聚乙二醇或十二烷基苯磺酸等,渗透剂为JFC、平平加O或(C12H25-O-C2HO)n系等。The dyeing auxiliary agent in this embodiment is one or a mixture of leveling agent and penetrating agent, wherein the leveling agent is NaCl, alkylphenol polyoxyethylene ether, polyethylene glycol or dodecylbenzenesulfonate Acid, etc., the penetrating agent is JFC, Pingping plus O or (C12H25-O-C2HO)n series, etc.

实例1:一种仿黑檀彩色竹地板生产方法:Example 1: A kind of production method of imitation ebony colored bamboo floor:

1.建立竹材仿实木染色配色数据库1. Establish a bamboo imitation solid wood dyeing and color matching database

1.1选取炭化碾压竹片,厚度为1mm~3mm,将其干燥到5%~15%的含水率,再选取酸性染料的三原色,酸性黄、酸性红、酸性蓝。1.1 Select carbonized and rolled bamboo slices with a thickness of 1 mm to 3 mm, dry them to a moisture content of 5% to 15%, and then select the three primary colors of acid dyes, acid yellow, acid red, and acid blue.

1.2选定酸性黄为三原色拼色的三色图中塔顶,塔底左右两只各为酸性红和酸性蓝,每往下一层就减少一份黄,从左至右拼入红并逐一减红加蓝,使每一格内染料份数之和为10,即确定三种酸性染料成分比例以1/10变化,得到66块色样配方。1.2 Acid yellow is selected as the top of the tower in the three-color map of the three primary colors, and the left and right two at the bottom of the tower are acid red and acid blue. Every time the lower layer is reduced, one part of yellow is added, and red is added one by one from left to right. Subtract red and add blue, so that the sum of the number of dyes in each grid is 10, that is to say, the ratio of the three acid dye components is determined to change by 1/10, and 66 color sample formulas are obtained.

1.3对每个色样配方最大染色饱和浓度1%分为12档,其分档浓度分别是0.01%、0.05%、0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1%。1.3 For each color sample formula, the maximum dyeing saturation concentration of 1% is divided into 12 levels, and the concentration of the levels are 0.01%, 0.05%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7% , 0.8%, 0.9%, 1%.

1.4按不同配方比例和浓度,分别称量好染料和助剂,在100℃的水中溶解60~100min后倒入染槽中,设定浴比为10∶1,加水到需要的体积,并加入0.05%~0.3%均染剂NaCl,0.1%~0.5%渗透剂JFC,用NH4Cl调节pH值为4.5~6。1.4 According to different formula ratios and concentrations, weigh the dyes and auxiliaries respectively, dissolve them in water at 100°C for 60-100 minutes, then pour them into the dyeing tank, set the bath ratio to 10:1, add water to the required volume, and add 0.05%~0.3% leveling agent NaCl, 0.1%~0.5% penetrant JFC, adjust the pH value to 4.5~6 with NH 4 Cl.

1.5)将干燥至含水率5%~15%的炭化碾压竹片放到染液中染色,染色温度为90℃,染色时间18~25小时;然后将染色竹片取出,水洗后在50℃条件下进行热风干燥,用分光测色仪测量其颜色。1.5) Put the carbonized and rolled bamboo chips dried to a moisture content of 5% to 15% in the dyeing solution for dyeing, the dyeing temperature is 90°C, and the dyeing time is 18 to 25 hours; Under the condition of hot air drying, the color was measured with a spectrophotometer.

1.6运用数据库建立方法,详细列出三原色酸性染料的相关资料和采用的染色条件,以及仿实木竹材染色色样信息,建立竹材仿实木染色专用的配色数据库。1.6 Use the database establishment method to list in detail the relevant materials of the three primary color acid dyes and the dyeing conditions used, as well as the color sample information of imitation solid wood bamboo dyeing, and establish a special color matching database for bamboo imitation solid wood dyeing.

2.竹材循环染色2. Cyclic dyeing of bamboo

2.1从配色数据库中选取竹材仿黑檀染色的配方和浓度,三种酸性染料配比为酸性黄:酸性红:酸性蓝=2∶3∶5,染液浓度为0.5%。2.1 Select the formula and concentration of bamboo imitation ebony dyeing from the color matching database. The ratio of the three acid dyes is acid yellow: acid red: acid blue = 2:3:5, and the concentration of the dye solution is 0.5%.

2.2准确称取酸性黄、酸性红、酸性蓝三种染料各1g,在100℃水中溶解并转移至1L容量瓶中,定容,再用移液管准确量取5ml至250ml容量瓶中,稀释至刻度。利用分光光度计测定三原色染料溶液最大吸收波长λ和其最大吸收波长处的吸光度值A。根据染料浓度与吸光值的关系A=Kc,确定其比例常数,从而建立三原色拼色后染液浓度计算公式CY=1.85A369-0.422A506-0.498A600,CR=-0.160A369+1.78A506-0.340A600,CB=-0.0266A369-0.229A506+2.42A6002.2 Accurately weigh 1g each of acid yellow, acid red and acid blue, dissolve in water at 100°C and transfer to a 1L volumetric flask, constant volume, then accurately measure 5ml with a pipette into a 250ml volumetric flask, dilute to scale. Use a spectrophotometer to measure the maximum absorption wavelength λ of the three primary color dye solutions and the absorbance value A at the maximum absorption wavelength. According to the relationship between dye concentration and light absorption value A=Kc, determine its proportional constant, and thus establish the formula for calculating the concentration of the dye solution after color matching of the three primary colors C Y =1.85A 369 -0.422A 506 -0.498A 600 , C R =-0.160A 369 +1.78A 506 -0.340A 600 , C B =-0.0266A 369 -0.229A 506 +2.42A 600 .

2.3染色方法和条件同1中建立竹材仿实木染色配色数据库步骤(4),从染液中量取10ml染液待测其三个最大波长处的吸光值A。2.3 Dyeing method and conditions are the same as step (4) in step (4) of establishing the database of bamboo imitation solid wood dyeing and color matching in 1. Measure 10ml of dyeing liquid from the dyeing liquid to measure the absorbance value A at the three maximum wavelengths.

2.4同1中建立竹材仿实木染色配色数据库步骤1.4~1.6。2.4 Same as step 1.4-1.6 in 1 to establish the bamboo imitation solid wood dyeing and color matching database.

2.5取出染色竹片后,在染槽中加水补充到染色之前的体积,再量取10ml染色残液,当其温度达到室温后,待测其三个最大波长处的吸光值A。2.5 After taking out the dyed bamboo slices, add water to the dyeing tank to make up the volume before dyeing, and then measure 10ml of dyeing residue. When the temperature reaches room temperature, the absorbance value A at the three maximum wavelengths is to be measured.

2.6根据建立的浓度计算公式,由染液前后的吸光值计算出其浓度,根据染液前后的浓度差值,补加染料,再加入一定的助剂,保证补加后的染液和首次染液相当,然后再次染色。2.6 According to the established concentration calculation formula, the concentration is calculated from the light absorption value before and after the dyeing solution, and the dye is added according to the concentration difference before and after the dyeing solution, and then certain auxiliaries are added to ensure that the added dyeing solution is the same as the first dyeing solution. solution, and then stained again.

2.7进行循环染色,重复步骤2.4到2.6,直至染色竹片的色差不能满足要求为止。2.7 Perform circular dyeing, repeat steps 2.4 to 2.6 until the color difference of the dyed bamboo slices cannot meet the requirements.

3.制取仿黑檀彩色竹地板3. Preparation of imitation ebony colored bamboo floor

3.1将染色竹片干燥至含水率为5%~15%后再浸渍改性酚醛树脂胶,胶液固含量为15%~32%,浸胶时间为8~15min,然后将其干燥到含水率为5%~15%。3.1 Dried the dyed bamboo slices until the water content was 5% to 15%, and then impregnated the modified phenolic resin glue. The solid content of the glue was 15% to 32%, and the dipping time was 8 to 15 minutes, and then dried to the water content. 5% to 15%.

3.2根据设定的密度值称重,把一定量的染色竹材在模具内纵向均匀放置。3.2 Weigh according to the set density value, and place a certain amount of dyed bamboo evenly in the mold longitudinally.

3.3采用冷压热固化工艺,将模具送入专用冷压机进行冷压,冷压压力为50~70MPa,时间为1~3min。然后将模具送入固化室进行热固化,固化温度为100~150℃,时间为4~12小时。固化后陈化24~72小时,然后缷模取出竹方。3.3 Using the cold pressing and heat curing process, send the mold into a special cold pressing machine for cold pressing, the cold pressing pressure is 50-70MPa, and the time is 1-3min. Then the mold is sent into a curing chamber for thermal curing, the curing temperature is 100-150° C., and the curing time is 4-12 hours. After curing, it is aged for 24-72 hours, and then the bamboo is removed from the mold.

3.4经锯切、修边、开榫槽、砂光、涂饰、干燥等工序制成仿黑檀彩色竹地板。3.4 After sawing, trimming, grooving, sanding, painting, drying and other processes, the imitation ebony colored bamboo floor is made.

实例2:一种仿樱桃木彩色竹地板生产方法Example 2: A kind of imitation cherry wood color bamboo floor production method

1.建立竹材仿实木染色配色数据库1. Establish a bamboo imitation solid wood dyeing and color matching database

1.1选取漂白碾压竹片,厚度为1mm~2.5mm,将其干燥到5%~15%的含水率;选取酸性染料的三原色,酸性黄、酸性红、酸性蓝。1.1 Select bleached and rolled bamboo slices with a thickness of 1 mm to 2.5 mm, and dry them to a moisture content of 5% to 15%; select the three primary colors of acid dyes, acid yellow, acid red, and acid blue.

1.2选定酸性黄为三原色拼色的三色图中塔顶,塔底左右两只各为酸性红和酸性蓝,每往下一层就减少一份黄,从左至右拼入红并逐一减红加蓝,使每一格内染料份数之和为20,即确定三种酸性染料成分比例以1/20变化,得到231块色样配方。1.2 Acid yellow is selected as the top of the tower in the three-color map of the three primary colors, and the left and right two at the bottom of the tower are acid red and acid blue. Every time the lower layer is reduced, one part of yellow is added, and red is added one by one from left to right. Subtract red and add blue, so that the sum of the number of dye parts in each grid is 20, that is to say, the ratio of the three acid dye components is determined to change by 1/20, and 231 color sample formulas are obtained.

1.3对每个色样配方最大染色饱和浓度2%分为8档,其分档浓度分别是0.02%、0.1%、0.2%、0.4%、0.8%、1.2%、1.6%、2%。1.3 For each color sample formula, the maximum dyeing saturation concentration of 2% is divided into 8 grades, and the grade concentrations are 0.02%, 0.1%, 0.2%, 0.4%, 0.8%, 1.2%, 1.6%, and 2%.

1.4同实施1建立竹材仿实木染色配色数据库中步骤1.4到1.61.4 Steps 1.4 to 1.6 in the same implementation 1 to establish the bamboo imitation solid wood dyeing and color matching database

2.竹材循环染色2. Cyclic dyeing of bamboo

2.1根据配色数据库,选取竹材仿樱桃木染色的配方和浓度,其中配方为酸性黄:酸性红:酸性蓝=2∶9∶1,染液浓度为0.2%。2.1 According to the color matching database, select the formula and concentration of bamboo imitation cherry wood dyeing, the formula is acid yellow: acid red: acid blue = 2:9:1, and the concentration of dyeing solution is 0.2%.

2.2同实施例1中竹材循环染色步骤2.2到2.7;2.2 With the steps 2.2 to 2.7 of bamboo cycle dyeing in embodiment 1;

3.制取仿樱桃木彩色竹地板,生产方法同实例1中步骤3。3. produce imitation cherry wood color bamboo floor, production method is with step 3 in example 1.

Claims (5)

1. colored bamboo floor manufacturing method of imitative solid wood, it is characterized in that: described production method may further comprise the steps:
1. set up the imitative solid wood dyeing of bamboo wood color matching database: the three primary colors of choosing acid dyes, Indian yellow, acid red, acid blue are matched colors, dyeing, colour examining, list the dyeing condition of three primary colors acid dyes and employing, and imitative solid wood bamboo dyeing tinctorial pattern information, set up the color matching database of the imitative solid wood dyeing of bamboo wood;
2. bamboo wood dyeing cycle specifically comprises following process:
2.1) fill a prescription and choose: according to the color matching database, choose the prescription of the imitative solid wood dyeing of bamboo wood;
2.2) set up three primary colors colorant match dye liquor concentration computational methods: the standard liquid of three kinds of acid dyes of preparation, and peak value and the wavelength of definite three kinds of dyestuffs, definite dyestuff proportionality constant is set up three primary colors colorant match dye liquor concentration computing formula: C at last then Y=1.85A 369-0.422A 506-0.498A 600, C R=-0.160A 369+ 1.78A 506-0.340A 600, C B=-0.0266A 369-0.229A 506+ 2.42A 600
Wherein, C YBe the dye liquor concentration of Indian yellow, C RBe the dye liquor concentration of acid red, C BBe the dye liquor concentration of acid blue, A 369Be the absorbance of Indian yellow maximum absorption wave strong point, A 506Be the absorbance of acid red maximum absorption wave strong point, A 600Absorbance for acid blue maximum absorption wave strong point;
2.3) the preparation dye liquor: according to prescription and dyeing condition, take by weighing three kinds of acid dyes, after in 80-100 ℃ water, dissolving 30min-100min earlier, the dye liquor that dissolving is good is poured in the staining bath, according to bath raio, add water to the volume of setting, add dyeing assistant again, regulating the pH value is 4.5~6.0, measures the light absorption value at 1~20ml dye liquor its three maximum wavelength places to be measured at last;
2.4) dyeing first: will roll bamboo chip and put into the dye liquor for preparing, and take out after dyeing 3~23 hours under 75 ℃~100 ℃ the environment, again to the washing of dyeing bamboo chip, and to be dried to moisture content be 5%~15%, measures its color with spectrophotometric color measurement instrument;
2.5) measure the light absorption value of dyestuff in the raffinate: after taking out the dyeing bamboo chip, in staining bath, add water and add to volume before the dyeing, measure 1~20ml dyeing residual liquid again, after its temperature reaches room temperature, the light absorption value at its three maximum wavelength places to be measured;
2.6) add dyestuff and auxiliary agent: according to described concentration computing formula, draw the dyeing concentration of dye liquor afterwards by light absorption value, the concentration difference according to before and after the dye liquor draws the amount of dye that need add, and the adding dyeing assistant, the dye liquor after guaranteeing to add and dye liquor is suitable first;
2.7) repeating step 2.4) to 2.6) carry out dyeing cycle;
3. produce the colored bamboo of imitative solid wood floor: successively by impregnation drying, assembly and glue molding, make the colored bamboo of imitative solid wood floor.
2. the colored bamboo floor manufacturing method of a kind of imitative solid wood as claimed in claim 1 is characterized in that: described step 1. in, the process of setting up the imitative solid wood dyeing of bamboo wood color matching database is as follows:
1.1) get the raw materials ready: choose the three primary colors of acid dyes, Indian yellow, acid red, acid blue;
1.2) color matching: according to the variation of three kinds of acid dyes component ratios, set up the trichromatic diagram of dyestuff three primary colors colorant match;
1.3) dyeing: according to trichromatic diagram and default stepping concentration, dye successively to rolling bamboo chip, then to its washing, and to be dried to moisture content be 5%~15%; Described stepping concentration is divided into 12 grades to the maximum dyeing of each tinctorial pattern prescription saturated concentration 1% exactly, is respectively 0.01%, 0.05%, 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%;
1.4) colour examining: use spectrophotometric color measurement instrument to measure one by one to the dyeing bamboo chip, every kind of dyeing bamboo chip is measured repeatedly, with mean value as its color value;
1.5) set up the color matching database: maintenance data storehouse method for building up, list the dyeing condition of three primary colors acid dyes and employing in detail, and imitative solid wood bamboo dyeing tinctorial pattern information, set up the special-purpose color matching database of the imitative solid wood dyeing of bamboo wood.
3. the colored bamboo floor manufacturing method of a kind of imitative solid wood as claimed in claim 2, it is characterized in that: described step 1.2), determine the Cmax that may use when every kind of dyestuff is actually used in colorant match, scope is 0.01%~8%, every kind of prescription carries out stepping from the least concentration to the Cmax then, is divided into 6~15 grades.
4. as the colored bamboo floor manufacturing method of the described a kind of imitative solid wood of one of claim 1~3, it is characterized in that: described step 3. in, the process of producing the colored bamboo of imitative solid wood floor is as follows:
3.1) the impregnation drying: it is to flood modified alkyd resin glue again behind the 5%-15% that the bamboo chip that will dye is dried to moisture content, and the glue solid content is 15%~32%, and the impregnation time is 8~15min, and being dried moisture content then is 5%~15%;
3.2) assembly: bamboo wood vertical assembly in mould will dye;
3.3) glue molding: adopt cold pressing heat cure or heat pressing process, the slab glue molding that group is good is made bamboo side or bamboo blank plate;
3.4) following process: make the colored bamboo of imitative solid wood floor through sawing, deburring, mortice opening, sanding, covering with paint, drying process.
5. the colored bamboo floor manufacturing method of a kind of imitative solid wood as claimed in claim 4 is characterized in that: described step 3.2), adopt single dyeing bamboo wood assembly, perhaps adopt two or more coloured differently bamboo wood assembly.
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