CN102251176B - Method for rolling ship plate pitting-resistant blue steel - Google Patents
Method for rolling ship plate pitting-resistant blue steel Download PDFInfo
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 43
- 239000010959 steel Substances 0.000 title claims abstract description 43
- 238000005096 rolling process Methods 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 230000009467 reduction Effects 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000007689 inspection Methods 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 4
- 230000007797 corrosion Effects 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000009749 continuous casting Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 230000000881 depressing effect Effects 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 238000012856 packing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 6
- 230000003746 surface roughness Effects 0.000 abstract description 3
- 241000502561 Acacia irrorata Species 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000003825 pressing Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000033764 rhythmic process Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
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Abstract
一种船板抗点蚀蓝皮钢的轧制方法,属于船体结构用钢技术领域。经清检后装入板坯加热炉加热,出炉后钢坯经高压水一次除鳞;一次除鳞后钢坯进粗轧机轧制,奇数道次开启二次除鳞,粗轧轧完后进精轧轧制,精轧接管厚度为成品钢板厚度的3-5倍,道次压下量1-20mm,钢板采用层流冷却。优点在于,提高船板表面质量,减少因表面粗糙、麻点、氧化铁皮压入等产生的带出品,降低生产成本,同时各项性能满足船级规范要求。
The invention discloses a rolling method of anti-pitting blue skin steel for ship plates, which belongs to the technical field of steel for ship hull structures. After cleaning and inspection, it is loaded into the slab heating furnace for heating. After being released from the furnace, the steel billet is descaled once by high-pressure water; The thickness of the finish rolling joint is 3-5 times the thickness of the finished steel plate, the reduction of each pass is 1-20mm, and the steel plate is cooled by laminar flow. The advantage is that it can improve the surface quality of the ship plate, reduce the carry-over products caused by surface roughness, pitting, iron oxide scale pressing, etc., reduce the production cost, and at the same time, various performances can meet the requirements of ship classification regulations.
Description
技术领域 technical field
本发明属于船体结构用钢技术领域,特别是涉及一种船板抗点蚀蓝皮钢的轧制方法。The invention belongs to the technical field of steel for ship hull structure, in particular to a rolling method of anti-pitting blue skin steel for ship plates.
背景技术 Background technique
船舶制造业是我国国民经济的重要组成部分,它既是技术密集型产业,又是劳动密集型产业。加快发展船舶制造业,对于提高我国制造业整体水平、带动钢铁及配套机电设备制造等相关产业发展和扩大就业,具有重要的推动作用。The shipbuilding industry is an important part of my country's national economy. It is both a technology-intensive industry and a labor-intensive industry. Accelerating the development of the shipbuilding industry plays an important role in improving the overall level of my country's manufacturing industry, promoting the development of related industries such as steel and supporting electromechanical equipment manufacturing, and expanding employment.
国产造船用钢板经过多年的努力,已基本能满足我国造船业的发展需要,特别是“十一五”期间钢铁企业中厚板生产线的改扩建和新建,使中厚板的生产从数量到质量都得到提高。然而是,由于船舶工作环境恶劣,船外壳要受海水的化学腐蚀,电化学腐蚀和海生物,微生物的腐蚀,对表面质量要求十分苛刻。表面质量是中厚板的主要质量指标之一,对中厚板的加工和使用均有重要影响,因而受到生产厂和用户的高度重视,可以说,没有优良外观质量的钢板是不被用户认可的钢板。受国际金融危机的影响,船东对船体表面质量提出极其苛刻的要求,随之而来的是造船厂家对钢厂船板的表面质量提出了更高的要求。After years of hard work, domestic steel plates for shipbuilding can basically meet the development needs of my country's shipbuilding industry. Especially during the "Eleventh Five-Year Plan" period, the reconstruction, expansion and new construction of medium and heavy plate production lines in iron and steel enterprises have made the production of medium and heavy plates from quantity to quality. have been improved. However, due to the harsh working environment of the ship, the hull of the ship is subject to chemical corrosion of seawater, electrochemical corrosion, and corrosion of marine organisms and microorganisms, and the requirements for surface quality are very strict. Surface quality is one of the main quality indicators of medium and heavy plates, which has an important impact on the processing and use of medium and heavy plates, so it is highly valued by manufacturers and users. It can be said that steel plates without good appearance quality are not recognized by users steel plate. Affected by the international financial crisis, shipowners put forward extremely strict requirements on the surface quality of the hull, followed by shipbuilders putting forward higher requirements on the surface quality of ship plates in steel factories.
目前,国内主要中厚板公司生产的船板表面颜色基本为红褐色,称为“红皮钢”,钢板表面氧化铁皮较厚,氧化铁皮厚而疏松,与钢的基体结合不强,表面抗点蚀性差,易在刮碰磨蹭中掉皮。而国外船板表面呈蓝黑色,氧化铁皮薄且致密,与钢的基体结合力强。要改变此现状,就要从船板的表层氧化铁皮结构入手,增加Fe3O4含最,使氧化铁皮呈蓝黑色,同时必须使表层氧化铁皮薄而致密。本发明与国外船板工艺相比,过程控制简单,无需对现有除鳞系统进行改造,且轧制节奏快,单位小时轧制船板块数增加。At present, the surface color of ship plates produced by major domestic medium and heavy plate companies is basically reddish brown, called "red skin steel". Poor pitting resistance, easy to peel off in scraping and rubbing. However, the surface of foreign ship plates is blue-black, the oxide scale is thin and dense, and has strong bonding force with the steel matrix. To change this situation, it is necessary to start with the structure of the surface oxide scale of the ship plate, increase the content of Fe 3 O 4 to make the oxide scale blue and black, and at the same time make the surface oxide scale thin and dense. Compared with foreign ship plate technology, the present invention has simple process control, does not need to modify the existing descaling system, has fast rolling rhythm, and increases the number of rolled ship plates per hour.
发明内容 Contents of the invention
本发明的目的在于提供一种船板抗点蚀蓝皮钢的生产方法,提高船板表面质量,减少因表面粗糙、麻点、氧化铁皮压入等产生的带出品,降低生产成本,同时各项性能满足船级规范要求。The purpose of the present invention is to provide a production method of anti-pitting blue steel for ship plate, improve the surface quality of ship plate, reduce the carry-over products caused by surface roughness, pitting, iron oxide scale pressing, etc., reduce production cost, and at the same time The performance meets the requirements of ship class regulations.
本发明所述的船板抗点蚀蓝皮钢一般强度(A、B、D、E)船板按重量百分比的成分设计为:Ship plate anti-pitting blue steel general strength (A, B, D, E) ship plate according to the composition design of weight percent of the present invention is:
C:0.15~0.18%,Si:0.10~0.30%,Mn:0.45~0.90%,Nb:0.005~0.02%,Ti:0.005~0.02%,S:≤0.01%,P≤0.02%,Als:0.020~0.04%,余量为Fe及不可避免的杂质。C: 0.15~0.18%, Si: 0.10~0.30%, Mn: 0.45~0.90%, Nb: 0.005~0.02%, Ti: 0.005~0.02%, S: ≤0.01%, P≤0.02%, Als: 0.020~ 0.04%, the balance is Fe and unavoidable impurities.
高强度(32kg级、36kg级)船板按重量百分比的成分设计为:The components of high-strength (32kg, 36kg) ship plates are designed according to weight percentage:
C:0.14~0.17%,Si:0.20~0.30%,Mn:1.30~1.50%,Nb:0.015~0.04%,Ti:0.005~0.02%,S:≤0.005%,P≤0.02%,Als:0.020~0.06%,余量为Fe及不可避免的杂质。C: 0.14~0.17%, Si: 0.20~0.30%, Mn: 1.30~1.50%, Nb: 0.015~0.04%, Ti: 0.005~0.02%, S: ≤0.005%, P≤0.02%, Als: 0.020~ 0.06%, the balance is Fe and unavoidable impurities.
在轧制工艺中控制如下技术参数:Control the following technical parameters in the rolling process:
(1)按以上化学成分设计及工艺流程冶炼的连铸厚板坯,经清检后装入板坯加热炉加热,加热温度为1160~1220℃,加热时间150-400min,残氧控制1%-6%,以尽可能减少钢坯表面氧化铁皮生成厚度;出炉后钢坯经高压水一次除鳞,高压水压力设定为19-21MPa,以保证一次除鳞质量;然后进入轧机轧制。(1) The continuous casting thick slab smelted according to the above chemical composition design and process flow, after cleaning and inspection, put it into the slab heating furnace for heating. The heating temperature is 1160-1220 ℃, the heating time is 150-400min, and the residual oxygen is controlled at 1%. -6%, in order to reduce the thickness of oxide scale on the surface of the billet as much as possible; after the billet is released from the furnace, it is descaled once by high-pressure water, and the pressure of the high-pressure water is set at 19-21MPa to ensure the quality of the first-time descaler; then it enters the rolling mill for rolling.
(2)一次除鳞后钢坯进粗轧机轧制,奇数道次开启二次除鳞(除鳞箱位于粗轧机前),防止未除尽的氧化铁皮压入钢板表面,经粗轧轧制7-9道,道次压下量10-35mm,通过大压下来保证粗轧晶粒完全变形;(2) After the first descaling, the steel billet is rolled into the roughing mill, and the second descaling is opened in odd passes (the descaling box is located in front of the roughing mill) to prevent the unremoved iron scale from being pressed into the surface of the steel plate, and after rough rolling for 7 -9 passes, the reduction of each pass is 10-35mm, and the rough rolling grains are completely deformed through large reductions;
粗轧轧完后立即进精轧轧制,精轧接管厚度为成品钢板厚度的3-5倍,使精轧具有一定的累积压下量,随着表面温度的下降氧化铁皮变脆,精轧阶段压下量需较小,道次压下量1-20mm为宜,精轧开轧温度控制在1000~950℃,以确保表面氧化铁皮在高温下具有良好的延展性,终轧钢板表面温度控制在920~980℃,使钢板表面形成以黑颜色致密的Fe3O4为主的氧化铁皮结构。Immediately after rough rolling, finish rolling is carried out. The thickness of the finish rolling joint is 3-5 times the thickness of the finished steel plate, so that the finish rolling has a certain cumulative reduction. As the surface temperature drops, the oxide scale becomes brittle, and the finish rolling The stage reduction needs to be small, and the pass reduction is preferably 1-20mm. The start-rolling temperature of the finish rolling is controlled at 1000-950°C to ensure that the surface oxide scale has good ductility at high temperatures, and the surface temperature of the final-rolled steel plate Control the temperature at 920-980°C, so that the surface of the steel plate forms an iron oxide scale structure dominated by black and dense Fe 3 O 4 .
(3)钢板采用层流冷却。成品钢板开始冷却温度900-950℃,为终轧温度基础上减去从精轧到ACC入口过程中的温降(30-50℃);设定终冷温度680~750℃,主要此温度段的表面质量较好较稳定;设定冷速6~10℃/s,低冷速有利得到稳定的表面质量。(3) The steel plate is cooled by laminar flow. The starting cooling temperature of the finished steel plate is 900-950°C, which is based on the final rolling temperature minus the temperature drop (30-50°C) from the finishing rolling to the entrance of the ACC; the final cooling temperature is set at 680-750°C, mainly in this temperature range The surface quality is better and more stable; the cooling rate is set at 6-10°C/s, and the low cooling rate is beneficial to obtain stable surface quality.
本发明的优点:目前此项发明已应用于船板表面质量问题上,经过此项新工艺的执行,船板表面粗糙等问题得到了解决,船板表面质量得到了质的改善,满足了船厂及船东的要求。Advantages of the present invention: At present, this invention has been applied to the surface quality of ship plates. After the implementation of this new process, the problems such as rough surface of ship plates have been solved, and the surface quality of ship plates has been qualitatively improved, which meets the needs of shipyards. and shipowner's requirements.
附图说明 Description of drawings
图1为船板“红皮钢”照片。Figure 1 is a photo of the "red steel" ship plate.
图2为新工艺生产后的船板“蓝皮钢”照片。Figure 2 is a photo of the ship plate "blue steel" produced by the new process.
具体实施方式 Detailed ways
钢板轧制后表面蓝黑色,表面氧化铁皮均匀致密,抛丸检查后表面都不存在氧化铁皮压入和表面粗糙等问题,说明了所确定的船板轧制工艺合理,且能够保证生产顺畅。After rolling, the surface of the steel plate is blue-black, and the iron scale on the surface is uniform and dense. After the shot blasting inspection, there are no problems such as scale indentation and surface roughness on the surface, which shows that the determined ship plate rolling process is reasonable and can ensure smooth production.
表1钢板的加热、水冷工艺参数Table 1 Heating and water cooling process parameters of steel plate
表2试制钢板的轧制工艺参数Table 2 The rolling process parameters of the trial steel plate
表3试制钢板的轧制工艺参数Table 3 The rolling process parameters of the trial steel plate
表4试制钢板的轧制工艺参数Table 4 The rolling process parameters of the trial steel plate
表5试制钢板的轧制工艺参数Table 5 The rolling process parameters of the trial steel plate
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CN102527735A (en) * | 2011-12-23 | 2012-07-04 | 秦皇岛首秦金属材料有限公司 | Method for controlling even deformation of edge portion in medium-thick board rolling |
CN102534152B (en) * | 2012-01-31 | 2014-08-27 | 首钢总公司 | Rolling method capable of preventing pockmarks on surface of ship plate |
CN103212571B (en) * | 2013-04-18 | 2015-06-10 | 湖南华菱湘潭钢铁有限公司 | Method for producing oxide scale capable of preventing steel plate surface from getting rusty |
CN103394529A (en) * | 2013-07-31 | 2013-11-20 | 秦皇岛首秦金属材料有限公司 | Secondary descaling method for improving surface quality of ship boards |
CN103962386B (en) * | 2014-04-18 | 2016-01-20 | 东北大学 | The corrosion proof iron scale control method of a kind of raising hot rolled steel plate |
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CN107282649A (en) * | 2016-04-04 | 2017-10-24 | 鞍钢股份有限公司 | Controlled cooling method for preventing iron scale of die steel plate from falling off |
CN110899331B (en) * | 2019-12-05 | 2022-03-01 | 马鞍山钢铁股份有限公司 | Control method of iron oxide powder on surface of hot rolled plate |
CN113369312A (en) * | 2021-04-13 | 2021-09-10 | 南京钢铁股份有限公司 | Control process for Q235 pockmarks with specification of 25-40mm |
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US5609818A (en) * | 1992-12-11 | 1997-03-11 | Nippon Steel Corporation | Steel excellent in corrosion resistance and processability |
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Address after: 066326 Du Zhuang Township, Funing County, Qinhuangdao, Hebei Co-patentee after: Shougang Group Co. Ltd. Patentee after: Qinhuangdao Shouqin Metal Material Co., Ltd. Address before: 066326 Du Zhuang Township, Funing County, Qinhuangdao, Hebei Co-patentee before: Capital Iron & Steel General Company Patentee before: Qinhuangdao Shouqin Metal Material Co., Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190410 Address after: 100041 Shijingshan Road, Shijingshan District, Shijingshan District, Beijing Patentee after: Shougang Group Co. Ltd. Address before: 066326 Du Zhuang Township, Funing County, Qinhuangdao, Hebei Co-patentee before: Shougang Group Co. Ltd. Patentee before: Qinhuangdao Shouqin Metal Material Co., Ltd. |