CN102250574A - Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline - Google Patents
Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline Download PDFInfo
- Publication number
- CN102250574A CN102250574A CN2010101752110A CN201010175211A CN102250574A CN 102250574 A CN102250574 A CN 102250574A CN 2010101752110 A CN2010101752110 A CN 2010101752110A CN 201010175211 A CN201010175211 A CN 201010175211A CN 102250574 A CN102250574 A CN 102250574A
- Authority
- CN
- China
- Prior art keywords
- pipeline
- hot melt
- melt adhesive
- hot
- joint coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004831 Hot glue Substances 0.000 title abstract description 14
- 230000007797 corrosion Effects 0.000 title abstract description 8
- 238000005260 corrosion Methods 0.000 title abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 229920001971 elastomer Polymers 0.000 claims abstract description 7
- 229920006000 epoxidized styrene-butadiene-styrene block copolymer Polymers 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000003208 petroleum Substances 0.000 claims abstract description 5
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 3
- 230000002421 anti-septic effect Effects 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 239000003292 glue Substances 0.000 claims description 13
- 239000012943 hotmelt Substances 0.000 claims description 13
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 7
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000012764 mineral filler Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 4
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 4
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 4
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- -1 titanic acid ester Chemical class 0.000 claims description 4
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 150000002632 lipids Chemical class 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000010008 shearing Methods 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 229920006163 vinyl copolymer Polymers 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the technical field of corrosion of repaired mouths of engineering and petroleum pipelines, in particular to a hot-melt adhesive for preventing the corrosion of a repaired mouth of a pipeline. The hot-melt adhesive comprises the following components in percentage by weight: 30 to 70 percent of epoxidized SBS (styrene-butadiene-styrene) resin, 5 to 40 percent of vinyl copolymer, 5 to 40 percent of rubber elastomer, 5 to 40 percent of tackifying resin, 5 to 20 percent of inorganic filler and 1 to 8 percent of aid; and the hot-melt adhesive is prepared by performing melt blending on the components by using an intensive shear banbury, and performing extrusion granulation by using a twin-screw extruder. The hot-melt adhesive for preventing the corrosion of the repaired mouth of the pipeline, which is prepared from the epoxidized SBS resin serving as a base material, solves the problem that the conventional hot-melt adhesive has insufficient toughness and brittle failure at low temperature and low peel strength at high temperature. The hot-melt adhesive has high toughness at low temperature and high peel strength at high temperature, hardly falls off or allows water to enter the pipeline in the long-term running process, is convenient to construct in field, has excellent bonding property and ensures reliable bonding.
Description
Technical field
The present invention relates to engineering, petroleum pipe line preventing corrosion of repaired mouth technical field, particularly joint coating on pipeline antiseptic hot melt glue.
Background technology
The long distance oil-gas pipeline transportation, it is the 5th big mode of transport after highway, railway, water route, air transportation, effect in the middle of industrial gas oil and even world economy becomes increasingly conspicuous, for inflammable, explosive, volatile oil and gas, best mode of transport is exactly the closed pipeline transportation.
The corrosion-resistanting interpolating port construction is the important procedure of long distance pipeline site operation, also is the link that easily goes wrong in the construction.Existing repaired mouth mode has multiple modes such as petroleum pitch repaired mouth, epoxide coal bituminous repaired mouth, adhesive tape repaired mouth, epoxy primer repaired mouth and PE material contracting with heat repaired mouth.At present, the pipeline corrosion protection pyrocondensation product with three layers of corrosionproof protection function is mainly used in domestic and international great pipework, and product is made up of three parts such as radiation crosslinking pyrocondensation belt, hot melt adhesive, double component solvent-free type epoxy primers.Wherein hot melt adhesive mainly is the material of main part preparation with EVA, its low-temperature flexibility is poor, the high temperature stripping strength is low, interfacial failure normally when peeling off, poor to high density polyethylene(HDPE), surface drying epoxy primer adhesiveproperties, in the long-time running process, occur easily coming off, intaking causes corrosive pipeline, make that pipeline is whole anticorrosionly falls short of success for lack of final effort, not only economy sustains a loss, and exists Serious Accident hidden danger.
Summary of the invention
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art, provide a kind of when low temperature good toughness, the stripping strength height during high temperature, in the long-time running process, be not prone to and come off, intake, site operation is convenient, adhesiveproperties excellence, bonding reliable joint coating on pipeline antiseptic hot melt glue.
Solution of the present invention is: a kind of joint coating on pipeline antiseptic hot melt glue is characterized in that the each component weight percent is as follows:
Epoxidized SBS (styrene-butadiene-styrene block copolymer) resin 30-70%;
Vinyl copolymerization 5-40%;
Rubber-like elastomerics 5-40%;
Tackifying resin 5-40%;
Mineral filler 5-20%;
Auxiliary agent 1-8%;
Each component is by shearing the Banbury mixer melt blending by force, preparing through double-screw extruding pelletizing.
Auxiliary agent comprises coupling agent, colorant, oxidation inhibitor in the solution of the present invention.Coupling agent can adopt titanic acid ester or aluminic acid ester or silane or tensio-active agent or lipid acid, and the coupling agent consumption is the 0.5-2% of mineral filler.Colorant can adopt high-melt index to make the Masterbatch or the carbon black powder of carrier, and the colorant consumption is the 1-5% of material total amount.Oxidation inhibitor can adopt Hinered phenols or monothioester class or composite antioxidant class, and the oxidation inhibitor consumption is the 0.5-3% of material total amount.
Ethylenic copolymer can adopt EVA (ethylene vinyl acetate copolymer) or EBA (ethylene butyl acrylate multipolymer) or EMA (ethylene methyl acrylate copolymer) or EAA (ethylene acrylic acid co polymer) in the solution of the present invention.
The rubber-like elastomerics can adopt isoprene-isobutylene rubber or silicon rubber or SIS (styrene-isoprene-styrene copolymer-) or EPDM (terpolymer EP rubber) in the solution of the present invention.
Tackifying resin can adopt its derivative of terpine resin or rosin and derivative or petroleum resin or naphthenic oil in the solution of the present invention.
Mineral filler can be adopted lime carbonate or talcum powder or white carbon black in the solution of the present invention.
Advantage of the present invention: the present invention solves existing hot melt adhesive toughness deficiency when low temperature, brittle rupture, the problem that the stripping strength during high temperature is low with the pipeline corrosion protection repaired mouth hot melt adhesive of epoxidized SBS as the base mateiral preparation.Good toughness during low temperature of the present invention, the stripping strength height during high temperature is not prone in the long-time running process and comes off, intakes, and site operation is convenient, and the adhesiveproperties excellence is bonding reliable.
Embodiment
Embodiment 1: take by weighing epoxidized SBS resin 8kg respectively, EVA (28/400) 2.4kg, SIS elastomerics 1.6kg, terpine resin 4kg, talcum powder 1.6kg, other auxiliary agents 0.4kg, 100 ℃ of mixing 20min dischargings down add twin screw extruder in Banbury mixer, and controlled temperature is at 100-140 ℃, extruding pelletization gets hot melt adhesive behind the cooling drying.
Embodiment 2: take by weighing epoxidized SBS resin 10kg respectively, EVA (28/150) 2kg, isoprene-isobutylene rubber 1.6kg, petroleum resin 3kg, lime carbonate 1kg, other auxiliary agents 0.4kg, 100 ℃ of mixing 20min dischargings down add twin screw extruder in Banbury mixer, and controlled temperature is at 100-140 ℃, extruding pelletization gets hot melt adhesive behind the cooling drying.
It is as follows that the pipeline corrosion protection repaired mouth hot melt adhesive of the foregoing description preparation detects performance index extremely:
Claims (9)
1. joint coating on pipeline antiseptic hot melt glue is characterized in that the each component weight percent is as follows:
Epoxidized SBS (styrene-butadiene-styrene block copolymer) resin 30-70%;
Vinyl copolymerization 5-40%;
Rubber-like elastomerics 5-40%;
Tackifying resin 5-40%;
Mineral filler 5-20%;
Auxiliary agent 1-8%;
Each component is by shearing the Banbury mixer melt blending by force, preparing through double-screw extruding pelletizing.
2. joint coating on pipeline antiseptic hot melt glue according to claim 1 is characterized in that described auxiliary agent comprises coupling agent, colorant, oxidation inhibitor.
3. joint coating on pipeline antiseptic hot melt glue according to claim 1 is characterized in that ethylenic copolymer is EVA (ethylene vinyl acetate copolymer) or EBA (ethylene butyl acrylate multipolymer) or EMA (ethylene methyl acrylate copolymer) or EAA (ethylene acrylic acid co polymer).
4. joint coating on pipeline antiseptic hot melt glue according to claim 1 is characterized in that the rubber-like elastomerics is isoprene-isobutylene rubber or silicon rubber or SIS (styrene-isoprene-styrene copolymer-) or EPDM (terpolymer EP rubber).
5. joint coating on pipeline antiseptic hot melt glue according to claim 1,, it is characterized in that tackifying resin is its derivative of terpine resin or rosin and derivative or petroleum resin or naphthenic oil.
6. joint coating on pipeline antiseptic hot melt glue according to claim 1 is characterized in that mineral filler is lime carbonate or talcum powder or white carbon black.
7. joint coating on pipeline antiseptic hot melt glue according to claim 2 is characterized in that coupling agent is titanic acid ester or aluminic acid ester or silane or tensio-active agent or lipid acid, and the coupling agent consumption is the 0.5-2% of mineral filler
8. joint coating on pipeline antiseptic hot melt glue according to claim 2 is characterized in that colorant is Masterbatch or the carbon black powder that high-melt index is made carrier, and the colorant consumption is the 1-5% of material total amount.
9. joint coating on pipeline antiseptic hot melt glue according to claim 2 is characterized in that oxidation inhibitor is Hinered phenols or monothioester class or composite antioxidant class, and the oxidation inhibitor consumption is the 0.5-3% of material total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101752110A CN102250574A (en) | 2010-05-18 | 2010-05-18 | Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101752110A CN102250574A (en) | 2010-05-18 | 2010-05-18 | Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102250574A true CN102250574A (en) | 2011-11-23 |
Family
ID=44978151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101752110A Pending CN102250574A (en) | 2010-05-18 | 2010-05-18 | Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102250574A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796317A (en) * | 2012-08-31 | 2012-11-28 | 福建省豪用环保科技有限公司 | Macromolecular self-complementary sealant |
| CN103146266A (en) * | 2013-04-09 | 2013-06-12 | 湖北联萌科技有限公司 | Anticorrosive paint and preparation method thereof |
| CN103540280A (en) * | 2013-09-27 | 2014-01-29 | 沈阳建筑大学 | Heat-conduction and electric-conduction hot melt glue and preparation method thereof |
| CN103571392A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive for automotive upholstery |
| CN103571384A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Modified ethylene-vinyl-acetate (eva) resin hot melt adhesive |
| CN104178084A (en) * | 2014-07-23 | 2014-12-03 | 安徽雪峰木业有限公司 | High-antimicrobial-effect hot-melt adhesive for pencil manufacturing |
| CN104479590A (en) * | 2014-12-23 | 2015-04-01 | 兰州理工大学 | Preparation method of epoxidized SSBR (solution polymerized butadiene styrene rubber) adhesive |
| CN104497917A (en) * | 2014-12-15 | 2015-04-08 | 江苏达胜热缩材料有限公司 | Low-temperature 3PE hot melt adhesive and preparation method thereof |
| CN104789170A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Shoe material bonding film, preparation method of film as well as method for using film for bonding soles |
| CN108611026A (en) * | 2018-04-28 | 2018-10-02 | 王锦云 | A kind of aqueous EVA adhesive and preparation method thereof |
| CN110358242A (en) * | 2019-05-29 | 2019-10-22 | 周宁东 | A kind of high-strength low-temperature-resistant CABLE MATERIALS and preparation method thereof |
| CN115537159A (en) * | 2022-12-02 | 2022-12-30 | 广州鹿山新材料股份有限公司 | Weather-resistant waterproof coiled material hot-melt pressure-sensitive adhesive and preparation method and application thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523343A (en) * | 1993-11-26 | 1996-06-04 | Enichem Elastomeri S.R.L. | Hot melt adhesive compositions for special applications |
| CN1210555A (en) * | 1996-12-02 | 1999-03-10 | 大瑟路化学工业株式会社 | Hot-melt adhesive composition with excellent heat and cold resistance |
| US6384138B1 (en) * | 1998-09-04 | 2002-05-07 | Exxonmobil Chemical Patents, Inc. | Hot melt pressure sensitive adhesive composition |
| CN1399662A (en) * | 1999-10-18 | 2003-02-26 | 克拉通聚合物研究有限公司 | Formulation for strippable adhesive and coating films and high preformance adhesives |
| CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
| CN1693399A (en) * | 2002-11-08 | 2005-11-09 | 蒂萨股份公司 | Adhesive and its use, used for pressure-sensitive adhesive band with at least one adhesive layer able to be speparated from the objec surface without residue and demage |
| CN101289605A (en) * | 2008-06-04 | 2008-10-22 | 金尔昇 | Environment protection type colourful flashing hot-melt adhesive |
| CN101429413A (en) * | 2008-11-18 | 2009-05-13 | 广州市鹿山化工材料有限公司 | Double-layer composite hot melt adhesive film for bonding metal and plastic |
| CN101684398A (en) * | 2008-09-11 | 2010-03-31 | 朗盛德国有限责任公司 | Hot-melt adhesive |
-
2010
- 2010-05-18 CN CN2010101752110A patent/CN102250574A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523343A (en) * | 1993-11-26 | 1996-06-04 | Enichem Elastomeri S.R.L. | Hot melt adhesive compositions for special applications |
| CN1210555A (en) * | 1996-12-02 | 1999-03-10 | 大瑟路化学工业株式会社 | Hot-melt adhesive composition with excellent heat and cold resistance |
| US6384138B1 (en) * | 1998-09-04 | 2002-05-07 | Exxonmobil Chemical Patents, Inc. | Hot melt pressure sensitive adhesive composition |
| CN1399662A (en) * | 1999-10-18 | 2003-02-26 | 克拉通聚合物研究有限公司 | Formulation for strippable adhesive and coating films and high preformance adhesives |
| CN1693399A (en) * | 2002-11-08 | 2005-11-09 | 蒂萨股份公司 | Adhesive and its use, used for pressure-sensitive adhesive band with at least one adhesive layer able to be speparated from the objec surface without residue and demage |
| CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
| CN101289605A (en) * | 2008-06-04 | 2008-10-22 | 金尔昇 | Environment protection type colourful flashing hot-melt adhesive |
| CN101684398A (en) * | 2008-09-11 | 2010-03-31 | 朗盛德国有限责任公司 | Hot-melt adhesive |
| CN101429413A (en) * | 2008-11-18 | 2009-05-13 | 广州市鹿山化工材料有限公司 | Double-layer composite hot melt adhesive film for bonding metal and plastic |
Non-Patent Citations (6)
| Title |
|---|
| 万绍群: "石油天然气输送管道补口防腐热熔胶的研制", 《第二届石油石化工业用材研讨会论文集》, 30 December 2001 (2001-12-30) * |
| 周卫平: "SBS/SIS嵌段共聚物的有机硅改性研究", 《化学与黏合》, vol. 28, no. 3, 30 May 2006 (2006-05-30) * |
| 周卫平: "嵌段共聚物的改性研究及其在胶黏剂中的应用", 《化学与黏合》, vol. 28, no. 2, 30 March 2006 (2006-03-30) * |
| 张伟君: "环氧化SBS压敏胶的研制", 《中国胶黏剂》, vol. 11, no. 3, 30 May 2002 (2002-05-30) * |
| 熊开生: "SIS/SDS压敏胶改性方法", 《中国胶黏剂》, vol. 12, no. 4, 30 July 2003 (2003-07-30) * |
| 贺曼罗: "《环氧树脂胶黏剂》", 31 December 2004, article "环氧树脂胶黏剂" * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796317A (en) * | 2012-08-31 | 2012-11-28 | 福建省豪用环保科技有限公司 | Macromolecular self-complementary sealant |
| CN103146266A (en) * | 2013-04-09 | 2013-06-12 | 湖北联萌科技有限公司 | Anticorrosive paint and preparation method thereof |
| CN103146266B (en) * | 2013-04-09 | 2015-09-09 | 湖北联萌科技有限公司 | A kind of anticorrosive coating and preparation method thereof |
| CN103540280A (en) * | 2013-09-27 | 2014-01-29 | 沈阳建筑大学 | Heat-conduction and electric-conduction hot melt glue and preparation method thereof |
| CN103540280B (en) * | 2013-09-27 | 2016-01-20 | 沈阳建筑大学 | A kind of heat conduction, conductive hot melt glue and preparation method thereof |
| CN103571392B (en) * | 2013-10-24 | 2016-04-13 | 芜湖众力部件有限公司 | A kind of Anti-corrosion hot melt adhesive for automotive upholstery |
| CN103571392A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive for automotive upholstery |
| CN103571384A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Modified ethylene-vinyl-acetate (eva) resin hot melt adhesive |
| CN104178084A (en) * | 2014-07-23 | 2014-12-03 | 安徽雪峰木业有限公司 | High-antimicrobial-effect hot-melt adhesive for pencil manufacturing |
| CN104497917A (en) * | 2014-12-15 | 2015-04-08 | 江苏达胜热缩材料有限公司 | Low-temperature 3PE hot melt adhesive and preparation method thereof |
| CN104479590A (en) * | 2014-12-23 | 2015-04-01 | 兰州理工大学 | Preparation method of epoxidized SSBR (solution polymerized butadiene styrene rubber) adhesive |
| CN104789170A (en) * | 2015-04-09 | 2015-07-22 | 茂泰(福建)鞋材有限公司 | Shoe material bonding film, preparation method of film as well as method for using film for bonding soles |
| CN104789170B (en) * | 2015-04-09 | 2017-05-17 | 茂泰(福建)鞋材有限公司 | Shoe material bonding film, preparation method of film as well as method for using film for bonding soles |
| CN108611026A (en) * | 2018-04-28 | 2018-10-02 | 王锦云 | A kind of aqueous EVA adhesive and preparation method thereof |
| CN110358242A (en) * | 2019-05-29 | 2019-10-22 | 周宁东 | A kind of high-strength low-temperature-resistant CABLE MATERIALS and preparation method thereof |
| CN115537159A (en) * | 2022-12-02 | 2022-12-30 | 广州鹿山新材料股份有限公司 | Weather-resistant waterproof coiled material hot-melt pressure-sensitive adhesive and preparation method and application thereof |
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Application publication date: 20111123 |