CN102226074A - Oil-containing refrigerant and production process thereof - Google Patents
Oil-containing refrigerant and production process thereof Download PDFInfo
- Publication number
- CN102226074A CN102226074A CN2011101009921A CN201110100992A CN102226074A CN 102226074 A CN102226074 A CN 102226074A CN 2011101009921 A CN2011101009921 A CN 2011101009921A CN 201110100992 A CN201110100992 A CN 201110100992A CN 102226074 A CN102226074 A CN 102226074A
- Authority
- CN
- China
- Prior art keywords
- lubricating oil
- refrigerant
- oil
- refrigeration
- refrigeration agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003507 refrigerant Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000005057 refrigeration Methods 0.000 claims abstract description 54
- 239000010687 lubricating oil Substances 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000003921 oil Substances 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 47
- 238000002156 mixing Methods 0.000 claims description 5
- 238000012423 maintenance Methods 0.000 abstract description 20
- 238000003912 environmental pollution Methods 0.000 abstract description 10
- 238000004378 air conditioning Methods 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000010726 refrigerant oil Substances 0.000 abstract description 3
- 230000008439 repair process Effects 0.000 abstract description 3
- 230000007246 mechanism Effects 0.000 abstract description 2
- 238000005086 pumping Methods 0.000 abstract description 2
- 230000001502 supplementing effect Effects 0.000 abstract 2
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 230000003090 exacerbative effect Effects 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000010725 compressor oil Substances 0.000 description 6
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 5
- 230000001050 lubricating effect Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000006200 vaporizer Substances 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Lubricants (AREA)
Abstract
The invention discloses an oil-containing refrigerant and a production process thereof and relates to maintenance of refrigeration equipment. The oil-containing refrigerant mainly comprises a pressure container and a mixture of the refrigerant and lubricating oil, and the mixture is sealed in the pressure container. As for air conditioning, refrigeration and other equipment with mechanical compression mechanisms, when leakage failure occurs, the lubricating oil can also leak along with the refrigerant, thereby causing the loss of the lubricating oil in a refrigeration pipeline system. After a repairman repairs the failure, the refrigerant has to be emptied due to the process need of supplementing and adding the lubricating oil, the inside of the refrigeration pipeline system needs to achieve a certain degree of vacuum, and then the lubricating oil can be conveniently supplemented and added, thereby causing the waste of the refrigerant and the lubricating oil and further exacerbating the environmental pollution. The invention aims at directly supplementing and adding the refrigerant and the lubricating oil without using the vacuum-pumping maintenance process flow under the situation that the refrigerant is arranged in the refrigeration pipeline system, simplifying the maintenance process, reducing the maintenance cost and further reducing the environmental pollution.
Description
Technical field
The present invention relates to the refrigeration plant maintenance.
Background technology
Artificial atmosphere, refrigeration waits these to have the equipment of mechanically compress mechanism, be used for refrigerating refrigeration agent and the lubricating oil that is used for compressor lubrication, all be in the piping system of a sealing and circulate, lubricating oil and refrigeration agent have certain mutual solubility, when the seepage fault appears in the piping system of sealing, in the refrigeration agent seepage, lubricating oil is also along with refrigeration agent seepage together, cause lubricating oil disappearance in the refrigeration pipe system, cause compressor lubrication bad, influence the work-ing life of compressor or directly make compressor produce fault, also make refrigerating efficiency decline, particularly automotive air-conditioning system, because the compressor power input shaft end is in the dynamic seal state, because working condition is abominable relatively, more be easy to generate such seepage fault again.The repairman is after repairing this class fault, because replenish the arts demand that adds lubricating oil, necessary flare refrigerant, with the refrigeration pipe system pumping with exhaust blower, make the vacuum that reaches certain in the refrigeration pipe system, could conveniently replenish then and add lubricating oil, like this, make the interior remaining cold-producing medium of refrigeration pipe system comprise that its interior lubricating oil of dissolving all is discharged into (because of the cost recovery height) in the environment, except wasting cold-producing medium and lubricating oil, increase maintenance cost, also aggravates environmental pollution.Purpose of the present invention, be in order to overcome the deficiencies in the prior art, a kind of refrigerating agent containing oil and production technique thereof have been invented, in refrigeration pipe system, have under the situation of refrigeration agent, need not to use the maintenance process flow process that vacuumizes, just can directly replenish and add refrigeration agent and lubricating oil, simplified maintenance process, reduce maintenance cost, also reduced environmental pollution.
Summary of the invention
The objective of the invention is in order to overcome the defective of above-mentioned prior art, a kind of refrigerating agent containing oil and production technique thereof are provided, can solve the waste refrigeration agent of above-mentioned existence and lubricating oil, increase maintenance cost reliably, problems such as aggravation environmental pollution, simplified maintenance process, reduce maintenance cost, also reduced environmental pollution.
Technical scheme of the present invention is: a kind of refrigerating agent containing oil, mainly form by the mixture of sealed refrigerant and lubricating oil in pressurized vessel and the pressurized vessel.
Described pressurized vessel is the pressurized vessel of the general corresponding refrigeration agent of can, the refrigeration agent difference of institute's can, and the requirement of withstand voltage of pressurized vessel is just different, must meet the requirement of relevant pressurized vessel corresponding standard.
Described refrigeration agent claims refrigeration working medium again, is the working medium of refrigeration cycle, utilizes the phase transformation of refrigeration agent to transmit heat, heat absorption when both refrigeration agent is vaporized in vaporizer, heat release when condensing in condenser.Current energy has kind more than 80 as the material of cold-producing medium, and the most frequently used is ammonia, fluorine Lyons class, water and minority hydrocarbon etc., to the whole CFC classes of R11, R12, R113, R114, R115, R502 and the R22 etc. in fluorine Lyons and carbon tetrachloride (CCL
4), methyl chloroform (C
2H
3CL
3) etc., limited at present or forbid producing, now, substantially use R123 among the HCFC and R134a as the substitute of R12 and R22 etc.R134a (HFC-134a C
2H
2F
4) be widely used in the automotive air-conditioning system at present.
Described lubricating oil, it is refrigerator oil, corresponding refrigeration agent composition difference, the corresponding difference of the composition of lubricating oil, the lubricating oil that is used for refrigeration compressor, in ISO 6743/3B classification,, refrigerator oil is divided into DRA, DRB, DRC and DRD kind according to the component characteristic of refrigerator oil, the service temperature of vaporizer and the type of used refrigeration agent.The refrigerator oil of the GB/T 16630 of China's promulgation in 1996 is divided into two big class: L-DRA, L-DRB/B.At present, adopt in the system of R134a cold-producing medium, lubricating oil can adopt polyether oil, and polyether oil is with oxirane (C
2H
4O), expoxy propane (C
3H
6O) and oxolane (C
3H
8The linear polymer that makes of open loop homopolymerization or copolymerization such as O).Its performance and molecular structure are closely related.The type of oxirane and ratio in the molecular chain, the classification of terminal group and concentration, initiator hydrocarbon chain structure and length, and pfpe molecule amount size and distribution etc. all influence their viscosity, viscosity index, condensation point, solvability and thermo-oxidative stability to some extent, can be according to actual needs, adjust molecular structure, obtain a series of polymkeric substance of different nature that have.Lubricating oil is in fact a kind ofly different kinds of molecules to be arranged by the different proportion composition mixture, does not have the molecular formula of standard, represents that with its main component the polyethers compressor oil is the molecular formula N of such combination
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O, N
1, N
2, N
3Be constant, N
1, N
2, N
3Ratio between the numerical value, the linear polymer that makes after the mixing are that the characteristic of lubricating oil is also different.
In sum, with R134a (HFC-134a C
2H
2F
4) cold-producing medium and polyethers compressor oil (N
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O) mixing filling is example, and its main component can be expressed like this: X%C
2H
4O+ (100-X) % (N
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O), X% is the part by weight of cold-producing medium in mixture, (100-X) % is the part by weight of lubricating oil in mixture, equally, setting A is that cold-producing medium, B are and the supporting lubricating oil of cold-producing medium, a kind of refrigerating agent containing oil of the present invention then, its composition shows as X%A+ (100-X) %B.According to actual service experience, the numerical value of X gets 85 to 95, and is proper, and promptly among the present invention, refrigeration agent accounts for 85% to 95% content, and lubricating oil accounts for 5% to 15% content.Cold-producing medium and lubricating oil also can mix by arbitrary proportion.
The production technique of this invention is fairly simple, mainly realizes by can.Earlier the air of pressurized vessel is extracted out, be evacuated down to prescribed value, connect lubricating pipe then, can suck lubricating oil automatically, when lubricants capacity reaches (100-X) %, close lubricating pipe, connect refrigerant tubing, the refrigeration agent of can X% amount, like this, by the lubricating oil and the refrigeration agent of priority can certainweight in pressurized vessel, realized that lubricating oil and refrigeration agent have been filled in the same pressurized vessel, because lubricating oil and refrigeration agent have mutual solubility, fluctuation through transportation or other processes, when the arrival user uses, just contain sufficient lubricating oil in the refrigeration agent, the repairman can directly use the refrigeration agent that contains of the present invention that the refrigeration pipe that keeps in repair is replenished interpolation.
A kind of refrigerating agent containing oil provided by the invention, can solve problems such as the waste refrigeration agent that exists in the refrigeration system maintenance and lubricating oil, increase maintenance cost, aggravation environmental pollution reliably, simplified maintenance process, reduced maintenance cost, also reduce environmental pollution, had the good social dissemination.
Description of drawings
Fig. 1: embodiments of the invention composition synoptic diagram;
Fig. 2: a kind of universaling component synoptic diagram of the present invention.
Implementation
Below in conjunction with Fig. 1,2, embodiments of the invention are described.In the accompanying drawing, N
1, N
2, N
3Be constant, C
2H
2F
4Be R134a cold-producing medium, C
2H
4O is oxirane, C
3H
6O is expoxy propane, C
3H
8O is oxolane, N
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O is the polyethers compressor oil, and X% is amount of refrigerant, and (100-X) % is lubricating oil content, and A is cold-producing medium, and B is lubricating oil.
A kind of refrigerating agent containing oil and production technique thereof mainly are made up of the mixture of sealed refrigerant and lubricating oil in pressurized vessel and the pressurized vessel.
Described pressurized vessel is the pressurized vessel of the general corresponding refrigeration agent of can.
Described cold-producing medium, present embodiment are mainly with R134a (HFC-134a C
2H
2F
4) be example, be widely used in the automotive air-conditioning system at present.
Described lubricating oil, mainly with and R134a (HFC-134a C
2H
2F
4) supporting polyethers compressor oil is example.Polyether oil is with oxirane (C
2H
4O), expoxy propane (C
3H
6O) and oxolane (C
3H
8The linear polymer that makes of open loop homopolymerization or copolymerization such as O), the polyethers compressor oil is the molecular formula N of such combination
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O, N
1, N
2, N
3Be constant, N
1, N
2, N
3Ratio between the numerical value, the linear polymer that makes after the mixing are that the characteristic of lubricating oil is also different.
With R134a (HFC-134a C
2H
2F
4) cold-producing medium and polyethers compressor oil (N
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O) mixing filling is example, and its main component can be expressed like this: X%C
2H
4O+ (100-X) % (N
1C
2H
4O+N
2C
3H
6O+N
3C
3H
8O), X% is the part by weight of cold-producing medium in mixture, (100-X) % is the part by weight of lubricating oil in mixture, equally, setting A is that cold-producing medium, B are and the supporting lubricating oil of cold-producing medium, a kind of refrigerating agent containing oil of the present invention then, its composition shows as X%A+ (100-X) %B.According to actual service experience, the numerical value of X gets 85 to 95, and is proper, and promptly among the present invention, refrigeration agent accounts for 85% to 95% content, and lubricating oil accounts for 5% to 15% content.Refrigeration agent and lubricating oil also can mix arbitrarily.
The production technique of this invention is fairly simple, mainly realizes by can.Earlier the air of pressurized vessel is extracted out, be evacuated down to prescribed value, connect lubricating pipe then, automatically suck lubricating oil, when lubricants capacity reaches (100-X) %, close lubricating pipe, connect refrigerant tubing, the refrigeration agent of can X% amount, like this, by the lubricating oil and the refrigeration agent of priority can certainweight in pressurized vessel, realized that lubricating oil and refrigeration agent have been filled in the same pressurized vessel, because lubricating oil and refrigeration agent have mutual solubility, fluctuation through transportation or other processes, when the arrival user uses, just contain sufficient lubricating oil in the refrigeration agent, the repairman can directly use the refrigeration agent that contains of the present invention that the refrigeration pipe that keeps in repair is replenished interpolation.
A kind of refrigerating agent containing oil provided by the invention, can solve problems such as the waste refrigeration agent that exists in the refrigeration system maintenance and lubricating oil, increase maintenance cost, aggravation environmental pollution reliably, simplified maintenance process, reduced maintenance cost, also reduce environmental pollution, had the good social dissemination.
Claims (3)
1. refrigerating agent containing oil and production technique thereof is characterized in that being made up of the mixture of sealed refrigerant in the pressurized vessel and lubricating oil, and refrigeration agent accounts for 85-95% weight, and lubricating oil accounts for the weight of 5-15%.
2. a kind of refrigerating agent containing oil according to claim 1 and production technique thereof is characterized in that the weight blending ratio of refrigeration agent and lubricating oil is arbitrarily.
3. a kind of refrigerating agent containing oil according to claim 1 and production technique thereof is characterized in that production technique is to extract the air of pressurized vessel out, sucks lubricating oil, then the can refrigeration agent automatically.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101009921A CN102226074A (en) | 2011-04-20 | 2011-04-20 | Oil-containing refrigerant and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101009921A CN102226074A (en) | 2011-04-20 | 2011-04-20 | Oil-containing refrigerant and production process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102226074A true CN102226074A (en) | 2011-10-26 |
Family
ID=44807073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101009921A Pending CN102226074A (en) | 2011-04-20 | 2011-04-20 | Oil-containing refrigerant and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102226074A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112283054A (en) * | 2020-10-12 | 2021-01-29 | 国家电投集团广西金紫山风电有限公司 | Waste oil discharge control method, device, equipment and medium |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6089032A (en) * | 1998-10-28 | 2000-07-18 | Interdynamics Inc. | Method of retrofitting air conditioner and system therefor |
| WO2002026913A2 (en) * | 2000-09-27 | 2002-04-04 | Honeywell International Inc. | Fluorocarbon refrigerant compositions |
| CN1890355A (en) * | 2003-10-21 | 2007-01-03 | 联合碳化化学及塑料技术公司 | Refrigerant composition |
| CN200965380Y (en) * | 2006-09-27 | 2007-10-24 | 蒋友荣 | A portable refrigerant recovery and filling machine with oil separator |
| CN101864278A (en) * | 2009-06-12 | 2010-10-20 | 苏威氟有限公司 | Refrigerant composition |
-
2011
- 2011-04-20 CN CN2011101009921A patent/CN102226074A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6089032A (en) * | 1998-10-28 | 2000-07-18 | Interdynamics Inc. | Method of retrofitting air conditioner and system therefor |
| WO2002026913A2 (en) * | 2000-09-27 | 2002-04-04 | Honeywell International Inc. | Fluorocarbon refrigerant compositions |
| CN1890355A (en) * | 2003-10-21 | 2007-01-03 | 联合碳化化学及塑料技术公司 | Refrigerant composition |
| CN200965380Y (en) * | 2006-09-27 | 2007-10-24 | 蒋友荣 | A portable refrigerant recovery and filling machine with oil separator |
| CN101864278A (en) * | 2009-06-12 | 2010-10-20 | 苏威氟有限公司 | Refrigerant composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112283054A (en) * | 2020-10-12 | 2021-01-29 | 国家电投集团广西金紫山风电有限公司 | Waste oil discharge control method, device, equipment and medium |
| CN112283054B (en) * | 2020-10-12 | 2024-01-30 | 国家电投集团广西金紫山风电有限公司 | Waste oil discharge control method, device, equipment and medium |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| DD01 | Delivery of document by public notice |
Addressee: Guo Weiming Document name: Notification of Patent Invention Entering into Substantive Examination Stage |
|
| DD01 | Delivery of document by public notice |
Addressee: Guo Weiming Document name: Notification that Application Deemed to be Withdrawn |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20111026 |