CN102225814B - Fluorine-containing waste water processing apparatus and processing method thereof - Google Patents
Fluorine-containing waste water processing apparatus and processing method thereof Download PDFInfo
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- CN102225814B CN102225814B CN2011100925973A CN201110092597A CN102225814B CN 102225814 B CN102225814 B CN 102225814B CN 2011100925973 A CN2011100925973 A CN 2011100925973A CN 201110092597 A CN201110092597 A CN 201110092597A CN 102225814 B CN102225814 B CN 102225814B
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- 239000002351 wastewater Substances 0.000 title claims abstract description 63
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 239000011737 fluorine Substances 0.000 title claims abstract description 10
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 10
- 238000003672 processing method Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000002699 waste material Substances 0.000 claims abstract description 19
- 239000010802 sludge Substances 0.000 claims abstract description 15
- 239000003814 drug Substances 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 57
- 238000002156 mixing Methods 0.000 claims description 28
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 19
- 239000000706 filtrate Substances 0.000 claims description 19
- 239000013505 freshwater Substances 0.000 claims description 15
- 238000004065 wastewater treatment Methods 0.000 claims description 10
- 238000001784 detoxification Methods 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 4
- -1 bucket Substances 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 231100000167 toxic agent Toxicity 0.000 claims description 3
- 239000003440 toxic substance Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 229940079593 drug Drugs 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 14
- 230000008569 process Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005189 flocculation Methods 0.000 description 6
- 230000016615 flocculation Effects 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000005352 clarification Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010786 composite waste Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 230000009347 mechanical transmission Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Removal Of Specific Substances (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a fluorine-containing waste water processing apparatus. A technical scheme of the apparatus is characterized in that: the apparatus comprises a waste water pool, a clean water pool, a sludge pool, a self-priming tank, a waste water pump, a purifier and a clean water pump; the waste water pool, the self-priming tank and the waste pump are connected in sequence through pipelines; an outlet of the waste water pump is connected to the lower part of the purifier through an inlet tube; the upper part of the purifier is provided with an opening, the opening part is provided with an upper cover, the upper cover is provided with a first through hole, the first through hole is provided with an inlet pipeline of the clean water pump, and an outlet pipeline of the clean water pump is connected to the clean water pool; and the lower part of the purifier is connected with the sludge pool through a sludge discharge tube, and the front end of the waste water pump is provided with a drug adding pipeline. The invention also discloses a fluorine-containing waste water processing method. The technical scheme of the present invention has the characteristics of thoroughly waste water processing and qualified discharge.
Description
Technical field
The present invention relates to a kind of wastewater processing technology, specifically, relate to a kind of fluoride waste treatment unit and treatment process thereof.
Background technology
In the industry, often contain the fluorochemical of high density in the waste water of industries such as fluorine-containing ore extraction, Metal smelting, aluminium processing, coke, glass, electronics, plating, chemical fertilizer, agricultural chemicals discharging, cause environmental pollution.For these fluoride wastes, present domestic majority factory does not still have perfect processing and does not execute, and the fluorine content's index does not reach discharging standards as yet in the waste water that is discharged, and severe contamination human environment of depending on for existence.According to national industrial wastewater discharge standard, fluorinion concentration should be less than 10mg/L; For tap water, fluorinion concentration requires below 1mg/L.The treatment process of fluoride waste has multiple, and method commonly used both at home and abroad roughly is divided into two types, i.e. the precipitator method and absorption method.
At present both at home and abroad to containing the composite waste of soda acid, oils and various heavy metal ion etc.; Usually adopt three-step approach (neutralization reaction pond-settling tank-strainer) to handle, the subject matter of existence is that treatment scheme is long, floor space is big, energy consumption is high and the management trouble.
Chinese patent notification number 101289260; Disclose name and be called " the Treatment of acidic fluoride-containing waste water system and method after a kind of graphite is purified "; Treatment system wherein comprises third order reaction pond or retort and the purification settling tank of one-level at least; Suspention has medicament reservoir in the reaction tank of each grade, is provided with deposition residue chamber at the bottom of the pond, on the purification settling tank of each grade, is equipped with high-pressure sprayer; Method of wastewater treatment is that waste water gets into first reaction tank, adds calcium cpd and is settled out the F in the waste water
-And metals ion; Get into second reaction tank, add alkali lye and flocculation agent, in waste water and be settled out residual metal ions; Get into the 3rd reaction tank, add aluminium salt and make waste water be neutralized into neutrality; Get into and purify settling tank, precipitate, filter out the harmful suspended substance in the waste water.Its weak point is that wastewater treatment is not thorough, and the water reuse rate is low.
Summary of the invention
The technical problem that the present invention solved provides a kind of fluoride waste treatment unit, have wastewater treatment thoroughly, the characteristics of emission compliance.
In order to solve the technical problem of above-mentioned existence, the technical scheme that the present invention adopts is following:
A kind of fluoride waste treatment unit; Comprise wastewater disposal basin, clean water basin and sludge sump; Also comprise self-sucking pot, waste water pump, cleaner and fresh water pump, said cleaner comprises first reaction chamber, second reaction chamber, mixing section, separate chamber, nozzle, filtrate, bucket, water inlet pipe and shell; Said first reaction chamber, second reaction chamber, mixing section, separate chamber, nozzle, filtrate and bucket are positioned at the inside of said shell; The bottom of said shell is taper, and the bottom of said shell is provided with bucket, and said filtrate is arranged on top, said separate chamber; Said wastewater disposal basin, self-sucking pot and waste water pump are connected through pipeline successively; Said waste water pump outlet is connected to the bottom of said cleaner through water inlet pipe; Said cleaner upper opening is provided with loam cake at said opening part, and the top of said loam cake has first through hole; Said first through hole is provided with the entrance pipe of fresh water pump; The outlet pipeline of said fresh water pump is connected to clean water basin, and the bottom of said cleaner connects said sludge sump through shore pipe, is provided with dosing pipe at the front end of said waste water pump.
Further: said dosing pipe is provided with dosing valve.
Further: the top of said loam cake has second through hole, and said second through hole is provided with upflow tube, and the said upflow tube the other end connects said clean water basin.
Further: said first reaction chamber and mixing section are flared structure, and the less end of bore is together interconnection, and said mixing section is positioned at the said first reaction chamber bottom; Said second reaction chamber is columnar structured, and opening one end is buckled in the top of said first reaction chamber.
Further: the space outerpace of said second reaction chamber is the separate chamber; Said nozzle is arranged on the end of said water inlet pipe, and it is inner to be positioned at said mixing section, and the other end of said water inlet pipe connects the water outlet of said waste water pump.
Another technical problem that the present invention solved provides a kind of fluorine-containing wastewater treatment method, have wastewater treatment thoroughly, the characteristics of emission compliance.
In order to solve the technical problem of above-mentioned existence, the technical scheme that the present invention adopts is following:
A kind of fluorine-containing wastewater treatment method comprises:
Fluoride waste is squeezed into wastewater disposal basin earlier; Carry out preliminary sedimentation; Open the dosing valve on waste water pump and the dosing pipe, the upper clear supernate that deposition is good in the said wastewater disposal basin is squeezed into cleaner through said waste water pump, the water inlet pipe of waste water bottom said cleaner that adds an amount of medicament gets into said cleaner inside; Spray through nozzle; Said nozzle top is the mixing section and first reaction chamber, and said nozzle and mixing section are formed an ejector, and the high velocity jet of said nozzle ejection contains the cleaner bottom in the said mixing section of water inspiration of flocs unit and mixes with water inlet; Overflow entering second reaction chamber through the said first reaction chamber hydraucone, said first reaction chamber and second reaction chamber have constituted the suspended substance district, and the said second reaction chamber water outlet gets into the separate chamber, and supernatant penetrates the filtrate overflow and discharges, and form sludge blanket at bucket;
In cleaner, carry out detoxification and purify, the mud in the bucket is squeezed into said sludge sump through shore pipe;
Clear water after up to standard extracts through fresh water pump and is discharged in the clean water basin, and when the clear water overflow took place, clear water was discharged in the said clean water basin through upflow tube.
Preferably: when said cleaner stops, closing dosing valve and water intaking valve earlier, close down said waste water pump and fresh water pump again.
Preferably: in cleaner, carry out detoxification and purify, the gac of the current behind the detoxification in filtrate done further absorption removal with toxic substance in the water and throw out.
Compared with prior art, the invention has the beneficial effects as follows:
1, technical scheme wastewater treatment of the present invention is thorough, and the water quality after the processing can reach the standard of three types of water quality that country can qualified discharge.
2, the whole technological process of technical scheme of the present invention is simple to operate, and the soup of being convenient to control adding is calcium hydroxide and flocculation agent.
3, technical scheme running cost of the present invention is low, is convenient to realize.The processing cost of waste water per ton only has less than 100 yuan, so the advance of its technology and cost are low has incomparable advantage.
4, technical scheme of the present invention can be practiced thrift sewage treatment equipment investment 35-40%;
5, technical scheme compact construction of the present invention can reduce floor space 30%, practices thrift initial cost 20-30%;
6, in the technical scheme of the present invention, treatment scheme is simplified greatly, operational administrative and easy for installation;
7, in the technical scheme of the present invention, equipment does not have voice, and is stable, inner no mechanical transmission consumable accessory;
8, technical scheme less investment of the present invention, last detective connects water pump and just can come into operation after equipment puts in place.
9, technical scheme of the present invention is prone to installing/dismounting, and the integral body in storehouse has mobility, can move to fixedly preservation and freshness of different location flexibly, also can carry fresh-keeping power and realize transportation fresh-retaining.
10, in the technical scheme of the present invention, the water that will pass through a series of processes processing returns settling tank or cycling and reutilization.Significantly reduced discharged waste water and promptly protected water resources, had and have obvious social and economic benefit.
11, technical scheme of the present invention mainly is applicable to the composite waste that produces in the industrial sector production processes such as plating, electroceramics, store battery; Can effectively remove objectionable impuritiess such as various heavy metal ions in waste water, prussiate, silt and suspended substance; Water after the processing reaches discharging standards, and can supply industry multiplexing.
12, technical scheme of the present invention is applicable to the improvement of the muddy surface water, coal washing water, system muddy water, and it can effectively be removed turbidity, floating class, mikrobe in the water, smell flavor etc., and the clear water turbidity after the processing reaches the standard of national tap water less than 3mgk.This equipment is specially adapted to the tap water of middle samll cities and towns, industrial enterprise and sub-district, rural area and supplies with, and says that in a sense a cleaner is exactly a waterworks, and this goes up rising with the feedwater exploitation of regions of the world at home.
Description of drawings
Fig. 1 is the schema of fluoride waste treatment process among the present invention;
Fig. 2 is the structure iron of cleaner among the present invention;
Fig. 3 purifies the schema that fluoride waste is handled among the present invention.
Embodiment
Below with reference to exemplary preferred embodiments and reference drawings, technical scheme of the present invention is done detailed description.
As shown in Figure 1; The structure of fluoride waste treatment unit comprises: wastewater disposal basin 101, self-sucking pot 102, waste water pump 103, cleaner 104, clean water basin 105, sludge sump 106 and fresh water pump 107; Said structure is connected through pipeline; Front end at waste water pump 103 is provided with dosing pipe 110, and dosing pipe 110 is provided with dosing valve 111.The effect of self-sucking pot 102 mainly is the diversion source that when start is provided for waste water pump, guarantees that 24 hours arbitrary time opened waste water pump 103 water outlet rapidly, and needn't in addition past again waste water pump 103 interior water fillings.In addition, in order to prevent overflow, draw upflow tube 108 on cleaner 104 tops, upflow tube 108 the other ends connect clean water basin 105; For the ease of maintenance, the upper opening of cleaner 104, and be provided with loam cake 109, and loam cake 109 tops have two through holes, are used to be provided with the entrance pipe of upflow tube 108 and fresh water pump 107, and the outlet pipeline of fresh water pump 107 is connected to clean water basin 105.Wherein, the outlet of waste water pump 103 is connected to the bottom of cleaner 104 through water inlet pipe 1048, and the bottom of cleaner 104 connects sludge sumps 106 through shore pipe 110.
As shown in Figure 2, be the structure iron of cleaner 104 among the present invention.The internal structure of cleaner 104 comprises first reaction chamber 1041, second reaction chamber 1042, mixing section 1043, separate chamber 1044, nozzle 1045, filtrate 1046, bucket 1047, water inlet pipe 1048 and shell 1049; First reaction chamber 1041, second reaction chamber 1042, mixing section 1043, separate chamber 1044, nozzle 1045, filtrate 1046, bucket 1047 are positioned at the inside of shell 1049; The bottom of shell 1049 is taper, and bucket 1047 is arranged on the bottom of shell 1049, and shell 1049 upper openings also are provided with loam cake 109; First reaction chamber 1041 is a flared structure with mixing section 1043, and the less end of bore is together interconnection, and mixing section 1043 is positioned at first reaction chamber, 1041 bottoms; Second reaction chamber 1042 is columnar structured, and opening one end is buckled in the top of first reaction chamber 1041; The space outerpace of second reaction chamber 1042 is separate chamber 1044; Filtrate 1046 is arranged on 1044 tops, separate chamber; Nozzle 1045 is arranged on the end of water inlet pipe 1048, and is positioned at mixing section 1043 inside, and the other end of water inlet pipe 1048 connects the water outlet of waste water pump 103.
Cleaner 104 is mainly based on principle and other physics and the chemism work of condensing with oxidation in the chemical reduction; Its inside is divided into 5 districts; Be respectively high-speed eddy reaction zone, the slow reaction zone of gradual change, suspension clarification settling region, powerful suction zone and mud enrichment region, wherein, the internal space of mixing section 1043 forms the high-speed eddy reaction zone; The internal space of first reaction chamber 1041 forms the slow reaction zone of gradual change; The internal space of second reaction chamber 1042 forms the clarification settling region that suspends, and the space of separate chamber 1044 forms powerful suction zone, and the internal space of bucket 1047 forms the mud enrichment region.
As shown in Figure 3, be to purify the schema that fluoride waste is handled among the present invention.Elaborate in the face of purifying method of the present invention down.
1, fluoride waste is squeezed into wastewater disposal basin 101 earlier, carry out preliminary sedimentation;
2, open waste water pump 103 and dosing valve 111, the upper clear supernate that deposition in the wastewater disposal basin 101 is good is squeezed into cleaner 104 through waste water pump 103;
Add water inlet pipe 1048 entering cleaners 104 inside of the waste water of an amount of medicament by cleaner 104 bottoms, through nozzle 1045 ejections, nozzle 1045 tops are the mixing section 1043 and first reaction chamber 1041.Nozzle 1045 is formed an ejector with mixing section 1043; The high velocity jet of nozzle 1045 ejections contains the pond conical lower portion water inspiration mixing section 1043 interior and water inlet mixing of a large amount of flocs units; After first reaction chamber, 1041 hydraucones overflow, get in second reaction chamber 1042.First reaction chamber and second reaction chamber have constituted a suspended substance district, and 1042 water outlets of second reaction chamber get into separate chamber 1044, and supernatant penetrates filtrate 1046 overflows and discharges; Various oxyhydroxide form slime layer, and throw out sedimentation under the self gravitation effect is constantly arranged, and form sludge blanket at bucket 1047.Filtrate 1046 is selected light filter material for use, and its density is overflowed to prevent filtrate 1046 so cleaner 104 tops need be provided with loam cake 109 less than water.
In this process, add medicines such as Ca (OH) 2, oxygenant and flocculation agent through dosing pipe 110, mix through jet, Ca (OH) 2, oxygenant and flocculation agent and waste water thorough mixing add NaOH adjustment pH value to neutral, adjust to usually between the pH value 6～8.Flocculation agent can be one or more in the high-performance flocculation agents such as white lake, poly-aluminum ferric chloride sulfate, Poly aluminum Chloride (PAC) or poly-epoxy succinic acid, and inorganic flocculating agent has Tai-Ace S 150, iron trichloride, Poly aluminum Chloride (PAC), bodied ferric sulfate etc. available.
3, in cleaner 104, carrying out detoxification purifies;
It is exactly with the F in the water that detoxification purifies
-With chromium ion and some other heavy metal ion and water sepn.Cleaner 104 combines jet mixing, reaction, clarification, sloping plate deposition and filtrate 1046 filtration procedurees.
4, the mud of bucket 1047 is squeezed into sludge sump 106 through shore pipe 110, further can squeeze into and carry out press filtration in the pressure filter, and filter cake is collected pack;
Behind the cleaner 104 running certain hours, need timely spoil disposal, spoil disposal 1-2 consuming time minute.
5, activated carbon filtration;
The gac of current behind the detoxification in filtrate 1046 done further absorption removal with toxic substance in the water and throw out.
6, draining up to standard.
Clear water after up to standard extracts through fresh water pump 107 and is discharged in the clean water basin 105, if the clear water overflow takes place, then clear water is discharged in the clean water basin 105 through upflow tube 108.
When cleaner stops, closing dosing valve 111 and water intaking valve earlier, close down waste water pump 103, fresh water pump 107 again.During cleaner 104 operation, delivery turbidity needs back flushing during greater than 3mgk; The sample of will often getting in service is observed change of water quality, in time adjusts dosage; After waste water pump 103 abundant stirrings, impel water to gather into thin mud layer, rely on action of gravity to slide back the body refuse suspended layer, sink to bucket 1047 then, remaining small flco is filtered by filtrate 1046.As find that water quality degenerates, and should take corresponding measure, amount when intaking as reducing increases or reduces dose, gets rid of mud, carries out back flushing etc.
Claims (8)
1. fluoride waste treatment unit; Comprise wastewater disposal basin, clean water basin and sludge sump; It is characterized in that: also comprise self-sucking pot, waste water pump, cleaner and fresh water pump, said cleaner comprises first reaction chamber, second reaction chamber, mixing section, separate chamber, nozzle, filtrate, bucket, water inlet pipe and shell; Said first reaction chamber, second reaction chamber, mixing section, separate chamber, nozzle, filtrate and bucket are positioned at the inside of said shell; The bottom of said shell is taper, and the bottom of said shell is provided with bucket, and said filtrate is arranged on top, said separate chamber; Said wastewater disposal basin, self-sucking pot and waste water pump are connected through pipeline successively; Said waste water pump outlet is connected to the bottom of said cleaner through water inlet pipe; Said cleaner upper opening is provided with loam cake at said opening part, and the top of said loam cake has first through hole; Said first through hole is provided with the entrance pipe of fresh water pump; The outlet pipeline of said fresh water pump is connected to clean water basin, and the bottom of said cleaner connects said sludge sump through shore pipe, is provided with dosing pipe at the front end of said waste water pump.
2. fluoride waste treatment unit as claimed in claim 1 is characterized in that: said dosing pipe is provided with dosing valve.
3. fluoride waste treatment unit as claimed in claim 2 is characterized in that: the top of said loam cake has second through hole, and said second through hole is provided with upflow tube, and the said upflow tube the other end connects said clean water basin.
4. like each described fluoride waste treatment unit of claim 1-3, it is characterized in that: said first reaction chamber and mixing section are flared structure, and the less end of bore is together interconnection, and said mixing section is positioned at the said first reaction chamber bottom; Said second reaction chamber is columnar structured, and opening one end is buckled in the top of said first reaction chamber.
5. fluoride waste treatment unit as claimed in claim 4 is characterized in that: the space outerpace of said second reaction chamber is the separate chamber; Said nozzle is arranged on the end of said water inlet pipe, and it is inner to be positioned at said mixing section, and the other end of said water inlet pipe connects the water outlet of said waste water pump.
6. fluorine-containing wastewater treatment method comprises:
Fluoride waste is squeezed into wastewater disposal basin earlier; Carry out preliminary sedimentation; Open the dosing valve on waste water pump and the dosing pipe, the upper clear supernate that deposition is good in the said wastewater disposal basin is squeezed into cleaner through said waste water pump, the water inlet pipe of waste water bottom said cleaner that adds an amount of medicament gets into said cleaner inside; Spray through nozzle; Said nozzle top is the mixing section and first reaction chamber, and said nozzle and mixing section are formed an ejector, and the high velocity jet of said nozzle ejection contains the cleaner bottom in the said mixing section of water inspiration of flocs unit and mixes with water inlet; Overflow entering second reaction chamber through the said first reaction chamber hydraucone, said first reaction chamber and second reaction chamber have constituted the suspended substance district, and the said second reaction chamber water outlet gets into the separate chamber, and supernatant penetrates the filtrate overflow and discharges, and form sludge blanket at bucket;
In cleaner, carry out detoxification and purify, the mud in the bucket is squeezed into said sludge sump through shore pipe;
Clear water after up to standard extracts through fresh water pump and is discharged in the clean water basin, and when the clear water overflow took place, clear water was discharged in the said clean water basin through upflow tube.
7. fluorine-containing wastewater treatment method as claimed in claim 6 is characterized in that: when said cleaner stops, closing dosing valve and water intaking valve earlier, close down said waste water pump and fresh water pump again.
8. fluorine-containing wastewater treatment method as claimed in claim 6 is characterized in that: in cleaner, carry out detoxification and purify, the gac of the current behind the detoxification in filtrate done further absorption removal with toxic substance in the water and throw out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100925973A CN102225814B (en) | 2011-04-13 | 2011-04-13 | Fluorine-containing waste water processing apparatus and processing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100925973A CN102225814B (en) | 2011-04-13 | 2011-04-13 | Fluorine-containing waste water processing apparatus and processing method thereof |
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| CN1616362A (en) * | 2004-07-28 | 2005-05-18 | 汤世伟 | Automatic processing process for acid waste water containing fluorine |
| CN101157507A (en) * | 2006-09-22 | 2008-04-09 | 栗田工业株式会社 | Treatment method of fluorine-containing wastewater |
| CN201301260Y (en) * | 2008-11-13 | 2009-09-02 | 山东华安新材料有限公司 | Equipment system of fluoride waste water processing technique |
| WO2010092946A1 (en) * | 2009-02-13 | 2010-08-19 | 株式会社神鋼環境ソリューション | Method for processing waste water containing fluorine and silicon, method for producing calcium fluoride, and facility for processing fluorine-containing waste water |
| CN101941752A (en) * | 2010-09-05 | 2011-01-12 | 中南大学 | Method and device for treating fluorine-containing waste water |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1616362A (en) * | 2004-07-28 | 2005-05-18 | 汤世伟 | Automatic processing process for acid waste water containing fluorine |
| CN101157507A (en) * | 2006-09-22 | 2008-04-09 | 栗田工业株式会社 | Treatment method of fluorine-containing wastewater |
| CN201301260Y (en) * | 2008-11-13 | 2009-09-02 | 山东华安新材料有限公司 | Equipment system of fluoride waste water processing technique |
| WO2010092946A1 (en) * | 2009-02-13 | 2010-08-19 | 株式会社神鋼環境ソリューション | Method for processing waste water containing fluorine and silicon, method for producing calcium fluoride, and facility for processing fluorine-containing waste water |
| CN101941752A (en) * | 2010-09-05 | 2011-01-12 | 中南大学 | Method and device for treating fluorine-containing waste water |
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