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CN102180646A - Non-base-return color ceramic tile joint mixture - Google Patents

Non-base-return color ceramic tile joint mixture Download PDF

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Publication number
CN102180646A
CN102180646A CN2011100331335A CN201110033133A CN102180646A CN 102180646 A CN102180646 A CN 102180646A CN 2011100331335 A CN2011100331335 A CN 2011100331335A CN 201110033133 A CN201110033133 A CN 201110033133A CN 102180646 A CN102180646 A CN 102180646A
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China
Prior art keywords
percent
accumulation
salt
vinyl acetate
surface soil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011100331335A
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Chinese (zh)
Inventor
田凤兰
段文峰
韩朝辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Oriental Yuhong Waterproof Technology Co., Ltd.
Xuzhou Woniushan New Waterproof Material Co., Ltd.
Beijing Oriental Yuhong Waterproof Technology Co Ltd
Original Assignee
Beijing Oriental Yuhong Waterproof Technology Co Ltd
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Publication date
Application filed by Beijing Oriental Yuhong Waterproof Technology Co Ltd filed Critical Beijing Oriental Yuhong Waterproof Technology Co Ltd
Priority to CN2011100331335A priority Critical patent/CN102180646A/en
Publication of CN102180646A publication Critical patent/CN102180646A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a safe environment-friendly non-base-return color ceramic tile joint mixture. The safe environment-friendly non-base-return color ceramic tile joint mixture comprises the following components in percentage by weight: 30 to 50 percent of white cement, 40 to 75 percent of filler, 0.03 to 0.30 percent of cellulose ether, 0.50 to 5 percent of adhesive, 0.05 to 0.40 percent of cellulose fiber, 0 to 0.10 percent of chemical fiber, 0 to 0.40 percent of thixotropic agent, 0 to 0.70 percent of water reducing agent, 0 to 0.80 percent of retarder, 0 to 0.4 percent of mildew preventive, 0 to 0.25 percent of water repellent and 0 to 5 percent of ferric oxide series pigment. The safe environment-friendly non-base-return color ceramic tile joint mixture can solve the base return problem of the joint mixture radically and has the advantages of moderate price, safety, environmental friendliness, convenience of production, transportation and storage, wide usable range and the like.

Description

No accumulation of salt in the surface soil color tile grout
Technical field
The present invention relates between the buildings indoor and outdoor ceramic tile slit fills used a kind of safety and environmental protection and does not have accumulation of salt in the surface soil color tile grout.
Background technology
Along with the development of society, ceramic tile has become one of material the most frequently used in the building decoration.For fear of producing hollowing owing to expanding with heat and contract with cold between ceramic tile and the ceramic tile, need between ceramic tile and the ceramic tile to reserve certain slit, this slit need be filled with material of construction.At first, used packing material by ordinary white silicate cement and coarse whiting or other white fillers by a certain percentage field mix form.Because the packing material rigidity that this scene arbitrarily mixes is big, aquation is insufficient, water regain reaches shortcomings such as color dullness greatly, cracking, dry linting, shortcoming such as not attractive in appearance often appear in packing material, and rainwater is easy to enter the ceramic tile back side, through freeze-thaw cycle cause the ceramic tile hollowing, phenomenon such as come off.At these problems that occur, domestic scholars is also studied.By analyzing, the main method one that adopts is to use the ordinary white silicate cement as inorganic coagulation material, and re-dispersible glue powder is as the organic gel gel material, and ether of cellulose is as water-holding agent, and silica powder is as filler.Though can solve defectives such as cracking that traditional ceramic tile pointing occurs, efflorescence by these methods to a certain extent,, thereby produce to a certain degree the accumulation of salt in the surface soil because the ordinary white silicate cement hydration is produced the calcium hydroxide product in the system.Can reduce the degree of the accumulation of salt in the surface soil by adding some properties-correcting agent, take place but can not fundamentally stop this phenomenon.Method two is to use reactive resin as adhesive material, and solidifying agent is as initiator, and inert material is as filler.Though this material can thoroughly solve accumulation of salt in the surface soil problem, prepare by a certain percentage at the scene of need, causes construction inconvenient, has hidden danger of quality, certain smell is also arranged, dangerous environmental protection, price height simultaneously.Method three is to use emulsion as the organic gel gel material, and inert material is as filler, and both mix.Though this material can thoroughly solve accumulation of salt in the surface soil problem, exist and produce, transport and the storage inconvenience, the wavelength width of a slit of being filled and the degree of depth all have certain limitation, and curing speed is slow.
Summary of the invention
In order to solve above-mentioned deficiency of the prior art, the invention provides a kind of safety and environmental protection does not have accumulation of salt in the surface soil color tile grout.Advantages such as this tile grout not only can thoroughly solve the accumulation of salt in the surface soil problem of spackling, and has moderate cost, and safety and environmental protection is produced, transported and stores conveniently, and use range is wide.
The invention provides a kind of safety and environmental protection does not have accumulation of salt in the surface soil color tile grout, and it comprises following component by weight percentage:
Extraordinary white cement 30%-50%;
Filler 40%-75%;
Ether of cellulose 0.03%-0.30%;
Tackiness agent 0.50%-5%;
Lignin fibre 0.05%-0.40%;
Man-made fiber 0%-0.10%;
Thixotropic agent 0%-0.40%;
Water reducer 0%-0.70%;
Retardant 0%-0.80%;
Mould inhibitor 0%-0.4%;
Hydrophober 0%-0.25%;
Pigment 0%-5%.
Described extraordinary white cement be No. 42.5 white quick hardening sulphoaluminate cements or alumina content at the white aluminate cement more than 70%, described filler is a kind of or two kinds in median size 40 orders~600 purpose quartz or the median size 40 orders~600 purpose coarse whitings.
Described ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and viscosity is between 10000mPa.s~40000mPa.s.
Described tackiness agent is one or more in vinyl acetate and ethylene copolymer rubber powder, ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder, vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder, vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder, vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder or the vinylformic acid homopolymerization rubber powder.
Described man-made fiber is one or more in polypropylene fibre, polyacrylonitrile fibre, trevira, polyethylene fibre or the polyvinyl alcohol fiber, and described mean fibre length is between 1mm~8mm.
Described thixotropic agent is a kind of in calcium-base bentonite thixotropic agent or the sodium bentonite thixotropic agent or two kinds, and described water reducer is a kind of in melamine high-efficiency water-reducing agent or the polycarboxylate water-reducer or two kinds.
Described retardant is one or more in gluconic acid, Sunmorl N 60S, calglucon, citric acid, Trisodium Citrate, tartrate or the sodium tartrate.
Described mould inhibitor is that N-(fluorine dichloromethane sulfenyl) phthalic imidine, 2-xenol, copper 8-quinolinolate, methylsulfonyl tetrachloro are given a tongue-lashing pyridine, 2-(thiazole-4-yl) benzoglyoxaline, 2-benzimidazole carbamate, 4-chloro-3, one or more in 5-xylenol or 1-(<Chloro-O-Phenyl〉diphenyl methyl) imidazoles.
Described hydrophober is organosilicon series hydrophober, and described pigment is ferric oxide series pigment.
Adopt safety and environmental protection provided by the invention not have the accumulation of salt in the surface soil problem that accumulation of salt in the surface soil color tile grout not only can thoroughly solve spackling, and have moderate cost, safety and environmental protection, advantages such as producing, transport and storage makes things convenient for, and use range is wide.
Embodiment
For further setting forth the present invention, provide embodiment below and illustrate.
In the present invention, described extraordinary white cement is No. 42.5 white quick hardening sulphoaluminate cements, and described filler is 300 orders~400 order coarse whitings.
Described ether of cellulose is a hydroxypropyl methyl cellulose ether, and viscosity is at 35000mPa.s~45000Pa.s.
Described tackiness agent is ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder.
Described man-made fiber is a polypropylene fibre, length 3mm.
Described thixotropic agent is a calcium-base bentonite, and described water reducer is a melamine high-efficiency water-reducing agent.
Described retardant is a Sunmorl N 60S.
Described mould inhibitor is N-(fluorine dichloromethane sulfenyl) phthalic imidine.
Described hydrophober is organosilicon moisture repellent, and described pigment is black iron oxide pigment.
Based on above-mentioned scope, the present invention provides first embodiment, and the concrete weight proportion of each component is as follows:
42.5 number white quick hardening sulphoaluminate cement 450.0;
300 orders~400 order coarse whitings 522.0;
Hydroxypropyl methyl cellulose ether 0.5;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 15.0;
Lignin fibre 1.5;
Polypropylene fibre 0.5;
Thixotropic agent 1.0;
Water reducer 2.0;
Retardant 4.0;
Mould inhibitor 1.5;
Hydrophober 2.0;
Pigment 0.
Based on above-mentioned scope, the present invention provides second embodiment, and the concrete weight proportion of each component is as follows:
42.5 number white quick hardening sulphoaluminate cement 350.0;
300 orders~400 order coarse whitings 579.8;
Hydroxypropyl methyl cellulose ether 1.0;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 20.0;
Lignin fibre 1.5;
Polypropylene fibre 0.2;
Thixotropic agent 1.0;
Water reducer 5.0;
Retardant 3.0;
Mould inhibitor 1.0;
Hydrophober 2.5;
Pigment 35.
Based on above-mentioned scope, the present invention provides the 3rd embodiment, and the concrete weight proportion of each component is as follows:
42.5 number white quick hardening sulphoaluminate cement 400.0;
300 orders~400 order coarse whitings 551.0;
Hydroxypropyl methyl cellulose ether 0.3;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 15.0;
Lignin fibre 2.0;
Polypropylene fibre 0.2;
Thixotropic agent 2.0;
Water reducer 3.0;
Retardant 4.0;
Mould inhibitor 1.5;
Hydrophober 1.0;
Pigment 20.
Based on above-mentioned scope, the present invention provides the 4th embodiment, and the concrete weight proportion of each component is as follows:
42.5 number white quick hardening sulphoaluminate cement 500.0;
300 orders~400 order coarse whitings 400.5;
Hydroxypropyl methyl cellulose ether 1.0;
Ethene and vinylchlorid and month silicic acid vinyl acetate rubber powder 35.0;
Lignin fibre 3.5;
Polypropylene fibre 0.5;
Thixotropic agent 3.0;
Water reducer 1.0;
Retardant 6.0;
Mould inhibitor 3.0;
Hydrophober 1.5;
Pigment 45.
The above-mentioned color tile grout that the present invention provides, performance satisfy CG1 type index request among the industry standard JC/T1004-2006 " ceramic wall and floor tile gap filler " fully, and the specific examples detected result is as follows:
Table 1 (example one, two, three, four detected results)
Figure BSA00000430457500061
Figure BSA00000430457500071

Claims (9)

1. no accumulation of salt in the surface soil color tile grout is characterized in that: comprise following component by weight percentage:
Extraordinary white cement 30%-50%;
Filler 40%-75%;
Ether of cellulose 0.03%-0.3%;
Tackiness agent 0.5%-5%;
Lignin fibre 0.05%-0.4%;
Man-made fiber 0%-0.1%;
Thixotropic agent 0%-0.4%;
Water reducer 0%-0.7%;
Retardant 0%-0.8%;
Mould inhibitor 0%-0.4%;
Hydrophober 0%-0.25%;
Pigment 0%-5%.
2. no accumulation of salt in the surface soil color tile grout according to claim 1, it is characterized in that: described extraordinary white cement be No. 42.5 white quick hardening sulphoaluminate cements or alumina content at the white aluminate cement more than 70%, described filler is median size 40 orders~600 purpose quartz or median size 40 orders~600 purpose coarse whitings or its mixture.
3. no accumulation of salt in the surface soil color tile grout according to claim 1 is characterized in that: described ether of cellulose is hydroxyethylmethyl-cellulose ether or hydroxypropyl methyl cellulose ether, and its viscosity is between 10000mPa.s~40000mPa.s.
4. no accumulation of salt in the surface soil color tile grout according to claim 1 is characterized in that: described tackiness agent is vinyl acetate and ethylene copolymer rubber powder, ethene and vinylchlorid and month silicic acid vinyl acetate terpolymer rubber powder, vinyl acetate and ethene and higher fatty acid vinyl acetate terpolymer rubber powder, vinyl acetate and higher fatty acid vinyl acetate copolymerization rubber powder, vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder, vinylformic acid homopolymerization rubber powder or its mixture.
5. no accumulation of salt in the surface soil color tile grout according to claim 1, it is characterized in that: described man-made fiber is polypropylene fibre, polyacrylonitrile fibre, trevira, polyethylene fibre, polyvinyl alcohol fiber or its mixture, and described mean fibre length is between 1mm~8mm.
6. no accumulation of salt in the surface soil color tile grout according to claim 1, it is characterized in that: described thixotropic agent is calcium-base bentonite thixotropic agent, sodium bentonite thixotropic agent or its mixture, and described water reducer is melamine high-efficiency water-reducing agent, polycarboxylate water-reducer or its mixture.
7. no accumulation of salt in the surface soil color tile grout according to claim 1 is characterized in that: described retardant is gluconic acid, Sunmorl N 60S, calglucon, citric acid, Trisodium Citrate, tartrate, sodium tartrate or its mixture.
8. no accumulation of salt in the surface soil color tile grout according to claim 1; it is characterized in that: described mould inhibitor is that N-(fluorine dichloromethane sulfenyl) phthalic imidine, 2-xenol, copper 8-quinolinolate, methylsulfonyl tetrachloro are given a tongue-lashing pyridine, 2-(thiazole-4-yl) benzoglyoxaline, 2-benzimidazole carbamate, 4-chloro-3,5-xylenol, 1-(<Chloro-O-Phenyl〉diphenyl methyl) or its mixture.
9. no accumulation of salt in the surface soil color tile grout according to claim 1 is characterized in that: described hydrophober is organosilicon series hydrophober, and described pigment is ferric oxide series pigment.
CN2011100331335A 2011-01-31 2011-01-31 Non-base-return color ceramic tile joint mixture Pending CN102180646A (en)

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Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503302A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 High-strength ceramic tile tackiness agent
CN102503301A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 Safe environment-friendly colored anti-efflorescence ceramic tile gap filler
CN102977821A (en) * 2012-12-31 2013-03-20 郑州大学 Preparation method of caulk compound special for rest room
CN103102123A (en) * 2012-12-17 2013-05-15 重庆市百世得建材有限公司 Environmentally-friendly interior wall putty powder and preparation method thereof
CN103420658A (en) * 2013-08-13 2013-12-04 潘保华 Tile seam filling agent
CN103467055A (en) * 2013-09-12 2013-12-25 德高(广州)建材有限公司 Mosaic binding agent integrating two purposes of binding and joint filling
CN103482930A (en) * 2013-09-12 2014-01-01 德高(广州)建材有限公司 Sticking waterproof three-in-one mosaic adhesive filling joints
CN103613339A (en) * 2013-11-21 2014-03-05 武汉鲁邦建材有限公司 Special adhering and sealing material for cement-based mosaic tile and preparation and using method thereof
CN105174805A (en) * 2015-09-19 2015-12-23 孙军 Waterproof accelerant of toilet ground gap filling agent and preparation method
CN105198317A (en) * 2015-09-19 2015-12-30 孙军 Building curtain wall joint mixture, preparation method and use method
CN105236880A (en) * 2015-08-31 2016-01-13 北京东泰富博新材料科技股份有限公司 Cement-based joint filling agent composition containing diatomite and application thereof
CN105272026A (en) * 2015-09-19 2016-01-27 孙军 Building top caulking agent and preparation method and application method thereof
CN105330249A (en) * 2015-11-26 2016-02-17 上海域金澜优电子商务有限公司 Production formula of seam beautifying agent with silver ions
CN105418034A (en) * 2015-12-28 2016-03-23 上海亚瓦新型建筑材料有限公司 Mosaic crack filler composition and preparation method thereof
CN105819796A (en) * 2016-06-13 2016-08-03 浙江共创建材科技有限公司 Joint mixture for thermal insulation material
CN105884286A (en) * 2016-04-10 2016-08-24 欧振云 Ceramic tile crack beautifying agent
CN106380143A (en) * 2016-08-30 2017-02-08 派丽(上海)管理有限公司 Temperature-variable cement-based colored caulking compound with lasting effect
CN107117906A (en) * 2017-06-14 2017-09-01 合肥易美特建材有限公司 A kind of tile grout and preparation method thereof
CN108101468A (en) * 2017-12-04 2018-06-01 华砂砂浆有限责任公司 A kind of tile grout
CN108359395A (en) * 2018-02-27 2018-08-03 合肥尚涵装饰工程有限公司 A kind of one pack system waterproof cracking resistance wall and floor tile gap filler and preparation method thereof
CN109231939A (en) * 2018-11-15 2019-01-18 东方雨虹民用建材有限责任公司 A kind of one-component paste gap filler and preparation method thereof
CN109336523A (en) * 2018-12-25 2019-02-15 佛山科学技术学院 A kind of anti-mildew waterproof tile grout and preparation method thereof
CN111333391A (en) * 2020-04-15 2020-06-26 福州市宇心建材科技有限公司 A kind of PTB jointing agent and construction method for waterproof treatment of bathroom tile joints

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CN101475354A (en) * 2008-10-29 2009-07-08 汕头经济特区龙湖科技有限公司 Anti-crystalline bloom exterior wall facing mortar
CN101817666A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Dry-powder color tile grout and preparation process thereof

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CN101125749A (en) * 2007-08-01 2008-02-20 深圳大学 A kind of hydraulic modulation aluminum phosphate color cement
CN101475354A (en) * 2008-10-29 2009-07-08 汕头经济特区龙湖科技有限公司 Anti-crystalline bloom exterior wall facing mortar
CN101817666A (en) * 2009-02-26 2010-09-01 北京东方雨虹防水技术股份有限公司 Dry-powder color tile grout and preparation process thereof

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503301A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 Safe environment-friendly colored anti-efflorescence ceramic tile gap filler
CN102503302A (en) * 2011-10-27 2012-06-20 北京东方雨虹防水技术股份有限公司 High-strength ceramic tile tackiness agent
CN103102123A (en) * 2012-12-17 2013-05-15 重庆市百世得建材有限公司 Environmentally-friendly interior wall putty powder and preparation method thereof
CN102977821A (en) * 2012-12-31 2013-03-20 郑州大学 Preparation method of caulk compound special for rest room
CN103420658A (en) * 2013-08-13 2013-12-04 潘保华 Tile seam filling agent
CN103467055A (en) * 2013-09-12 2013-12-25 德高(广州)建材有限公司 Mosaic binding agent integrating two purposes of binding and joint filling
CN103482930A (en) * 2013-09-12 2014-01-01 德高(广州)建材有限公司 Sticking waterproof three-in-one mosaic adhesive filling joints
WO2015035840A1 (en) * 2013-09-12 2015-03-19 德高(广州)建材有限公司 Three-in-one mosaic adhesive for pasting, seam-filling and water-resisting
CN103613339A (en) * 2013-11-21 2014-03-05 武汉鲁邦建材有限公司 Special adhering and sealing material for cement-based mosaic tile and preparation and using method thereof
CN103613339B (en) * 2013-11-21 2016-08-31 湖北鲁邦建材股份有限公司 A kind of cement base mosaic special stickup pointing and preparation, using method
CN105236880A (en) * 2015-08-31 2016-01-13 北京东泰富博新材料科技股份有限公司 Cement-based joint filling agent composition containing diatomite and application thereof
CN105272026A (en) * 2015-09-19 2016-01-27 孙军 Building top caulking agent and preparation method and application method thereof
CN105198317A (en) * 2015-09-19 2015-12-30 孙军 Building curtain wall joint mixture, preparation method and use method
CN105174805A (en) * 2015-09-19 2015-12-23 孙军 Waterproof accelerant of toilet ground gap filling agent and preparation method
CN105330249A (en) * 2015-11-26 2016-02-17 上海域金澜优电子商务有限公司 Production formula of seam beautifying agent with silver ions
CN105418034A (en) * 2015-12-28 2016-03-23 上海亚瓦新型建筑材料有限公司 Mosaic crack filler composition and preparation method thereof
CN105884286A (en) * 2016-04-10 2016-08-24 欧振云 Ceramic tile crack beautifying agent
CN105819796A (en) * 2016-06-13 2016-08-03 浙江共创建材科技有限公司 Joint mixture for thermal insulation material
CN106380143A (en) * 2016-08-30 2017-02-08 派丽(上海)管理有限公司 Temperature-variable cement-based colored caulking compound with lasting effect
CN107117906A (en) * 2017-06-14 2017-09-01 合肥易美特建材有限公司 A kind of tile grout and preparation method thereof
CN108101468A (en) * 2017-12-04 2018-06-01 华砂砂浆有限责任公司 A kind of tile grout
CN108101468B (en) * 2017-12-04 2021-02-23 华砂砂浆有限责任公司 Tile joint mixture
CN108359395A (en) * 2018-02-27 2018-08-03 合肥尚涵装饰工程有限公司 A kind of one pack system waterproof cracking resistance wall and floor tile gap filler and preparation method thereof
CN109231939A (en) * 2018-11-15 2019-01-18 东方雨虹民用建材有限责任公司 A kind of one-component paste gap filler and preparation method thereof
CN109231939B (en) * 2018-11-15 2021-06-01 东方雨虹民用建材有限责任公司 Single-component paste joint mixture and preparation method thereof
CN109336523A (en) * 2018-12-25 2019-02-15 佛山科学技术学院 A kind of anti-mildew waterproof tile grout and preparation method thereof
CN111333391A (en) * 2020-04-15 2020-06-26 福州市宇心建材科技有限公司 A kind of PTB jointing agent and construction method for waterproof treatment of bathroom tile joints

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