CN102153908A - Aqueous dye ink for broad-width piezoelectric printer - Google Patents
Aqueous dye ink for broad-width piezoelectric printer Download PDFInfo
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- CN102153908A CN102153908A CN2011100703906A CN201110070390A CN102153908A CN 102153908 A CN102153908 A CN 102153908A CN 2011100703906 A CN2011100703906 A CN 2011100703906A CN 201110070390 A CN201110070390 A CN 201110070390A CN 102153908 A CN102153908 A CN 102153908A
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Abstract
The invention relates to aqueous dye ink for a broad-width piezoelectric printer. The aqueous dye ink is characterized by mainly comprising the following components in percentage by weight: 2-5 percent of dye, 5-40 percent of humectant, 1-10 percent of viscosity modifier, 0-1 percent of bactericide, 0-1 percent of chelating agent, 0-1 percent of pH buffering agent, 0-5 percent of surfactant and the balance of deionized water. The aqueous dye ink for the broad-width piezoelectric printer has the characteristic of high printing adaptability to the recently arisen home-made piezoelectric printer, including printing smoothness, printing stability, shutdown to startup starting performance, response frequencies of different driving voltages, wide color gamut representation and excellent storage stability.
Description
Technical field
The present invention relates to a kind of aqueous dye ink, particularly a kind of aqueous dye ink that is applicable to wide cut piezoelectricity printer.
Background technology
Printer can be divided into ink-jet, laser, heat sublimation, stylus printer.Domestic in the past wide format printer all is a dependence on import, and main brand mainly contains MUTOH, ROLAND, MIMAKI, EPSON and CANON etc.It is all meticulousr that the printer mainboard control of import is done, and temperature sensor is also arranged, and the temperature of perception nozzle surface is also bigger to the latitude of ink set at any time.And the fine degree that home-made machine is done in this respect is more poor, and this is just to the demands for higher performance of ink.And the driving voltage waveform that a lot of homemade wide cut piezoelectricity printers are arranged at present is manually control, there are not such intelligence of import machine and automatization, this just requires to adjust parameters such as the viscosity of ink and surface tension, makes it have in wide region more adaptability to different driving voltage.No matter it is exactly colour print that any printing simultaneously has a common to call.Wherein with ink-jet with the fastest developing speed, captured the huge market.Especially large-breadth printing (air brushing, description) is the rapidest in the China's Mainland development, now basic realization production domesticization except that shower nozzle and motor.Almost can contend with import equipment.Formed the huge market at home.No matter we can see that whole printing industry is in research and development, still making, still promoting and using in all vigorous growths.
At the market requirement, the present invention has developed a kind ofly can have fine adaptive aqueous dye ink on wide cut piezoelectricity printer.
Summary of the invention
The purpose of this invention is to provide a kind of fine adaptive aqueous dye ink that on wide cut piezoelectricity printer, has.
The objective of the invention is to reach by the following technical programs:
A kind of wide cut piezoelectricity printer use dye ink is characterized in that mainly being made up of following proportioning component:
1-5 weight % dyestuff; The wetting Agent for Printing Inks of 5-40 weight %; 1-10 weight % viscosity modifier; 0-1 weight % sterilant; 0-1 weight % sequestrant; 0-1 weight %pH buffer reagent; The 0-5% tensio-active agent; Surplus is a deionized water.
A kind of optimal technical scheme is characterized in that: described dyestuff is a sun blue 199, and is directly yellow 132, REACTIVE Red 195 or directly black 168.
A kind of optimal technical scheme is characterized in that: described wetting Agent for Printing Inks is a glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1,5-pentanediol, the mixing of Virahol or their arbitrary proportions.
A kind of optimal technical scheme, it is characterized in that: described viscosity modifier is a glycerol, TriMethylolPropane(TMP), Macrogol 200, poly(oxyethylene glycol) 400, SMA1440(polystyrene maleic anhydride 1440) or the mixing of their arbitrary proportions Polyethylene Glycol-600, SMA1000H(polystyrene maleic anhydride 1000H).
A kind of optimal technical scheme is characterized in that: described sterilant is 1 of GXL(20%, the dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone).
A kind of optimal technical scheme is characterized in that: described sequestrant is EDTA(ethylenediamine tetraacetic acid (EDTA) (Ethylene Diamine Tetraacetic Acid)).
A kind of optimal technical scheme is characterized in that: described pH buffer reagent is Tris (Tutofusin tris).
A kind of optimal technical scheme, it is characterized in that: described tensio-active agent is the BYK345(polyether modified siloxane), SA-07(modification alcohol ethoxylate, 8390(alkyl diphenyl ether disulfonate)) or the mixing of their arbitrary proportions the broken bubble of BYK020(polysiloxane solution).
Wide cut piezoelectricity printer use dye ink of the present invention to the kind of viscosity modifier and content requirement than higher, polyoxyethylene glycol series can significantly change viscosity parameter, but also can have influence on rate of drying.SMA series can change viscosity, but amplitude is not clearly.TriMethylolPropane(TMP) can relatively significantly change viscosity, and can well control rate of drying.
Wide cut piezoelectricity printer aqueous dye ink of the present invention has good printing adaptability to homemade piezoelectricity printer, comprise the startability of printing fluency, printing stability, shut down and start shooting again, the response frequency of different driving voltage, wide colour gamut performance and good stability in storage.
The homemade wide cut piezoelectricity of the present invention printer aqueous dye ink has good stability in storage.
The homemade wide cut piezoelectricity of the present invention printer aqueous dye ink has good responsiveness under the southern and northern condition of different temperatures.
The present invention will be further described below by the drawings and specific embodiments, but and do not mean that limiting the scope of the invention.
Description of drawings
Fig. 1 adds viscosity modifier (TMP (TriMethylolPropane(TMP)), PEG-600 (Polyethylene Glycol-600), PEG1000 (cetomacrogol 1000)), the viscograph of JV33 original C (original-pack China ink) ink.
Fig. 2 adds viscosity modifier SMA1000H(polystyrene maleic anhydride 1000H), SMA1440 (polystyrene maleic anhydride 1440), the viscograph of the ink of JV33 original ink (original-pack China ink).
Fig. 3 is the viscograph that adds the ink of viscosity modifier glycerine and TriMethylolPropane(TMP).
Fig. 4 is the viscograph of ink 1 of the present invention.
Fig. 5 is the temperature variant curve of the surface tension of ink 1 of the present invention.
Embodiment
Wide cut piezoelectricity printer use dye ink of the present invention, its proportioning is as follows:
3.0 the dyestuff sun blue 199 of weight %;
The glycerine of 25 weight %, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:10:2:2:1(weight) mixed solution formed of ratio;
5 weight % TriMethylolPropane(TMP)s;
0.1 weight %GXL;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.05 weight %BYK345;
66.65 weight % deionized water.
The preparation method:
With 25 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:10:2:2:1(weight) mixed solution formed of ratio puts into reactor, add 5 weight % TriMethylolPropane(TMP)s again, 1 of 0.1 weight %GXL(20%, the dipropylene glycol aqueous solution of 2-benzisothiazole-3-ketone), 0.1 weight %EDTA(ethylenediamine tetraacetic acid (EDTA) (Ethylene Diamine Tetraacetic Acid)), 0.1 weight %Tris (Tutofusin tris), 0.05 weight %BYK345(polyether modified siloxane), 66.65 weight % deionized waters, stirring at low speed to solution is clarified, and adds 3.0 weight % dyestuff sun blue 199 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 1.
Wide cut piezoelectricity printer use dye ink, its proportioning is as follows:
3.5 weight % dye activity red 195;
20 weight % glycerine;
8 weight % TriMethylolPropane(TMP)s;
0.1 weight %GXL;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.05 weight %BYK345;
68.15 weight % deionized water.
The preparation method:
20 weight % glycerine are put into reactor, add 8 weight % TriMethylolPropane(TMP)s again, 0.1 weight %GXL, 0.1 weight %EDTA, 0.1 weight %Tris (Tutofusin tris), 0.05 weight %BYK345,68.15 weight % deionized waters, stirring at low speed to solution is clarified, and adds 3.5 weight % dye activities red 195 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 2.
Homemade wide cut piezoelectricity printer use dye ink, its proportioning is as follows:
2.4 weight % is Huang 132 directly;
28 weight % Diethylene Glycol butyl ether;
5 weight % Macrogol 200s;
0.1 weight %GXL;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.05 weight %BYK345;
64.25 weight % deionized water.
The preparation method:
28 weight % Diethylene Glycol butyl ether are put into reactor, add 5 weight % Macrogol 200s again, 0.1 weight %GXL, 0.1 weight %EDTA, 0.1 weight %Tris (Tutofusin tris), 0.05 weight %BYK345,64.25 weight % deionized waters, stirring at low speed to solution is clarified, and adds directly Huang 132 of 2.4 weight % dyestuffs again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 3.
Wide cut piezoelectricity printer aqueous dye ink, its proportioning is as follows:
4.5 weight % dyestuff directly deceives 168;
20 weight %2-methyl-2, the 4-pentanediol;
5 weight % TriMethylolPropane(TMP)s;
0.1 weight %GXL;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.05 weight %BYK345;
70.15 weight % deionized water.
The preparation method:
With 20 weight % 2-methyl-2, the 4-pentanediol is put into reactor, add 5 weight % TriMethylolPropane(TMP)s again, 0.1 weight %GXL, 0.1 weight %EDTA, 0.1 weight %Tris (Tutofusin tris), 0.05 weight %BYK345,70.15 weight % deionized water, stirring at low speed to solution is clarified, and adds 4.5 weight % dyestuffs again and directly deceives 168.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 4.
Wide cut piezoelectricity printer aqueous dye ink, its proportioning is as follows:
1.0 weight % dyestuff directly deceives 168;
20 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 3:5:8:2:1:1(weight) mixed solution of ratio;
5 weight %SMA1440;
0.1 weight %EDTA;
0.1 weight %Tris (Tutofusin tris);
0.05 weight %BYK345;
73.75 weight % deionized water.
The preparation method:
With 20 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1, the 5-pentanediol, Virahol is with 3:5:8:2:1:1(weight) mixed solution of ratio puts into reactor, adds 5 weight %SMA1440 again, 0.1 weight %EDTA, 0.1 weight %Tris (Tutofusin tris), 0.05 weight %BYK345,73.75 weight % deionized waters, stirring at low speed to solution is clarified, and adds 1.0 weight % dyestuffs again and directly deceives 168.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 5.
Wide cut piezoelectricity printer aqueous dye ink, its proportioning is as follows:
5 weight % dyestuffs directly deceive 168;
20 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 3:5:8:2:1:1(weight) mixed solution of ratio;
3 weight % Polyethylene Glycol-600s;
0.1 weight %GXL;
0.1 weight %Tris (Tutofusin tris);
0.02 the broken bubble of weight %BYK020(polysiloxane solution);
0.1 weight 8390(cetyl diphenyl ether sodium disulfonate);
0.15% weight SA-07(modification alcohol ethoxylate);
71.53 weight % deionized water.
The preparation method:
With 20 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol 3:5:8:2:1:1(weight) proportioning concentration is put into reactor, add 3 weight % Polyethylene Glycol-600s again, 0.1 weight %GXL, 0.1 weight %Tris (Tutofusin tris), 0.02 weight %BYK020,0.1 weight 8390(cetyl diphenyl ether sodium disulfonate); 0.15% weight SA-07(modification alcohol ethoxylate), 71.35 weight % deionized waters, stirring at low speed to solution is clarified, and adds 5 weight % dyestuffs again and directly deceives 168.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 6.
Embodiment 7
Wide cut piezoelectricity printer aqueous dye ink of the present invention, its proportioning is as follows:
2.5 the dyestuff sun blue 199 of weight %;
40 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 10:5:10:5:5:5(weight) mixed solution of ratio;
5 weight % Polyethylene Glycol-600s;
1 weight %GXL;
1 weight %EDTA;
1 weight %Tris (Tutofusin tris);
49.5 weight % deionized water.
The preparation method:
With 40 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1, the 5-pentanediol, Virahol is with 10:5:10:5:5:5(weight) mixed solution of ratio puts into reactor, adds 5 weight % Polyethylene Glycol-600s again, 1 weight %GXL, 1 weight %EDTA, 1 weight %Tris (Tutofusin tris), 49.5 weight % deionized waters, stirring at low speed to solution is clarified, and adds 2.5 weight % dyestuff sun blue 199 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 7.
Wide cut piezoelectricity printer aqueous dye ink of the present invention, its proportioning is as follows:
2.5 the dyestuff sun blue 199 of weight %;
25 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio;
5 weight %SMA 1000H;
0.05 weight %GXL;
0.02 weight %EDTA;
0.03 weight %Tris (Tutofusin tris);
67.4 weight % deionized water.
The preparation method:
With 25 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio puts into reactor, adds 5 weight %SMA1000H again, 0.1 weight %GXL, 0.1 weight %EDTA, 0.1 weight %Tris (Tutofusin tris), 67.4 weight % deionized waters, stirring at low speed to solution is clarified, and adds 2.5 weight % dyestuff sun blue 199 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 8.
Embodiment 9
Wide cut piezoelectricity printer aqueous dye ink of the present invention, its proportioning is as follows:
2.5 the dyestuff sun blue 199 of weight %;
25 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio;
5 weight %SMA 1000H;
67.5 weight % deionized water.
The preparation method:
With 25 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio puts into reactor, add 5 weight %SMA1000H again, 67.5 weight % deionized water, stirring at low speed to solution is clarified, and adds 2.5 weight % dyestuff sun blue 199 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 9.
Wide cut piezoelectricity printer aqueous dye ink of the present invention, its proportioning is as follows:
2.5 the dyestuff sun blue 199 of weight %;
25 weight % glycerine, ethylene glycol, the Diethylene Glycol butyl ether, 2-methyl-2, the 4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio;
5 weight %SMA 1000H;
1 weight %GXL;
1 weight %EDTA;
1 weight %Tris (Tutofusin tris);
5 weight %SA-07(modification alcohol ethoxylates);
59.5 weight % deionized water.
The preparation method:
With 25 weight % glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1, the 5-pentanediol, Virahol is with 5:5:8:3:3:1(weight) mixed solution of ratio puts into reactor, adds 5 weight %SMA1000H again, 1 weight %GXL, 1 weight %EDTA, 1 weight %Tris (Tutofusin tris), 5 weight %SA-07(modification alcohol ethoxylates), 59.5 weight % deionized water, stirring at low speed to solution is clarified, and adds 2.5 weight % dyestuff sun blue 199 again.After 2 hours, filter the degassing in high-speed stirring, packing gets dye ink 10.
Need to prove that the inventor is limit all similar prescriptions of the present invention not.Those of ordinary skills also can reach identical goal of the invention according to technical scheme of the present invention with essentially identical prescription, also belong to protection scope of the present invention.
Testing method:
1. print performance: respectively get dye ink 1 of the present invention, dye ink 2, dye ink 3 and dye ink 4 1L install on the wind of homemade piezoelectricity wide cut printer universe and print test, change the oscillogram of different driving voltages, carry out the printing of various patterns.
2. startability: printer has been adorned shutdown after 10 square metres of the ink printed, directly printing of week back start.
3. viscograph: get 30 gram dye inks 1, attemperation every viscosity of 5 ℃ of tests, is made the change curve of viscosity with temperature from 15 ℃-40 ℃.See accompanying drawing 1-4.Shown in Fig. 1-2, the viscosity of each viscosity modifier all descends with the rising of temperature.Though wherein PEG600 and PEG1000 can regulate the more approaching of viscograph and original-pack China ink, they add ink set, and the rate of drying of ink can be slack-off, thus the imaged image quality.And TriMethylolPropane(TMP) promptly can be regulated viscograph and original-pack China ink is more approaching, can well regulate rate of drying again.As shown in Figure 3, along with the increase of the content of viscosity modifier, the viscosity of ink increases thereupon.And glycerine and TriMethylolPropane(TMP) to influence trend comparison approaching.As shown in Figure 4, the rising of the viscosity with temperature of dye ink 1 of the present invention and descending.
4. surface tension curve: get 30 grams dye ink 1 of the present invention, attemperation from 15 ℃-40 ℃ every 5 ℃ of test one-time surface tension force, make surface tension with the variation of temperature curve.As shown in Figure 5, be the ink that the embodiment of the invention 1 makes, total trend be to rise with temperature to descend, but be in very little scope, to fluctuate, surface tension is not violent especially variation with temperature.
Stability in storage: dye ink 1 of the present invention is put under 60 ℃ and-20 ℃ of conditions test physical and chemical performance and print performance after aging January.
The fundamental performance parameter of ink of the present invention sees the following form:
Table 1
| ? | pH | Surface tension (mN/m) | Viscosity (cP) | Specific conductivity (ms/cm) |
| |
8.732 | 27.5 | 3.2 | 3.86 |
| |
8.456 | 27.3 | 3.3 | 4.05 |
| |
8.654 | 27.3 | 3.2 | 2.95 |
| |
8.786 | 27.5 | 3.4 | 4.56 |
As above shown in the table 1, wherein, pH measures under 25 ℃ of conditions with E-201-C type combined electrode; Surface tension is measured under 25 ℃ of conditions with the full-automatic surface tension instrument of BZY-1 type; Viscosity is measured under 25 ℃ of conditions with SNB-AI digital-type intelligent viscometer; Specific conductivity DDS-307A conductivitimeter is measured under 25 ℃ of conditions.
The pH value of the above ink of the present invention is more stable, and between 8.0-9.0, specific conductivity is between 2.0-5.0ms/cm, and long-term the printing do not have corrosion to shower nozzle.Capillary scope can well adapt to the printing requirement of homemade piezoelectricity wide cut printer.The viscosity change curve can adapt to homemade piezoelectricity wide cut printer and carry out works better under different temperature condition.
Claims (8)
1. wide cut piezoelectricity printer use dye ink is characterized in that mainly containing following proportioning component and forms:
1-5 weight % dyestuff;
5-40 weight % wetting Agent for Printing Inks;
1-10 weight % viscosity modifier;
0-1 weight % sterilant;
0-1 weight % sequestrant;
0-1 weight %pH buffer reagent;
The 0-5% tensio-active agent;
Surplus is a deionized water.
2. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described dyestuff is a sun blue 199, and is directly yellow 132, REACTIVE Red 195 or directly black 168.
3. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described wetting Agent for Printing Inks is a glycerine, ethylene glycol, Diethylene Glycol butyl ether, 2-methyl-2,4-pentanediol, 1,5-pentanediol, the mixing of Virahol or its arbitrary proportion.
4. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described viscosity modifier is a glycerol, TriMethylolPropane(TMP), Macrogol 200, poly(oxyethylene glycol) 400, Polyethylene Glycol-600, SMA1000H, the mixing of SMA1440 or its arbitrary proportion.
5. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described sterilant is GXL.
6. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described sequestrant is EDTA.
7. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described pH buffer reagent is a Tutofusin tris.
8. wide cut piezoelectricity printer use dye ink according to claim 1, it is characterized in that: described tensio-active agent is BYK345, BYK020,8390, the mixing of SA-07 or its arbitrary proportion.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102304306A (en) * | 2011-10-17 | 2012-01-04 | 北京联创佳艺影像新材料技术有限公司 | Water-based dye ink for jet printing of black and white images |
| CN102585590A (en) * | 2012-03-08 | 2012-07-18 | 北京联创佳艺影像新材料技术有限公司 | Digital-printing active ink suitable for wide-width micro-piezoelectric printer |
| CN105331197A (en) * | 2015-11-03 | 2016-02-17 | 北京联创佳艺影像新材料技术有限公司 | Ink for digital printing and imaging on aluminum plate and preparation method thereof |
| CN106243777A (en) * | 2016-08-15 | 2016-12-21 | 泉州市山水电脑耗材有限公司 | Middle Resist Reactive Dyes 195 bright red stability of pigment paste formula and preparation method thereof |
| CN109266091A (en) * | 2018-09-20 | 2019-01-25 | 珠海荣威添彩打印耗材有限公司 | A kind of ink process |
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| CN1453316A (en) * | 2002-04-23 | 2003-11-05 | 中国乐凯胶片集团公司 | Aqueous jet printing ink |
| CN101240129A (en) * | 2007-02-09 | 2008-08-13 | 上海中大科技发展有限公司 | Ink-jet ink composition used for photosensitive plate fabrication and fabricating method thereof |
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| CN1343747A (en) * | 2000-09-20 | 2002-04-10 | 三星电子株式会社 | Ink compsn. for ink-jet printer |
| US20020137816A1 (en) * | 2001-03-22 | 2002-09-26 | Xerox Corporation | Phase change inks |
| CN1453316A (en) * | 2002-04-23 | 2003-11-05 | 中国乐凯胶片集团公司 | Aqueous jet printing ink |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102304306A (en) * | 2011-10-17 | 2012-01-04 | 北京联创佳艺影像新材料技术有限公司 | Water-based dye ink for jet printing of black and white images |
| CN102585590A (en) * | 2012-03-08 | 2012-07-18 | 北京联创佳艺影像新材料技术有限公司 | Digital-printing active ink suitable for wide-width micro-piezoelectric printer |
| CN105331197A (en) * | 2015-11-03 | 2016-02-17 | 北京联创佳艺影像新材料技术有限公司 | Ink for digital printing and imaging on aluminum plate and preparation method thereof |
| CN106243777A (en) * | 2016-08-15 | 2016-12-21 | 泉州市山水电脑耗材有限公司 | Middle Resist Reactive Dyes 195 bright red stability of pigment paste formula and preparation method thereof |
| CN109266091A (en) * | 2018-09-20 | 2019-01-25 | 珠海荣威添彩打印耗材有限公司 | A kind of ink process |
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Application publication date: 20110817 |