CN102145554B - Environment-friendly recyclable basalt fiber and fibrilia automobile door plate and preparation process thereof - Google Patents
Environment-friendly recyclable basalt fiber and fibrilia automobile door plate and preparation process thereof Download PDFInfo
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- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000000835 fiber Substances 0.000 claims abstract description 94
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 239000004743 Polypropylene Substances 0.000 claims abstract description 24
- 229920001155 polypropylene Polymers 0.000 claims abstract description 24
- 239000012792 core layer Substances 0.000 claims abstract description 22
- 239000002344 surface layer Substances 0.000 claims abstract description 21
- -1 polypropylene Polymers 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 6
- 229920000728 polyester Polymers 0.000 claims description 16
- 239000010410 layer Substances 0.000 claims description 13
- 244000025254 Cannabis sativa Species 0.000 claims description 11
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 11
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 11
- 235000009120 camo Nutrition 0.000 claims description 11
- 235000005607 chanvre indien Nutrition 0.000 claims description 11
- 239000011487 hemp Substances 0.000 claims description 11
- 229920002334 Spandex Polymers 0.000 claims description 10
- 239000004759 spandex Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 238000004080 punching Methods 0.000 claims description 7
- 230000007613 environmental effect Effects 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000010008 shearing Methods 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 2
- 238000009958 sewing Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 238000009966 trimming Methods 0.000 claims description 2
- 238000001467 acupuncture Methods 0.000 claims 2
- 238000005516 engineering process Methods 0.000 claims 1
- 239000000758 substrate Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 244000198134 Agave sisalana Species 0.000 description 1
- 235000011624 Agave sisalana Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
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- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
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Abstract
Description
技术领域technical field
本发明涉及用天然纤维和化学纤维混合制作而成的汽车门板及其制备工艺。The invention relates to an automobile door panel made by mixing natural fibers and chemical fibers and its preparation process.
背景技术Background technique
随着汽车工业的迅速发展,汽车保有量的飞速增加,人们对于汽车内饰件的质量和环保要求越来越高。汽车内饰件材料朝着绿色环保可回收的方向发展,目前用于汽车内饰件生产的复合基材通常是聚氨酯(PU)板、聚丙烯(PP)木粉板、玻璃钢板等。由于存在有毒化学药品污染方面的缺陷,原有的PU板及PP木粉板等已不能适应现代汽车发展的需要,正逐步被天然纤维复合材料所取代。天然纤维复合材料的加工通常都是把天然纤维和化学纤维混合制成毡子再热压成型。With the rapid development of the automobile industry and the rapid increase of automobile ownership, people have higher and higher requirements for the quality and environmental protection of automobile interior parts. The materials for automotive interior parts are developing in the direction of green environmental protection and recyclability. The composite substrates currently used for the production of automotive interior parts are usually polyurethane (PU) boards, polypropylene (PP) wood powder boards, glass steel plates, etc. Due to the defects of toxic chemical pollution, the original PU board and PP wood powder board can no longer meet the needs of modern automobile development, and are gradually being replaced by natural fiber composite materials. The processing of natural fiber composites usually involves mixing natural fibers and chemical fibers into felts and then hot pressing.
专利文献(公开号:CN101549671A)公开了一种麻纤维汽车内饰件及其生产方法,其步骤为:对包装好的原料进行开松处理,按照比例将黄麻纤维和丙纶纤维在梳棉机中混合,同时纤维成网,再通过针刺机针刺成毡,对成毡后的产品进行切片处理,然后将麻毡直接在烘箱中进行烘烤加热及表面粘合,烘烤加热温度为180-200℃,然后经过产品模具进行冷压成型,最后制出成品;或者先将麻毡做成板材进行储存,后续根据需要再对板材进行烘烤加热及相应的产品成型。The patent document (publication number: CN101549671A) discloses a hemp fiber automotive interior trim and a production method thereof, the steps of which are: opening the packaged raw materials, mixing jute fiber and polypropylene fiber in a carding machine according to the proportion Mixing, and at the same time, the fibers are formed into a net, and then needled into a felt by a needle punching machine, and the felted product is sliced, and then the hemp felt is directly baked in an oven for heating and surface bonding, and the baking temperature is 180 -200℃, and then cold-pressed and formed by the product mold, and finally the finished product is produced; or the hemp felt is made into a plate for storage, and then the plate is baked and heated according to the need and the corresponding product is formed.
专利文献(专利号ZL200410041912.X)公开了一种环保型热塑性天然棕麻纤维汽车内饰件复合基材,由中间基板、面料层和底层即胶面层复合制成,面料层采用无纺布,胶面层采用PP膜,中间基板由棕丝、麻纤维、涤纶纤维和丙纶纤维混料铺网制成毛毡,再在中间基板上下两面分别铺设无纺布和PP膜制成复合基材半成品,再加热加压、模压成型。这种板材由于采用了天然棕、麻植物纤维,具有密度小、质量轻、吸湿性好、无毒环保、成本低等优点,是用作汽车内饰件的较为理想的材料。其缺点是制作工艺复杂,生产效率低;天然纤维使用量较少,板材的强度低。The patent document (Patent No. ZL200410041912.X) discloses an environment-friendly thermoplastic natural brown hemp fiber automotive interior composite base material, which is made of a composite substrate, a fabric layer and a bottom layer, namely the rubber surface layer, and the fabric layer is made of non-woven fabric. , the rubber surface layer is made of PP film, the middle substrate is made of brown silk, hemp fiber, polyester fiber and polypropylene fiber mixed to make felt, and then the upper and lower sides of the middle substrate are laid with non-woven fabric and PP film respectively to make a composite substrate semi-finished product , then heated and pressurized, and molded. Due to the use of natural brown and hemp plant fibers, this board has the advantages of low density, light weight, good hygroscopicity, non-toxic and environmentally friendly, and low cost. It is an ideal material for automotive interior parts. Its disadvantages are that the production process is complicated and the production efficiency is low; the amount of natural fiber used is less, and the strength of the board is low.
发明内容Contents of the invention
本发明目的在于克服上述不足,提供一种密度小、质量轻、成本低、强度高、韧性好、安全性高、环保可回收的天然玄武岩纤维/麻纤维汽车门板。The purpose of the present invention is to overcome the above disadvantages and provide a natural basalt fiber/hemp fiber car door panel with low density, light weight, low cost, high strength, good toughness, high safety, environmental protection and recyclability.
为实现本发明目的,采用以下方法:一种环保可回收天然纤维汽车门板,由芯层和面层组成;所述的芯层由玄武岩纤维和麻纤维两种天然纤维以及涤纶纤维和丙纶纤维两种化学纤维混料铺网针刺制成;所述的面层由涤纶纤维、丙纶纤维和氨纶纤维三种化学纤维混料铺网针刺制成。In order to realize the purpose of the present invention, the following methods are adopted: an environmentally friendly recyclable natural fiber automobile door panel is composed of a core layer and a surface layer; The surface layer is made of three kinds of chemical fiber mixed materials, polyester fiber, polypropylene fiber and spandex fiber, which are laid by needle punching.
所述芯层各组份的重量百分比为:麻纤维10-30%、玄武岩纤维10-30%、涤纶纤维20-30%、丙纶纤维30-40%。The weight percent of each component of the core layer is: hemp fiber 10-30%, basalt fiber 10-30%, polyester fiber 20-30%, polypropylene fiber 30-40%.
所述面层各组份的重量百分比为:涤纶纤维30-40%、丙纶纤维40-50%、氨纶纤维10-20%。The weight percentage of each component of the surface layer is: 30-40% of polyester fiber, 40-50% of polypropylene fiber and 10-20% of spandex fiber.
本发明还公开了一种环保可回收天然纤维汽车门板的制备工艺,包括如下制备步骤:The invention also discloses a preparation process of an environmentally friendly recyclable natural fiber automobile door panel, which includes the following preparation steps:
步骤1:制备面层Step 1: Prepare the Topping
1.1将制备面层的纤维进行开松处理;1.1 Opening the fibers for preparing the surface layer;
1.2按组成比例混合;1.2 Mix according to the composition ratio;
1.3铺设成纤维网;1.3 Lay into a fiber net;
1.4通过针刺成毡材;1.4 Through needle punching into felt;
1.5剪切成卷并回收处理面层余料;1.5 Cut into rolls and recycle the remaining surface materials;
步骤2:制备芯层Step 2: Prepare the core layer
2.1将芯层纤维进行开松处理;2.1 Open the core fiber;
2.2按组成比例混合;2.2 Mix according to the composition ratio;
2.3铺设成纤维网;2.3 Lay into a fiber net;
2.4通过针刺成毡材;2.4 Through needle punching into felt;
2.5剪切成卷并回收处理芯层余料;2.5 Cut into rolls and recycle the rest of the core layer;
步骤3:制备门板Step 3: Prepare the Door Panel
3.1将面层和芯层毡材组成复合毡材;3.1 Compose the surface layer and the core layer of felt to form a composite felt;
3.2对复合毡材进行预热处理;3.2 Preheat the composite felt;
3.3将预热后的复合毡材在汽车门板模具上液压成型;3.3 Hydroforming the preheated composite felt on the automobile door panel mold;
3.4按照门板构件的样式裁剪修饰复合毡材;3.4 Cut and modify the composite felt according to the style of the door panel components;
3.5在门板构件和复合毡材上分别喷胶;3.5 Spray glue on the door panel components and the composite felt;
3.6压合复合毡材。3.6 Laminated composite felt.
步骤3中所述预热处理的温度为200℃-250℃,预热处理的时间为60-100秒。The temperature of the preheating treatment in step 3 is 200°C-250°C, and the time of the preheating treatment is 60-100 seconds.
步骤3中所述汽车门板模具上液压成型的模压压力为15MPa-20MPa,液压成型时间为60秒-100秒。The molding pressure of hydroforming on the automobile door panel mold described in step 3 is 15 MPa-20 MPa, and the hydroforming time is 60 seconds-100 seconds.
上述纤维经复配后,在保证汽车内饰件复合基材达到所需要的强度、成型性及隔音效果的前提下,本发明无毒,环保,且分量低,吸湿性好,成本较低。同时,本发明大幅度提高了汽车门板的抗张强度和抗冲击强度,提高其安全性。After the above fibers are compounded, the present invention is non-toxic, environmentally friendly, low in weight, good in hygroscopicity, and low in cost under the premise of ensuring the required strength, formability and sound insulation effect of the composite base material for automotive interior parts. Simultaneously, the invention greatly improves the tensile strength and impact strength of the automobile door panel, and improves its safety.
具体实施方式Detailed ways
下面将描述本发明的实施例,更进一步了解本发明。Examples of the present invention will be described below for further understanding of the present invention.
实施例1:Example 1:
第一步:制备面层Step 1: Prepare the Topping
a、三台开松机分别对丙纶、涤纶和氨纶纤维开松。按面层的用途或工艺要求,在电脑中设定构成比例。工作开始后,三台开松机按照设定比例将丙纶、涤纶和氨纶纤维开松后送进空气输送管路。a. Three openers respectively open polypropylene, polyester and spandex fibers. According to the use or process requirements of the surface layer, the composition ratio is set in the computer. After the work starts, the three openers open the polypropylene, polyester and spandex fibers according to the set ratio and send them into the air conveying pipeline.
b、丙纶、涤纶和氨纶纤维进入混棉箱后,由凝棉器将其均匀地撒到工作刺辊上,工作刺辊将三种纤维混合后,由角钉帘子和振动推板将其送人空气铺设机中。b. After the polypropylene, polyester and spandex fibers enter the mixing box, they are evenly sprinkled on the working licker-in roller by the condenser. man air laying machine.
c、空气铺设机将混合后的纤维经筛网滚筒和铺设帘子共同作用后形成具有一定厚度(重量)的纤维网。c. The air laying machine forms a fiber web with a certain thickness (weight) after the mixed fibers pass through the screen drum and the laying curtain.
d、经铺设机成网后的纤维进入针刺机,由针刺机刺针的上下往复运动使纤维抱合,形成具有一定强度和厚度的毡材。d. The fibers formed into a net by the laying machine enter the needle loom, and the up and down reciprocating motion of the needle of the needle loom makes the fibers cohere, forming a felt with a certain strength and thickness.
e、剪切机的纵向切刀按设定的面层毡材宽度将两侧多余的部分切掉,成卷机按电脑设定长度将剪切机横向切刀,切断后的面层毡材成卷。粉碎机将可回用处理的面层毡材撕碎送入输送管道,经凝棉器进入混棉箱,同来自开松的原料一起由输送带送入空气铺设机。e. The longitudinal cutter of the shearing machine cuts off the excess parts on both sides according to the set width of the surface layer felt, and the coiler cuts the shearing machine horizontally according to the length set by the computer, and cuts off the surface layer felt into rolls. The pulverizer shreds the reusable surface layer felt and sends it into the conveying pipeline, then enters the cotton mixing box through the condenser, and sends it to the air laying machine by the conveyor belt together with the raw materials from the opening.
第二步:制备芯层Step 2: Prepare the core layer
a、四台开松机分别对玄武岩纤维、麻纤维、丙纶纤维和涤纶纤维开松。按芯层的用途或工艺要求,在电脑中设定构成比例。工作开始后,开松机按照设定比例将芯层纤维开松后送进空气输送管路。a. Four opening machines respectively open basalt fiber, hemp fiber, polypropylene fiber and polyester fiber. According to the use or process requirements of the core layer, the composition ratio is set in the computer. After the work starts, the opener will open the core fiber according to the set ratio and send it into the air delivery pipeline.
b、开松后的芯层纤维进入混棉箱,由凝棉器将其均匀地撒到工作刺辊上,工作刺辊将两种纤维混合后,由角钉帘子和振动推板将其送人空气铺设机中。b. The core layer fiber after opening enters the mixing box, and is evenly sprinkled on the working licker-in roller by the condenser. man air laying machine.
c、空气铺设机将混合后的纤维经筛网滚筒和铺设帘子作用后形成具有一定厚度(重量)的纤维网。c. The air laying machine forms a fiber web with a certain thickness (weight) after the mixed fibers pass through the screen drum and the laying curtain.
d、经铺设机成网后的纤维进入针刺机,由针刺机刺针的上下往复运动使纤维抱合,形成具有一定强度和厚度的毡材。d. The fibers formed into a net by the laying machine enter the needle loom, and the up and down reciprocating motion of the needle of the needle loom makes the fibers cohere, forming a felt with a certain strength and thickness.
e、剪切机纵向切刀按设定的芯层毡材宽度将两侧多余的部分切掉。横向切刀按设定的长度将芯层毡材切断,粉碎机将可回用处理的芯层毡材撕碎,送入输送管道,经凝棉器进入混棉箱,同来自开松(混料机)的原料一起由输送带送入空气铺设机。e. The longitudinal cutter of the shearing machine cuts off the excess parts on both sides according to the set width of the core felt material. The horizontal cutter cuts the core layer felt according to the set length, and the pulverizer shreds the reusable core layer felt, sends it into the conveying pipeline, enters the cotton mixing box through the cotton condenser, and comes from the opening (mixing) The raw materials of the material machine) are sent to the air laying machine by the conveyor belt.
第三步:制备门板Step Three: Prepare the Door Panel
a、基材需要双层面层复合时,在第一台针刺机前将一层面层送入,在第三台针刺机前送入另一层面层;如果复合的基材只需要一层面层,则只在第三台针刺机前送入面层。a. When the base material needs to be compounded with double layers, feed one layer before the first needle punching machine, and feed the other layer before the third needle punching machine; if the composite base material only needs one The layer layer is only sent to the surface layer before the third needle loom.
b、将复合毡材置于电加热机的加热板上预热,上下预温度控制在200-250℃、预热时间60-100秒。b. Place the composite felt on the heating plate of the electric heater for preheating. The upper and lower preheating temperatures are controlled at 200-250°C and the preheating time is 60-100 seconds.
c、将预热后的材料放到门板模具的下模上,启动模压成型设备,模具闭合,开始作业。计时结束,设备自动升起复位,将成型件取出,放在修边工作台上。模压压力15-20MPa,成型时间60-100秒。c. Put the preheated material on the lower mold of the door panel mold, start the molding equipment, close the mold, and start the operation. When the timing is over, the equipment automatically rises and resets, and the molded parts are taken out and placed on the trimming workbench. Molding pressure 15-20MPa, molding time 60-100 seconds.
d、将待被覆的表皮复合毡材置于门板构件下,按构件大小划线、裁剪被覆表皮织物、缝合。d. Place the skin composite felt to be covered under the door panel component, draw lines according to the size of the component, cut the coated skin fabric, and sew it up.
e、将门板构件和裁剪缝合后的被覆表皮复合毡材分别喷胶、晾晒。将喷胶后的件放置于专用工装上晾晒,保证溶剂充分挥发,而且不要叠放。e. Spray glue and air-dry the door panel member and the coated skin composite felt after cutting and sewing. Place the sprayed parts on the special tooling to dry to ensure that the solvent is fully volatilized, and do not stack them.
f、将面料挂在绷框的4个钉子上,上部及右侧用一个大夹子夹紧,下面分别在左下角右下角用四个小夹子夹紧,取喷胶后的门板构件置于复合模具的下模上,将复合毡材夹在绷框上放在构件上,启动按钮,合模保压,复合结束,自动开启,取出复合的件,至此汽车门板件完成。f. Hang the fabric on the 4 nails of the stretching frame, clamp the upper part and the right side with a large clip, and clamp the lower part with four small clips in the lower left and right corners respectively, and place the door panel components after spraying glue on the compound On the lower mold of the mold, clamp the composite felt on the stretcher frame and place it on the component, start the button, close the mold and maintain pressure, after the composite is completed, it will automatically open, take out the composite part, and the car door panel is completed.
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CN103072345A (en) * | 2011-10-26 | 2013-05-01 | 延锋伟世通汽车饰件系统有限公司 | Fiber-net-reinforced composite material used in automotive decorative parts, and production method thereof |
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CN1456118A (en) * | 2002-05-08 | 2003-11-19 | 曾令福 | High temperature disinfectant blanket |
CN1321807C (en) * | 2004-09-07 | 2007-06-20 | 江阴市延利塑料制品有限公司 | Environment-friendly type thermoplastic natural palm fibrilia composite base material for automobile interior decoration |
KR101015513B1 (en) * | 2005-02-21 | 2011-02-16 | (주)리앤에스 | Lightweight composite sheet for automotive interior |
CN100354123C (en) * | 2005-12-29 | 2007-12-12 | 上海汽车地毯总厂 | Composite material for interior decoration of automobiles and manufacturing method thereof |
CN101045310B (en) * | 2006-03-28 | 2012-04-25 | 铜陵华源汽车内饰材料有限公司 | A kind of natural hemp fiber composite board for automobile interior decoration |
CN1951654B (en) * | 2006-11-17 | 2010-05-12 | 刘畅 | Waste natural fiber thermoplastic composite plate reclamation and regeneration method |
CN101230193B (en) * | 2007-12-28 | 2010-08-18 | 深圳市科聚新材料有限公司 | High-strength basalt fibre reinforced nylon composition and preparation method thereof |
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