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CN102132704A - Efficient sterilization crosslinking agent and method of for preparing hygienic sterilization product by using efficient sterilization crosslinking agent - Google Patents

Efficient sterilization crosslinking agent and method of for preparing hygienic sterilization product by using efficient sterilization crosslinking agent Download PDF

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CN102132704A
CN102132704A CN2010105903548A CN201010590354A CN102132704A CN 102132704 A CN102132704 A CN 102132704A CN 2010105903548 A CN2010105903548 A CN 2010105903548A CN 201010590354 A CN201010590354 A CN 201010590354A CN 102132704 A CN102132704 A CN 102132704A
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crosslinking agent
sterilization
crosslinked
original liquid
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CN102132704B (en
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常晋西
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Xi'an Guanyu Chemical Technology Co ltd
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Abstract

The invention belongs to the technical field of the production of hygienic sterilization products and comprises an efficient sterilization crosslinking agent prepared from raw materials such as imazali sulfate, OP, EDTA (Ethylene Diamine Tetraacetic Acid), polyethylene glycol, sodium hydrogen carbonate, distilled water and the like in a certain proportion, and a method for preparing the hygienic sterilization products such as hygienic sterilization finished fabrics, paper tissues, wood, bamboo and fur products and the like by using the efficient sterilization crosslinking agent. The efficient sterilization crosslinking agent and the hygienic sterilization products all have efficient, long-acting and strong sterilization functions; the growth, transmission and infection of various bacteria and viruses can be effectively prevented; the hygiene level and physical health level of human beings can be improved; and the healthy and sanitary habits of people more conform to the new health mode that 'an ounce of prevention is worth a pound of cure'.

Description

Efficient sterilizing crosslinking agent and utilize it to prepare the method for sanitary disinfecting articles for use
Technical field
Content of the present invention belongs to sanitary disinfecting articles for use manufacture technology field, relates to a kind ofly being used for the efficient sterilizing crosslinking agent of the depollution of environment and human body health care and utilizing this crosslinking agent to prepare the method for sanitary disinfecting articles for use.
Background technology
Owing between natural environment influence and the personnel or factors such as the way of contact between personnel and the article and circulation way, cause growing and polluting of malignant bacteria unavoidably, cause human body diseases and then threat human beings'health in the daily life.With regard to common medical science general knowledge, strengthening sterilization in people's daily life and clean link---as wash one's hands, bathing, washed and chemical sterilization disinfectant to the cleaning and sterilizing of clothing, public tableware and washing etc.---is prophylactic important measures.But be all kinds of soap that people were accustomed to using now, perfumed soap, medicated soap, removers etc. generally can only play decontamination, but very limited to diseases induced viral fungus matter killing action, and more known chemosterilants such as aldehydes, alcohols, the iodine class, peroxide, though quaternary ammonium salts preparation etc. can be used for killing multiple virus and bacterial propagule, but it is all having some such or such defectives in actual applications in varying degrees, if any the bactericide product human body is had significantly toxicity or excitant, some bactericide product has heat erosion or radiation corrosion effect etc. to the article of some non-refractories.In addition, article such as current phase people institute's article that often contact particularly wears and bedding is used such as clothing, bed clothes, felt rug, sheet are basically without sterilization processing, very easily make human body direct infection germ, although and existing market all kinds of known living-hygienic article on sale such as sanitary paper towel, hygienic chopsticks, antiseptic gauze, Disinfectant absorbent cotton etc. will be handled through strict sterilizing in manufacture process, but in accumulating, sale and use, still cause breeding and the pollution of bacterium unavoidably, therefore also fail to play most effectively environment purification and the effect that ensures health.Designer of the present invention had once disclosed a kind of high-effective broad-spectrum fungicide that is mixed with by raw materials such as hibitane, TritonX, EDTA in notification number is the patent application text of CN1090904, this bactericide all has more potent killing action to diseases induced viral fungus matter such as staphylococcus aureus, Escherichia coli, hay bacillus, candida albicans etc., but in actual applications, this bactericide still comes with some shortcomings in some aspects, is still remaining to be further enhanced especially aspect the killing rate of some pathogenic bacteria.In recent years, along with deepening continuously of domestic reform and opening-up, very big variation has taken place in society's general layout, personnel's flowability has reached unprecedented scale, and various diseases is also following, and the development of society should people-oriented, people's development will be based on health, this just require the government and even the public to build one more the living space of safe and sanitary is ensureing the life of human health, and good physical constitution is the valuable source of socio-economic development, the happiness that affects the livelihood of every family is safe and comfortable.
Summary of the invention
The present invention makes for satisfying present social demand and overcoming the existing in prior technology defective, its purpose one provides a kind of prescription science, easy to prepare, dependable performance and efficient sterilizing crosslinking agent applied widely, and two provide one group of method for preparing multiple long-acting hygiene sterilization articles for use according to this efficient sterilizing crosslinking agent.
Efficient sterilizing crosslinking agent of the present invention is a kind of by sterilizing, active washing, materials such as emulsification humidification dispose by a certain percentage and are processed into liquid formulation, with said preparation " crosslinked " at all kinds of daily hygiene articles for use (as clothing, bowls and chopsticks, felt rug, fur etc.) after on, can be to the various common and uncommon pathogenic germ that exists therebetween, bacterial propagule and various virus produce fast, stable, hold λ, killing action completely, more can prevent growing and the propagation infection of bacterial virus effectively, thereby improve human health level and body health level, also make people's health custom meet the new fitness mode of " putting prevention first; treatment is auxilliary " more.
The prescription of this efficient sterilizing crosslinking agent original liquid is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.05~3%, OP 0.1~1%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~2%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus.
The effect that above material composition is had in preparation stoste separately is such:
Imazalil sulfate---English Imazalil sulfate by name, molecular formula is C 14H 14C 2N 2O.H 2SO 4, molecular weight is 395.26, is a kind of light yellow sol particle, belongs to the antimycotic medicine, is interior absorption protective fungicide, has extremely strong inhibition to kill ability to fungi and common bacteria, can produce extremely strong binding ability by technical finesse and fiber etc.;
OP---be polyoxyethylene nonylphenol ether, be non-ionic surface active agent, have good anti-hard water and acid resistance, and have good emulsibility, wetability, dispersed and stronger infiltration capacity, in prescription, can play the bactericidal action of strengthening Imazalil sulfate;
EDTA---being ethylenediamine tetra-acetic acid, is a kind of important comprehensive agent, does water quality treatment agent in the present invention, and the impurity in it and the water forms stable comprehensive, and itself also has bacteriostasis;
Polyethylene glycol---do softening agent and dibutyl phthalate in prescription, its Heat stability is good with not directly generation effect, the not hydrolysis of many chemicals, never degenerate, can make medicament equably attached to body surface, reaches effective sterilization purpose;
Sodium bicarbonate---be a kind of antiacid, antimycotic adjuvant, make pH value conditioning agent in prescription, the pH value of this product is 6.0~7.0.
The method that is used to prepare this efficient sterilizing crosslinking agent comprises following processing step: after distilled water is heated to 40 ℃~80 ℃, in distilled water, add Imazalil sulfate, OP, EDTA, polyethylene glycol and sodium bicarbonate while stirring successively, after being stirred well to evenly, cooling solution is to room temperature, with the solution left standstill post precipitation, get supernatant by 200 orders or the above stainless steel sift net filtration of 200 orders, filtered fluid is warehouse-in after check, packing.
The further realization of the technology of the present invention solution also is: the efficient sterilizing crosslinking agent original liquid that is provided is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.05~0.295%, OP 0.2~0.8%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~1.5%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus.
The further realization of the technology of the present invention solution also is: the efficient sterilizing crosslinking agent original liquid that is provided is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.75~2.9%, OP 0.2~0.9%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~1.5%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus.
Efficient sterilizing crosslinking agent of the present invention is all multi-functional chemical industry preparations of one that are such as collection sterilization, sterilization, skin care, has nontoxic, non-stimulated, without any side effects, sterilization wide spectrum (almost can kill all harmful bacteriums), is widely used and advantage such as safe and reliable.In concrete the enforcement; make the material fiber knot in the material composition of this bacteriocide formula and multiple mankind essential items commonly used such as pin spun articles, towel products, the Bamboo and wood product poly-by the sterilization crosslinking technological; can prepare the multiple sterilization amenities efficient, the long-acting bactericidal effect that has; its product relates to numerous areas such as life, medical treatment, health, thereby has been able to more effectively play in bigger range of application the effect of protection health and environment purification.
It is mainly as described below to utilize this efficient sterilizing crosslinking agent to prepare the method for sanitary disinfecting articles for use.
One, preparation sanitary disinfecting finished product fabric such as underwear, underpants, socks, hair (bath) towel, carpet, the method of cloth products such as felt and chemical fibre product: at first utilize the slurry matter foreign material on the caustic soda stripping finished product fabric, then respectively by washing, washing powder is washed with clear water rinsing three process and is cleaned the removal caustic soda, dry after the fabric that cleaned crossed distilled water, fabric after will drying again immersed in 50 ℃~80 ℃ the crosslinking agent original liquid crosslinked 20~40 minutes, also the fabric after drying can be immersed in the 15 ℃~crosslinking agent original liquid of 30 ℃ (room temperatures) crosslinked 40~60 minutes, after crosslinked fabric is dried (recovery medicament) by taking out in the soup, again fabric is dried with drying plant, bake out temperature is 50 ℃~90 ℃, at last textile finishing is checked, the packing warehouse-in.
Two, the method for preparing goods such as sanitary disinfecting peltry goods such as leather, felt, fur: with the slurry matter foreign material on the caustic soda stripping peltry goods, then goods being purified decontamination handles, again goods were immersed in 50 ℃~80 ℃ the crosslinking agent original liquid crosslinked 20~40 minutes, also goods can be immersed in the 15 ℃~crosslinking agent original liquid of 30 ℃ (room temperatures) crosslinked 40~60 minutes, crosslinked later with goods by taking out dewatered drying in the soup, bake out temperature is 50 ℃~90 ℃, at last with goods arrangement check, packing warehouse-in.
Three, the method for preparing goods such as sanitary disinfecting towel products such as sanitary napkin, toilet paper, fragrant towel paper, script: will be through crosslinked 30~40 minutes (normal temperature soaks down, also can spray) in the crosslinking agent original liquid of 60 ℃~80 ℃ of the immersions of the towel products after the cleaning, crosslinked later with the paper handkerchief article by taking out dewatered drying in the soup, bake out temperature is 50 ℃~80 ℃, at last with sanitary disinfecting paper handkerchief arrangement check, packing warehouse-in.
Four, the method for preparing health bacterium Bamboo and wood product such as goods such as chopsticks, tableware: will immerse in 60 ℃~80 ℃ the crosslinking agent original liquid crosslinked 30~40 minutes through the Bamboo and wood product after the cleaning, also Bamboo and wood product can be immersed in the 15 ℃~crosslinking agent original liquid of 30 ℃ (normal temperature) crosslinked 50~60 minutes, crosslinked later with wooden bamboo article by taking out dewatered drying in the soup, bake out temperature is 60 ℃~80 ℃, at last with sterilization Bamboo and wood product arrangement check, packing warehouse-in.
The simple science of the above various preparation method's process route, convenient and easy, small investment, instant effect, be suitable for pin and spin enterprise, paper products enterprise, Bamboo and wood product enterprise, multiclass enterprises such as leather and fur products enterprise practice midwifery, even in average family, also can utilize this efficient sterilizing crosslinking agent easily to more existing wearing in the family, carry out " crosslinked " sterilization with article and (carry out the crosslinked available electric iron of fabric in the family, baking box, radiators etc. replace dedicated drying equipment), crosslinked soup can use repeatedly, and the soup of Hui Shouing then can be used as the usefulness of environment disinfected sterilization at last.
The present invention is the technology of having carried out significant improvement on the basis of former CN1090904 bulletin text patented technology, utilize the sanitary disinfecting articles for use of this " crosslinked " technology preparation all to have efficiently, long-acting bactericidal action, product detects check (attached as follows table 1~table 3) repeatedly through Shaanxi Province health and epidemic prevention station, all meet state health standards, it is to staphylococcus aureus, Escherichia coli, Friedlander, Candida albicanss etc. all have significantly kills inhibitory action, (the once washing counting procedure is sanitary disinfecting fabric articles for use: rub with washing powder and soap earlier after washing 50 times, use the clear water rinsing again, drying is also dried), still hold good bactericidal effect.Be apparent that especially, sterilizing cloth 1 hour killing rate to Friedlander of its effect after washing 50 times with the present invention's preparation can reach 96.55%, and the sterilizing cloth of former patented technology (CN1090904) preparation acts on 4 hours under the same conditions, its killing rate is less than 50%, the killing rate of staphylococcus aureus after washing 50 times, is acted on 1 hour sterilizing rate and brings up to 99.16% (having improved 5.5%) from 93.99%; Particularly simplified (soak at room temperature, oven dry) behind the preparation technology, after washing 50 times, the prepared product sterilizing rate is also greater than 90%.
By above-mentioned situation as seen, the technical products that content is released according to the present invention is to implementing the health strategy general objective that proposes in the national Eleventh Five-Year Plan, implement to put prevention first, to have profound significance, also will have a tremendous social and economic benefits towards basic unit and family and the development that promotes the health new standard.
Table 1 series sanitary sterilization articles for use are to colibacillary antibacterial effect
Figure BDA0000038409470000061
Table 2 series sanitary sterilization articles for use are to the antibacterial effect of staphylococcus aureus
Figure BDA0000038409470000071
Table 3 series sanitary sterilization articles for use are to the oidiomycetic antibacterial effect of white
Figure BDA0000038409470000072
Embodiment
Embodiment one
A kind of embodiment material of the present invention is made by containing following raw materials by weight percentage:
Imazalil sulfate 0.15%, OP 0.6%,
EDTA 0.05%, polyethylene glycol 0.8%,
Sodium bicarbonate 0.15%, distilled water 98.25%.
Preparation method: after distilled water is heated to 70 ℃~80 ℃, in distilled water, add Imazalil sulfate, OP, EDTA, polyethylene glycol and sodium bicarbonate while stirring successively, stir about 1 hour is after evenly, cooling solution is to room temperature (15 ℃~30 ℃), with the solution left standstill post precipitation, get supernatant by 200 order stainless steel sift net filtrations, filtered fluid is warehouse-in after check, packing.The Imazalil sulfate goods that the Imazalil sulfate of preparation in the raw material can adopt Belgian Yang Sen company to produce.
Embodiment two
A kind of embodiment material of the present invention is made by containing following raw materials by weight percentage:
Imazalil sulfate 0.29%, OP 0.5%,
EDTA 0.15%, polyethylene glycol 1.0%,
Sodium bicarbonate 0.10%, distilled water 97.96%.
The preparation method is with embodiment one.
Embodiment three
A kind of embodiment material of the present invention is made by containing following raw materials by weight percentage:
Imazalil sulfate 1.20%, OP 0.8%,
EDTA 0.20%, polyethylene glycol 1.2%,
Sodium bicarbonate 0.15%, distilled water 96.45%.
The preparation method is with embodiment one.
Embodiment four
A kind of embodiment material of the present invention is made by containing following raw materials by weight percentage:
Imazalil sulfate 2%, OP 0.25%,
EDTA 0.25%, polyethylene glycol 1.8%,
Sodium bicarbonate 0.28%, distilled water 93.9%.
The preparation method is with embodiment one.
Embodiment five
A kind of embodiment material of the present invention is made by containing following raw materials by weight percentage:
Imazalil sulfate 1.8%, OP 0.65%,
EDTA 0.2%, polyethylene glycol 1.2%,
Sodium bicarbonate 0.15%, distilled water 96%.
The preparation method is with embodiment one.

Claims (7)

1. amenities efficient sterilizing crosslinking agent is characterized in that the crosslinking agent original liquid is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.05~3%, OP 0.1~1%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~2%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus;
The method that is used to prepare this efficient sterilizing crosslinking agent comprises following processing step: after distilled water is heated to 40 ℃~80 ℃, in distilled water, add Imazalil sulfate, OP, EDTA, polyethylene glycol and sodium bicarbonate while stirring successively, after being stirred well to evenly, cooling solution is to room temperature, with the solution left standstill post precipitation, get supernatant by 200 orders or the above stainless steel sift net filtration of 200 orders, filtered fluid is warehouse-in after check, packing.
2. amenities efficient sterilizing crosslinking agent according to claim 1 is characterized in that the crosslinking agent original liquid is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.05~0.295%, OP 0.2~0.8%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~1.5%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus.
3. amenities efficient sterilizing crosslinking agent according to claim 1 is characterized in that the crosslinking agent original liquid is made up of the raw material of substance of following weight percentage:
Imazalil sulfate 0.75~2.9%, OP 0.2~0.9%,
EDTA 0.01~0.3%, polyethylene glycol 0.05~1.5%,
Sodium bicarbonate 0.1~0.3%, distilled water surplus.
4. method of utilizing claim 1 or 2 or 3 described sterilization crosslinking agents to prepare sanitary disinfecting finished product fabric, comprise the method for preparing sanitary disinfecting cloth products and chemical fibre product, it is characterized in that: at first utilize the slurry matter foreign material on the caustic soda stripping finished product fabric, then respectively by washing, washing powder is washed with clear water rinsing three process and is cleaned the removal caustic soda, dry after the fabric that cleaned crossed distilled water, fabric after will drying again immersed in 50 ℃~80 ℃ the crosslinking agent original liquid crosslinked 20~40 minutes, fabric after maybe will drying immersed in 15 ℃~30 ℃ the crosslinking agent original liquid crosslinked 40~60 minutes, after crosslinked fabric is dried by taking out in the soup, again fabric is dried with drying plant, bake out temperature is 50 ℃~90 ℃, at last textile finishing is checked, the packing warehouse-in.
5. method of utilizing claim 1 or 2 or 3 described sterilization crosslinking agents to prepare sanitary disinfecting peltry goods, it is characterized in that: with the slurry matter foreign material on the caustic soda stripping peltry goods, then goods being purified decontamination handles, again goods were immersed in 50 ℃~80 ℃ the crosslinking agent original liquid crosslinked 20~40 minutes, or goods were immersed in 15 ℃~30 ℃ the crosslinking agent original liquid crosslinked 40~60 minutes, crosslinked later with goods by taking out dewatered drying in the soup, bake out temperature is 50 ℃~90 ℃, at last with goods arrangement check, packing warehouse-in.
6. method of utilizing claim 1 or 2 or 3 described sterilization crosslinking agents to prepare the sanitary disinfecting towel products, it is characterized in that: will immerse in 60 ℃~80 ℃ the crosslinking agent original liquid crosslinked 30~40 minutes through the towel products after the cleaning, crosslinked later with the paper handkerchief article by taking out dewatered drying in the soup, bake out temperature is 50 ℃~80 ℃, at last with sanitary disinfecting towel products arrangement check, packing warehouse-in.
7. method of utilizing claim 1 or 2 or 3 described sterilization crosslinking agents to prepare the sanitary disinfecting Bamboo and wood product, it is characterized in that: will immerse in 60 ℃~80 ℃ the crosslinking agent original liquid crosslinked 30~40 minutes through the Bamboo and wood product after the cleaning, or Bamboo and wood product immersed in 15 ℃~30 ℃ the crosslinking agent original liquid crosslinked 50~60 minutes, crosslinked later with wooden bamboo article by taking out dewatered drying in the soup, bake out temperature is 60 ℃~80 ℃, at last with sanitary disinfecting Bamboo and wood product arrangement check, packing warehouse-in.
CN 201010590354 2010-12-15 2010-12-15 Efficient sterilization crosslinking agent and method of for preparing hygienic sterilization product by using efficient sterilization crosslinking agent Expired - Fee Related CN102132704B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104476640A (en) * 2014-11-13 2015-04-01 阜南县富民工艺品有限公司 Rice straw health-care aroma-enhancing anticorrosion modified soaking liquid and use method thereof
CN105802764A (en) * 2016-04-18 2016-07-27 句容东发生活用品有限公司 Wet tissue for kitchen

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1253727A (en) * 1998-11-17 2000-05-24 常晋西 High-effective broad-spectrum fungicide and method for preparing sanitary disinfecting articles by using one
CN1934945A (en) * 2006-09-08 2007-03-28 黄存林 Use of imazalil for sunitary product and sterilizer product and its use method
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1253727A (en) * 1998-11-17 2000-05-24 常晋西 High-effective broad-spectrum fungicide and method for preparing sanitary disinfecting articles by using one
CN1934945A (en) * 2006-09-08 2007-03-28 黄存林 Use of imazalil for sunitary product and sterilizer product and its use method
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104476640A (en) * 2014-11-13 2015-04-01 阜南县富民工艺品有限公司 Rice straw health-care aroma-enhancing anticorrosion modified soaking liquid and use method thereof
CN105802764A (en) * 2016-04-18 2016-07-27 句容东发生活用品有限公司 Wet tissue for kitchen

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