CN102121763B - Diffusion absorption type thermal converter - Google Patents
Diffusion absorption type thermal converter Download PDFInfo
- Publication number
- CN102121763B CN102121763B CN2011100468431A CN201110046843A CN102121763B CN 102121763 B CN102121763 B CN 102121763B CN 2011100468431 A CN2011100468431 A CN 2011100468431A CN 201110046843 A CN201110046843 A CN 201110046843A CN 102121763 B CN102121763 B CN 102121763B
- Authority
- CN
- China
- Prior art keywords
- port
- gas
- liquid separator
- regenerator
- absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 20
- 238000009792 diffusion process Methods 0.000 title description 15
- 239000007788 liquid Substances 0.000 claims abstract description 70
- 239000006096 absorbing agent Substances 0.000 claims abstract description 28
- 230000002745 absorbent Effects 0.000 claims abstract description 12
- 239000002250 absorbent Substances 0.000 claims abstract description 12
- 239000003507 refrigerant Substances 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 239000001648 tannin Substances 0.000 claims description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 6
- -1 carbon hydrocarbons Chemical class 0.000 claims description 6
- 150000002170 ethers Chemical class 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000004820 halides Chemical class 0.000 claims description 5
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- 239000002608 ionic liquid Substances 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000005086 pumping Methods 0.000 abstract description 3
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
Landscapes
- Sorption Type Refrigeration Machines (AREA)
Abstract
本发明公开了一种扩散吸收式热变换器。本发明包括具有依次连接的发生器、提升管、第一气液分离器、精馏装置、冷凝器、第二气液分离器、蒸发器、吸收器、储液器、回热器、风机。本发明采用热驱动气泡泵实现吸收剂溶液和制冷剂液体的同时泵送，无需使用机械式溶液泵和制冷剂泵，大幅简化了热变换器的结构，节约了宝贵的电能，提高了运行的可靠性。特别适用于中低温热资源丰富，同时又需要使用高温热的场合，有良好的应用前景。
The invention discloses a diffusion-absorption heat exchanger. The invention includes a generator, a riser, a first gas-liquid separator, a rectifying device, a condenser, a second gas-liquid separator, an evaporator, an absorber, a liquid storage device, a regenerator and a fan connected in sequence. The invention adopts heat-driven air bubble pump to realize simultaneous pumping of absorbent solution and refrigerant liquid, without using mechanical solution pump and refrigerant pump, greatly simplifies the structure of the heat converter, saves precious electric energy, and improves the efficiency of operation. reliability. It is especially suitable for occasions where medium and low temperature heat resources are abundant and high temperature heat is required at the same time, and has a good application prospect.
Description
Technical field
The invention belongs to absorption heat pump and low-grade energy utilizes the field, relate in particular to a kind of diffusion absorbing thermal converter.
Background technology
The absorption type heat converter can adopt low-grade energy to drive; Can effectively utilize low-grade energies such as industrial exhaust heat, underground heat, solar energy; In addition, the absorption type heat converter can avoid the use of the refrigeration working medium that atmospheric ozone layer is had destruction, so all have great importance with environmental protection to energy-conservation.Traditional H
2O/LiBr absorption type heat converter has dropped into commercial application, but because the temperature of mechanical type solution pump operation is higher, H
2The severe corrosive of O/LiBr solution has limited its extensive use.
Diffusion absorption refrigerating machine is to spread in diffusion gas through cold-producing medium to obtain cool effect; Circulation inside is isobaric basically; The thermosyphon action of utilizing heat to drive airlift pump just can promote absorbent and cold-producing medium and in system, flow, and need not to use pyrosol pump and refrigerated medium pump just can work.
The present invention is applied to the diffusion absorption refrigerating machine circulation theory in traditional absorption type heat converter; A kind of diffusion absorbing thermal converter is proposed; Utilize absorbent, cold-producing medium and the diffusion gas phase equilibrium relationship under different temperatures and concentration to change; Build in absorber and the generator absorbent solution to the different absorption potential differences of refrigerant vapour, thereby can adopt heat to drive the simultaneous pumping that airlift pump is realized absorbent solution and refrigerant liquid, can not re-use more mechanical type pyrosol pump and the refrigerated medium pump of consumed power in traditional absorption type heat converter; Only needing the micro-blower fan electric energy of consumption to blow diffusion gas just can work; Significantly reduce the consumption of valuable electric energy, simplified the structure of thermal converter, improved reliability of operation.Low-temperature heat aboundresources in being specially adapted to, the while need be used the occasion of elevated temperature heat again, and good prospects for application is arranged.
Summary of the invention
The objective of the invention is to overcome the deficiency of prior art, a kind of diffusion absorbing thermal converter is provided.
The diffusion absorbing thermal converter comprises generator, riser, first gas-liquid separator, rectifier unit, condenser, second gas-liquid separator, evaporimeter, absorber, reservoir, regenerator and blower fan; First port of generator links to each other with second port of regenerator; Second port of generator links to each other with second port of blower fan; The 3rd port of generator links to each other with the bottom inlet of riser; The top exit of riser inserts more than 1/2 of the first gas-liquid separator height through first port of first gas-liquid separator, and second port of first gas-liquid separator links to each other with the 3rd port of regenerator, and the 3rd port of first gas-liquid separator links to each other with first port of rectifier unit; Second port of rectifier unit links to each other with first port of condenser; Second port of condenser links to each other with first port of second gas-liquid separator, and second port of second gas-liquid separator links to each other with first port of blower fan, and the 3rd port of second gas-liquid separator links to each other with first port of evaporimeter; Second port of evaporimeter links to each other with first port of absorber; Second port of absorber links to each other with the 4th port of regenerator, and the 3rd port of absorber links to each other with first port of reservoir, and second port of reservoir links to each other with first port of regenerator.
Described condenser is positioned at the highest position of thermal converter; The position of second gas-liquid separator is lower than the position of condenser, and the position of evaporimeter is lower than the position of second gas-liquid separator, and the position of absorber is lower than the position of evaporimeter; The position of reservoir is lower than the position of absorber; The position of regenerator is lower than the position of reservoir, and the position of rectifier unit is lower than the position of condenser, and the position of first gas-liquid separator is lower than the position of rectifier unit; The position of riser is lower than the position of first gas-liquid separator, and second port of first gas-liquid separator is higher than second port of absorber.
Described cold-producing medium is one or more in halide, alcohols or the ethers of water, carbon hydro carbons, hydrocarbon.Absorbent is one or more in salt, alcohols, ethers, ketone, amine, aldehydes or the ionic liquid.Diffusant is the halide or the carbon dioxide of hydrogen, inert gas, carbon hydro carbons, hydrocarbon.
The present invention compares with traditional absorption type heat converter, does not re-use high-temperature machinery formula solution pump and refrigerated medium pump in traditional absorption type heat converter, has following beneficial effect:
1) behind employing hot driving airlift pump simultaneous pumping absorbent solution and the refrigerant liquid, only needs the micro-blower fan electric energy of consumption to blow diffusion gas and just can work, significantly reduced the consumption of valuable electric energy
2) thoroughly solve a mechanical type solution pump corrosion difficult problem at high temperature, simplified the structure of thermal converter, improved reliability of operation.
Description of drawings
Accompanying drawing is a diffusion absorbing thermal converter structural representation;
Among the figure: generator 1, riser 2, first gas-liquid separator 3, rectifier unit 4, condenser 5, second gas-liquid separator 6, evaporimeter 7, absorber 8, reservoir 9, regenerator 10, blower fan 11.
The specific embodiment
Shown in accompanying drawing, the diffusion absorbing thermal converter of movement-less part comprises generator 1, riser 2, first gas-liquid separator 3, rectifier unit 4, condenser 5, second gas-liquid separator 6, evaporimeter 7, absorber 8, reservoir 9, regenerator 10 and blower fan 11; The first port one a of generator 1 links to each other with the second port one 0b of regenerator 10; The second port one b of generator 1 links to each other with the second port one 1b of blower fan 11; The 3rd port one c of generator 1 links to each other with the bottom inlet of riser 2; The top exit of riser 2 inserts more than 1/2 of first gas-liquid separator, 3 height through the first port 3a of first gas-liquid separator 3; The second port 3b of first gas-liquid separator 3 links to each other with the 3rd port one 0c of regenerator 10; The 3rd port 3c of first gas-liquid separator 3 links to each other with the first port 4a of rectifier unit 4, and the second port 4b of rectifier unit 4 links to each other with the first port 5a of condenser 5, and the second port 5b of condenser 5 links to each other with the first port 6a of second gas-liquid separator 6; The second port 6b of second gas-liquid separator 6 links to each other with the first port one 1a of blower fan 11; The 3rd port 6c of second gas-liquid separator 6 links to each other with the first port 7a of evaporimeter 7, and the second port 7b of evaporimeter 7 links to each other with the first port 8a of absorber 8, and the second port 8b of absorber 8 links to each other with the 4th port one 0d of regenerator 10; The 3rd port 8c of absorber 8 links to each other with the first port 9a of reservoir 9, and the second port 9b of reservoir 9 links to each other with the first port one 0a of regenerator 10.
Described condenser (5) is positioned at the highest position of thermal converter; The position of second gas-liquid separator (6) is lower than the position of condenser (5); The position of evaporimeter (7) is lower than the position of second gas-liquid separator (6); The position of absorber (8) is lower than the position of evaporimeter (7), and the position of reservoir (9) is lower than the position of absorber (8), and the position of regenerator (10) is lower than the position of reservoir (9); The position of rectifier unit (4) is lower than the position of condenser (5); The position of first gas-liquid separator (3) is lower than the position of rectifier unit (4), and the position of riser (2) is lower than the position of first gas-liquid separator (3), and second port (3b) of first gas-liquid separator (3) is higher than second port (8b) of absorber (8).
Described cold-producing medium is one or more in halide, alcohols or the ethers of water, carbon hydro carbons, hydrocarbon.Absorbent is one or more in salt, alcohols, ethers, ketone, amine, aldehydes or the ionic liquid.Diffusant is the halide or the carbon dioxide of hydrogen, inert gas, carbon hydro carbons, hydrocarbon.
Described diffusant is that boiling point is lower than cold-producing medium, and density is little, does not react with cold-producing medium, absorbent.
Described absorbent is the solvent of ability absorption refrigeration agent.
Described generator 1, condenser 5, evaporimeter 7, absorber 8 and regenerator 10 all are heat exchangers, can adopt fountain or immersion, also can be bushing type or other forms, and its heat exchanger tube can be that common tube also can be an enhanced tube.
Described riser 2 mainly plays and promotes solution and the effect that drives the solution circulation, can be the common metal pipe, also can be pressure hose.
The effect of described first gas-liquid separator 3 and second gas-liquid separator 6 is with the two-phase mixture equilibrium separation that gets into wherein, and gas phase flows out from its top, and liquid phase flows out from its bottom.
Reservoir is similar in described reservoir 9 and the common refrigerating plant; Rectifier unit is similar in rectifier unit 4 and the common refrigerating plant.
Connection between above-mentioned described each parts adopts metal tubes to connect high temperature conduit outerwrap insulation material.
Present embodiment adopts H
2O is a cold-producing medium, and tetraethylene glycol dimethyl ether (E181) is an absorbent, and He is a diffusant.
Cold-producing medium H
2Warm amount during O absorbs in generator 1, the evaporation diffusion forms mixture H in diffusant He gas
2The O/He bubble rises in riser 2, promotes the E181/H after taking place simultaneously
2The O weak solution gets into first gas-liquid separator 3, separates the top inflow rectifier unit 4 of back from first gas-liquid separator 3 therein.H
2After O/He gas is purified in rectifier unit 4, upwards get in the condenser 5 by the cooling of normal temperature cooling medium, cold-producing medium H
2O is liquefied, and diffusant He still is a gaseous state.Then, cold-producing medium H
2O liquid gets into second gas-liquid separator 6 with diffusant He gas, and separated therein.Diffusant He gas flows out from the top of second gas-liquid separator 6, after blower fan 11 pressurizations, gets into generator 1.Liquid refrigerant H
2O then flows out from second gas-liquid separator, 6 bottoms, get in the evaporimeter 8 by in warm amount heating vaporization, cold-producing medium H then
2O gas gets into absorber by E181/H
2The O weak solution absorbs.
E181/H from 3 outflows of first gas-liquid separator
2The O weak solution gets into regenerator 10, by the E181/H from reservoir 9
2O concentrated solution heating back gets into the cold-producing medium H that absorber 8 absorbs flash-pot 8
2O gas.E181/H after the absorption
2The O concentrated solution gets into regenerator 10 through reservoir 9, is flowed in the generator 1 by the weak solution cooling back from first gas-liquid separator 3 and is taken place once more.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100468431A CN102121763B (en) | 2011-02-28 | 2011-02-28 | Diffusion absorption type thermal converter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100468431A CN102121763B (en) | 2011-02-28 | 2011-02-28 | Diffusion absorption type thermal converter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102121763A CN102121763A (en) | 2011-07-13 |
| CN102121763B true CN102121763B (en) | 2012-06-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100468431A Expired - Fee Related CN102121763B (en) | 2011-02-28 | 2011-02-28 | Diffusion absorption type thermal converter |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102121763B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107100685A (en) * | 2017-04-26 | 2017-08-29 | 辽宁工程技术大学 | A kind of combined generating system based on organic Rankine bottoming cycle and absorption heat pump cycle |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103161709A (en) * | 2013-03-27 | 2013-06-19 | 上海理工大学 | A bubble pump device |
| DK3026990T3 (en) * | 2014-11-28 | 2019-04-23 | Abb Schweiz Ag | interior design |
| CN104562595B (en) * | 2014-12-23 | 2017-11-28 | 珠海格力电器股份有限公司 | Clothes dryer |
| CN107192163B (en) * | 2017-07-06 | 2023-07-18 | 华南理工大学 | A semiconductor-absorption-diffusion coupling refrigeration device |
| CN116358190B (en) * | 2023-04-27 | 2024-04-09 | 大连海事大学 | Double-ejector driving diffusion absorption type heat converter |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB505174A (en) * | 1936-10-27 | 1939-04-27 | Electrolux Ltd | Improvements in or relating to refrigerating systems |
| US5282507A (en) * | 1991-07-08 | 1994-02-01 | Yazaki Corporation | Heat exchange system |
| CN2485601Y (en) * | 2001-06-01 | 2002-04-10 | 热能科技开发股份有限公司 | Absorption Diffusion Freezer |
| DE10206226A1 (en) * | 2002-02-12 | 2003-08-21 | Entex Energy Ag Eggenwil | Gas absorber for a refrigeration heat pump |
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| CN100489417C (en) * | 2007-04-13 | 2009-05-20 | 中国家用电器研究院 | Sodium sulfocyanate-ammonia diffusion absorbing refrigerator |
-
2011
- 2011-02-28 CN CN2011100468431A patent/CN102121763B/en not_active Expired - Fee Related
Patent Citations (7)
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|---|---|---|---|---|
| GB505174A (en) * | 1936-10-27 | 1939-04-27 | Electrolux Ltd | Improvements in or relating to refrigerating systems |
| US5282507A (en) * | 1991-07-08 | 1994-02-01 | Yazaki Corporation | Heat exchange system |
| CN2485601Y (en) * | 2001-06-01 | 2002-04-10 | 热能科技开发股份有限公司 | Absorption Diffusion Freezer |
| DE10206226A1 (en) * | 2002-02-12 | 2003-08-21 | Entex Energy Ag Eggenwil | Gas absorber for a refrigeration heat pump |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107100685A (en) * | 2017-04-26 | 2017-08-29 | 辽宁工程技术大学 | A kind of combined generating system based on organic Rankine bottoming cycle and absorption heat pump cycle |
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| Publication number | Publication date |
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| CN102121763A (en) | 2011-07-13 |
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