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CN102117767A - Fully transparent TFT (Thin Film Transistor) active matrix manufacturing method based on colloidal sol mode - Google Patents

Fully transparent TFT (Thin Film Transistor) active matrix manufacturing method based on colloidal sol mode Download PDF

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CN102117767A
CN102117767A CN2010106106406A CN201010610640A CN102117767A CN 102117767 A CN102117767 A CN 102117767A CN 2010106106406 A CN2010106106406 A CN 2010106106406A CN 201010610640 A CN201010610640 A CN 201010610640A CN 102117767 A CN102117767 A CN 102117767A
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陈龙龙
李喜峰
张建华
王赛
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SHANGHAI UNIVERSITY
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Abstract

本发明涉及一种基于溶胶式全透明TFT有源矩阵制造方法。本方法采用溶胶旋涂的方式将溶胶转移到玻璃基板上,利用光刻的方式直接实现了TFT有源矩阵的栅极电极层、绝缘层、有源层、源漏电极层以及保护层的图形化转移,采用本方法的TFT有源矩阵制造工艺简单,减少了湿刻等工艺步骤,节省了干刻等工艺步骤,并且不需要CVD以及PVD等大型成膜设备的投入,大幅节约了工艺设备、工艺制造成本的投入,并且制造的TFT有源矩阵为全透明式,开口率增加。

The invention relates to a sol-based fully transparent TFT active matrix manufacturing method. In this method, the sol is transferred to the glass substrate by sol spin coating, and the patterns of the gate electrode layer, insulating layer, active layer, source-drain electrode layer and protective layer of the TFT active matrix are directly realized by photolithography. The TFT active matrix manufacturing process using this method is simple, reduces wet etching and other process steps, saves dry etching and other process steps, and does not require investment in large-scale film-forming equipment such as CVD and PVD, greatly saving process equipment , The input of process manufacturing cost, and the manufactured TFT active matrix is fully transparent, and the aperture ratio increases.

Description

基于溶胶式全透明TFT有源矩阵制造方法Sol-based fully transparent TFT active matrix manufacturing method

技术领域technical field

本发明涉及一种平板显示屏制造领域的制造方法,具体的说是一种基于溶胶式全透明TFT(薄膜晶体管)有源矩阵的制造方法,采用溶胶旋涂的制造方法实现全透明TFT有源矩阵的制作。The invention relates to a manufacturing method in the field of flat panel display manufacturing, in particular to a manufacturing method based on a sol-type fully transparent TFT (thin film transistor) active matrix, which uses a sol spin coating manufacturing method to realize a fully transparent TFT active matrix. Matrix production.

背景技术Background technique

TFT英文全称为Thin Film Transistor,意思为薄膜晶体管。现有的TFT有源矩阵采用如下的制造工艺流程(见图1):首先在清洗洁净的TFT玻璃基板上溅射底栅金属层,通过光刻工艺将底栅金属层图形化处理,得到底栅电极的图形;接下来在图形化后的底栅金属层之上依次淀积绝缘层、有源层及欧姆接触层;再对欧姆接触层作图形化处理,将TFT沟道处的欧姆接触层刻蚀掉,但保留源、漏电极处的欧姆接触层;最后再溅射一层金属电极层,图形化处理后得到TFT有源矩阵的源、漏电极。此种工艺的TFT有源矩阵的薄膜生长在玻璃基板上,需有PVD、CVD等工艺设备的投入,制造工艺复杂,工艺要求非常高,且部分制作工艺需要高温下制造、处理,工艺节拍低,制造成本高。The full English name of TFT is Thin Film Transistor, which means thin film transistor. The existing TFT active matrix adopts the following manufacturing process (see Figure 1): Firstly, the bottom gate metal layer is sputtered on the cleaned TFT glass substrate, and the bottom gate metal layer is patterned by photolithography to obtain the bottom gate metal layer. The pattern of the gate electrode; next, an insulating layer, an active layer, and an ohmic contact layer are sequentially deposited on the patterned bottom gate metal layer; The layer is etched away, but the ohmic contact layer at the source and drain electrodes is retained; finally, a layer of metal electrode layer is sputtered, and the source and drain electrodes of the TFT active matrix are obtained after patterning. The thin film of the TFT active matrix of this process is grown on the glass substrate, which requires the investment of PVD, CVD and other process equipment. The manufacturing process is complicated and the process requirements are very high, and some of the production processes need to be manufactured and processed at high temperature, and the process cycle is low. , high manufacturing cost.

本发明采用溶胶式试剂作为TFT有源矩阵的制作材料,通过旋涂的方式将溶胶转移到玻璃基板上,利用光刻的方式直接实现了TFT有源矩阵的栅极电极层、绝缘层、有源层、源漏电极层以及保护层的图形化转移,采用本方法的TFT有源矩阵制造工艺简单,减少了湿刻等工艺步骤,节省了干刻等工艺步骤,并且不需要CVD以及PVD等大型成膜设备的投入,大幅节约了工艺设备、工艺制造成本的投入,并且制造的TFT有源矩阵为全透明式,开口率增加。The present invention adopts the sol-type reagent as the manufacturing material of the TFT active matrix, transfers the sol to the glass substrate by spin coating, and directly realizes the gate electrode layer, the insulating layer, the active matrix of the TFT active matrix by photolithography. Patterned transfer of source layer, source-drain electrode layer, and protective layer, the TFT active matrix manufacturing process using this method is simple, reduces wet etching and other process steps, saves dry etching and other process steps, and does not require CVD and PVD, etc. The investment in large-scale film-forming equipment greatly saves the investment in process equipment and process manufacturing costs, and the manufactured TFT active matrix is fully transparent, and the aperture ratio increases.

发明内容Contents of the invention

本发明的目的是针对己有技术存在的缺陷提供一种基于溶胶式全透明TFT有源矩阵制造方法,该方法采用溶胶旋涂、光刻、显影的方式,直接实现TFT有源矩阵的栅极、绝缘层、源电极、漏电极的图形制作,加工工艺简单,并且可大幅提高器件的开口率。The purpose of the present invention is to provide a method for manufacturing a fully transparent TFT active matrix based on a sol-type fully transparent TFT based on the defects of the existing technology. , Insulation layer, source electrode, and drain electrode pattern making, the processing technology is simple, and the aperture ratio of the device can be greatly improved.

为达到上述目的,本发明采用如下技术方案:To achieve the above object, the present invention adopts the following technical solutions:

一种基于溶胶式全透明TFT有源矩阵制造方法,其特征在于,采用溶胶旋涂的方式实现TFT有源矩阵的栅极电极层、有源层、源漏电极层以及保护层的制作,其制造工艺步骤如下:A method for manufacturing a sol-based fully transparent TFT active matrix, characterized in that the gate electrode layer, active layer, source-drain electrode layer and protective layer of the TFT active matrix are fabricated by means of sol spin coating. The manufacturing process steps are as follows:

1) 利用旋涂机在清洗洁净的玻璃基板上旋涂栅极溶胶材料,使栅极溶胶材料均匀分布在玻璃基板之上;对溶胶材料均进行前烘固化,之后进行曝光光刻处理,显影、后烘,得到栅极图形;1) Use a spin coater to spin-coat the gate sol material on the cleaned glass substrate, so that the gate sol material is evenly distributed on the glass substrate; all the sol materials are pre-baked and cured, and then exposed to photolithography and developed , post-baking to obtain the gate pattern;

2) 旋涂一层有机绝缘膜作为绝缘层,加热前烘,曝光、显影、后烘,从而实现绝缘层图形的转移;2) Spin-coat a layer of organic insulating film as the insulating layer, bake before heating, expose, develop, and post-baking, so as to realize the transfer of the insulating layer pattern;

3) 旋涂构成有源层的溶胶材料,之后进行前烘、曝光、显影、后烘,湿法刻蚀有源层,从而实现有源层材料的制备以及有源层图形的转移;3) Spin-coat the sol material that constitutes the active layer, then perform pre-baking, exposure, development, post-baking, and wet-etch the active layer, so as to realize the preparation of the active layer material and the transfer of the active layer pattern;

4) 旋涂构成源漏电极层的溶胶材料,并作前烘、曝光、显影、后烘,将源电极、漏电极的图形转移到基板之上;4) Spin-coat the sol material that constitutes the source-drain electrode layer, and perform pre-baking, exposure, development, and post-baking to transfer the pattern of the source electrode and the drain electrode to the substrate;

5) 旋涂构成保护层的溶胶材料,经过前烘、曝光、显影、后烘之后,制作出接触孔,从而将接触孔图形转移到基板之上。5) Spin-coat the sol material that constitutes the protective layer. After pre-baking, exposure, development, and post-baking, contact holes are made, so that the contact hole pattern is transferred to the substrate.

至此,本发明的溶胶式全透明TFT有源矩阵制造工艺完成。So far, the sol-type fully transparent TFT active matrix manufacturing process of the present invention is completed.

本发明与现有技术相比较,具有如下显而易见的突出实质性特点和显著优点:Compared with the prior art, the present invention has the following obvious outstanding substantive features and significant advantages:

本发明制造的TFT有源矩阵为全透明的、溶胶式方法制造,制作工艺简单,并且对设备的投入要求低,制造的TFT有源矩阵开口率增加。The TFT active matrix manufactured by the invention is fully transparent and manufactured by a sol-type method, the manufacturing process is simple, and the investment requirement for equipment is low, and the aperture ratio of the manufactured TFT active matrix is increased.

附图说明Description of drawings

图1 传统TFT有源矩阵制造方式工艺流程框图;Figure 1 Traditional TFT active matrix manufacturing process flow diagram;

图2 本发明基于溶胶式全透明TFT有源矩阵制造方法工艺流程框图;Fig. 2 The present invention is based on sol-type fully transparent TFT active matrix manufacturing method process flow block diagram;

图3-图12 溶胶式全透明TFT有源矩阵制造工艺流程中TFT有源矩阵的结构示意图。Figure 3-Figure 12 Schematic diagram of the structure of the TFT active matrix in the sol-type fully transparent TFT active matrix manufacturing process.

具体实施方式Detailed ways

下面结合附图对本发明的优选实施例进行说明:Preferred embodiments of the present invention are described below in conjunction with accompanying drawing:

实施例1:     参见图2,本发明基于溶胶式全透明TFT有源矩阵制造方法,采用旋涂机旋涂的方式将溶胶均匀涂布到基板之上,并且直接通过光刻、显影的方式实现各层膜的图形制作,Embodiment 1: Referring to Figure 2, the present invention is based on the sol-type fully transparent TFT active matrix manufacturing method, and the sol is evenly coated on the substrate by means of spin coating machine, and is directly realized by photolithography and development. The graphic production of each layer of film,

从而实现TFT有源矩阵的制造。Thereby realizing the manufacture of TFT active matrix.

首先在清洗洁净的玻璃基板10上均匀涂布一层ITO溶胶膜21,其中ITO溶胶膜21为光敏材料;将ITO溶胶膜21放在热板上前烘之后,对其曝光、显影,放在后烘热板上烘烤固化,制作完成栅极电极层20;下一步,均匀涂布一层绝缘层有机膜31,前烘之后作曝光、显影,并后烘固化制作成绝缘层30;均匀涂布一层IGZO溶胶膜41,同样经过前烘、曝光、显影、后烘等工艺之后,实现有源层40图形的转移;最后,在有源层40之上涂布源漏电极层50,采用ITO溶胶膜51,再次前烘、曝光、显影、后烘等工艺,制作成源电极52以及漏电极53;再次涂布一层绝缘层有机膜61作为保护层60,前烘、光刻、显影、后烘之后,形成接触孔62。First, evenly coat a layer of ITO sol film 21 on the cleaned glass substrate 10, wherein the ITO sol film 21 is a photosensitive material; after the ITO sol film 21 is placed on a hot plate, it is exposed and developed, and placed Bake and solidify on the post-baking hot plate to complete the grid electrode layer 20; the next step is to evenly coat a layer of insulating layer organic film 31, perform exposure and development after pre-baking, and post-baking and curing to form an insulating layer 30; Coating a layer of IGZO sol film 41, also after pre-baking, exposure, development, post-baking and other processes, the transfer of the pattern of the active layer 40 is realized; finally, the source and drain electrode layer 50 is coated on the active layer 40, Using the ITO sol film 51, pre-baking, exposure, development, post-baking and other processes are used to make the source electrode 52 and the drain electrode 53; a layer of insulating organic film 61 is applied again as the protective layer 60, and the pre-baking, photolithography, After development and post-baking, contact holes 62 are formed.

本发明的基于溶胶式全透明TFT有源矩阵制造完成。The sol-based fully transparent TFT active matrix of the present invention is manufactured.

实施例2:     本实施例与实施例1基本相同,特别之处在于:    参见图2,选取200mm′200mm的玻璃基板作为溶胶式全透明TFT有源矩阵制造的玻璃基板10;ITO溶胶膜21的配制物质成份包括:三甲氧基醋酸丁酯、丙二醇甲醚醋酸酯,粘度为13~15cP;IGZO溶胶膜41是将二水醋酸锌、硝酸镓水合物、硝酸铟水合物溶于氨水中配制而成。Embodiment 2: This embodiment is basically the same as Embodiment 1, and the special features are: Referring to Fig. 2, a glass substrate of 200mm'200mm is selected as the glass substrate 10 manufactured by the sol-type fully transparent TFT active matrix; the ITO sol film 21 The ingredients of the prepared materials include: trimethoxybutyl acetate, propylene glycol methyl ether acetate, and the viscosity is 13~15cP; IGZO sol film 41 is prepared by dissolving zinc acetate dihydrate, gallium nitrate hydrate, and indium nitrate hydrate in ammonia water. become.

参见图3和图4,首先在玻璃基板10上均匀涂布厚度为300nm的ITO溶胶膜21,ITO溶胶膜21为光敏性材料,可直接光刻显影制作;将ITO溶胶膜21放置在热板上,在120℃情形下烘烤12分钟,之后在栅极电极掩膜板下曝光,曝光剂量为250mJ/cm-2,放置于显影液中显影、清洗、吹干之后,再在220℃之下烘烤60分钟,使ITO溶胶膜21完全固化,栅极电极层20制作完成。Referring to Fig. 3 and Fig. 4, at first on the glass substrate 10 uniform coating thickness is the ITO sol film 21 of 300nm, ITO sol film 21 is a photosensitive material, can directly photolithographic development manufacture; ITO sol film 21 is placed on the hot plate On the surface, bake at 120°C for 12 minutes, then expose under the gate electrode mask, the exposure dose is 250mJ/cm -2 , place it in a developer for development, wash, and dry, and then expose it at 220°C Bake for 60 minutes to completely cure the ITO sol film 21 and complete the fabrication of the gate electrode layer 20 .

参见图5和图6,栅极电极层20之上均匀涂布一层厚度为200nm的绝缘层有机膜31作为绝缘层,本发明中选用的材料为JSR PC405G,其为光敏性材料;在90℃预烘60秒,之后光刻处理,曝光剂量为100 mJ/cm-2,再进行显影、清洗、吹干,放置于220℃之下烘烤60分钟,使绝缘层有机膜31完全固化,绝缘层30制作完成。Referring to Fig. 5 and Fig. 6, on the gate electrode layer 20, evenly coating one deck thickness is the insulating layer organic film 31 of 200nm as insulating layer, and the material selected for use in the present invention is JSR PC405G, and it is photosensitive material; Pre-baking at ℃ for 60 seconds, followed by photolithography treatment with an exposure dose of 100 mJ/cm -2 , development, cleaning, drying, and baking at 220°C for 60 minutes to completely cure the organic film 31 of the insulating layer. The insulating layer 30 is finished.

参见图7和图8,绝缘层30之上均匀涂布一层厚度为300nm的IGZO溶胶膜41,在180℃温度下加热烘烤60分钟,制作完成有源层;之后在其表面涂布光刻胶,经过前烘、曝光、显影、清洗、吹干、后烘等工艺步骤之后,对其进行湿法刻蚀,利用IGZO刻蚀液刻蚀,得到有源层40图形,之后再进行脱膜、清洗、吹干,有源层40制作完成。Referring to Figures 7 and 8, an IGZO sol film 41 with a thickness of 300nm is evenly coated on the insulating layer 30, heated and baked at 180°C for 60 minutes to complete the active layer; Resist, after pre-baking, exposure, development, cleaning, drying, post-baking and other process steps, it is wet-etched, etched with IGZO etching solution to obtain the pattern of the active layer 40, and then stripped Filming, washing, and drying, the active layer 40 is fabricated.

参见图9和图10,再次涂布ITO溶胶膜51,涂布厚度为200nm,将ITO溶胶膜51放置在热板上,在120℃情形下烘烤12分钟,经过曝光、显影、清洗、吹干之后,再在220℃之下烘烤60分钟,使ITO溶胶膜51完全固化;光刻之后得到源电极52以及漏电极53图形;源漏电极层50制作完成。Referring to Fig. 9 and Fig. 10, coat the ITO sol film 51 again with a coating thickness of 200nm, place the ITO sol film 51 on a hot plate, and bake it at 120°C for 12 minutes, after exposure, development, cleaning, blowing, etc. After drying, bake at 220° C. for 60 minutes to completely cure the ITO sol film 51 ; obtain the pattern of the source electrode 52 and the drain electrode 53 after photolithography; the source-drain electrode layer 50 is completed.

参见图11和图12,涂布一层厚度为300nm的绝缘层有机膜61,采用与绝缘层30相同的材料与工艺条件制作,掩膜板采用接触孔掩膜板制作,经曝光、显影、清洗、吹干、后烘之后,形成接触孔62图形,保护层60制作完成。Referring to Fig. 11 and Fig. 12, an insulating layer organic film 61 with a thickness of 300nm is coated, which is manufactured using the same materials and process conditions as the insulating layer 30, and the mask plate is made of a contact hole mask plate, after exposure, development, After cleaning, drying, and post-baking, a pattern of contact holes 62 is formed, and the protective layer 60 is completed.

至此,基于溶胶式全透明TFT有源矩阵的制造工艺完成。So far, the manufacturing process based on the sol-type fully transparent TFT active matrix is completed.

Claims (1)

1.一种基于溶胶式全透明TFT有源矩阵制造方法,其特征在于采用溶胶旋涂的方式实现TFT有源矩阵的栅极电极层(20)、绝缘层(30)、有源层(40)、源漏电极层(50)以及保护层(60)的制作,其制作工艺步骤如下:1) 利用旋涂机在清洗洁净的玻璃基板(10)上旋涂栅极溶胶材料,使栅极溶胶材料均匀分布在玻璃基板(10)之上;对溶胶材料均进行前烘固化,之后进行曝光光刻处理,显影、后烘,得到栅极电极层(20)图形;2) 旋涂一层绝缘有机膜(31)作为绝缘层(30),加热前烘,曝光、显影、后烘,从而实现绝缘层(30)图形的转移;3) 旋涂构成有源层(40)溶胶材料,之后进行前烘、曝光、显影、后烘,湿法刻蚀有源层(40),从而实现有源层材料的制备以及有源层(40)图形的转移;4) 旋涂构成源漏电极层(50)溶胶材料,并作前烘、曝光、显影、后烘,将源电极、漏电极的图形转移到基板之上;5) 旋涂保护层(60)的有机材料,经过前烘、曝光、显影、后烘之后,制作出接触孔(62),从而将接触孔图形转移到基板之上。1. A method for manufacturing a fully transparent TFT active matrix based on sol formula, characterized in that the gate electrode layer (20), insulating layer (30), active layer (40) of TFT active matrix are realized by means of sol spin coating ), the source-drain electrode layer (50) and the protective layer (60), the manufacturing process steps are as follows: 1) use a spin coater to spin-coat the grid sol material on the cleaned glass substrate (10), so that the grid The sol material is evenly distributed on the glass substrate (10); the sol material is pre-baked and cured, and then exposed to photolithography, developed, and post-baked to obtain the pattern of the gate electrode layer (20); 2) spin-coating a layer The insulating organic film (31) is used as the insulating layer (30), which is baked before heating, exposed, developed, and post-baked, thereby realizing the transfer of the pattern of the insulating layer (30); 3) spin-coating the sol material to form the active layer (40), and then Perform pre-baking, exposure, development, post-baking, and wet-etch the active layer (40), thereby realizing the preparation of the active layer material and the transfer of the pattern of the active layer (40); 4) Spin coating to form the source-drain electrode layer (50) sol material, and do pre-baking, exposure, development, post-baking, transfer the pattern of source electrode and drain electrode to the substrate; , developing, and post-baking, making a contact hole (62), so that the contact hole pattern is transferred to the substrate.
CN2010106106406A 2010-12-29 2010-12-29 Fully transparent TFT (Thin Film Transistor) active matrix manufacturing method based on colloidal sol mode Pending CN102117767A (en)

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Application publication date: 20110706