CN102107536B - Forming equipment and forming method for macrofiber-reinforced thermoplastic resin - Google Patents
Forming equipment and forming method for macrofiber-reinforced thermoplastic resin Download PDFInfo
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- 229920005992 thermoplastic resin Polymers 0.000 title claims description 24
- 238000000034 method Methods 0.000 title description 14
- 239000000835 fiber Substances 0.000 claims abstract description 292
- 229920005989 resin Polymers 0.000 claims abstract description 54
- 239000011347 resin Substances 0.000 claims abstract description 54
- 239000000155 melt Substances 0.000 claims abstract description 28
- 238000000465 moulding Methods 0.000 claims abstract description 18
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- 230000000694 effects Effects 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 238000005470 impregnation Methods 0.000 claims description 43
- 238000010438 heat treatment Methods 0.000 claims description 17
- 238000009826 distribution Methods 0.000 claims description 4
- 238000006424 Flood reaction Methods 0.000 claims 1
- 229920001431 Long-fiber-reinforced thermoplastic Polymers 0.000 abstract description 18
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000007493 shaping process Methods 0.000 description 8
- 230000008595 infiltration Effects 0.000 description 5
- 238000001764 infiltration Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000005485 electric heating Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 238000009434 installation Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
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Abstract
本发明公开了一种长纤维增强热塑性树脂的成型设备,包括:纤维圈分解成纤维束并预处理的设备,其纤维束独立通道与纤维预蓬松与预热系统连接;熔融树脂对纤维充分浸渍及成型设备,其熔体入口口模通过熔体流入通道与纤维浸渍体相通,并倾斜向上一定角度,纤维入口口模用以连接纤维预蓬松与预热系统和纤维浸渍体,能够使得纤维水平进入纤维浸渍体、纤维浸渍体的另一端与成型口模相连接。其制备方法,包括:(一)20~40束纤维通过各自的独立通道后,以“一”字排开的方式进入纤维预蓬松与预热系统,纤维束通过预热导辊时,纤维与导辊圆弧表面接触,在牵引力的拉伸作用下,纤维束呈布或带状,纤维束起到了预蓬松处理作用;(二)预蓬松与预热后的纤维束水平牵入纤维入口口模、浸渍体纤维入孔后,上下交错穿过浸渍体内纤维张力辊,纤维束在与纤维张力辊接触时呈布状或带状;(三)浸润好的长纤维与料流一起通过浸渍体的输出流道、成型口模。其优点在于,可获得较长纤维树脂的同时降低成本。
The invention discloses a long-fiber-reinforced thermoplastic resin molding device, which includes: a device for decomposing fiber loops into fiber bundles and pretreating them; the independent channel of the fiber bundles is connected with a fiber pre-fluffing and preheating system; the molten resin fully impregnates the fibers And forming equipment, the melt inlet die communicates with the fiber impregnated body through the melt inflow channel, and is inclined upward at a certain angle. The fiber inlet die is used to connect the fiber pre-fluffing and preheating system and the fiber impregnated body, which can make the fiber level Enter the fiber impregnated body, and the other end of the fiber impregnated body is connected with the forming die. Its preparation method includes: (1) After 20~40 bundles of fibers pass through their own independent channels, they enter the fiber pre-fluffing and preheating system in the form of a "one" line. When the fiber bundles pass through the preheating guide roller, the fibers and The surface of the guide roller is in contact with the circular arc, and under the stretching effect of the traction force, the fiber bundles are in the shape of cloth or ribbon, and the fiber bundles play a role in pre-fluffing treatment; (2) The pre-fluffing and preheated fiber bundles are drawn horizontally into the fiber inlet After the fiber of the mold and the impregnated body enters the hole, it passes through the fiber tension roller in the impregnated body staggered up and down, and the fiber bundle is in the shape of cloth or ribbon when it contacts the fiber tension roller; (3) The soaked long fiber passes through the impregnated body together with the material flow The output runner and forming die. The advantage is that longer fiber resins can be obtained while reducing costs.
Description
技术领域 technical field
本发明涉及一种长纤维增强热塑性树脂的成型设备,具体地说,包括纤维圈分解成纤维束并预处理设备、熔融树脂对纤维充分浸渍及成型设备;本发明还涉及一种长纤维增强热塑性树脂的成型方法。 The present invention relates to a long-fiber-reinforced thermoplastic resin molding equipment, specifically, including fiber loops decomposed into fiber bundles and pretreatment equipment, molten resin fully impregnating and forming equipment for fibers; the present invention also relates to a long-fiber-reinforced thermoplastic resin Resin molding method.
背景技术 Background technique
长纤维增强热塑性树脂指的是纤维取向完全是同一方向,所制得的纤维长度与塑料粒子长度一致。它与常规方法制备的纤维增强树脂相比:机械性能更好,赋予制品更高的刚度、强度和抗冲击力、抗蠕变及更好的微观质量。在汽车工业、家电、机械等场所能代替部分铸铁、铝和热固性塑料等,可有效降低制品的重量与制造成本。 Long fiber reinforced thermoplastic resin means that the fiber orientation is completely in the same direction, and the length of the obtained fiber is consistent with the length of the plastic particle. Compared with fiber-reinforced resins prepared by conventional methods, it has better mechanical properties, endows products with higher stiffness, strength, impact resistance, creep resistance and better microscopic quality. In the automotive industry, home appliances, machinery and other places, it can replace some cast iron, aluminum and thermosetting plastics, etc., which can effectively reduce the weight and manufacturing cost of the product.
目前,熔体浸渍法是长纤维增强热塑性树脂的主要方法,其工艺过程是将连续的长纤维在张力的牵引下导入一个具有特殊结构的浸渍体内,同时从挤出机输入的塑料熔体将导入的长纤维浸泡,而后长纤维从浸渍体的口模拉出,经冷却后,切断成所需长度的粒料。但已公开的专利都存在一些共同的缺陷:1)树脂对纤维浸润效果差,纤维在穿过浸渍体时易断裂,从而影响产品的品质与生产效率;2)浸渍体与熔体入口口模、纤维入口口模、定型口模为一个整体,当上述口模流道由于磨损而需要更换时造成成本较高。因而需要纤维浸渍设备和纤维拉伸方法进行改进。 At present, the melt impregnation method is the main method of long fiber reinforced thermoplastic resin. The process is to introduce the continuous long fiber into an impregnation body with a special structure under the traction of tension, and at the same time, the plastic melt input from the extruder will be The imported long fiber is soaked, and then the long fiber is pulled out from the die of the impregnated body, and after cooling, it is cut into pellets of required length. However, the published patents all have some common defects: 1) The resin has poor impregnation effect on the fiber, and the fiber is easy to break when passing through the impregnated body, thus affecting the quality and production efficiency of the product; 2) The impregnated body and the melt inlet die , the fiber inlet die, and the shaping die are integrated, and the cost is relatively high when the above-mentioned die flow path needs to be replaced due to wear and tear. Therefore, fiber impregnation equipment and fiber drawing methods are required to be improved.
中国专利200680049562.9公开了一种长纤维增强热塑性树脂材料的制造装置及其制造方法,其所述的浸渍模具有在内部收纳熔融热塑性树脂的浸渍室、用于向所述浸渍室内供给热塑性树脂的树脂供给通路、设于所述浸渍室的上游侧的入口板上并用于向所述浸渍室的下游侧的出口板上兵用于将浸渍有熔融热塑性树脂的纤维束向外部拉拔的多个拉拔孔,所述入口板的各导入孔在入口板的外侧设有能分别开闭各导入孔的闸门。 Chinese patent 200680049562.9 discloses a long-fiber-reinforced thermoplastic resin material manufacturing device and its manufacturing method. The impregnation mold has an impregnation chamber for accommodating molten thermoplastic resin, and a resin for supplying thermoplastic resin to the impregnation chamber. A supply passage, an inlet plate provided on the upstream side of the impregnation chamber, and a plurality of pullers for drawing fiber bundles impregnated with molten thermoplastic resin to the outside toward the outlet plate on the downstream side of the impregnation chamber. The holes are drawn, and each introduction hole of the entrance plate is provided with a gate on the outside of the entrance plate, which can open and close each introduction hole respectively.
中国专利200610122459.4公开了一种连续长纤维增强热塑性树脂的成型方法及其成型设备,包括熔融浸渍模,其所述的熔融浸渍模包括浸渍模外体以及设在浸渍模外体中的热塑性树脂熔体夹缝流道,浸渍独立流道,连续长纤维入口通道和浸渍出口,所述的热塑性树脂熔体夹缝流道设在浸渍模外体的上游端,浸渍出口设在浸渍设备外体下游端且与浸渍独立流道末端连通,浸渍独立流道中还设有至少一组可自由旋转的张力辊。 Chinese patent 200610122459.4 discloses a continuous long fiber reinforced thermoplastic resin molding method and its molding equipment, including a melt impregnation mold, the melt impregnation mold includes an impregnated outer body and a thermoplastic resin melt in the impregnated outer body. Body gap flow channel, impregnation independent flow channel, continuous long fiber inlet channel and impregnation outlet, the thermoplastic resin melt gap flow channel is set at the upstream end of the impregnation mold outer body, and the impregnation outlet is set at the downstream end of the impregnation equipment outer body and It communicates with the end of the independent impregnation flow channel, and at least one set of freely rotatable tension rollers is arranged in the independent impregnation flow channel.
中国专利201010105774.2公开了一种长纤维增强热塑性树脂的制造装置,包括熔体浸渍室,浸渍室内容纳用于浸渍纤维束的树脂熔体,熔体浸渍室一个侧壁上设置有纤维束入口、在熔体浸渍室的与设置纤维束入口的侧壁相对的侧壁上设有纤维束出口,纤维束出口数目小于纤维束入口的数目所述增强纤维树脂束为增强纤维树脂成型材料。 Chinese patent 201010105774.2 discloses a long-fiber-reinforced thermoplastic resin manufacturing device, including a melt impregnation chamber, which contains a resin melt for impregnating fiber bundles, and a fiber bundle inlet is provided on one side wall of the melt impregnation chamber. Fiber bundle outlets are provided on the side wall of the melt impregnation chamber opposite to the side wall where fiber bundle inlets are provided, and the number of fiber bundle outlets is smaller than the number of fiber bundle inlets. The reinforced fiber resin bundles are reinforced fiber resin molding materials.
上述在先专利的缺点在于,(1)从熔融树脂以水平的方式进入浸渍体,而长纤维呈布或带的形状的长度稍大于接触长度,在弯曲通道非接触点纤维由于受到拉伸力而迅速恢复到圆束状,降低了熔融树脂对圆形束状中心纤维浸润效果;(2)纤维束由许多纤维丝粘接在一起影响熔融树脂对纤维的浸润效果;(3)纤维与树脂的温差过大,会造成纤维的浸润不良;(4)纤维入口口模流道、熔体入口口模流道,浸渍流道与定型口模流道为一个整体的部件,容易造成设备的磨损,从而造成整个浸渍体需要重新更换,浪费安装成本。 The disadvantages of the above-mentioned prior patents are that (1) the molten resin enters the impregnated body in a horizontal manner, and the length of the long fibers in the shape of cloth or tape is slightly longer than the contact length, and the fibers at the non-contact point of the curved channel are subjected to tensile force However, it quickly returns to the round bundle shape, which reduces the infiltration effect of the molten resin on the circular bundle-shaped central fiber; (2) The fiber bundle is bonded together by many fiber filaments to affect the infiltration effect of the molten resin on the fiber; (3) Fiber and resin If the temperature difference is too large, it will cause poor infiltration of the fiber; (4) The fiber inlet die flow channel, the melt inlet die flow channel, the impregnation flow channel and the shaping die flow channel are an integral part, which is easy to cause equipment wear , so that the entire impregnated body needs to be replaced, wasting installation costs.
发明内容 Contents of the invention
本发明的目的在于克服现有长纤维增强热塑性树脂制备设备中的各种缺陷,提供一种能稳定生产且纤维束能得到理想浸润效果的长纤维增强热塑性树脂的设备。 The purpose of the present invention is to overcome various defects in the existing long-fiber-reinforced thermoplastic resin preparation equipment, and provide a long-fiber-reinforced thermoplastic resin equipment that can stably produce long-fiber-reinforced thermoplastic resin with ideal infiltration effect for fiber bundles.
本发明的另一个目的在于提供一种可提高长纤维增强热塑性树脂产品的生产效率、品质的制造方法。 Another object of the present invention is to provide a production method capable of improving the production efficiency and quality of long fiber reinforced thermoplastic resin products.
长纤维增强热塑性树脂的成型设备,包括: Molding equipment for long fiber reinforced thermoplastic resins, including:
纤维圈分解成纤维束并预处理的设备,其纤维束独立通道与纤维预蓬松与预热系统连接; Fiber loops are decomposed into fiber bundles and pretreated, and the fiber bundle independent channel is connected to the fiber pre-fluffing and preheating system;
熔融树脂对纤维充分浸渍及成型设备,其熔体入口口模通过熔体流入通道与纤维浸渍体相通,并倾斜向上一定角度,纤维入口口模用以连接纤维预蓬松与预热系统和纤维浸渍体,能够使得纤维水平进入纤维浸渍体、纤维浸渍体的另一端与成型口模相连接。 The molten resin fully impregnates the fiber and forms the equipment. The melt inlet die communicates with the fiber impregnated body through the melt inflow channel, and is inclined upward at a certain angle. The fiber inlet die is used to connect the fiber pre-fluffing and preheating system and fiber impregnation. The body can make the fiber enter the fiber impregnated body horizontally, and the other end of the fiber impregnated body is connected with the forming die.
另外,所述熔体入口口模、纤维入口口模、成型口模与纤维浸渍体之间可拆卸并灵活组合;所述纤维束独立通道为纤维导管;纤维独立通道呈1~4层分布,每层纤维束通道并排展开;所述纤维预蓬松与预热系统内包括预蓬松与预热导辊或可调整导辊高度及距离的支撑架;所述纤维预蓬松与预热导辊共有4~6组,沿导辊圆周方向的表面开有15~40道弧形小沟槽,每导沟槽间的中心距15~22mm;所述纤维预蓬松与预热导辊为电加热或油加热,预热温度在80~250℃;预蓬松与预热导辊的高度与水平距离可自由调节;熔体入口口模与水平呈一斜向上30°~45°角度;纤维浸渍体通过纤维输入流道与纤维入口口模相连,纤维浸渍体内的腔体中有纤维张力辊,其另一端通过输出流道与成型口模连接;纤维输入流道横截面呈圆形,直径2~5mm;浸渍体的输出流道的横截面呈圆形直径2.5~5mm;纤维张力辊的横截面开有2~6个内凹特征的圆弧形或内凹多边形的小沟槽;成型口模通过螺栓固定在纤维浸渍体的外壁,并可自由拆卸与更换,成型口模的外侧还有树脂收集装置;成型口模流道的横截面呈圆形,沿熔体流动方向,横截面的直径逐渐减小,起始截面的直径为3~5mm,末端截面的直径为2.5mm~3.5mm;成型口模的模口外表面与竖直方向呈向下15°~60°的角度,出口面上的口模孔之间开有小凹槽。 In addition, the melt inlet die, fiber inlet die, forming die and fiber impregnated body can be disassembled and flexibly combined; the fiber bundle independent channel is a fiber conduit; the fiber independent channel is distributed in 1-4 layers, Each layer of fiber bundle passages is developed side by side; the fiber pre-fluffing and preheating system includes pre-fluffing and preheating guide rollers or a support frame that can adjust the height and distance of the guide rollers; the fiber pre-fluffing and preheating guide rollers have 4 ~6 groups, there are 15~40 arc-shaped small grooves on the surface along the circumferential direction of the guide roller, and the center distance between each guide groove is 15~22mm; the fiber pre-fluffing and preheating guide rollers are electric heating or oil heating Heating, the preheating temperature is 80~250℃; the height and horizontal distance of the pre-fluffing and preheating guide rollers can be adjusted freely; the melt inlet die and the horizontal form an oblique angle of 30°~45°; the fiber impregnated body passes through the fiber The input channel is connected to the fiber inlet die, and there is a fiber tension roller in the cavity of the fiber impregnation body, the other end of which is connected to the forming die through the output channel; the cross section of the fiber input channel is circular, with a diameter of 2~5mm; The cross-section of the output flow channel of the impregnated body is circular with a diameter of 2.5~5mm; the cross-section of the fiber tension roller has 2~6 arc-shaped or concave polygonal small grooves with concave characteristics; the forming die passes through the bolt It is fixed on the outer wall of the fiber impregnated body and can be disassembled and replaced freely. There is also a resin collection device on the outside of the forming die; the cross section of the flow channel of the forming die is circular, and the diameter of the cross section decreases gradually along the direction of melt flow. Small, the diameter of the initial section is 3~5mm, and the diameter of the end section is 2.5mm~3.5mm; the outer surface of the die mouth of the forming die is at an angle of 15°~60°downward to the vertical direction, and the mouth on the exit surface There are small grooves between the die holes.
熔融树脂对纤维充分浸渍及成型设备中,纤维进入浸渍体的纤维入口口模,熔融树脂浸润纤维的浸渍体,增加纤维浸润性能的张力辊,熔融树脂入口口模,定型口模。纤维入口口模、熔融树脂入口口模及定型口模通过固定结构获螺栓装配在浸渍体外侧,其中纤维入口口模、定型口模及浸渍体的进出口流道在同一水平线上,熔融树脂入口口模安装在浸渍体的下方,流道方向沿水平向上30~45°。张力辊组安装在浸渍体内,张力辊的横截面内凹特征的圆弧形或内凹多边形的小沟槽,张力辊的外表面有20~40道内凹的圆弧槽。浸渍体由纤维输入孔、熔体输入流道、浸渍腔及料流输出孔组成,沿熔体流动方向,浸渍腔截面呈梯形,熔体从浸渍体的底面流入浸渍腔。 The molten resin fully impregnates the fiber and the molding equipment, the fiber enters the fiber entrance die of the impregnated body, the molten resin infiltrates the fiber impregnated body, the tension roller increases the fiber impregnation performance, the molten resin enters the die, and the shaping die. The fiber inlet die, the molten resin inlet die and the shaping die are assembled on the outside of the impregnated body by bolts through the fixed structure. The die is installed under the impregnated body, and the direction of the flow channel is 30~45° horizontally upward. The tension roller group is installed in the dipping body, the cross section of the tension roller is concave in the circular arc shape or the concave polygonal small groove, and the outer surface of the tension roller has 20~40 concave arc grooves. The impregnation body is composed of a fiber input hole, a melt input channel, an impregnation cavity and a material flow output hole. Along the direction of melt flow, the section of the impregnation cavity is trapezoidal, and the melt flows into the impregnation cavity from the bottom surface of the impregnation body.
长纤维增强热塑性树脂的制备方法,包括: A method for preparing a long fiber reinforced thermoplastic resin, comprising:
(一)20~40束纤维通过各自的独立通道后,以“一”字排开的方式进入纤维预蓬松与预热系统,纤维束通过预热导辊时,纤维与导辊圆弧表面接触,在牵引力的拉伸作用下,纤维束呈布或带状,纤维束起到了预蓬松处理作用; (1) After 20~40 bundles of fibers pass through their respective independent channels, they enter the fiber pre-fluffing and preheating system in the form of a "one" line. When the fiber bundles pass through the preheating guide roller, the fiber is in contact with the arc surface of the guide roller. , under the stretching action of the traction force, the fiber bundles are in the shape of cloth or ribbon, and the fiber bundles play the role of pre-fluffing treatment;
(二)预蓬松与预热后的纤维束水平牵入纤维入口口模、浸渍体纤维入孔后,上下交错穿过浸渍体内纤维张力辊,纤维束在与纤维张力辊接触时呈布状或带状; (2) The pre-fluffed and preheated fiber bundles are drawn horizontally into the fiber inlet die and impregnated body fibers into the holes, and then crossed up and down through the fiber tension rollers in the impregnated body. The fiber bundles are cloth-like or in contact with the fiber tension rollers Ribbon;
(三)浸润好的长纤维与料流一起通过浸渍体的输出流道、成型口模。 (3) The infiltrated long fibers pass through the output channel of the impregnated body and the forming die together with the material flow.
另外,所述纤维预蓬松与预热导辊可电加热或油加热,预热温度在80~250℃。 In addition, the fiber pre-fluffing and preheating guide rollers can be heated by electricity or oil, and the preheating temperature is 80-250°C.
第一步中,纤维束通过预热导辊时,纤维与导辊圆弧表面接触,在牵引力的拉伸作用下,纤维束呈布或带状,纤维束起到了预蓬松处理作用,这种预蓬松处理不仅有利于预热导滚的热能较好的传递至纤维束中心区,而且对后续浸润效率有提高作用; In the first step, when the fiber bundles pass through the preheating guide roller, the fibers are in contact with the arc surface of the guide roller, and under the stretching action of the traction force, the fiber bundles are in the shape of cloth or ribbon, and the fiber bundles play a role of pre-fluffing treatment. The pre-fluffing treatment is not only conducive to the better transfer of heat energy of the preheating guide roll to the central area of the fiber bundle, but also improves the subsequent infiltration efficiency;
第二步中,熔融树脂能较好的浸润至纤维的中心区,由于本发明的张力辊的特殊结构,纤维束通过一根张力辊时,至少有两次与张力辊接触,且能使得两个接触点之间的纤维束一直呈布或带状,这样大大提高纤维浸润效率,在降低纤维张力的条件下足够保证纤维浸润效果,因而可提升长纤维的牵引速率,达到提升产能的目的。挤出机来的熔融树脂由下向上流入浸渍腔,重力的因素降低了中心区与边缘区的料流速度差异,从而保证流道中心区与边缘区物料更新速度尽可能一致,克服边缘区长纤维增强树脂易出现黄线条的品质缺陷。 In the second step, the molten resin can better infiltrate into the central area of the fiber. Due to the special structure of the tension roller of the present invention, when the fiber bundle passes through a tension roller, it is at least twice in contact with the tension roller, and can make both The fiber bundles between the contact points are always in the shape of cloth or ribbon, which greatly improves the fiber wetting efficiency, and can ensure the fiber wetting effect under the condition of reducing the fiber tension, so that the pulling speed of long fibers can be increased to achieve the purpose of increasing production capacity. The molten resin from the extruder flows into the impregnation chamber from bottom to top, and the gravity factor reduces the difference in material flow velocity between the central area and the edge area, so as to ensure that the material renewal speed in the center area and the edge area of the runner is as consistent as possible, and overcome the long edge area. Fiber-reinforced resin is prone to quality defects such as yellow lines.
第三步中,操作者可通过改变口模口径的大小来调节产品中的纤维含量,定型口模是独立的,因此可大大降低口模更换与安装的成本。浸润好的长纤维增强树脂产品经过冷却后,根据市场的需要切成所需的长度。 In the third step, the operator can adjust the fiber content in the product by changing the diameter of the die. The shaping die is independent, so the cost of die replacement and installation can be greatly reduced. After the impregnated long fiber reinforced resin product is cooled, it is cut into the required length according to the needs of the market.
与现有技术相比,本发明具有以下有益效果: Compared with the prior art, the present invention has the following beneficial effects:
Ⅰ) 采用纤维导管的方式通入待处理的纤维,使得每束长纤维都能够沿着独立的方向前进,避免了纤维束之间干扰,同时降低纤维束在牵引过程中的阻力,减少长纤维的折断,保证长时间的连续稳定的生产,在一定范围内轻松的提升长纤维牵引速度。 Ⅰ) The fibers to be treated are introduced in the way of fiber conduits, so that each bundle of long fibers can advance along an independent direction, avoiding interference between fiber bundles, and at the same time reducing the resistance of the fiber bundles during traction and reducing the length of long fibers The breakage ensures long-term continuous and stable production, and the long-fiber pulling speed can be easily increased within a certain range.
Ⅱ) 采用预蓬松与预热系统、并加入特殊形状的张力辊,足够保证长纤维的浸润效果,因而可在保证纤维浸润质量的前提下,顺利提升长纤维的牵引速度时,从而提升生产效率。 Ⅱ) The pre-fluffing and preheating system, and the addition of special-shaped tension rollers are sufficient to ensure the wetting effect of long fibers, so that the pulling speed of long fibers can be smoothly increased under the premise of ensuring the quality of fiber wetting, thereby improving production efficiency .
Ⅲ) 本发明采用从下往上熔融树脂进料方式,可降低流道边缘区物料更新速度与流道中心区的差异,减少边缘长纤维增强树脂产品出现黄线条的产品缺陷;同时定型口模的出口面设定为向下内倾,减少从定型口模溢流出的料流滞留在模头上,从而影响到口模出来。 Ⅲ) The present invention adopts the method of feeding molten resin from bottom to top, which can reduce the difference between the material renewal speed in the edge area of the flow channel and the center area of the flow channel, and reduce the product defects of long fiber reinforced resin products with yellow lines at the edge; at the same time, the die is shaped The outlet surface of the outlet is set to incline downward to reduce the material flow overflowing from the shaping die and stay on the die, thereby affecting the exit of the die.
Ⅳ) 纤维入口口模、熔融树脂入口口模及定型口模设计成可拆卸方式,与整体式浸渍模相比,能够大大降低由于磨损而需要更换的加工与使用成本。 Ⅳ) The fiber inlet die, molten resin inlet die and shaping die are designed to be detachable. Compared with the integral impregnation die, the processing and use costs that need to be replaced due to wear can be greatly reduced.
附图说明 Description of drawings
图1为本发明的结构示意图; Fig. 1 is a structural representation of the present invention;
图2熔融树脂对纤维充分浸渍及成型设备示意图; Fig. 2 Schematic diagram of fully impregnating and forming equipment for fibers by molten resin;
图3为定型口模横截面示意图。 Figure 3 is a schematic cross-sectional view of the shaping die.
具体实施方式 Detailed ways
实施例一 Embodiment one
如图1-3所示的熔体浸渍法制取长纤维增强热塑性树脂的设备,包括纤维圈分解成纤维束并预处理的设备,其纤维束独立通道1与纤维预蓬松与预热系统2连接;熔融树脂对纤维充分浸渍及成型设备,其熔体入口口模6通过熔体流入通道12与纤维浸渍体5相通,并倾斜向上一定角度,纤维入口口模4用以连接纤维预蓬松与预热系统2和纤维浸渍体5,能够使得纤维水平进入纤维浸渍体5、纤维浸渍体5的另一端与成型口模8相连接。
As shown in Figure 1-3, the equipment for producing long fiber reinforced thermoplastic resin by melt impregnation method includes the equipment for decomposing fiber loops into fiber bundles and pretreatment, and the fiber bundle independent channel 1 is connected with fiber pre-fluffing and preheating system 2 ; Molten resin fully impregnates fibers and molding equipment, and its melt inlet die 6 communicates with the fiber impregnated body 5 through the
另外,所述熔体入口口模6、纤维入口口模4、成型口模8与纤维浸渍体5之间可拆卸并灵活组合;所述纤维束独立通道1为纤维导管;纤维独立通道1呈4层分布,每层纤维束通道1并排展开;所述纤维预蓬松与预热系统2内包括预蓬松与预热导辊3或可调整导辊高度及距离的支撑架;所述纤维预蓬松与预热导辊3共有6组,沿导辊圆周方向的表面开有30道弧形小沟槽,每导沟槽间的中心距20mm;所述纤维预蓬松与预热导辊3为电加热或油加热,预热温度在200℃;预蓬松与预热导辊3的高度与水平距离可自由调节;熔体入口口模6与水平呈一斜向上45°角度;纤维浸渍体5通过纤维输入流道与纤维入口口模相连,纤维浸渍体5内的腔体15中有纤维张力辊7,其另一端通过输出流道14与成型口模8连接;纤维输入流道横截面呈圆形,直径5mm;浸渍体的输出流道13的横截面呈圆形直径5mm;纤维张力辊7的横截面开有6个内凹特征的圆弧形或内凹多边形的小沟槽;成型口模8通过螺栓固定在纤维浸渍体5的外壁,并可自由拆卸与更换,成型口模8的外侧还有树脂收集装置9;成型口模8流道的横截面呈圆形,沿熔体流动方向,横截面的直径逐渐减小,起始截面的直径为5mm,末端截面的直径为3.5mm;成型口模8的模口外表面与竖直方向呈向下60°的角度,出口面上的口模孔之间开有小凹槽17。
In addition, the melt inlet die 6, the fiber inlet die 4, the forming
长纤维增强热塑性树脂的制备方法,包括: A method for preparing a long fiber reinforced thermoplastic resin, comprising:
(一)20束纤维通过各自的独立通道后,以“一”字排开的方式进入纤维预蓬松与预热系统2,纤维束通过预热导辊3时,纤维与导辊圆弧表面接触,在牵引力的拉伸作用下,纤维束呈布或带状,纤维束起到了预蓬松处理作用,所述纤维预蓬松与预热导辊3可电加热或油加热,预热温度在200℃; (1) After 20 bundles of fibers pass through their respective independent channels, they enter the fiber pre-fluffing and preheating system 2 in the form of a "one" line. When the fiber bundles pass through the preheating guide roller 3, the fibers are in contact with the arc surface of the guide roller , under the stretching effect of the traction force, the fiber bundles are in the shape of cloth or ribbon, and the fiber bundles play a role of pre-fluffing treatment. The fiber pre-fluffing and preheating guide roller 3 can be heated by electricity or oil, and the preheating temperature is 200°C ;
(二)预蓬松与预热后的纤维束水平牵入纤维入口口模4、浸渍体纤维入孔后,上下交错穿过浸渍体内纤维张力辊7,纤维束在与纤维张力辊7接触时呈布状或带状;
(2) The pre-fluffed and preheated fiber bundles are drawn horizontally into the fiber entrance die 4. After the fibers of the impregnated body enter the hole, they cross up and down through the
(三)浸润好的长纤维与料流一起通过浸渍体的输出流道13、成型口模8。
(3) The infiltrated long fibers pass through the
实施例二 Embodiment two
如图1-3所示的熔体浸渍法制取长纤维增强热塑性树脂的设备,包括纤维圈分解成纤维束并预处理的设备,其纤维束独立通道1与纤维预蓬松与预热系统2连接;熔融树脂对纤维充分浸渍及成型设备,其熔体入口口模6通过熔体流入通道12与纤维浸渍体5相通,并倾斜向上一定角度,纤维入口口模4用以连接纤维预蓬松与预热系统2和纤维浸渍体5,能够使得纤维水平进入纤维浸渍体5、纤维浸渍体5的另一端与成型口模8相连接。
As shown in Figure 1-3, the equipment for producing long fiber reinforced thermoplastic resin by melt impregnation method includes the equipment for decomposing fiber loops into fiber bundles and pretreatment, and the fiber bundle independent channel 1 is connected with fiber pre-fluffing and preheating system 2 ; Molten resin fully impregnates fibers and molding equipment, and its melt inlet die 6 communicates with the fiber impregnated body 5 through the
另外,所述熔体入口口模6、纤维入口口模4、成型口模8与纤维浸渍体5之间可拆卸并灵活组合;所述纤维束独立通道1为纤维导管;纤维独立通道1呈4层分布,每层纤维束通道1并排展开;所述纤维预蓬松与预热系统2内包括预蓬松与预热导辊3或可调整导辊高度及距离的支撑架;所述纤维预蓬松与预热导辊3共有6组,沿导辊圆周方向的表面开有40道弧形小沟槽,每导沟槽间的中心距22mm;所述纤维预蓬松与预热导辊3为电加热或油加热,预热温度在250℃;预蓬松与预热导辊3的高度与水平距离可自由调节;熔体入口口模6与水平呈一斜向上30°角度;纤维浸渍体5通过纤维输入流道与纤维入口口模相连,纤维浸渍体5内的腔体15中有纤维张力辊7,其另一端通过输出流道13与成型口模8连接;纤维输入流道16横截面呈圆形,直径2mm;浸渍体的输出流道13的横截面呈圆形直径2mm;纤维张力辊7的横截面开有6个内凹特征的圆弧形或内凹多边形的小沟槽;成型口模8通过螺栓固定在纤维浸渍体5的外壁,并可自由拆卸与更换,成型口模8的外侧还有树脂收集装置9;成型口模8流道的横截面呈圆形,沿熔体流动方向,横截面的直径逐渐减小,起始截面的直径为3mm,末端截面的直径为2.5mm;成型口模8的模口外表面与竖直方向呈向下30°的角度,出口面上的口模孔之间开有小凹槽17。
In addition, the melt inlet die 6, the fiber inlet die 4, the forming die 8 and the fiber impregnated body 5 are detachable and flexibly combined; the fiber bundle independent channel 1 is a fiber conduit; the fiber independent channel 1 is 4-layer distribution, each layer of fiber bundle channel 1 is unfolded side by side; the fiber pre-fluffing and preheating system 2 includes pre-fluffing and preheating guide rollers 3 or a support frame that can adjust the height and distance of the guide rollers; the fiber pre-fluffing There are 6 groups with the preheating guide roller 3, and 40 arc-shaped small grooves are opened on the surface of the guide roller circumferential direction, and the center distance between each guide groove is 22mm; the fiber pre-fluffing and the preheating guide roller 3 are electric Heating or oil heating, the preheating temperature is 250°C; the height and horizontal distance of the pre-fluffing and preheating guide rollers 3 can be adjusted freely; the melt inlet die 6 is at an angle of 30° upward to the horizontal; the fiber impregnated body 5 passes through The fiber input flow channel is connected with the fiber inlet die, and there is a fiber tension roller 7 in the cavity 15 in the fiber impregnated body 5, and the other end thereof is connected with the forming die 8 through the output flow channel 13; the cross section of the fiber input flow channel 16 is Circular shape with a diameter of 2 mm; the cross-section of the output flow channel 13 of the impregnated body is circular with a diameter of 2 mm; the cross-section of the fiber tension roller 7 has 6 arc-shaped or concave polygonal small grooves with concave characteristics; forming The die 8 is fixed on the outer wall of the fiber impregnated body 5 by bolts, and can be disassembled and replaced freely. There is also a resin collection device 9 on the outside of the forming
其制备方法中,纤维预蓬松与预热导辊3可电加热或油加热,预热温度在250℃,其余与实施例一相同。 In the preparation method, the fiber pre-fluffing and pre-heating guide roller 3 can be heated by electricity or oil, and the pre-heating temperature is 250° C., and the rest are the same as the first embodiment.
实施例三 Embodiment Three
如图1-3所示的熔体浸渍法制取长纤维增强热塑性树脂的设备,包括纤维圈分解成纤维束并预处理的设备,其纤维束独立通道1与纤维预蓬松与预热系统2连接;熔融树脂对纤维充分浸渍及成型设备,其熔体入口口模6通过熔体流入通道12与纤维浸渍体5相通,并倾斜向上一定角度,纤维入口口模4用以连接纤维预蓬松与预热系统2和纤维浸渍体5,能够使得纤维水平进入纤维浸渍体5、纤维浸渍体5的另一端与成型口模8相连接。
As shown in Figure 1-3, the equipment for producing long fiber reinforced thermoplastic resin by melt impregnation method includes the equipment for decomposing fiber loops into fiber bundles and pretreatment, and the fiber bundle independent channel 1 is connected with fiber pre-fluffing and preheating system 2 ; Molten resin fully impregnates fibers and molding equipment, and its melt inlet die 6 communicates with the fiber impregnated body 5 through the
另外,所述熔体入口口模6、纤维入口口模4、成型口模8与纤维浸渍体5之间可拆卸并灵活组合;所述纤维束独立通道1为纤维导管;纤维独立通道1呈4层分布,每层纤维束通道1并排展开;所述纤维预蓬松与预热系统2内包括预蓬松与预热导辊3或可调整导辊高度及距离的支撑架;所述纤维预蓬松与预热导辊3共有6组,沿导辊圆周方向的表面开有40道弧形小沟槽,每导沟槽间的中心距15mm;所述纤维预蓬松与预热导辊3为电加热或油加热,预热温度在80℃;预蓬松与预热导辊3的高度与水平距离可自由调节;熔体入口口模6与水平呈一斜向上45°角度;纤维浸渍体5通过纤维输入流道与纤维入口口模相连,纤维浸渍体5内的腔体15中有纤维张力辊7,其另一端通过输出流道13与成型口模8连接;纤维输入流道横截面呈圆形,直径4mm;浸渍体的输出流道13的横截面呈圆形直径4mm;纤维张力辊7的横截面开有6个内凹特征的圆弧形或内凹多边形的小沟槽;成型口模8通过螺栓固定在纤维浸渍体5的外壁,并可自由拆卸与更换,成型口模8的外侧还有树脂收集装置9;成型口模8流道的横截面呈圆形,沿熔体流动方向,横截面的直径逐渐减小,起始截面的直径为4mm,末端截面的直径为3mm;成型口模8的模口外表面与竖直方向呈向下45°的角度,出口面上的口模孔之间开有小凹槽17。
In addition, the melt inlet die 6, the fiber inlet die 4, the forming die 8 and the fiber impregnated body 5 are detachable and flexibly combined; the fiber bundle independent channel 1 is a fiber conduit; the fiber independent channel 1 is 4-layer distribution, each layer of fiber bundle channel 1 is unfolded side by side; the fiber pre-fluffing and preheating system 2 includes pre-fluffing and preheating guide rollers 3 or a support frame that can adjust the height and distance of the guide rollers; the fiber pre-fluffing There are 6 groups with the preheating guide roller 3, and 40 arc-shaped small grooves are opened on the surface of the guide roller circumferential direction, and the center distance between each guide groove is 15mm; the fiber pre-fluffing and the preheating guide roller 3 are electric Heating or oil heating, the preheating temperature is 80°C; the height and horizontal distance of the pre-fluffing and preheating guide rollers 3 can be adjusted freely; the melt inlet die 6 is at an angle of 45° upward to the horizontal; the fiber impregnated body 5 passes through The fiber input flow channel is connected with the fiber inlet die, and the fiber tension roller 7 is arranged in the cavity 15 in the fiber impregnated body 5, and the other end thereof is connected with the forming die 8 through the output flow channel 13; the cross section of the fiber input flow channel is circular shape, diameter 4mm; the cross-section of the output channel 13 of the impregnated body is circular in diameter 4mm; the cross-section of the fiber tension roller 7 has 6 arc-shaped or concave polygonal small grooves with concave characteristics; the forming port The mold 8 is fixed on the outer wall of the fiber impregnated body 5 by bolts, and can be disassembled and replaced freely. There is also a resin collection device 9 on the outside of the forming
其制备方法中,纤维预蓬松与预热导辊3可电加热或油加热,预热温度在80℃,其余与实施例一相同。 In the preparation method, the fiber pre-fluffing and pre-heating guide roller 3 can be heated by electricity or oil, and the pre-heating temperature is 80° C., and the rest are the same as the first embodiment.
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CN111438967B (en) * | 2020-04-15 | 2022-02-01 | 北京机科国创轻量化科学研究院有限公司 | Forming device and process of long fiber reinforced thermoplastic resin composite material |
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CN202021821U (en) * | 2010-12-22 | 2011-11-02 | 绵阳东方特种工程塑料有限公司 | Long-fiber enhanced thermoplastic resin forming equipment |
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CA2205313C (en) * | 1996-05-28 | 2005-01-18 | Tecton Products | Method of manufacture of a plastic component which is insensitive to the elements, and a plastic component so manufactured |
FR2807967B1 (en) * | 2000-04-25 | 2003-01-17 | Lapeyre | JOINING ELEMENT FORMED FROM EXTRUDABLE ORGANIC MATERIAL REINFORCED BY REINFORCING FIBERS, METHOD AND DEVICE FOR MANUFACTURING |
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CH384196A (en) * | 1960-03-31 | 1964-11-15 | Honnigstad Birger | Method for impregnating strands of fibrous material |
CN1872913A (en) * | 2005-05-30 | 2006-12-06 | 中国石化仪征化纤股份有限公司 | Method for preparing polycondensation reaction type reinforced thermoplastic resin in long fibres |
CN101277800A (en) * | 2005-08-05 | 2008-10-01 | Ocv知识产权资产有限公司 | Method and apparatus for producing long fiber-reinforced thermoplastic resin molding material |
CN1775515A (en) * | 2005-12-08 | 2006-05-24 | 东华大学 | A kind of preparation method and equipment of continuous long fiber reinforced nylon 66 |
CN202021821U (en) * | 2010-12-22 | 2011-11-02 | 绵阳东方特种工程塑料有限公司 | Long-fiber enhanced thermoplastic resin forming equipment |
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