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CN102095049B - Vacuum heat-insulating plate capable of reducing price and preventing gas permeation and package method thereof - Google Patents

Vacuum heat-insulating plate capable of reducing price and preventing gas permeation and package method thereof Download PDF

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Publication number
CN102095049B
CN102095049B CN 201110058088 CN201110058088A CN102095049B CN 102095049 B CN102095049 B CN 102095049B CN 201110058088 CN201110058088 CN 201110058088 CN 201110058088 A CN201110058088 A CN 201110058088A CN 102095049 B CN102095049 B CN 102095049B
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layer
gas
top layer
insulating plate
vacuum heat
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Expired - Fee Related
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CN 201110058088
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CN102095049A (en
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周介明
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Xu Lijiang
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Suzhou VIP New Material Co Ltd
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Abstract

The invention discloses a vacuum heat-insulating plate capable of reducing price and preventing gas permeation. The vacuum heat-insulating plate comprises a surface gas separation layer, a glass fiber core material and sealing ports, wherein the surface layer of the outer surface of the glass fiber core material is wrapped by the gas separation layer, and the two ends of the glass fiber core material are provided with the sealing ports; and the gas separation layer on the surface layer consists of a surface heat sealing layer, a surface heat resistance layer, a surface gas resistance layer and a surface radiation protection layer from inside to outside in turn. Through the vacuum heat-insulating plate, the problem of influence of the gas permeation on vacuum degree is effectively solved; the overall service life of the entire vacuum heat-insulating plate is effectively maintained; and if many price reduction gas resistance and separation layers are available in the vacuum heat-insulating plate, a gas adsorbent can be saved, the production cost is reduced, and the vacuum heat-insulating plate has high safety and stability in use.

Description

A kind of vacuum heat-insulating plate and packaging method thereof of making a price reduction the inverse gas infiltration
Technical field
The invention belongs to the thermoinsulation material field of engineering technology, specifically relate to a kind of inverse gas infiltration vacuum heat-insulating plate and packaging method thereof take glass fibre as core.
Background technique
Low-carbon (LC) and energy-saving and emission-reduction have become the elementary tactics of national energy strategy and economic life, research institution of country is is actively researching and developing the low energy consumption product or is improving existing equipment with when reducing its energy consumption, and also pay attention to day by day improves the heat-insulating capability of enclosed structure to prevent excessively scattering and disappearing of energy.Vaccum thermal insulation technique just arises at the historic moment under this background.The low 5mW/(m ﹒ k that reaches of glass fibre core heat conductivity of vacuum insulation panel) below, be the best thermal insulating material of present heat-insulating property.China starts late to the development of vacuum heat-insulating plate, but its technology is day by day perfect in China, and a lot of enterprises in the whole nation are are all actively researching and developing vacuum heat-insulating plate.
Vacuum heat-insulating plate relies on and significantly improves internal vacuum and realize adiabaticly, and the key of its making is except will being pumped in the vacuum heat-insulating plate the extremely low atmospheric pressure, and vacuum is an important technology in the retaining plate within the whole vacuum heat-insulating plate cycle in working life.And this task mainly relies on barrier to finish.
At present, the barrier of vacuum heat-insulating plate all adopts composite material both at home and abroad, generally all adopt aluminium foil and polyester-based to be composited, conventional vacuum heat-insulating plate barrier package bag as shown in Figure 1, formed by two barrier heat-sealings, generally first with the heat-sealing of three limits, then the glass fibre core that pretreatment is good is filled in the bag-shaped barrier, through vacuum chamber with core in gas extract out, and the heat-sealing four edges gets final product in vacuum chamber; The product profile that consists of as shown in Figure 2.Conventional vacuum heat-insulating plate is larger because of differential pressure inside and outside the plate, inevitably having a small amount of gas is penetrated in the plate by barrier and sealing, thereby the riser internal pressure causes the increase of heat conductivity of vacuum insulation panel, affect its thermal property, thereby reduced its working life, even if the existence of gas adsorption material is arranged, thus can not be for a long time and effectively absorb the gas that penetrates in the plate and guarantee not rise in whole life cycle internal pressure.
Summary of the invention
Goal of the invention: the objective of the invention is in order to overcome the deficiencies in the prior art, a kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration is provided, this packaging method of making a price reduction the vacuum heat-insulating plate of inverse gas infiltration also is provided simultaneously.
Technological scheme: in order to solve the problems of the technologies described above, the invention provides a kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration, it comprises top layer gas barrier, glass fibre core and sealing; Glass fibre core outer surface parcel top layer gas barrier, two ends are provided with sealing; Described top layer gas barrier comprises: top layer hot sealing layer, top layer gas barrier layer, top layer heat resistant layer, top layer radiation protective layer; The top layer gas barrier sequentially is from inside to outside successively: top layer hot sealing layer, top layer heat resistant layer, top layer gas barrier layer, top layer radiation protective layer.Described top layer hot sealing layer adopts high density polyethylene (HDPE) or vinyl-acetic ester; The top layer gas barrier layer adopts polyvinyl alcohol or/and choke coats with lacquer, the general acrylic lacquer that adopts of choke lacquer; The top layer heat resistant layer adopts polyolefin, such as polyethylene or polypropylene or polyethylene and ethylene copolymers; The top layer radiation protective layer adopts metallic thin film, and metallic thin film generally adopts aluminium foil or stainless steel film.The thickness of top layer gas barrier is the 200-500 micron, and preferred 500 microns, the top layer gas barrier has lower gas permeability.
The core of glass fibre described in the present invention inside is provided with inner price reduction gas-barrier separated gas-bearing formation.Described inner price reduction gas-barrier separated gas-bearing formation is sandwich structure, and two-layer up and down is the internal heat seal, and middle one deck is inner gas barrier layer.The internal heat seal adopts high density polyethylene (HDPE) or vinyl-acetic ester; Inner gas barrier layer adopts polyvinyl alcohol or/and the choke lacquer.
The top layer gas barrier adopts tackiness agent with top layer hot sealing layer, top layer heat resistant layer, top layer gas barrier layer, top layer radiation protective layer bonding and presses together.
Inner price reduction gas-barrier separated gas-bearing formation adopts tackiness agent with internal heat seal and inner gas barrier layer bonding and presses together.
Described glass fibre core inside is provided with getter.Described Bond is: polyurethane adhesive.
A kind of packaging method of making a price reduction the vacuum heat-insulating plate of inverse gas infiltration, its step is as follows:
(1) with top layer gas barrier and inner price reduction gas-barrier separated gas-bearing formation, perhaps the top layer gas barrier adopts the mode elder generation inside back cover limit of heat-sealing to make bag, and an end is reserved vacuum orifice;
(2) the glass fibre core is placed in the interior chamber of bag afterwards to vacuumizing at interior glass fibre core;
(3) vacuumize and keep 1-3 minute post heat-seal.
The glass fibre core is separated by bag-shaped chamber independently among the present invention, and can prevent getter in the inside of glass fibre core, gas because inside and outside larger pressure reduction can trace be penetrated into outermost one deck vacuum heat-insulating plate, less because of pressure reduction between outermost one deck and internal layer, gas infiltration capacity is very little, thereby makes whole glass fibre core maintain good heat-insulating property under lower vacuum state.
Beneficial effect: the present invention compared with prior art has the following advantages:
1, vacuum heat-insulating plate of the present invention adopts the sublevel step-down, and gas permeates step by step, can effectively keep the heat-insulating property of vacuum heat-insulating plate, increases the service life.
2, sublevel step-down can effectively reduce gas to glass fibre core infiltration, in the situation of inapplicable getter, also can be for a long time in maintenance internal layer degree of vacuum, keep higher thermal resistance and heat-insulating property preferably.
3, outer field top layer gas barrier has also played protective action to internal layer, even in the situation that the top layer gas barrier is punctured, still can keep the whole heat-insulating property of vacuum heat-insulating plate.
4, vacuum heat-insulating plate of the present invention, effectively reduce gas permeation, prolonged the whole service life of whole vacuum heat-insulating plate, if the number of plies of the price reduction of the inside in vacuum heat-insulating plate gas-barrier separated gas-bearing formation is many, can save adsorbent, reduced cost of production, Security is good, stable high when using simultaneously.
Description of drawings
Fig. 1 is the structural representation of vacuum heat-insulating plate in the prior art.
Fig. 2 is the sectional view of vacuum heat-insulating plate in the prior art.
Fig. 3 is structural representation of the present invention.
Fig. 4 is a kind of sectional view of the present invention.
Fig. 5 is the structural representation of mesexine gas barrier of the present invention.
Fig. 6 is the structural representation of inner price reduction gas-barrier separated gas-bearing formation among the present invention.
Embodiment
Below in conjunction with specific embodiment, further illustrate the present invention, should understand these embodiments only is used for explanation the present invention and is not used in and limits the scope of the invention, after having read the present invention, those skilled in the art all fall within the application's claims to the modification of the various equivalent form of values of the present invention and limit.
Embodiment 1
A kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration, it comprises top layer gas barrier 12, glass fibre core 13 and seals 11; Glass fibre core 13 outer surfaces parcel top layer gas barrier 12, two ends are provided with sealing 11; Described top layer gas barrier 12 comprises: top layer hot sealing layer 121, top layer gas barrier layer 122, top layer heat resistant layer 123, top layer radiation protective layer 124; Top layer gas barrier 12 sequentially is from inside to outside successively: top layer hot sealing layer 121, top layer heat resistant layer 123, top layer gas barrier layer 122, top layer radiation protective layer 124.
Embodiment 2
A kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration, it comprises top layer gas barrier 12, glass fibre core 13 and seals 11; Glass fibre core 13 outer surface top layers parcel gas barrier 12, two ends are provided with sealing 11; Described top layer gas barrier 12 comprises: top layer hot sealing layer 121, top layer gas barrier layer 122, top layer heat resistant layer 123, top layer radiation protective layer 124; Top layer gas barrier 12 sequentially is from inside to outside successively: top layer hot sealing layer 121, top layer heat resistant layer 123, top layer gas barrier layer 122, top layer radiation protective layer 124.Described glass fibre core 13 inside are provided with inner price reduction gas-barrier separated gas-bearing formation 25.Described glass fibre core 13 inside are provided with inner price reduction gas-barrier separated gas-bearing formation 25.Described inner price reduction gas-barrier separated gas-bearing formation 25 is sandwich structure, and two-layer up and down is internal heat seal 251, and middle one deck is inner gas barrier layer 252.Described glass fibre core 13 inside are provided with getter 14.
Described top layer hot sealing layer 121 adopts high density polyethylene (HDPE) or vinyl-acetic ester; Top layer gas barrier layer 122 adopts polyvinyl alcohol and choke lacquer; Top layer heat resistant layer 123 adopts polyethylene; Top layer radiation protective layer 124 adopts metallic thin film.Internal heat seal 251 adopts high density polyethylene (HDPE); Inner gas barrier layer 252 adopts polyvinyl alcohol and choke lacquer.
Top layer gas barrier 12 adopts tackiness agent that top layer hot sealing layer 121, top layer heat resistant layer 123, top layer gas barrier layer 122, top layer radiation protective layer 124 are adopted the polyurethane adhesive bonding and presses together.Inner price reduction gas-barrier separated gas-bearing formation 25 adopts polyurethane binder with internal heat seal 251 and inner gas barrier layer 252 bondings and presses together.
A kind of packaging method of making a price reduction the vacuum heat-insulating plate of inverse gas infiltration, its step is as follows:
(1) with top layer gas barrier and inner price reduction gas-barrier separated gas-bearing formation, perhaps the top layer gas barrier adopts the mode elder generation inside back cover limit of heat-sealing to make bag, and an end is reserved vacuum orifice;
(2) the glass fibre core is placed in the interior chamber of bag afterwards to vacuumizing at interior glass fibre core;
(3) vacuumize and keep 1-3 minute post heat-seal, obtain the described vacuum heat-insulating plate of making a price reduction the inverse gas infiltration of present embodiment.

Claims (6)

1. can make a price reduction the vacuum heat-insulating plate that inverse gas permeates for one kind, it comprises top layer gas barrier (12), glass fibre core (13) and sealing (11); Glass fibre core (13) outer surface parcel top layer gas barrier (12), two ends are provided with sealing (11); It is characterized in that: described top layer gas barrier (12) comprising: top layer hot sealing layer (121), top layer gas barrier layer (122), top layer heat resistant layer (123), top layer radiation protective layer (124); Top layer gas barrier (12) sequentially is from inside to outside successively: top layer hot sealing layer (121), top layer heat resistant layer (123), top layer gas barrier layer (122), top layer radiation protective layer (124); Described glass fibre core (13) inside is provided with inner price reduction gas-barrier separated gas-bearing formation (25); Described inner price reduction gas-barrier separated gas-bearing formation (25) is sandwich structure, and two-layer up and down is the internal heat seal, and middle one deck is inner gas barrier layer; Described glass fibre core (13) inside is provided with getter (14).
2. a kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration according to claim 1 is characterized in that: described top layer hot sealing layer (121) employing high density polyethylene (HDPE) or vinyl-acetic ester; Top layer gas barrier layer (122) adopts polyvinyl alcohol or/and the choke lacquer; Top layer heat resistant layer (123) adopts polyolefin; Top layer radiation protective layer (124) adopts metallic thin film.
3. a kind of vacuum heat-insulating plate of making a price reduction the inverse gas infiltration according to claim 1 is characterized in that: internal heat seal employing high density polyethylene (HDPE) or vinyl-acetic ester; Inner gas barrier layer adopts polyvinyl alcohol or/and the choke lacquer.
4. a kind of vacuum heat-insulating plate of making a price reduction inverse gas infiltration according to claim 1, it is characterized in that: top layer gas barrier (12) adopts tackiness agent that top layer hot sealing layer (121), top layer heat resistant layer (123), top layer gas barrier layer (122), top layer radiation protective layer (124) are bondd and presses together.
5. a kind of vacuum heat-insulating plate of making a price reduction inverse gas infiltration according to claim 1, it is characterized in that: inner price reduction gas-barrier separated gas-bearing formation (25) adopts tackiness agent with internal heat seal and inner gas barrier layer bonding and presses together.
6. packaging method of making a price reduction the vacuum heat-insulating plate of inverse gas infiltration claimed in claim 1, it is characterized in that: its step is as follows:
(1) adopt the mode elder generation inside back cover limit of heat-sealing to make bag top layer gas barrier and inner price reduction gas-barrier separated gas-bearing formation, an end is reserved vacuum orifice;
(2) the glass fibre core is placed in the interior chamber of bag afterwards to vacuumizing at interior glass fibre core;
(3) vacuumize and keep 1-3 minute post heat-seal.
CN 201110058088 2011-03-11 2011-03-11 Vacuum heat-insulating plate capable of reducing price and preventing gas permeation and package method thereof Expired - Fee Related CN102095049B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102628538A (en) * 2012-03-30 2012-08-08 周介明 Layered vacuum insulation board core material and preparation method thereof
JP6132826B2 (en) * 2014-10-23 2017-05-24 三菱電機株式会社 Vacuum insulation and insulation box
CN109707954A (en) * 2018-12-28 2019-05-03 青岛海尔股份有限公司 Vacuum heat-insulating plate and refrigerator with it
CN111578045B (en) * 2020-05-22 2022-01-28 上海海事大学 Multifunctional composite vacuum insulation panel and manufacturing and packaging method thereof
GB2625043A (en) * 2022-06-09 2024-06-12 Univ Shanghai Maritime Marine vacuum insulation panel and packaging method therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245888A (en) * 2008-03-20 2008-08-20 绍兴纳诺气凝胶新材料研发中心有限公司 High-strength vacuum insulation plate
CN101963267A (en) * 2010-10-09 2011-02-02 上海海事大学 Air insulating structure of vacuum insulation panel and packaging method thereof
CN201944493U (en) * 2011-03-11 2011-08-24 苏州维艾普新材料有限公司 Valence-reducible anti-gas-permeation vacuum heat insulation plate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245888A (en) * 2008-03-20 2008-08-20 绍兴纳诺气凝胶新材料研发中心有限公司 High-strength vacuum insulation plate
CN101963267A (en) * 2010-10-09 2011-02-02 上海海事大学 Air insulating structure of vacuum insulation panel and packaging method thereof
CN201944493U (en) * 2011-03-11 2011-08-24 苏州维艾普新材料有限公司 Valence-reducible anti-gas-permeation vacuum heat insulation plate

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Owner name: SUZHOU V.I.P. NEW MATERIAL CO., LTD.

Free format text: FORMER NAME: SUZHOU WEIAIPU NEW MATERIALS CO., LTD.

CP03 Change of name, title or address

Address after: 215400 Taicang City, Jiangsu Province town of Chengxiang City Industrial Park, Yanshan Mountain Road No. 136

Patentee after: SUZHOU V.I.P. NEW MATERIAL Co.,Ltd.

Address before: 215400 Jiangsu city of Suzhou province Taicang city Chengxiang Town Industrial Park, Yanshan Mountain Road No. 136

Patentee before: SUZHOU V.I.P. NEW MATERIAL Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20191121

Address after: Room 2321, building 1, No. 268, Jiqingmen street, Gulou District, Nanjing City, Jiangsu Province

Patentee after: Xu Lijiang

Address before: 215400 Taicang City, Jiangsu Province town of Chengxiang City Industrial Park, Yanshan Mountain Road No. 136

Patentee before: SUZHOU V.I.P. NEW MATERIAL Co.,Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130116