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CN102087220A - Method for detecting mixture concentration field of liquids - Google Patents

Method for detecting mixture concentration field of liquids Download PDF

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CN102087220A
CN102087220A CN 201010603080 CN201010603080A CN102087220A CN 102087220 A CN102087220 A CN 102087220A CN 201010603080 CN201010603080 CN 201010603080 CN 201010603080 A CN201010603080 A CN 201010603080A CN 102087220 A CN102087220 A CN 102087220A
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concentration field
solution
detection method
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liquid mixing
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CN102087220B (en
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邱白晶
徐溪超
杨宁
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Jiangsu University
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Abstract

本发明涉及一种用于液体混合浓度场表征的方法。更具体地说,涉及一种利用脱色反应颜色变化的特点,来表征不同液体混合后整个混合区域浓度场的方法。无色的NaS2O3溶液作为水的携流剂A,蓝色的淀粉I2溶液作为农药的携流剂B,将带有携流剂A的水和带有携流剂B的农药同时注入到混药器中进行混合;随着混合过程的进行,混合液颜色会发生变化;混合器混合区域部分采用透明的材料,高速CCD相机通过透明的混合区域来获取农药和水混合后的图片,对获取的图片经过灰度二值化、水平集和边界跟踪等图像处理等技术处理后表征浓度场信息。本发明简单实用,成本低且机动性好。

Figure 201010603080

The invention relates to a method for characterization of liquid mixed concentration field. More specifically, it relates to a method of characterizing the concentration field of the entire mixing region after mixing different liquids by using the characteristics of the color change of the decolorization reaction. The colorless NaS 2 O 3 solution is used as the water-carrying agent A, and the blue starch I 2 solution is used as the pesticide B-carrying agent, and the water with the carrying agent A and the pesticide with the carrying agent B are simultaneously Inject into the drug mixer for mixing; as the mixing process progresses, the color of the mixed liquid will change; the mixing area of the mixer is made of transparent materials, and the high-speed CCD camera can obtain the picture of the mixed pesticide and water through the transparent mixing area , to characterize the concentration field information after image processing techniques such as grayscale binarization, level set and boundary tracking etc. are processed on the acquired pictures. The invention is simple and practical, has low cost and good maneuverability.

Figure 201010603080

Description

液体混合浓度场检测方法Liquid Mixed Concentration Field Detection Method

技术领域technical field

本发明涉及一种液体混合浓度场检测方法。更具体地说,涉及一种利用脱色反应颜色变化的特点,来检测不同液体混合后整个混合区域浓度场的方法,属于植保机械领域。The invention relates to a liquid mixed concentration field detection method. More specifically, it relates to a method for detecting the concentration field of the whole mixing area after different liquids are mixed by utilizing the color change characteristic of the decolorization reaction, and belongs to the field of plant protection machinery.

背景技术Background technique

混药是机械化施药的基本单元,其设计除了要考虑混药器水力学性能外(如流速、压力降等),更为重要的品质是混药均匀度。如果药液不能在目标靶区均匀分布,则只能按分布的最小值来确定防治用药量,从而导致在分布的最大值处用药量超标。超标用药不仅降低了农药的有效利用率,而且严重污染环境。因此,有必要对农药和水混合后整个混合区域的浓度场均匀度进行检测,从而优化混药器结构参数达到提高农药有效利用率的目的。Drug mixing is the basic unit of mechanized pesticide application. In addition to considering the hydraulic performance of the drug mixer (such as flow rate, pressure drop, etc.), its design is more important than the uniformity of drug mixing. If the liquid medicine cannot be evenly distributed in the target area, the dosage of the preventive medicine can only be determined according to the minimum value of the distribution, resulting in excessive dosage at the maximum value of the distribution. Excessive use of pesticides not only reduces the effective utilization of pesticides, but also seriously pollutes the environment. Therefore, it is necessary to detect the uniformity of the concentration field in the entire mixing area after the pesticide and water are mixed, so as to optimize the structural parameters of the pesticide mixer to improve the effective utilization of pesticides.

在对不同液体混合后浓度检测的现有技术中,申请者未发现有对不同液体混合后整个混合区域浓度场检测的介绍。在对相近技术现有专利进行检索时发现,申请日期为2008.1.16,申请号为200810019185.5的中国专利《液体浓度检测装置及检测方法》公开了一种利用不同浓度的溶液具有不同折光率的特点检测浓度的方法。但是上述检测方法检测的仅仅是浓度场空间中单点或一小部分区域的浓度信息,而非整个混合区域的浓度信息。类似上述这种检测浓度场区域中单点浓度或一小部分区域浓度的专利还有:申请日期为1994.06.28,申请号为94107246.0的中国专利《用于混合在线探测混合物均匀性的设备及方法》及申请日期为2006.11.8,申请号为200610114378.X的中国专利《一种检测不同物质混合均匀度的方法》等。In the prior art of detecting the concentration of different liquids mixed, the applicant did not find any introduction to the detection of the concentration field of the entire mixing area after the mixing of different liquids. When searching the existing patents of similar technologies, it was found that the Chinese patent "Liquid Concentration Detection Device and Detection Method" with the application date of 2008.1.16 and the application number of 200810019185.5 discloses a method that uses different concentrations of solutions with different refractive indices. Method for detecting concentration. However, the above detection method only detects the concentration information of a single point or a small area in the concentration field space, rather than the concentration information of the entire mixed area. Similar to the above-mentioned patents for detecting the concentration of a single point in the concentration field area or a small part of the area: the application date is 1994.06.28, and the application number is 94107246.0 Chinese patent "Equipment and method for mixing on-line detection of mixture uniformity "and the Chinese patent "A Method for Detecting the Mixing Uniformity of Different Substances" with the application date of 2006.11.8 and the application number of 200610114378.X.

尽管一些光学测量设备(如PIV,PLIF等)可以对液体混合后整个混合区域进行浓度场进行检测,但这些设备存在成本高且机动性不灵活等特点。Although some optical measurement devices (such as PIV, PLIF, etc.) can detect the concentration field of the entire mixing area after liquid mixing, these devices have the characteristics of high cost and inflexible mobility.

发明内容Contents of the invention

本发明的目的是提供一种水和农药混合后整个混合区域浓度场检测方法。The purpose of the present invention is to provide a method for detecting the concentration field of the whole mixing area after water and pesticide are mixed.

为达到上述目的,本发明采取的技术方案是:无色的                                                

Figure 2010106030801100002DEST_PATH_IMAGE001
溶液作为水的携流剂A,蓝色的淀粉I2溶液作为农药的携流剂B,然后将带有携流剂的农药和水溶液同时注入到混药器中进行混合。随着混合过程的进行,混合液颜色会发生变化。具体表现为:随着混合时间的进行,蓝色的混合液逐渐变成无色。混合器混合区域部分采用透明的材料,高速CCD相机通过透明的混合区域来获取农药和水混合后的图片,对获取的图片经过灰度二值化、水平集和边界跟踪等图像处理等技术处理后表征浓度场信息;In order to achieve the above object, the technical scheme adopted by the present invention is: colorless
Figure 2010106030801100002DEST_PATH_IMAGE001
The solution is used as water-carrying agent A, and the blue starch I 2 solution is used as pesticide carrier B, and then the pesticide and the aqueous solution with the carrier agent are simultaneously injected into the drug mixer for mixing. As the mixing process proceeds, the color of the mixture will change. The specific performance is: as the mixing time goes on, the blue mixed solution gradually becomes colorless. The mixing area of the mixer is made of transparent materials, and the high-speed CCD camera obtains the mixed pictures of pesticides and water through the transparent mixing area, and the acquired pictures are processed by image processing techniques such as grayscale binarization, level set, and boundary tracking. After characterizing the concentration field information;

上述淀粉I2溶液为含有过量1%~5%的KI作为溶剂的溶液;Above-mentioned starch I 2 solution is the solution that contains excessive 1%~5% KI as solvent;

上述淀粉I2溶液中淀粉为能充分溶解在农药中的直链淀粉;Starch in above-mentioned starch I 2 solution is the amylose that can fully dissolve in pesticide;

上述淀粉I2溶液制备完成后须在空气中暴露1~3小时后再使用;After the preparation of the above-mentioned starch I 2 solution, it must be exposed in the air for 1 to 3 hours before use;

上述

Figure 391316DEST_PATH_IMAGE002
溶液溶质为
Figure 2010106030801100002DEST_PATH_IMAGE003
;the above
Figure 391316DEST_PATH_IMAGE002
The solution solute is
Figure 2010106030801100002DEST_PATH_IMAGE003
;

上述混合器混合区域部分采用透明的材料制作,如钢化玻璃、有机玻璃等;The mixing area of the above-mentioned mixer is made of transparent materials, such as tempered glass, plexiglass, etc.;

上述高速CCD相机与混合器之间的距离为50~200cm;The distance between the above-mentioned high-speed CCD camera and the mixer is 50~200cm;

上述高速CCD相机的数量为1台或多台。The quantity of the above-mentioned high-speed CCD cameras is one or more.

本技术与现有技术相比,优势如下:Compared with the prior art, this technology has the following advantages:

(1) 本技术采用的药剂均是易于获取的化学药剂,价格低廉;(1) The medicaments used in this technology are easy-to-obtain chemical medicaments with low prices;

(2) 本技术利用两种化学药剂之间的脱色反应的颜色变化,然后用这种颜色变化来表示浓度的变化,因而可以表征不同液体反应后整个混合浓度场的信息;(2) This technology uses the color change of the decolorization reaction between two chemical agents, and then uses this color change to represent the change of concentration, so it can characterize the information of the entire mixed concentration field after the reaction of different liquids;

(3) 本技术采用普通的高速CCD相机获取浓度场信息,避免了采用光学测量设备(如PIV,PLIF等)带来的机动不灵活性。(3) This technology uses ordinary high-speed CCD cameras to obtain concentration field information, avoiding the inflexibility brought about by optical measurement equipment (such as PIV, PLIF, etc.).

附图说明Description of drawings

图1为本发明的原理图。Fig. 1 is a schematic diagram of the present invention.

图2为实施本发明的整个系统示意图。Fig. 2 is a schematic diagram of the whole system for implementing the present invention.

其中1为混药器,2和2’为高速CCD相机。Among them, 1 is a drug mixer, and 2 and 2' are high-speed CCD cameras.

具体实施方式Detailed ways

下面结合附图对本发明做进一步的说明。The present invention will be further described below in conjunction with the accompanying drawings.

本发明的技术原理图如图1所示:无色的

Figure 583525DEST_PATH_IMAGE001
溶液作为水的携流剂A,蓝色的I2(淀粉)溶液作为农药的携流剂B,将带有携流剂的农药和水溶液分别同时注入到混药器1中进行混合。在混合过程中混合液颜色会发生变化,具体表现为随着混合时间的进行,蓝色的混合液逐渐变成无色。The technical schematic diagram of the present invention is as shown in Figure 1: colorless
Figure 583525DEST_PATH_IMAGE001
The solution is used as the carrier agent A for water, and the blue I 2 (starch) solution is used as the carrier agent B for the pesticide. The pesticide and the aqueous solution with the carrier agent are simultaneously injected into the drug mixer 1 for mixing. The color of the mixed solution will change during the mixing process, specifically as the blue mixed solution gradually becomes colorless as the mixing time progresses.

图2表示的是将带有携流剂的水和农药溶液分别通过(a)和(b)进口进入混药器1,(c)为混合液出口。高速CCD相机2或2’用来获取农药和水混合后整个混合区域颜色变化图像,获取的图片经灰度二值化、水平集和边界跟踪等图像处理等技术处理后来表征浓度场信息。What Fig. 2 shows is that the water and the pesticide solution with the entrainer enter the drug mixer 1 through (a) and (b) inlets respectively, and (c) is the mixed solution outlet. The high-speed CCD camera 2 or 2' is used to obtain the color change image of the entire mixing area after the pesticide and water are mixed, and the acquired image is processed by image processing techniques such as grayscale binarization, level set, and boundary tracking to represent the concentration field information.

Claims (7)

1. a liquid mixing concentration field detection method is characterized in that, and is colourless
Figure 2010106030801100001DEST_PATH_IMAGE002
Solution flows agent A, blue starch I as taking of water 2Solution is taken stream agent B as agricultural chemicals, will have the water of taking stream agent A and have the agricultural chemicals of taking stream agent B to be injected in the medicine mixer simultaneously and to mix; Along with the carrying out of mixed process, the mixed liquor color can change; Mixer Mixed Zone part adopts material transparent, high-speed CCD camera obtains agricultural chemicals and the mixed picture of water by transparent Mixed Zone, to characterizing concentration field information after the technical finesses such as Flame Image Process such as picture process gray scale binaryzation, level set and border tracking of obtaining.
2. liquid mixing concentration field detection method according to claim 1 is characterized in that, described starch I 2Contain excessive 1% ~ 5% KI solution in the solution as solvent.
3. liquid mixing concentration field detection method according to claim 1 and 2 is characterized in that, described starch I 2The starch I of solution 2For fully being dissolved in the amylose in the agricultural chemicals.
4. liquid mixing concentration field detection method according to claim 3 is characterized in that, described starch I 2Must expose 1 ~ 3 hour after formulations prepared from solutions is finished in air re-uses.
5. liquid mixing concentration field detection method according to claim 1 is characterized in that, and is described
Figure 2010106030801100001DEST_PATH_IMAGE004
Solution's solute is
Figure 2010106030801100001DEST_PATH_IMAGE006
6. liquid mixing concentration field detection method according to claim 1 is characterized in that the distance between described high-speed CCD camera and the mixer is 50 ~ 200cm.
7. liquid mixing concentration field detection method according to claim 1 is characterized in that the quantity of described high-speed CCD camera is more than 1 or 2.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103630502A (en) * 2013-12-09 2014-03-12 江苏大学 Device and method for representing on-line medicine mixing uniformity of medicine mixer based on decolorizing reaction
CN104316291A (en) * 2014-10-08 2015-01-28 华南理工大学 PIV (Particle Image Velocimetry)-based mixed liquid flow field and concentration measuring device and measuring method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103630502A (en) * 2013-12-09 2014-03-12 江苏大学 Device and method for representing on-line medicine mixing uniformity of medicine mixer based on decolorizing reaction
CN104316291A (en) * 2014-10-08 2015-01-28 华南理工大学 PIV (Particle Image Velocimetry)-based mixed liquid flow field and concentration measuring device and measuring method
CN104316291B (en) * 2014-10-08 2017-04-05 华南理工大学 Flow field and apparatus for measuring concentration and measuring method based on the mixing liquid of PIV

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