CN102084894A - Chinese chestnut brown stain preventing processing technology - Google Patents
Chinese chestnut brown stain preventing processing technology Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及食品加工技术领域,特别是涉及一种能够板栗防褐变加工方法。The invention relates to the technical field of food processing, in particular to a processing method capable of preventing browning of chestnuts.
背景技术Background technique
板栗是中国的特产干果之一,特别是中国北方的板栗,其色、香、味、形俱佳,在日本、韩国等市场占有率极高,需求量也在逐年上升。有资料显示,目前全球板栗年总产量约为70~80万吨,中国板栗年总产量占全球板栗总产量的60%左右,而全球每年的板栗需求量在200万吨以上,市场缺口很大。由于中国板栗总体产量还远远不足,西欧、北美市场几乎还没有开拓,因此其市场前景十分广阔。Chestnut is one of the special dried fruits in China, especially the chestnut in northern China, which has excellent color, fragrance, taste, and shape. It has a very high market share in Japan and South Korea, and the demand is also increasing year by year. According to data, the current global annual output of chestnuts is about 700,000 to 800,000 tons, and the annual output of Chinese chestnuts accounts for about 60% of the global total output of chestnuts. However, the global annual demand for chestnuts is more than 2 million tons, and the market gap is very large. . Since the overall output of chestnuts in China is still far from enough, the markets in Western Europe and North America have hardly been developed, so their market prospects are very broad.
但是,板栗加工过程中极易褐变,目前市场上真空或充气小包装的板栗仁均为黑褐色,商品外观差,褐变导致营养损失、抗氧化等生物有效性降低。However, chestnuts are prone to browning during processing. Currently, the chestnut kernels in vacuum or air-filled small packages on the market are all dark brown, and the appearance of the product is poor. Browning leads to nutrient loss and reduced bioavailability such as anti-oxidation.
板栗的褐变包括酶促褐变和非酶促褐变。酶促褐变是由于多酚氧化酶(PPO)和过氧化物酶(POD)引起板栗中的酚类与单宁等成分氧化而产生的颜色变化,其产物是复杂的聚合物--类黑精。非酶促褐变主要是Maillard(美拉德)反应、抗坏血酸氧化及由于金属离子引起的褐变。Chestnut browning includes enzymatic browning and non-enzymatic browning. Enzymatic browning is a color change caused by the oxidation of phenols and tannins in chestnuts caused by polyphenol oxidase (PPO) and peroxidase (POD). Refined. Non-enzymatic browning is mainly Maillard (Maillard) reaction, ascorbic acid oxidation and browning caused by metal ions.
近年来,科研工作者对板栗褐变控制的研究,主要采用护色液来防止其褐变,而护色液配方以含硫配方为主,而非硫护色液配方很少。由于含硫物质对人身体存在的潜在危害,世界各国已经逐步限制含硫护色液配方的使用,非硫、安全的护色液配方已成为发展趋势。为此,中国发明专利CN101406212A公开了一种控制板栗褐变的方法,将去皮后的板栗投入已配制好的非硫护色液中浸泡,该护色液为茶多酚、曲酸、L-谷耽甘肤或L-酒石酸,或上述全部组合;浸泡后用清水冲洗掉板栗表面的护色液。In recent years, scientific research workers have mainly used color protection solution to prevent browning of chestnut browning control, and the formula of color protection solution is mainly sulfur-containing formula, and there are few formulas of non-sulfur color protection solution. Due to the potential harm of sulfur-containing substances to the human body, countries around the world have gradually restricted the use of sulfur-containing color protection liquid formulations, and non-sulfur, safe color protection liquid formulations have become a development trend. For this reason, Chinese invention patent CN101406212A discloses a kind of method of controlling the browning of chestnut, the Chinese chestnut after the peeling is dropped into and soaked in the non-sulfur color-protecting liquid prepared, and this color-protecting liquid is tea polyphenol, kojic acid, L - Gudanganfu or L-tartaric acid, or a combination of all of the above; after soaking, rinse off the color protection solution on the chestnut surface with clean water.
上述方法虽然使用的护色液不含硫,但是存在以下缺点:Though the color protecting liquid that above-mentioned method uses does not contain sulfur, there is following shortcoming:
(1)不进行高温杀菌时,该方法加工的板栗保质期不超过3~5天,经过121℃、30min高温完全杀菌时,褐变还是比较严重,不能保持本色;(2)加工后的板栗产品风味变差,失去了板栗特有的香气和口感。(1) When high-temperature sterilization is not carried out, the shelf life of chestnuts processed by this method does not exceed 3 to 5 days. After complete sterilization at 121°C and 30 minutes, the browning is still serious and the original color cannot be maintained; (2) Processed chestnut products The flavor deteriorates and loses the unique aroma and taste of chestnut.
发明内容Contents of the invention
本发明要解决的技术问题是提供一种既能防止板栗褐变,保持其金黄色原色,又能保持板栗原有的谷香、甘甜的真味风味的本色板栗防褐变加工技术。The technical problem to be solved by the present invention is to provide a natural chestnut anti-browning processing technology that can prevent the chestnut from browning, maintain its golden color, and maintain the original grain fragrance and sweet flavor of the chestnut.
为此本发明的技术方案如下:For this reason the technical scheme of the present invention is as follows:
一种板栗的防褐变加工技术,包括以下步骤:A kind of anti-browning processing technology of chestnut, comprises the following steps:
1)板栗的筛选:选择果肉饱满、充分成熟的果实,去除各种杂质;1) Screening of chestnuts: select fruits with plump flesh and full maturity to remove various impurities;
2)低温处理:在环境相对湿度为80%~95%下,控制板栗的温度每天下降1~2℃,至板栗温度下降至0~1℃;2) Low-temperature treatment: at an ambient relative humidity of 80% to 95%, the temperature of the chestnut is controlled to drop by 1 to 2°C every day until the temperature of the chestnut drops to 0 to 1°C;
3)CO2处理:将步骤2)处理后的板栗放置在CO2浓度为5%~30%(体积百分比)、温度10~20℃、相对湿度85%~95%的环境中,时间为2~20天;3) CO2 treatment: the chestnut after step 2) is placed in CO2 concentration is 5%~30% (volume percentage), temperature 10~20 ℃, in the environment of relative humidity 85%~95%, time is 2 ~20 days;
4)气体熏蒸处理:采用乙烯、乙醇中的一种或两种混合对经步骤3)处理后的板栗进行熏蒸处理,其中乙烯浓度为0.5~1.5mg/kg、乙醇5%~10%,温度15~25℃、相对湿度85%~95%,乙醇或乙烯单独使用时,熏蒸处理时间为1~4天;混合使用时,其浓度与单独使用时一样,但是,熏蒸处理时间为1~2天;4) Gas fumigation treatment: adopt one or both of ethylene and ethanol to fumigate the chestnut after step 3) treatment, wherein the ethylene concentration is 0.5-1.5 mg/kg, ethanol 5%-10%, and the temperature 15~25℃, relative humidity 85%~95%, when ethanol or ethylene is used alone, the fumigation treatment time is 1~4 days; sky;
5)去壳、去红衣,得到板栗仁;5) Remove the shell and red coat to obtain chestnut kernels;
6)杀酶处理:将板栗仁置于80~100℃酸性食品浆液或食品级酸性液体中,或者置于100~110℃食品级酸性蒸汽中,控制所述液体或蒸汽的pH值为1~6,处理时间为5~20min;6) Enzyme-killing treatment: place chestnut kernels in acidic food slurry or food-grade acidic liquid at 80-100°C, or in food-grade acidic steam at 100-110°C, and control the pH of the liquid or steam to 1-100°C. 6. The processing time is 5-20 minutes;
7)固化处理:在90~100℃下,将步骤6)处理后的板栗仁放入pH值为7~12的食品级碱性液体中,处理5~20min;7) Curing treatment: Put the chestnut kernels treated in step 6) into a food-grade alkaline liquid with a pH value of 7-12 at 90-100°C for 5-20 minutes;
8)装袋、密封;8) Packing and sealing;
9)高温、高压、反压灭菌:在温度115~130℃、压力1~2kg/cm2下灭菌10~40min;9) High temperature, high pressure, and back pressure sterilization: Sterilize at a temperature of 115-130°C and a pressure of 1-2kg/ cm2 for 10-40 minutes;
10)冷却、常温条件下存放。10) Store under cooling and normal temperature conditions.
优选的是,步骤3)中CO2浓度为10%~15%(体积百分比),处理的时间不超过8~10天。Preferably, the CO 2 concentration in step 3) is 10%-15% (volume percentage), and the treatment time does not exceed 8-10 days.
优选的是,步骤4)中乙醇或乙烯单独使用时,气体熏蒸时间为2天。Preferably, when ethanol or ethylene are used alone in step 4), the gas fumigation time is 2 days.
优选的是,在步骤6)之前还包括对果实进行破损修复、抛光打磨和削除病虫果肉的步骤。Preferably, the step 6) also includes the steps of repairing the damage of the fruit, polishing and grinding and removing the pulp of diseases and insect pests.
上述方法中,所述的酸性食品浆液为农产品或植物浆液的水溶液,所述食品级酸性液体为无机或有机酸性物质的水溶液或含微生物代谢产生的酸性物质的水溶液。In the above method, the acidic food slurry is an aqueous solution of agricultural products or plant slurry, and the food-grade acidic liquid is an aqueous solution of inorganic or organic acidic substances or an aqueous solution containing acidic substances produced by microbial metabolism.
优选的是,步骤6)中杀酶处理的pH值为3~5,时间为6~10min。Preferably, the pH value of the enzyme killing treatment in step 6) is 3-5, and the time is 6-10 minutes.
上述方法中,步骤7)中所述的食品级碱性液体为无机或有机碱性物质的水溶液,固化处理的pH值为8~9,时间为6~10min。In the above method, the food-grade alkaline liquid described in step 7) is an aqueous solution of inorganic or organic alkaline substances, the pH value of the solidification treatment is 8-9, and the time is 6-10 minutes.
本发明的加工方法,通过对板栗的低温处理使其果实完全成熟,从而将果实的色、香、味调控到最佳值;通过用CO2对果实进行处理促进了果实糖化;通过用乙烯、乙醇对板栗进行熏蒸,不仅提高了板栗的糖化度和板栗的谷香味,还防止了板栗加工过程中的褐变反应。本发明的方法加工后的板栗仁,在保持板栗本色的同时,还保持了其特有的谷香味和甘甜真味,使其色、香、味俱佳。In the processing method of the present invention, the fruit is fully ripened by low-temperature treatment of chestnuts, thereby regulating the color, fragrance and taste of the fruit to an optimal value; by using CO 2 The fruit is processed to promote the saccharification of the fruit; by using ethylene, Fumigation of chestnuts with ethanol not only improves the saccharification degree of chestnuts and the valley flavor of chestnuts, but also prevents the browning reaction of chestnuts during processing. The chestnut kernel processed by the method of the present invention maintains its unique grain flavor and sweet taste while maintaining the natural color of the chestnut, so that the color, fragrance and taste are all excellent.
具体实施方式Detailed ways
下面对本发明的加工方法进行详细说明。The processing method of the present invention will be described in detail below.
本发明的板栗防褐变加工方法包括以下步骤:Chestnut anti-browning processing method of the present invention comprises the following steps:
(1)板栗的筛选。选择糖、淀粉含量高,果肉饱满、充分成熟的果实,剔除病、虫、霉、瘪果实,分级,去除各种杂质。(1) Screening of chestnuts. Choose fruits with high sugar and starch content, full flesh and full maturity, remove diseases, insects, mildew, and shriveled fruits, grade them, and remove various impurities.
(2)对筛选好的板栗进行低温处理:控制板栗的温度每天下降1~2℃,至板栗温度下降至0~1℃时长期贮藏,始终控制环境相对湿度为80%~95%。(2) Carry out low-temperature treatment to the screened chestnuts: control the temperature of the chestnuts to drop by 1-2°C every day, store them for a long time when the temperature of the chestnuts drops to 0-1°C, and control the relative humidity of the environment to be 80%-95% all the time.
(3)对步骤(2)处理后的板栗进行CO2处理:CO2处理浓度5%~30%(体积百分比,以下同)、温度10~20℃、相对湿度85%~95%、时间2~20天。上述条件中,优选的是:CO2浓度为10%~15%,处理时间不超过8~10天,例如,如20℃时,对于浓度15%的CO2,处理时间不超过8天,浓度10%的CO2,处理时间不超过10天。(3) carry out CO to the Chinese chestnut after step (2) treatment: CO treatment concentration 5%~30% (volume percentage, the same below), temperature 10~20 ℃, relative humidity 85%~95%, time 2 ~20 days. Among the above conditions, it is preferred that the CO2 concentration is 10% to 15%, and the treatment time is not more than 8 to 10 days, for example, at 20°C, for CO2 with a concentration of 15%, the treatment time is not more than 8 days, and the concentration 10% CO 2 , the treatment time does not exceed 10 days.
(4)气体熏蒸处理:采用乙烯、乙醇中的一种或两种混合对经步骤3)处理后的板栗进行熏蒸,其中乙烯浓度为0.5~1.5mg/kg、乙醇5%~10%,温度15~25℃、相对湿度85%~90%、乙烯、乙醇单独使用时,处理时间1~4天,最优处理时间为2天;乙烯、乙醇两种混合处理时,其浓度与单独使用时相同,但是,处理时间1~2天。(4) Gas fumigation treatment: adopt one or both of ethylene and ethanol to fumigate the chestnut after step 3) treatment, wherein the ethylene concentration is 0.5~1.5mg/kg, ethanol 5%~10%, temperature 15~25℃, relative humidity 85%~90%, when ethylene and ethanol are used alone, the treatment time is 1 to 4 days, and the optimal treatment time is 2 days; Same, however, processing time 1-2 days.
熏蒸处理有利于提高带皮板栗的风味、防止果肉褐变。熏蒸处理不仅提高了板栗的糖化度、提高了果实谷香味,还可以防治加工过程中的酶促、非酶促褐变。Fumigation treatment is beneficial to improve the flavor of chestnut with skin and prevent the pulp from browning. Fumigation treatment not only improves the saccharification degree of chestnut, improves the fruit flavor, but also prevents enzymatic and non-enzymatic browning in the process of processing.
优选的是,在乙烯浓度1mg/kg、乙醇浓度8%(体积百分比)混合处理时,在温度20℃、相对湿度90%条件下,熏蒸1天时处理效果最佳。Preferably, when the ethylene concentration is 1 mg/kg and the ethanol concentration is 8% (volume percentage), the treatment effect is the best when fumigated for 1 day at a temperature of 20°C and a relative humidity of 90%.
用乙烯气体单独熏蒸时,优选的是:乙烯浓度为1mg/kg、温度20℃、相对湿度90%、处理时间为2天。When fumigated with ethylene gas alone, it is preferred that the ethylene concentration is 1 mg/kg, the temperature is 20° C., the relative humidity is 90%, and the treatment time is 2 days.
用乙醇气体单独熏蒸时,优选的是:乙醇6%、温度20℃、相对湿度90%、处理时间为2天。When using ethanol gas alone for fumigation, the preferred conditions are: 6% ethanol, 20°C temperature, 90% relative humidity, and 2 days of treatment time.
(5)去壳、去红衣,得到板栗仁,并进行整形处理,以提高其品质、色泽。去壳、去红衣时采用机械或人工方式均可。去壳、去红衣后,最好在-1~0℃下短期冷藏或-20~-10℃下长期冻藏。其中在-18~-15℃下保质效果更好。(5) Remove the shell and red coat to obtain the chestnut kernel, and perform plastic treatment to improve its quality and color. Either mechanical or manual methods can be used for shelling and red coat removal. After shelling and removing the red coat, it is best to refrigerate for a short time at -1~0°C or freeze for a long time at -20~-10°C. Among them, the quality preservation effect is better at -18~-15°C.
所述的整型处理包括果实破损修复、抛光打磨去沟纹、削除病虫果肉。通过手工或机械整型均可。如果是低温整形处理,将去壳、去红衣的果实进行破损修复、削除病虫果肉,再速冻至-18~-20℃,然后再抛光打磨去沟纹整型。The shaping treatment includes repairing fruit damage, polishing and grinding to remove grooves, and removing pulp from diseases and insect pests. Shaping can be done manually or mechanically. If it is a low-temperature plastic treatment, the shelled and red-coated fruits are damaged and repaired, and the pulp of diseased insects is removed, and then quick-frozen to -18~-20°C, and then polished to remove grooves and plastic.
(6)杀酶:将板栗仁置于80~100℃食品级酸性液体或100~110℃食品级酸性蒸汽中,控制所述液体或蒸汽的pH值为1~6,依据pH值高低,取决定于高温处理时间长短,一般处理时间为2~20min。优选在pH值为3~5下,高温处理6~10min。(6) Enzyme killing: put chestnut kernels in food-grade acidic liquid at 80-100°C or food-grade acidic steam at 100-110°C, and control the pH of the liquid or steam to 1-6. It depends on the length of high-temperature treatment time, and the general treatment time is 2 to 20 minutes. Preferably, the pH value is 3-5, and the high temperature treatment is carried out for 6-10 minutes.
所述食品级酸性液体为农产品或植物浆液的水溶液、无机或有机酸性物质的水溶液或含微生物代谢产生的酸性物质的水溶液。例如,可以是添加了农产品、植物的鲜榨汁、浸提汁液的水溶液,含其浆液、碎块的水溶液;也可以是乳酸溶液或以及其它无机或有机酸性物质的水溶液。The food-grade acidic liquid is an aqueous solution of agricultural products or plant slurries, an aqueous solution of inorganic or organic acidic substances or an aqueous solution containing acidic substances produced by microbial metabolism. For example, it can be an aqueous solution added with agricultural products, freshly squeezed juice of plants, leaching juice, an aqueous solution containing its slurry and fragments; it can also be an aqueous solution of lactic acid solution or other inorganic or organic acidic substances.
(7)固化:在90~100℃下,将步骤6)处理后的板栗仁放入pH值为7~12的食品级碱性液体中,处理2~10min。优选在pH值为8~9条件下处理6~10min。固化后最好用饮用水进行清洗。(7) Curing: put the chestnut kernels treated in step 6) into a food-grade alkaline liquid with a pH value of 7-12 at 90-100°C for 2-10 minutes. It is preferred to treat for 6-10 minutes under the condition that the pH value is 8-9. It is best to wash with potable water after curing.
所述的食品级碱性液体可以是碳酸氢钠、碳酸氢钙的水溶液,也可以是羧酸盐、胺(如三乙胺,哌啶)、吡啶、喹啉等碱性物质的水溶液,或者是其它农产品、植物等碱性物质的水溶液,只要溶液的pH值为8~9即可。Described food-grade alkaline liquid can be the aqueous solution of sodium bicarbonate, calcium bicarbonate, also can be the aqueous solution of alkaline substances such as carboxylate, amine (as triethylamine, piperidine), pyridine, quinoline, or It is an aqueous solution of alkaline substances such as other agricultural products and plants, as long as the pH value of the solution is 8-9.
(8)装袋:采用铝箔袋或常规高温蒸煮袋均可,充N2包装或真空包装。(8) Packing: Aluminum foil bags or conventional high-temperature retort bags can be used, N2 filled or vacuum packed.
(9)高温、高压、反压灭菌:在温度115~130℃、压力1~2kg/cm2下灭菌10~40min。优选的温度是120~125℃,更优选的温度是121℃。(9) High temperature, high pressure, and back pressure sterilization: Sterilize at a temperature of 115-130°C and a pressure of 1-2kg/cm 2 for 10-40 minutes. A preferred temperature is 120-125°C, and a more preferred temperature is 121°C.
经上述方法处理后的板栗仁冷却到常温后,可以常温保质12个月以上。After the chestnut kernels processed by the above method are cooled to normal temperature, they can be preserved at normal temperature for more than 12 months.
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