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CN102060505B - Preparation method of dolomite tailing bricks - Google Patents

Preparation method of dolomite tailing bricks Download PDF

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Publication number
CN102060505B
CN102060505B CN201010562493XA CN201010562493A CN102060505B CN 102060505 B CN102060505 B CN 102060505B CN 201010562493X A CN201010562493X A CN 201010562493XA CN 201010562493 A CN201010562493 A CN 201010562493A CN 102060505 B CN102060505 B CN 102060505B
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rhombspar
tailing
mine tailing
mixed
seconds
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CN102060505A (en
Inventor
张正文
毛静民
伍朝蓬
季佳善
王姝娟
高大峰
刘捷
涂永刚
刘浪
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Wuhan Iron and Steel Group Corp
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Wuhan Iron and Steel Group Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The invention relates to a preparation method of dolomite tailing bricks, solving the problems of low forming compactness, low demolding perfectness ratio, low initial strength of brick blanks and difficult practical application existing in brick manufacture because of high water and slurry contents and fine granularity of traditional dolomite tailings. The preparation method comprises the following steps of: (1) sieving impurities with size of larger than 5mm in dolomite tailing slurry, naturally airing or drying with equipment to obtain dolomite tailings with the water content of smaller than 5 percent; (2) grinding and uniformly mixing 9-10.8 percent by weight of firming agent, 81-82.93 percent by weight of dolomite tailings and 6.27-10 percent by weight of water; and (3) conveying the mixed mixture into a mold, pressing and forming to obtain a brick blank and culturing. The invention has extremely simple process; and the prepared tailing blocks have high forming compactness and demolding perfectness ratio, high initial strength of brick blanks and various excellent performance as well as waterproof performance, and can be used as bearing bricks, and the like.

Description

The preparation method of rhombspar tailing-bricks
Technical field
The present invention relates to the environmental protection field, a kind of specifically preparation method of rhombspar tailing-bricks.
Background technology
Exploitation and the mine that produces the rhombspar product through to operations such as the fragmentation of raw ore, screening, washups, have about 10% rhombspar mine tailing of raw ore output to produce approximately; This type rhombspar mine tailing is the ore pulp that produces after the washup of mine, and color is the yellow mud look, is loose fine-grannular or clod shape after the drying; Maximum silt content and clod content reach 90%; Also possibly contain rhizome, stone etc., rhombspar mine tailing typical size such as following table: (following percentage ratio is weight percentage, and said proportion is dry weight)
The rhombspar mine tailing is different with common mine tailing; Have that it is moisture, silt content is high, the characteristics that granularity is tiny, during the preparation tailing-bricks in the raw material silt content height can cause the pug caking; Clod is sneaked into forms cavity, plane of weakness in the tailing-bricks, influence freeze proof, the anti-permeability performance of mine tailing; The tiny mine tailing particulate total surface area that then can increase of granularity, the gelling material of mixing are difficult to parcel, bonding mine tailing particle, cause and do not form enough cohesive strengths between particle.
Problems such as moulding is a current technical barrier to fine granules, makes tailing-bricks by common mix, forming method, and its hardness, intensity and shrinkage performance are difficult to meet the demands, and often have the moulding degree of compactness low, and demoulding serviceability rate is low, and the adobe initial strength is low.Therefore this type mine tailing is not utilized so far yet, is stored up in the mine tailing storehouse, not only to have taken land resources, has formed the dangerous matter sources that environment is produced safety hazard and pollution, and has needed financial resources, material resources, manpower, often the mine tailing storehouse is safeguarded.
Summary of the invention
To the objective of the invention is in order solving the problems of the technologies described above, the preparation method of the rhombspar tailing-bricks that a kind of technology is simple, production cost is low, each item performance index are excellent to be provided.
Rhombspar tailing-bricks of the present invention is made by following method: (1) remove rhombspar mine tailing pulp screen>and the foreign material of 5mm, through obtaining the rhombspar mine tailing of water cut<5% after natural air drying or the equipment oven dry; (2) with solidifying agent 9~10.8 weight parts and rhombspar mine tailing 81~82.93 weight parts, that water 6.27~10 weight parts roll mix is even; (3) compound behind the mix is sent into mould, and compression moulding obtains adobe, carries out promptly getting after the maintenance again.
Solidifying agent is cement-based solidified dose in the said step (2), the long-pending 400m that reaches of its specific grain surface 2More than/the kg.
Earlier solidifying agent and rhombspar mine tailing compound mix are rolled evenly in the step (2), then the mode of water with spraying sprayed in the compound, mix while spraying into and grind full and uniform to compound.
In the said step (2); Said rolling makes that clod is broken into powdery in the compound after the dry mixing, and peels off the tailings mud skin of mine tailing sand grains surface attachment parcel, makes mud grain graininess<0.5mm; Mist droplet granularity is<0.5mm that spray velocity reaches 0.8~1.6kg/s during said spraying.
In the said step (2); Use in following three kinds of methods any: 1. earlier with solidifying agent and rhombspar mine tailing mix 50~70 seconds; Obtain solidifying agent and rhombspar mine tailing mixed dry material, mixed dry material is mixed ground 50~70 seconds again, spray into vaporific waterside backmost and mixed stone roller 170~200 seconds; 2. earlier the rhombspar mine tailing was mixed stone roller 50~70 seconds, add solidifying agent again and mixed stone roller 50~70 seconds, spray into vaporific waterside backmost and mixed stone roller 170~200 seconds; 3. stone roller mixed 100~130 seconds to rhombspar mine tailing and the solidifying agent that adds together wherein in elder generation, and the limit sprays into vaporific waterside and mixed stone roller 170~200 seconds then.
Send into mould through the compound of mode of vibration after in the said step (3) with mix.
Compound in said step (3) mould during hydrostatic profile, requires hydrostatic profile pressure>=24MPa through the mode moulding of static pressure or dynamic pressure; During dynamic forming, require vibrational frequency>=50Hz, vibration acceleration>=68.6m/s 2
Solidifying agent can be cement-based solidified dose among the present invention, like the PCSB solidifying agent, also can be to be other solidifying agent of major ingredient with cement clinker and/or pozzolanic material.Solidifying agent can produce the effect of the combined process of mixing effect, polymerization, hydration, chemical action in the rhombspar mine tailing; Various mineral in the rhombspar mine tailing are produced erosion; Cause the mineral crystal surface imperfection; Promote various mineral generation chemical reactions in mineral and the mine tailing that lattice imperfection is arranged in the solidifying agent, the product of solidifying agent mineral self hydration reaction is attached to plane of crystal, constantly growth simultaneously, combines with hydrated product; Parcel mine tailing particle forms membrane structure, grid frame structure.This characteristic has been improved curing performance greatly: increase elasticity, seal intergranular space, increase stability.Specific surface area should reach 400m after the solidifying agent mixing fine grinding 2More than/the kg,, increase activity index to guarantee that particle is tiny.
Facts have proved: when PM for particulate matter>2mm, common alr mode can make and produce extruding, friction effect between the particle, clod, mud skin under this effect promptly quilt disperseed.And rhombspar mine tailing silt content is high, granularity is tiny, only depends on common alr mode can't reach mud composition dispersive purpose., granularity tiny problem high to the mine tailing silt content; The contriver improves existing mine tailing preparation technology; Discovered before adding water; Earlier white clouds mine tailing and solidifying agent are mixed and grind extremely important (even add solidifying agent before earlier mine tailing mixed grind according to the special domestic animal needs of rhombspar mine tailing), grind the block that makes in the material and scatter (the particularly pug of caking) the mud skin effect of simultaneously the CHARACTERISTICS OF TAILINGS SAND surface being wrapped up through mixing fully; Force CHARACTERISTICS OF TAILINGS SAND to be separated, make its mud grain graininess<0.5mm with the mud skin.
Further; Add water to doing to mix in back white clouds mine tailing and the solidifying agent through the mode of spraying; Because rhombspar mine tailing granularity is very thin, therefore directly add water or water droplet mix when big, mine tailing will be bonded to clod; Hindered solidifying agent material and the abundant mixing of mine tailing particulate, this will have a strong impact on the mix quality of compound and the performance of moulding product.This situation is directly implemented to solidify if do not handle, will directly have influence on the ultimate compression strength and other correlated performance of solidifying block.Because clod is present in to solidify to be equivalent to solidify in the block and has the cavity in the block, has not only reduced the carrying area that solidifies block, causes intensity to reduce, and can make that also solidifying the block water-intake rate increases, correlated performances such as coefficient of softening reduction worsen, and this is an one of which; The tailings mud interface that exists between the CHARACTERISTICS OF TAILINGS SAND particle greatly reduces the polymerization power between the sand particle, makes that the bonding force between the sand particle is weakened, and causes mechanics and correlated performance to worsen, this be its two; Clod has also influenced the continuous unanimity of block density in solidifying block, under external force, form crack tip easily, cause solidifying the block drag and descend and form crackle, this be its three.For fear of the problems referred to above, the mode that the contriver adopts spraying especially adds water in the material of doing after mixing, and (spray velocity reaches 0.8~1.6kg/s) for mist droplet particle size through the control spraying and spray velocity; Roll simultaneously, mix and stir; Make tiny droplet homodisperse ground mix, get in the material, just make the solidifying agent particle in aquation constantly expose the surface that makes new advances with the mine tailing particle, one side is strengthened solidifying agent aquation effect; The aquation intermediate product depends on mine tailing particle surface lattice defect on the other hand; Constantly growth, accumulation, parcel mine tailing particle forms membrane structure, grid frame structure.Mix, the comprehensive action of stone roller, spray water xi, make the compound activation, eliminate the agglomerate in the compound, it is high further to have overcome the mine tailing silt content, the defective that granularity is tiny is for subsequent handling creates favorable conditions.
Preferably send into mould through the compound after using the vibration cloth with mix; Can guarantee continuity, the smoothness of compound course of conveying; Be convenient to compound uniform distribution further in mould simultaneously; Go into mould compound controllable number, avoid fine particle to adhere to the problem of transfer passage, and then make the tailing-bricks that makes more closely knit.
In pressing process, can use the mode moulding of static pressure or dynamic pressure, but consider the tiny problem of rhombspar tailing-bricks granularity, during hydrostatic profile, require hydrostatic profile pressure>=24MPa; During dynamic forming, require vibrational frequency>=50Hz, vibration acceleration>=68.6m/s 2, through above-mentioned parameter control, improve mobile property of compound and liquefaction effect, further improve the tailing-bricks degree of compactness, ensure the quality of products and stabilize and increase ratio of briquetting.
Beneficial effect:
(1) solved existing rhombspar mine tailing owing to silt content is high, the little problem that can't prepare tailing-bricks of particle diameter, the tailing-bricks each item excellent performance that makes, intensity >=10MPa; The freezing-thawing strength damage leads<and 15%; Mass loss rate<1.8%, and, can be used as heavy-load bearing brick etc. with water resistance.
(2) technology is simple, production cost is low, facility investment is little, the rhombspar mine tailing is almost all capable of using; Successfully solved the variety of issue that tailings impoundment brings; Be not only applicable to the rhombspar mine tailing, for the fine granules mine tailing of raw material particle size<2mm, all suitable equally like limestone tailing etc.
(3) the rhombspar tailing-bricks moulding degree of compactness that makes is high, and demoulding serviceability rate is high, adobe initial strength height (>0.01MPa).
Embodiment
Embodiment 1
Raw material is prepared:
Rhombspar mine tailing pre-treatment: rhombspar mine tailing pulp screen is removed the rhombspar mine tailing that natural air drying behind root system of plant and the ratchel obtains water cut<1%.
Raw material: PCSB solidifying agent 9 weight parts, rhombspar mine tailing 81 weight parts, water 10 weight parts.
Method: PCSB solidifying agent and rhombspar mine tailing stirred 50~70 seconds, obtained solidifying agent and rhombspar mine tailing mixed dry material, mixed dry material is mixed ground 50~70 seconds again; Make mud grain diameter<0.5mm in the compound; And then mixed dry material is carried out secondary force to mix ground 170~200 seconds, mixed stone roller sprays into water in the compound with Sprayable simultaneously, mist droplet granularity<0.5mm during said spraying; Spray velocity 0.8~1.6kg/s; Roll the uniform compound of mix and import mould, utilize the hydrostatic profile machine that the mine tailing compound is processed adobe, hydrostatic profile pressure >=24MPa with mode of vibration; Obtain obtaining the rhombspar tailing-bricks after certified products is sent into the maintenance of maintenance place through conveying belt or fork truck dispersion coefficient, substandard products or leakage material loopback secondary are forced to mix and are ground.Said mixed stone roller can use mixing pan.
Embodiment 2
Raw material is prepared:
Rhombspar mine tailing pre-treatment: rhombspar mine tailing pulp screen is removed the rhombspar mine tailing that natural air drying behind root system of plant and the ratchel obtains water cut 4.5%.
Raw material: solidifying agent 10.8 weight parts, rhombspar mine tailing 82.93 weight parts, water 6.27 weight parts.
Method: the rhombspar mine tailing is mixed ground 50~70 seconds earlier, add solidifying agent again and mixed stone roller 50~70 seconds, make mud grain diameter<0.5mm in the compound; Then mixed dry material is imported mixing pan and carried out the mixed stone roller of secondary pressure 170~200 seconds; Mixed stone roller is sneaked into water in the compound with Sprayable simultaneously, mist droplet granularity<0.5mm during said spraying, and spray velocity reaches 0.8~1.6kg/s; Roll the uniform compound of mix and import mould with mode of vibration; The utilization pressing machine that shakes is processed adobe with the mine tailing compound, vibrational frequency>=50Hz, vibration acceleration>=68.6m/s 2, obtaining obtaining the rhombspar tailing-bricks after certified products is sent into the maintenance of maintenance place through conveying belt or fork truck dispersion coefficient, substandard products or leakage material loopback secondary are forced to mix and are ground.Said mixed stone roller can use mixing pan.
Embodiment 3
Raw material is prepared:
Rhombspar mine tailing pre-treatment: rhombspar mine tailing pulp screen is removed the rhombspar mine tailing that natural air drying behind root system of plant and the ratchel obtains water cut 2.5%.
Raw material: cement-based solidified dose 9.9 weight part, rhombspar mine tailing 82.15 weight parts, water 7.95 weight parts.
Method: stone roller mixed 100~130 seconds with mixing the stone roller device to rhombspar mine tailing and solidifying agent compound in elder generation; Make mud grain diameter<0.5mm in the compound, the mixed dry material after mixed stone roller is even carries out secondary to be forced to mix stone roller 170~200 seconds, and mixed stone roller sprays into water in the compound with Sprayable simultaneously; Mist droplet granularity<0.5mm during said spraying; Spray velocity is 0.8~1.6kg/s, rolls the uniform compound of mix and imports mould with mode of vibration, utilizes the pressing machine that shakes that the mine tailing compound is processed adobe; Vibrational frequency>=50Hz, vibration acceleration>=68.6m/s 2, obtaining obtaining the rhombspar tailing-bricks after certified products is sent into the maintenance of maintenance place through conveying belt or fork truck dispersion coefficient, substandard products or leakage material loopback secondary are forced rolling.
The rhombspar mine tailing of processing with the foregoing description 1~3 is that mine tailing test specimen and mine tailing standard brick detect correlated performance such as following table:
Figure BDA0000034588500000061

Claims (5)

1. the preparation method of a rhombspar tailing-bricks is characterized in that, is made by following method: (1) remove rhombspar mine tailing pulp screen>and the foreign material of 5mm, through obtaining the rhombspar mine tailing of water cut<5% after natural air drying or the equipment oven dry; (2) with solidifying agent 9~10.8 weight parts and rhombspar mine tailing 81~82.93 weight parts, that water 6.27~10 weight parts roll mix is even; (3) compound behind the mix is sent into mould, and compression moulding obtains adobe, carries out promptly getting after the maintenance again; Earlier solidifying agent and rhombspar mine tailing compound mix are rolled evenly in the said step (2); Then the mode of water with spraying sprayed in the compound, mix while spraying into and grind full and uniform, make mud grain graininess<0.5mm in the compound behind the said mixed stone roller to compound; Mist droplet granularity<0.5mm during said spraying, spray velocity reaches 0.8~1.6kg/s.
2. the preparation method of rhombspar tailing-bricks as claimed in claim 1 is characterized in that, solidifying agent is cement-based solidified dose in the said step (2), long-pending 400 m that reach of its specific grain surface 2More than/the kg.
3. the preparation method of rhombspar tailing-bricks as claimed in claim 1; It is characterized in that; In the said step (2), use in following three kinds of methods any: 1. earlier solidifying agent and rhombspar mine tailing were mixed and stirred 50~70 seconds, obtain solidifying agent and rhombspar mine tailing mixed dry material; Again mixed dry material is mixed and ground 50~70 seconds, spray into vaporific waterside backmost and mixed stone roller 170~200 seconds; 2. earlier the rhombspar mine tailing was mixed stone roller 50~70 seconds, add solidifying agent again and mixed stone roller 50~70 seconds, spray into vaporific waterside backmost and mixed stone roller 170~200 seconds; 3. stone roller mixed 100~130 seconds to rhombspar mine tailing and the solidifying agent that adds together wherein in elder generation, and the limit sprays into vaporific waterside and mixed stone roller 170~200 seconds then.
4. the preparation method of rhombspar tailing-bricks as claimed in claim 1 is characterized in that, sends into mould through the compound of mode of vibration after with mix in the said step (3).
5. the preparation method of rhombspar tailing-bricks as claimed in claim 1 is characterized in that, the compound in said step (3) mould during hydrostatic profile, requires hydrostatic profile pressure>=24MPa through the mode moulding of static pressure or dynamic pressure; During dynamic forming, require vibrational frequency>=50Hz, vibration acceleration>=68.6m/s 2
CN201010562493XA 2010-11-26 2010-11-26 Preparation method of dolomite tailing bricks Expired - Fee Related CN102060505B (en)

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CN103011704B (en) * 2012-12-10 2014-07-23 傅绍斌 Method for preparing building brick from oil field oily sludge
KR101597519B1 (en) * 2015-04-23 2016-02-25 (유)신기Ati Continuous soil solidification processing method and apparatus for preventing yellow dust and constructing meadow in desertificated area
CN104944880B (en) * 2015-06-16 2017-05-24 武汉钢铁(集团)公司 Low-silica iron ore tailing non-autoclave block with good hydrolytic resistance and preparation method
CN112266173B (en) * 2020-11-04 2023-04-18 郭伟江 Foamed glass particles and preparation method thereof
CN112408898A (en) * 2020-11-26 2021-02-26 华新水泥股份有限公司 Process for producing baking-free type filter-pressing soil tailing bricks through cogeneration and co-maintenance of cement plant
CN113429188B (en) * 2021-06-18 2022-06-10 湖北沛高环保科技有限公司 Comprehensive treatment and utilization method for solid waste of tailings

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4476235A (en) * 1982-11-24 1984-10-09 Societe Nationale De Liamiante Green molded product containing asbestos tailings suitable for firing
CN1172082A (en) * 1996-07-25 1998-02-04 营口青花镁矿总公司 Burnt oil-immersed conite and its manufacturing process
CN1528696A (en) * 2003-09-30 2004-09-15 武汉理工大学 Manufacturing method of gypsum tailings brick
CN101638924A (en) * 2009-08-11 2010-02-03 武汉钢铁(集团)公司 Limestone tailing-bricks and preparation method thereof
RU2394790C1 (en) * 2009-04-01 2010-07-20 Государственное образовательное учреждение высшего профессионального образования "Самарский государственный архитектурно-строительный университет" (СГАСУ) Method of making acid-resistant tiles

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4476235A (en) * 1982-11-24 1984-10-09 Societe Nationale De Liamiante Green molded product containing asbestos tailings suitable for firing
CN1172082A (en) * 1996-07-25 1998-02-04 营口青花镁矿总公司 Burnt oil-immersed conite and its manufacturing process
CN1528696A (en) * 2003-09-30 2004-09-15 武汉理工大学 Manufacturing method of gypsum tailings brick
RU2394790C1 (en) * 2009-04-01 2010-07-20 Государственное образовательное учреждение высшего профессионального образования "Самарский государственный архитектурно-строительный университет" (СГАСУ) Method of making acid-resistant tiles
CN101638924A (en) * 2009-08-11 2010-02-03 武汉钢铁(集团)公司 Limestone tailing-bricks and preparation method thereof

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