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CN102030466A - Additive capable of prolonging service life of chemically strengthened fused salt - Google Patents

Additive capable of prolonging service life of chemically strengthened fused salt Download PDF

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Publication number
CN102030466A
CN102030466A CN2010105559184A CN201010555918A CN102030466A CN 102030466 A CN102030466 A CN 102030466A CN 2010105559184 A CN2010105559184 A CN 2010105559184A CN 201010555918 A CN201010555918 A CN 201010555918A CN 102030466 A CN102030466 A CN 102030466A
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CN
China
Prior art keywords
fused salt
tempering
chemical tempering
work
additive
Prior art date
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Application number
CN2010105559184A
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Chinese (zh)
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CN102030466B (en
Inventor
周群飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lens Technology (Hunan) Co Ltd
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Lens Technology (Hunan) Co Ltd
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Priority to CN2010105559184A priority Critical patent/CN102030466B/en
Publication of CN102030466A publication Critical patent/CN102030466A/en
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Publication of CN102030466B publication Critical patent/CN102030466B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping
    • Y02P40/57Improving the yield, e-g- reduction of reject rates

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Abstract

The invention discloses an additive capable of prolonging the service life of chemically strengthened fused salt, which comprises the following major constituents: several kinds of carbonates, bicarbonates, nitrates, nitrites and other active constituents, wherein the ratio of carbonates to bicarbonates to nitrates to nitrites to others is 5:2-5:60-63:25:5. The invention has the characteristics of low cost, rapid effect taking and the like. The additive can effectively prolong the service life of fused salt, increase the yield of fused salt per unit and play the function of reducing production cost.

Description

A kind ofly can prolong the chemical tempering fused salt additive in work-ing life
Technical field
The present invention relates to a kind of additive, particularly relate to and a kind ofly can prolong the chemical tempering fused salt additive in work-ing life.
Background technology
In the eyeglass processing industry,, require that eyeglass is carried out chemical tempering and satisfy service requirements to reach certain intensity for surface hardness and the shock resistance that improves product.But along with widespread use to glass mirror, portioned product is had higher requirement to the chemical enhanced performance index of glass mirror, that have even require eyeglass (just can satisfy service requirements fully) need reaching through its surface stress behind the chemical tempering more than the 800MPa as long as common product reaches 400MPa, this need adopt the quite high fused salt of purity to carry out tempering with regard to requiring us, but the employed fused salt of chemical tempering itself is a kind of running stores, increase along with tempering product amount, the purity of its fused salt also can decrease, after the fused salt purity drop arrives to a certain degree, then must change whole fused salts and just can reach corresponding tempering performance index.In other words, as if the chemical tempering performance index of wanting to reach higher, then must take frequent replacing fused salt to reach, this is unfavorable for the production in enormous quantities of product fully.
Summary of the invention
It is low that technical problem to be solved by this invention provides a kind of cost, instant effect can prolong the chemical tempering fused salt additive in work-ing life.
In order to solve the problems of the technologies described above, provided by the inventionly can prolong the chemical tempering fused salt additive in work-ing life, it is characterized in that: the weight proportion of each component is:
Carbonate: acid carbonate: nitrate: nitrite: other=5: 2~5: 60~63: 25: 5.
By the ratio that the present invention sets, has the prolongation in work-ing life of good chemical tempering fused salt.
Carbonate and acid carbonate are technical grade or above purity grade product.
Nitrate and nitrite are industrial first grade or above purity grade product.
Other components are analytical pure or above purity grade product.
That adopts technique scheme can prolong the chemical tempering fused salt additive in work-ing life, according to the requirement of the different chemical tempering performance index of product, carbonate, acid carbonate, nitrate, nitrite and some other material thereof are obtained additive of the present invention by certain ratio requirement mixing.And reach by the proportioning between each component in this change additive and to prolong the chemical tempering fused salt purpose in work-ing life.
The present invention shows as by its outstanding effect of the advantage that effective proportioning had of above composition: under same chemical tempering performance requriements, can improve more than 100% the work-ing life of fused salt, even longer.The additive that can prolong chemical tempering fused salt work-ing life can directly be added in the fused salt, simple and quick, need not the operation of complicated specialty, can reach the required chemical tempering fused salt prolongation effect in work-ing life in 2 hours as long as after the complete fusion of additive, leave standstill.
The present invention is applied to the chemical tempering processes of glass mirror, utilizes the two-phase coexistent relation of various ingredients, has reached raising ion-exchange activity, prolongs chemical tempering fused salt work-ing life, improves unit fused salt production capacity and reduces production costs.
Description of drawings
Fig. 1 is the corresponding relation graphic representation of product surface stress behind normal fused salt concentration and the tempering.
Fig. 2 is the corresponding relation graphic representation of product surface stress behind fused salt concentration in the case study on implementation 1 and the tempering.
Fig. 3 is the corresponding relation graphic representation of product surface stress behind fused salt concentration in the case study on implementation 2 and the tempering.
Fig. 4 is the corresponding relation graphic representation of product surface stress behind fused salt concentration in the case study on implementation 3 and the tempering.
Fig. 5 is the corresponding relation graphic representation of product surface stress behind fused salt concentration in the case study on implementation 4 and the tempering.
Fig. 6 is the corresponding relation curve generalization comparison diagram of product surface stress behind fused salt concentration and the tempering.
Embodiment
By the detailed description of carrying out below in conjunction with accompanying drawing, particular exemplary of the present invention and the characteristics in case study on implementation, advantage and others will become apparent.
Provide following description to help the of the present invention exemplary case study on implementation that complete understanding is limited by claim and equivalent thereof with reference to accompanying drawing.Below describe and comprise various specific details helping described understanding, but these details should be understood that to be exemplary.Therefore, it will be understood by those skilled in the art that under situation about not departing from the scope of the present invention with spirit, can carry out various changes and modification case study on implementation described here.In addition, for clarity and conciseness for the purpose of, omit description to known function and structure.
With reference to Fig. 1, this figure is a theoretical basis of the present invention, normal, glass its surface stress size behind chemical tempering can reduce along with the reduction of fused salt concentration, can prolong fused salt work-ing life by the mode of taking to add additive, and additive can carry out the adjustment of different ratios according to proportioning of the present invention, to reach the maximum extension fused salt effect in work-ing life.
What select for use in the concrete embodiment of the present invention is a kind ofly can prolong the chemical tempering fused salt additive in work-ing life, wherein carbonate and acid carbonate are technical grade or above purity grade product, nitrate and nitrite are industrial first grade or above purity grade product, and other components are analytical pure or above purity grade product.
In following case study on implementation, be statement and the explanation that embodiment does correlated performance of the present invention only with carbonate and acid carbonate.
Embodiment 1:
Salt of wormwood: saleratus: saltpetre: potassium nitrite: Repone K+diatomite+antimonous oxide=5: 2: 63: 25: 3.5+1+0.5.
Behind the chemical tempering behind its fused salt concentration and the tempering corresponding relation graphic representation of product surface stress referring to Fig. 2.
Fused salt concentration Surface stress
100% 749
99% 716
97% 684
96% 651
95% 619
94% 586
Embodiment 2:
Salt of wormwood: saleratus: saltpetre: potassium nitrite: Repone K+diatomite+antimonous oxide=5: 3: 62: 25: 3.5+1+0.5.
Behind the chemical tempering behind its fused salt concentration and the tempering corresponding relation graphic representation of product surface stress referring to Fig. 3.
Fused salt concentration Surface stress
100% 754
99% 724
97% 693
96% 665
95% 632
94% 598
Embodiment 3:
Salt of wormwood: saleratus: saltpetre: potassium nitrite: Repone K+diatomite+antimonous oxide=5: 4: 61: 25: 3.5+1+0.5.
Behind the chemical tempering behind its fused salt concentration and the tempering corresponding relation graphic representation of product surface stress referring to Fig. 4.
Fused salt concentration Surface stress
100% 760
99% 734
97% 707
96% 680
95% 654
94% 628
Embodiment 4:
Salt of wormwood: saleratus: saltpetre: potassium nitrite: Repone K+diatomite+antimonous oxide=5: 5: 60: 25: 3.5+1+0.5.
Behind the chemical tempering behind its fused salt concentration and the tempering corresponding relation graphic representation of product surface stress referring to Fig. 5.
Fused salt concentration Surface stress
100% 767
99% 743
97% 719
96% 696
95% 672
94% 648
Fig. 6 is the corresponding relation curve generalization comparison diagram of product surface stress behind fused salt concentration and the tempering.
Though shown and described the present invention with reference to this particular exemplary case study on implementation, but those skilled in the art should understand that, under the situation that does not break away from the scope and spirit of the present invention that limit by claim and equivalent thereof, can make in form and the various changes on the details at this.

Claims (4)

1. one kind can prolong the chemical tempering fused salt additive in work-ing life, and it is characterized in that: the weight proportion of each component is carbonate: acid carbonate: nitrate: nitrite: other=5: 2~5: 60~63: 25: 5.
2. according to claim 1ly can prolong the chemical tempering fused salt additive in work-ing life, it is characterized in that: described carbonate and acid carbonate are technical grade or above purity grade product.
3. according to claim 1 and 2ly can prolong the chemical tempering fused salt additive in work-ing life, it is characterized in that: described nitrate and nitrite are industrial first grade or above purity grade product.
4. describedly can prolong the chemical tempering fused salt additive in work-ing life according to claim 1,2 or 3, it is characterized in that: described other components are analytical pure or above purity grade product.
CN2010105559184A 2010-11-19 2010-11-19 Additive capable of prolonging service life of chemically strengthened fused salt Active CN102030466B (en)

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Application Number Priority Date Filing Date Title
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CN102030466B CN102030466B (en) 2013-03-27

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103781739A (en) * 2011-09-09 2014-05-07 Hoya株式会社 Process for producing cover glass for potable appliance
CN104326648A (en) * 2013-12-31 2015-02-04 东旭集团有限公司 Catalyst for chemical reinforcement of glass, and preparation method of reinforcement liquid thereof
CN108947271A (en) * 2018-08-21 2018-12-07 河南省海川电子玻璃有限公司 A kind of glass chemistry toughening catalyst and its application method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000335916A (en) * 1999-05-31 2000-12-05 Akio Henmi Method and apparatus for producing artificial zeolite from slag
CN1381415A (en) * 2002-06-04 2002-11-27 上海耀华皮尔金顿玻璃股份有限公司 Process for preparing chemically strengthened glass
CN1559942A (en) * 2004-02-21 2005-01-05 广东金刚玻璃科技股份有限公司 Method for mfg. high strength fireproof signle sheet cesium potash glass
CN101798170A (en) * 2010-04-15 2010-08-11 秦皇岛星箭特种玻璃有限公司 Method for preparing high-strength overlarge and ultrathin cover glass for satellite

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000335916A (en) * 1999-05-31 2000-12-05 Akio Henmi Method and apparatus for producing artificial zeolite from slag
CN1381415A (en) * 2002-06-04 2002-11-27 上海耀华皮尔金顿玻璃股份有限公司 Process for preparing chemically strengthened glass
CN1559942A (en) * 2004-02-21 2005-01-05 广东金刚玻璃科技股份有限公司 Method for mfg. high strength fireproof signle sheet cesium potash glass
CN101798170A (en) * 2010-04-15 2010-08-11 秦皇岛星箭特种玻璃有限公司 Method for preparing high-strength overlarge and ultrathin cover glass for satellite

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103781739A (en) * 2011-09-09 2014-05-07 Hoya株式会社 Process for producing cover glass for potable appliance
CN104326648A (en) * 2013-12-31 2015-02-04 东旭集团有限公司 Catalyst for chemical reinforcement of glass, and preparation method of reinforcement liquid thereof
CN104326648B (en) * 2013-12-31 2017-08-01 东旭集团有限公司 A kind of catalyst and its preparation method of forced fluid for chemically enhancing glass
CN108947271A (en) * 2018-08-21 2018-12-07 河南省海川电子玻璃有限公司 A kind of glass chemistry toughening catalyst and its application method

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Application publication date: 20110427

Assignee: LENS TECHNOLOGY CHANGSHA CO., LTD.

Assignor: Lens Technology Co., Ltd.

Contract record no.: 2013430000117

Denomination of invention: Additive capable of prolonging service life of chemically strengthened fused salt

Granted publication date: 20130327

License type: Exclusive License

Record date: 20130729

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