CN102029106A - Calcium-based CO2 absorption furnace - Google Patents
Calcium-based CO2 absorption furnace Download PDFInfo
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Abstract
本发明公开了一种钙基CO2吸收炉,用于燃煤锅炉二氧化碳回收技术领域。其特征在于:包括吸收反应炉炉体,吸收反应炉炉体的一侧安装有石灰石进料口和燃烧器,另一侧相向安装有烟气输入口,出料口安装于炉体的底部位置,旋风分离器安装于炉体的一侧并与吸收反应炉相连通,旋风分离器的顶部设有烟气出口,旋风分离器的底部设有出料口和放空管,放空管与吸收反应炉炉体相连。本发明具有反应效果好,结构简单,经济性和环保性好等特点。
The invention discloses a calcium-based CO2 absorption furnace, which is used in the technical field of carbon dioxide recovery of coal-fired boilers. It is characterized in that it includes an absorption reaction furnace body, one side of the absorption reaction furnace body is installed with a limestone feed port and a burner, the other side is oppositely equipped with a flue gas input port, and the discharge port is installed at the bottom of the furnace body , the cyclone separator is installed on one side of the furnace body and communicated with the absorption reaction furnace. The top of the cyclone separator is provided with a flue gas outlet, and the bottom of the cyclone separator is provided with a discharge port and a vent pipe. The vent pipe is connected to the absorption reaction furnace. The furnace body of the reaction furnace is connected. The invention has the characteristics of good reaction effect, simple structure, good economy and environmental protection.
Description
技术领域:Technical field:
本发明涉及一种钙基CO2吸收炉,用在燃煤锅炉吸收二氧化碳排放场合。The invention relates to a calcium-based CO2 absorption furnace, which is used in the occasion of absorbing carbon dioxide emission by a coal-fired boiler.
背景技术:Background technique:
全球气候变暖主要是由于以CO2为主的温室气体大量排放而导致地球温室效应的加剧而造成的,控制和减少CO2的排放量对于解决大气温室效应和全球变暖的影响具有重要作用。我国是CO2排放大国,排放量约占世界CO2排放总量的1/5,其中大部分CO2是由燃煤产生的。在未来相当长的时期内,我国以煤炭为主的能源格局不会改变,煤炭消耗量将持续增长。在以化石燃料为主要的能源生产中,CO2的排放量约占人类各种活动所引起的CO2排放总量的70%以上,是CO2的最大单点固定排放,控制和减少燃煤生产中CO2的排放对于解决大气温室效应和全球变暖具有显著的作用。因此从燃煤锅炉的尾气中分离CO2是非常必要的,从燃烧排气中分离回收CO2的技术变得十分重要。Global warming is mainly caused by the aggravation of the earth's greenhouse effect caused by the massive emission of CO2 - based greenhouse gases. Controlling and reducing CO2 emissions plays an important role in solving the impact of atmospheric greenhouse effect and global warming . China is a major CO 2 emitter, accounting for about 1/5 of the world's total CO 2 emissions, most of which are produced by coal combustion. For a long period of time in the future, my country's coal-based energy structure will not change, and coal consumption will continue to grow. In fossil fuel-based energy production, CO2 emissions account for more than 70% of the total CO2 emissions caused by various human activities, which is the largest single-point fixed emission of CO2 . To control and reduce coal burning The emission of CO2 from production plays a significant role in addressing the atmospheric greenhouse effect and global warming. Therefore, it is very necessary to separate CO 2 from the tail gas of coal-fired boilers, and the technology of separating and recovering CO 2 from combustion exhaust gas becomes very important.
有基于此,申请人作出本发明。Based on this, the applicant has made the present invention.
发明内容:Invention content:
针对上述所要解决的技术问题,本发明的主要目的是提供一种结构设计合理、适用范围广、低能耗且环保性好的钙基CO2吸收炉。In view of the technical problems to be solved above, the main purpose of the present invention is to provide a calcium-based CO2 absorption furnace with reasonable structural design, wide application range, low energy consumption and good environmental protection.
本发明采取的技术方案如下,一种钙基CO2吸收炉,其特征在于:包括吸收反应炉炉体,吸收反应炉炉体的一侧安装有石灰石进料口和燃烧器,另一侧相向安装有烟气输入口,出料口安装于炉体的底部位置,旋风分离器安装于炉体的一侧并与吸收反应炉相连通,旋风分离器的顶部设有烟气出口,旋风分离器的底部设有出料口和放空管,放空管与吸收反应炉炉体相连。The technical scheme adopted by the present invention is as follows, a calcium-based CO2 absorption furnace is characterized in that: it includes an absorption reaction furnace body, one side of the absorption reaction furnace body is equipped with a limestone feed port and a burner, and the other side faces A flue gas input port is installed, and the discharge port is installed at the bottom of the furnace body. The cyclone separator is installed on one side of the furnace body and communicated with the absorption reaction furnace. The top of the cyclone separator is provided with a flue gas outlet. The cyclone separator The bottom of the furnace is provided with a discharge port and a vent pipe, and the vent pipe is connected with the body of the absorption reaction furnace.
优选地:吸收反应炉炉体采用石棉包裹,吸收反应炉炉体采用圆形载面,烟气输入口、石灰石进料口从炉体相切处输入。Preferably: the furnace body of the absorption reaction furnace is wrapped with asbestos, the furnace body of the absorption reaction furnace adopts a circular loading surface, and the flue gas input port and the limestone feed port are input from the tangent part of the furnace body.
本发明的工作原理如下:CaO在吸收反应炉中吸收从锅炉出来混合烟气中低浓度CO2,生成CaCO3。气固混合物在旋风分离器中分离出纯CaCO3,从旋风分离器下部流出,未反应混合物回到吸收反应炉,余气从上部出口放空,生成CaCO3所需温度在650度左右,由燃烧器提供热量;CaO从原料口输入,从锅炉出来混合烟气从烟气输入口输入;完成一个工作循环。The working principle of the present invention is as follows: CaO absorbs low-concentration CO 2 in the mixed flue gas from the boiler in the absorption reaction furnace to generate CaCO 3 . The gas-solid mixture is separated into pure CaCO 3 in the cyclone separator, which flows out from the lower part of the cyclone separator, and the unreacted mixture returns to the absorption reactor, and the remaining gas is vented from the upper outlet. The temperature required to generate CaCO 3 is about 650 degrees. The device provides heat; CaO is input from the raw material port, and the mixed flue gas from the boiler is input from the flue gas input port; a working cycle is completed.
本发明的有益效果如下:The beneficial effects of the present invention are as follows:
1、本发明采用钙基吸收剂CaO在吸收反应炉中吸收从锅炉出来混合烟气中低浓度CO2,生成CaCO3,有效的降低了CO2排放,具有良好的经济效益和环保效益。1. The present invention uses calcium-based absorbent CaO to absorb low-concentration CO 2 in the mixed flue gas from the boiler in the absorption reaction furnace to generate CaCO 3 , which effectively reduces CO 2 emissions and has good economic and environmental benefits.
2、本发明的钙基CO2吸收炉,采用烟气进口、石灰石送料口从炉体切向输入,相向喷入,形成旋转气流,以利反应充分进行。2. In the calcium-based CO2 absorption furnace of the present invention, flue gas inlets and limestone feed ports are used to input tangentially from the furnace body and spray them in opposite directions to form a swirling airflow so that the reaction can be fully carried out.
下面结合附图1和具体实施例对本发明进一步的详细说明,以下实施例是对本发明的解释但本发明不局限于以下实施例。The present invention will be further described in detail below in conjunction with accompanying
附图说明:Description of drawings:
图1为本发明的钙基CO2吸收炉的结构示意图;Fig. 1 is calcium base CO of the present invention The structural representation of absorption furnace;
图2为本发明的钙基CO2吸收炉的剖面图。Figure 2 is a cross-sectional view of the calcium-based CO2 absorption furnace of the present invention.
具体实施方式:Detailed ways:
如图1、图2所示,本发明的钙基CO2吸收炉,包括吸收反应炉炉体1,吸收反应炉炉体1的一侧安装有石灰石进料口3和燃烧器4,另一侧相向安装有烟气输入口5,出料口6安装于炉体1的底部位置,旋风分离器2安装于炉体1的一侧并与吸收反应炉相连通,旋风分离器2的顶部设有烟气出口7,旋风分离器2的底部设有出料口8和放空管9,出料口8用于排出分离的纯CaCO3,放空管9与吸收反应炉炉体1相连,用于将未反应完的原料送入炉体1中继续反应。As shown in Fig. 1 and Fig. 2, the calcium-based CO2 absorption furnace of the present invention comprises an absorption reaction
本发明的工作原理如下:从燃煤锅炉出来的混合烟气从烟气输入口5进入吸收反应炉炉体1中,另一方面,钙基吸收剂CaO从进料口3中输入,燃烧器4中是煤粉和空气的混合物,点火燃烧产生热量,使吸收反应炉炉体1的温度保持在650度左右,在吸收反应炉1中吸收低浓度CO2,生成CaCO3。The working principle of the present invention is as follows: the mixed flue gas that comes out from coal-fired boiler enters in the absorption reaction
反应式为:CaO+CO2→CaCO3+178Kj/mol。The reaction formula is: CaO+CO 2 →CaCO 3 +178Kj/mol.
另一方面,从吸收反应炉1出来的气固混合物进入到旋风分离器2中,经旋风分离器2分离出纯CaCO3,分离出的纯CaCO3从旋风分离器2底部的出料口8排出,未反应的混合物通过放空管9回到吸收反应炉1中继续反应,余气则从旋风分离器2上部的烟气出口7放空,吸收反应炉炉体1中,报废的CaO和残渣从炉体1底部的出料口6放出。On the other hand, the gas-solid mixture from the
本发明中,吸收反应炉炉体1采用石棉等绝热材料包裹,保存热量。吸收反应炉1采用圆形载面,烟气进口5、石灰石进料口3从炉体相切处输入,采用相向喷入,引成旋转气流,以利化学反应充分进行;燃烧器4的喷射口则从中间进入。In the present invention, the
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CN110500578A (en) * | 2019-08-21 | 2019-11-26 | 青岛科技大学 | A chemical loop conversion device and method for coupling solid fuel reaction and separation |
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Patent Citations (5)
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CN1126235A (en) * | 1994-06-16 | 1996-07-10 | 英国石油化学品有限公司 | waste disposal |
JP2002273163A (en) * | 2001-03-19 | 2002-09-24 | Susumu Otsuki | Method for removing carbon dioxide included in combustion exhaust gas |
CN101422691A (en) * | 2008-11-20 | 2009-05-06 | 武汉凯迪电力环保有限公司 | Multi-pollutant removing technique and device of fuel coal smoke |
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Application publication date: 20110427 |