CN102020431B - Method for preparing concrete additive by using vinasse obtained by distilling cane molasses - Google Patents
Method for preparing concrete additive by using vinasse obtained by distilling cane molasses Download PDFInfo
- Publication number
- CN102020431B CN102020431B CN200910211689.1A CN200910211689A CN102020431B CN 102020431 B CN102020431 B CN 102020431B CN 200910211689 A CN200910211689 A CN 200910211689A CN 102020431 B CN102020431 B CN 102020431B
- Authority
- CN
- China
- Prior art keywords
- vinasse
- product
- concrete
- brix
- cane molasses
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 11
- 235000013379 molasses Nutrition 0.000 title claims abstract description 8
- 239000000654 additive Substances 0.000 title abstract 2
- 230000000996 additive effect Effects 0.000 title abstract 2
- 239000000047 product Substances 0.000 claims abstract description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000009833 condensation Methods 0.000 claims abstract description 5
- 230000005494 condensation Effects 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000004821 distillation Methods 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 238000005496 tempering Methods 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims 2
- 239000004568 cement Substances 0.000 abstract description 13
- 239000000203 mixture Substances 0.000 abstract description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 4
- 240000000111 Saccharum officinarum Species 0.000 abstract description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000012263 liquid product Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000000855 fermentation Methods 0.000 description 3
- 230000004151 fermentation Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- RBNWAMSGVWEHFP-UHFFFAOYSA-N cis-p-Menthan-1,8-diol Natural products CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229930006948 p-menthane-3,8-diol Natural products 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- RBNWAMSGVWEHFP-WAAGHKOSSA-N terpin Chemical compound CC(C)(O)[C@H]1CC[C@@](C)(O)CC1 RBNWAMSGVWEHFP-WAAGHKOSSA-N 0.000 description 2
- 229950010257 terpin Drugs 0.000 description 2
- 208000034189 Sclerosis Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000016639 Syzygium aromaticum Nutrition 0.000 description 1
- 244000223014 Syzygium aromaticum Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
- C04B24/14—Peptides; Proteins; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
Abstract
The invention relates to a method for preparing a concrete additive by using vinasse obtained by distilling cane molasses, which is different from Chinese patent No.36.110 of 1, 4 days in 1997, wherein the vinasse before condensation is used instead of powder in the initial stage of the method, and a liquid product is finally obtained. The improvement comprises collecting a specified amount of sugarcane stillage having an insoluble content of between 8-10%, concentrating in two (2) steps to achieve a Brix of 60 ° at a temperature of 66 ℃, and mixing into a tank containing formaldehyde and soda ash. Thereafter, the mixture was decanted into an additional tank having a height of three (3) outlets that allowed a product with less than 1% insoluble. The product can change the characteristics of concrete structure, improve the plasticity of the concrete structure and improve the electrostatic dispersion of cement in concrete mixture.
Description
Technical field
The present invention relates to the concrete admixture preparation method's that a kind of building industry used especially in concrete mix improvement, this admixture makes with the vinasse that cane molasses distillation produces.
Background technology
Building industry is used different mixtures to improve concrete performance according to various purposes.
While preparing concrete according to special purpose, with the special modified product that cane molasses distillation obtains, improve and adjust some characteristic particularly important.For example, if need more increase resistance, must reduce water cement ratio with liquid agent.These products for every kind of specific function are known as concrete admixture.Modal concrete admixture is that those improve the liquid agent of fresh concrete usability by changing concrete surface tension force.They also reduce intergranular friction, and make cement granules with static charge, and cement granules is repelled mutually, thereby avoid agglomerating, and therefore improve concrete quality.Use liquid agent can also reduce concrete water-content, gain in strength, provide better concrete quality, and because it has replaced a part of cement in concrete mix, so more cheap, these are all known.
The important character of another one of admixture is that it allows the more mobile mixture of preparation, and eliminates air content.
Admixture of the present invention can be used according to concrete desired use together with other concrete hardenerss, promotor or slow setting composition.For example, if this concrete must transport at a distance, must postpone to condense the time opening.On the contrary, if concrete, for the manufacture of pre-manufactured product, can shorten time of coagulation.
Summary of the invention
The present invention relates to a kind of vinasse that obtained by sugarcane distillation and prepare the novel method of concrete admixture.
The admixture making is by the concrete preparation for building industry.
As previously mentioned, this technique is usingd the product that is known as vinasse that cane molasses distillation obtains as initial.
For removing the calcium sulfate insolubles that may stop up dosage valve in final product, vinasse are disperseed under the action of the centrifugal and remove described insolubles.The vinasse concentration that does not contain insolubles of this distillation is between 8 ° of-10 ° of Brixs (Brix).
For reducing fermentation capacity and water-content, be beneficial to carry, vinasse are delivered to plate-type condenser.Vinasse enter this thickener, and make its Brix bring up to 45 ° from 8 ° in the first stage; In the second thickener and subordinate phase, make the Brix of vinasse be increased to 60 °.The product of condensation is discharged the temperature of 66 ℃, and keep this temperature that described product is sent in tempering tank, in tempering tank, added formaldehyde and sodium hydroxide (SODA ASH LIGHT 99.2).It is sent into decanting tank from this groove, and this decanting tank has three outlets at various height, is used in each outlet test by the insolubles percentage after concentrated.At this temperature, reduced viscosity is to certain value, and insolubles is precipitated to container bottom very soon.
During due to condensation, water is removed, and insolubles is also removed and has reached minimum percentage with the form of calcium sulfate, between 0-1%, thereby provides the fermentation capacity reducing above-mentioned treatment stage.
Concentrated vinasse product is a kind of water reducer, and not with cement or any other cement component generation chemical reaction, its effect just changes the physical properties of cement, particularly for the physical properties of the tensile surface of cement.As tension active agent composition, it has the hydrophobic free base being formed by propyl group cloves (propilsyringilic) class phenyl, the repulsion that it is positioned at one end of molecule and is subject to water.At the other end of molecule, it comprises a hydrophilic free radical being formed by water acceptor sulfate.These compound effects are on cement granules, make it more easily infiltrate, flow, slide, and become the mixture that has more mobility, simultaneously, better water absorbability is provided and has flowed to be penetrated into the performance in the cement of sclerosis, to obtain the denseness of expectation in the situation that reducing water cement ratio.
For obtaining this concrete admixture, vinasse enriched material adopts encapsulant (blocking agent), stablizer and for example terpin calcium (calcium terpenate) and the product of sodium hydroxide to process.Terpin calcium produce as have 2-4 micron diameter bubble contain air.Yet, its not remarkably influenced concrete resistance.And the heat that the thermopositive reaction of water-cement produces has improved the mobility of mixture.Sodium hydroxide is increased to 7.5 by the pH value of product, has avoided the fermentation of product.These compositions have changed the acidity of product, make it become water reducer fluidisation admixture.
Accompanying drawing explanation: Fig. 1 is process flow sheet of the present invention
Embodiment
Final product provides the improvement of the patented method that focuses on fine concrete admixture, and the vinasse that this admixture is obtained by cane molasses distillation make, and more specifically, the vinasse enriched material being obtained by the method by following steps as shown in the schema of Fig. 1 is made:
The first step: the vinasse that preparation comprises the solid between 8 ° of-10 ° of per-cents of Brix.
Second step: vinasse are sent into the thickener I with plate-type condenser, in the first stage, the Brix of vinasse is increased to 45 ° by 8 °-10 °.
The 3rd step: the vinasse that second step is obtained are sent into plate-condenser thickener II, is increased to 60 ° by the Brix of described product by 45 ° in subordinate phase.
The 4th step: the enriched product with low viscosity and 66 ℃ of temperature is taken out, and keep this temperature, sent into tempering tank, add formaldehyde and sodium hydroxide (SODA ASH LIGHT 99.2) in tempering tank.
The 5th step: mix products is transported in decanting tank, and this decanting tank has three (3) the individual different open heights (I, II and III) that go out, and it allows to detect insolubles percentage.At the temperature of 66 ℃, reduced viscosity is to certain value, and insolubles is deposited to container bottom, and because insolubles is precipitated to container bottom, so this situation allows product to discharge from going out open height I, II and III.
Claims (1)
1. with the vinasse that produced by cane molasses distillation, prepare a method for concrete admixture, it comprises the following steps:
A) the described vinasse with the Brix concentration between 8 °-10 ° of centrifugation predetermined amount are to remove insolubles;
B) vinasse of described centrifugation are delivered in thickener, in the first condensation phase, by condenser, the Brix that is delivered to the vinasse in thickener are concentrated into 45 ° from 8 °-10 °;
C) by step b) vinasse that obtain are delivered in other thickener, in the second condensation phase by condenser by step b) Brix of the vinasse that obtains is concentrated into 60 ° from 45 °;
D) by step c) product that obtains is taken out in tempering tank the temperature of 66 ℃ from thickener, adds formaldehyde and sodium hydroxide in tempering tank;
E) temperature is remained to 66 ℃, product is delivered to and is had in three decanting tanks that go out open height, to extract the final product of insolubles percentage between 0-1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910211689.1A CN102020431B (en) | 2009-09-10 | 2009-09-10 | Method for preparing concrete additive by using vinasse obtained by distilling cane molasses |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910211689.1A CN102020431B (en) | 2009-09-10 | 2009-09-10 | Method for preparing concrete additive by using vinasse obtained by distilling cane molasses |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102020431A CN102020431A (en) | 2011-04-20 |
| CN102020431B true CN102020431B (en) | 2014-09-17 |
Family
ID=43862258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910211689.1A Expired - Fee Related CN102020431B (en) | 2009-09-10 | 2009-09-10 | Method for preparing concrete additive by using vinasse obtained by distilling cane molasses |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102020431B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3026032A1 (en) | 2014-11-25 | 2016-06-01 | PORISMA Trading GmbH | Additive for a hydraulically curable composition |
| WO2018095897A1 (en) * | 2016-11-22 | 2018-05-31 | Sika Technology Ag | Producing dispersants for solid suspensions from vinasse type materials |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108147732B (en) * | 2016-12-03 | 2020-07-10 | 广东省永固电力科技有限公司 | Composite telegraph pole |
| CN108147733B (en) * | 2016-12-03 | 2020-11-13 | 广西宏泰水泥制品有限责任公司 | Insulated telegraph pole and machining process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4899990A (en) * | 1988-11-18 | 1991-08-08 | Luis Perez Barrenechea | Procedure for the manufacture of additives for concrete from natural byproducts derived from sugar cane |
| CN1067231A (en) * | 1992-06-08 | 1992-12-23 | 黑龙江省低温建筑科学研究所 | Setting retardant type-high-early strength water-reducing agent preparation method and product |
| CN1072912A (en) * | 1992-06-15 | 1993-06-09 | 广西壮族自治区武鸣栲胶厂 | Produce powdery solid additive with molasses-spirit lees |
-
2009
- 2009-09-10 CN CN200910211689.1A patent/CN102020431B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU4899990A (en) * | 1988-11-18 | 1991-08-08 | Luis Perez Barrenechea | Procedure for the manufacture of additives for concrete from natural byproducts derived from sugar cane |
| CN1058765A (en) * | 1988-11-18 | 1992-02-19 | 路易斯·佩雷斯·巴兰那卡 | New method for preparing and processing concrete admixture from natural product |
| CN1067231A (en) * | 1992-06-08 | 1992-12-23 | 黑龙江省低温建筑科学研究所 | Setting retardant type-high-early strength water-reducing agent preparation method and product |
| CN1072912A (en) * | 1992-06-15 | 1993-06-09 | 广西壮族自治区武鸣栲胶厂 | Produce powdery solid additive with molasses-spirit lees |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3026032A1 (en) | 2014-11-25 | 2016-06-01 | PORISMA Trading GmbH | Additive for a hydraulically curable composition |
| WO2018095897A1 (en) * | 2016-11-22 | 2018-05-31 | Sika Technology Ag | Producing dispersants for solid suspensions from vinasse type materials |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102020431A (en) | 2011-04-20 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140917 Termination date: 20180910 |
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| CF01 | Termination of patent right due to non-payment of annual fee |