CN1020156C - Titanite type composite emulsion and its preparing process - Google Patents
Titanite type composite emulsion and its preparing process Download PDFInfo
- Publication number
- CN1020156C CN1020156C CN 89105692 CN89105692A CN1020156C CN 1020156 C CN1020156 C CN 1020156C CN 89105692 CN89105692 CN 89105692 CN 89105692 A CN89105692 A CN 89105692A CN 1020156 C CN1020156 C CN 1020156C
- Authority
- CN
- China
- Prior art keywords
- tio
- glaze
- sio
- aspidelite
- cao
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims description 4
- 239000002131 composite material Substances 0.000 title abstract 3
- 229910052861 titanite Inorganic materials 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 239000003605 opacifier Substances 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 22
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 229910052681 coesite Inorganic materials 0.000 abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 229910052682 stishovite Inorganic materials 0.000 abstract 2
- 229910052905 tridymite Inorganic materials 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 229910052845 zircon Inorganic materials 0.000 description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- 206010023126 Jaundice Diseases 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011468 face brick Substances 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
A sphene-type compound emulsion is prepared from CaO and TiO2、SiO2、P2O5As main components and synthesized at high temperature, the chemical composition range of the material is as follows: TiO 2215-40%、CaO20-40%、SiO215-25%、P2O55 to 15 percent. Wherein P is2O5Is a stabilizer. The synthesized composite opacifier can be directly introduced into raw glaze or made into frits to be added into the glaze, and the sphene-type composite structure is quite stable and has good opacifying effect. Changes the direct handling of TiO by people2By introducing into the glaze as opacifying agents, thereby avoidingFree TiO2The transformation into rutile turns yellow the glaze surface.
Description
The invention belongs to ceramic glaze with emulsion and the method for making this opacifying agent.
In the common opacifying agent of ceramic industry, with TiO
2Milkiness the strongest, its optical index is at 2.50-2.60, far above zircon (1.97) commonly used at present.Use TiO
2Making opacifying agent also has some successful examples at ceramic industry, as Italy, the Soviet Union is with regard to useful TiO
2Do that wall floor tile opaque glaze produces, China Wenzhou face brick factory also once used TiO
2Produce as the face brick opaque glaze, and that find to play the milkiness effect in the glaze mainly is Xie five (CaOTiO
2SiO
2), since it is so, why we extensively do not adopt TiO now
2And the lower zircon of selective refraction rate? its key just is that the titanium opaque glaze that we use at present all is TiO
2Directly add in the glaze with the free form, because the composition complexity in the glaze is difficult to make TiO
2Be completed into stable aspidelite crystal, mostly exist the free TiO of non-aspidelite type like this in the glaze
2These free TiO
2In high temperature, often from glaze, separate out, and rutile crystal very easily makes the glaze flavescence with the rutile form.In addition, free TiO
2Crystal formation transform, also extremely responsive to the change of glaze composition.Because these defectives, make TiO
2Be difficult to extensively in ceramic industry, use as emulsion.
The objective of the invention is to avoid above-mentioned defective, make TiO
2Can form more stable aspidelite structure morely, thereby make it can become the opacifying agent of widespread use.
The present invention is achieved in that and uses C
αO(C α CO
3), TiO
2, SiO
2(quartz) and P
2O
5(C α
3(PO
4) or the calcining bone ash] or other phosphoric acid salt as main component, high temperature synthesizes Xie type multiple emulsion.Its chemical composition range is: TiO
215-40%, CaO
20-40%, SiO
215-25%, P
2O
55-15%, wherein P
2O
5The main stabilization that rises, its TiO that can draw up effectively
2Change into rutile, but itself also has the milkiness effect, generally by Ca
3(PO
4)
2Or calcining bone ash or the introducing of other phosphoric acid salt.For guaranteeing aspidelite type structure rate of formation height, wherein CaO, TiO
2And SiO
2Content is than preferably trying one's best near aspidelite molecular formula (CaOTiO
2SiO
2Mole ratio.
The manufacture method of aspidelite type compound opacifier of the present invention is: the prescription batching by above-mentioned chemical constitution forms 1000-1400 ℃ of calcining after pulverizing mixes.
Promoting meaning of the present invention is: with TiO
2When using as opacifying agent, TiO
2Not directly to add in the glaze, but add in the glaze, thereby suppressed TiO effectively with a kind of stable aspidelite type macromolecular structure with the free form
2Change into the defective that rutile causes the glaze jaundice.So the stable aspidelite type compound opacifier of institute of the present invention synthetic both can replace extensively adopting opacifying agent to use at present in the low temperature frit glaze.
It and zircon, free TiO
2Compare, following characteristics arranged:
1, fusing point and high temperature viscosity are lower than zircon.The fusing that can reduce frit thus is molten, reduces the glaze pin hole, and replaces the zirconium megalith with equivalent amount, and the whip opaque effect is equally good.
2, TiO
2The source extensive more than zircon.Therefore, person in all parts of the country can synthesize this stable Xie type compound opacifier.
3, it does not resemble free TiO
2Like that very easily at high temperature change into rutile and cause the glaze jaundice.Therefore, it both can be used for the low temperature frit glaze, can be used for the high temperature raw glaze again, and it adapts to the TiO at the property specific ionization
2Extensively.
4, cost is all than zircon and TiO
2Low.
Embodiments of the invention: take by weighing 27.5% industrial TiO by weight percentage respectively
2, 35.0% industrial CaCO
3, 20.8% quartz (contains SiO
2More than 98%) and 16.7% industrial Ca
3(PO
4)
2Or the calcining bone ash (contains Ca
3(PO
4)
2More than 95%).Cross 200 mesh sieves, oven dry after then the wet-milling of ball milling altar being put in their mixing.These scholar's materials are put into biscuiting porcelain dish or saggar, and 1200 ℃ of calcinings down 1200 ℃ of insulations 1-2 hour, become a kind of white thing after the cooling in electric furnace.This white thing is stable aspidelite type compound opacifier, it can directly introduce in the raw glaze or the low temperature frit glaze in as opacifying agent.After introducing in the glaze, its aspidelite type structure is very stable, is not subjected to the influence of other composition in the glaze substantially.
Claims (3)
1, a kind of aspidelite type compound opacifier the invention is characterized in: with CaO, TiO
2, SiO
2And P
2O
5Be major ingredient, its chemical composition range is: TiO
215-40%, CaO20-40%, SiO
215-25%, P
2O
55-15%.
2, aspidelite type compound opacifier according to claim 1 is characterized in that CaO, TiO
2And SiO
2Content than pressing aspidelite molecular formula (CaO
2SiO
2) middle mole ratio dosage.
3, make the manufacture method of claim 1 or 2 described aspidelite type multiple emulsions, it is characterized in that: by the prescription batching of described chemical composition range, after pulverizing mixes at 1000-1400 ℃ of temperature lower calcination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89105692 CN1020156C (en) | 1989-03-28 | 1989-03-28 | Titanite type composite emulsion and its preparing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89105692 CN1020156C (en) | 1989-03-28 | 1989-03-28 | Titanite type composite emulsion and its preparing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1045963A CN1045963A (en) | 1990-10-10 |
| CN1020156C true CN1020156C (en) | 1993-03-24 |
Family
ID=4856344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89105692 Expired - Fee Related CN1020156C (en) | 1989-03-28 | 1989-03-28 | Titanite type composite emulsion and its preparing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1020156C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106448792B (en) * | 2016-10-11 | 2018-08-31 | 西南科技大学 | A kind of preparation method of aspidelite type prosthetic graft |
| CN106977104A (en) * | 2017-03-10 | 2017-07-25 | 华南理工大学 | A kind of preparation method of reflective insulation ceramics using titanium sphene as principal crystalline phase |
| CN107777694B (en) * | 2017-11-20 | 2020-09-15 | 吉林大学 | Method for preparing sphene from xonotlite |
| CN109320088B (en) * | 2018-11-28 | 2020-10-02 | 中国地质大学（北京） | Composite opacifier and preparation method thereof, ceramic glaze, ceramic and application |
| CN111875414B (en) * | 2020-06-30 | 2022-08-05 | 蒙娜丽莎集团股份有限公司 | High solar light reflectivity ceramic plate and preparation method thereof |
| CN111499202B (en) * | 2020-06-30 | 2020-11-13 | 蒙娜丽莎集团股份有限公司 | Opaque glaze with high solar light reflectivity and preparation method thereof |
| CN113860728B (en) * | 2021-11-24 | 2023-05-09 | 中国地质大学（北京） | A SiO2-CaCO3-TiO2 composite ceramic emulsifier based on ordered interface bonding and its preparation method |
| CN116947536B (en) * | 2023-09-18 | 2024-02-23 | 新明珠集团股份有限公司 | Zirconium-free ground glaze, titanium raw material opacified glazed tile and preparation method thereof |
-
1989
- 1989-03-28 CN CN 89105692 patent/CN1020156C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1045963A (en) | 1990-10-10 |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |