CN102002258B - Black cationic dye composition - Google Patents
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- CN102002258B CN102002258B CN2010102695844A CN201010269584A CN102002258B CN 102002258 B CN102002258 B CN 102002258B CN 2010102695844 A CN2010102695844 A CN 2010102695844A CN 201010269584 A CN201010269584 A CN 201010269584A CN 102002258 B CN102002258 B CN 102002258B
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- 125000002091 cationic group Chemical group 0.000 title claims abstract description 107
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 58
- 239000000975 dye Substances 0.000 claims description 67
- 239000012752 auxiliary agent Substances 0.000 claims description 21
- 239000002994 raw material Substances 0.000 claims description 15
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 claims description 13
- 229940039790 sodium oxalate Drugs 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 4
- 241000579895 Chlorostilbon Species 0.000 claims 9
- 229910052876 emerald Inorganic materials 0.000 claims 9
- 239000010976 emerald Substances 0.000 claims 9
- 238000004043 dyeing Methods 0.000 abstract description 20
- 239000000654 additive Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 10
- 238000001514 detection method Methods 0.000 description 4
- 239000001045 blue dye Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229920002972 Acrylic fiber Polymers 0.000 description 2
- 0 CCCIN*c1ccc(*=*C(*(*)C=*2)=*2NC)cc1 Chemical compound CCCIN*c1ccc(*=*C(*(*)C=*2)=*2NC)cc1 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000001044 red dye Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- VRAOBFWNUBUCRN-UHFFFAOYSA-N CC1(C)c(cccc2)c2[N+](C)=C1/C=N\N(C)c(cc1)ccc1OC Chemical compound CC1(C)c(cccc2)c2[N+](C)=C1/C=N\N(C)c(cc1)ccc1OC VRAOBFWNUBUCRN-UHFFFAOYSA-N 0.000 description 1
- 241000083869 Polyommatus dorylas Species 0.000 description 1
- LFXFSRBKXFUAKC-UHFFFAOYSA-N [Ar]Nc1ccccc1 Chemical compound [Ar]Nc1ccccc1 LFXFSRBKXFUAKC-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 1
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Abstract
本发明公开了一种黑色阳离子染料组合物，其原料重量百分比组成为：20％～51％的组分A，为如式(1)所示化合物中的一种；10％～22％的组分B，为如式(2)所示化合物中的一种；13％～21％的组分C，为如式(3)所示化合物中的一种；8.0％～20％的组分D，为如式(4)所示化合物中的一种；4.5％～16％的组分E，为如式(5)所示化合物中的一种；其余为助剂。本发明的黑色阳离子染料组合物牢度性能优异、色光鲜艳，配伍值为5，具有极佳的匀染性，能满足所有配伍值为5的使用场合，且使用过程中各项牢度性能稳定。The invention discloses a black cationic dye composition, which is composed of 20% to 51% of component A, which is one of the compounds shown in formula (1); 10% to 22% of component A Component B is one of the compounds shown in formula (2); 13% to 21% of component C is one of the compounds shown in formula (3); 8.0% to 20% of component D , is one of the compounds shown in formula (4); 4.5% to 16% of component E is one of the compounds shown in formula (5); the rest are additives. The black cationic dye composition of the present invention has excellent fastness performance, bright shade, a compatibility value of 5, has excellent level dyeing property, can meet all use occasions with a compatibility value of 5, and has stable fastness properties during use .
Description
技术领域technical field
本发明涉及一种阳离子染料组合物，尤其涉及一种适用于聚丙烯腈材料和改性涤纶的印染的黑色阳离子染料组合物。The invention relates to a cationic dye composition, in particular to a black cationic dye composition suitable for printing and dyeing polyacrylonitrile materials and modified polyester.
背景技术Background technique
随着近几年染料技术的飞速发展，多种染料的混拼技术在印染行业的占据越来越大的空间。不同阳离子染料对纤维的亲和力不同，在纤维中的扩散速率也不同。在两种或两种以上阳离子染料拼染时，如果染料的亲和力和上染速率差别较大，染色过程中容易造成染色不匀和色泽变化。因此，在阳离子染料染色时，应选择上染速率接近的染料拼染，使染得的产品色泽均匀一致，这种染料的拼染性能就是染料的配伍性。目前在阳离子染料配伍性能的测定方法中，最常用的方法为配伍值法，用数值表示阳离子染料的配伍性能称为配伍值，常以K值代表。配伍值相同的才可以拼染。配伍值的测定方法，采用黄、蓝两组标准染料，每组由5个染料组成，每个染料有一定的配伍值。配伍值越大，染料的吸尽速度越慢，匀染性越好；配伍值越小，染料吸尽速度越快，匀染性不好。国内腈纶和改性涤纶的染色用黑色阳离子染料的配伍值以3为主，匀染性不是很好。公开号为CN100374510C的专利文献公开了一种匀染性极佳的阳离子黑色染料，因其配伍值为5，深受印染行业的喜爱，但仅仅一种匀染性极佳的阳离子黑色染料远远不能满足大量对染料匀染性要求较高的场合的需求，且上述阳离子黑色染料组合物使用过程中各项牢度性能不稳定。因此，继续探寻配伍值高且应用性能优异的阳离子黑色染料是印染业一项急切的任务。With the rapid development of dye technology in recent years, the mixing technology of various dyes occupies more and more space in the printing and dyeing industry. Different cationic dyes have different affinity to fibers and different diffusion rates in fibers. When two or more cationic dyes are blended and dyed, if the affinity and dyeing rate of the dyes are quite different, it is easy to cause uneven dyeing and color changes during the dyeing process. Therefore, when dyeing with cationic dyes, dyes with close dyeing rate should be selected for blending dyeing, so that the dyed products have uniform color and luster. The blending performance of this dye is the compatibility of dyes. At present, in the determination method of the compatibility of cationic dyes, the most commonly used method is the compatibility value method. The compatibility value of cationic dyes is expressed by numerical values, which is called compatibility value, often represented by K value. Only those with the same compatibility value can be dyed together. The determination method of compatibility value adopts two groups of standard dyes, yellow and blue, each group consists of 5 dyes, and each dye has a certain compatibility value. The greater the compatibility value, the slower the exhaustion speed of the dye, and the better the level dyeing property; the smaller the compatibility value, the faster the dye exhaustion rate, and the poor leveling property. The compatibility value of black cationic dyes for domestic acrylic fiber and modified polyester dyeing is mainly 3, and the level dyeing property is not very good. Publication No. CN100374510C discloses a cationic black dye with excellent level dyeing property, which is deeply loved by the printing and dyeing industry because of its compatibility value of 5, but only a cationic black dye with excellent level dyeing property is far away. It cannot meet the needs of a large number of occasions that require high dye levelness, and the fastness properties of the above-mentioned cationic black dye composition are unstable during use. Therefore, it is an urgent task for the printing and dyeing industry to continue to search for cationic black dyes with high compatibility and excellent application performance.
发明内容Contents of the invention
本发明提供了一种匀染性极佳、配伍值为5，且摩擦牢度、耐洗牢度、耐汗渍牢度等各项牢度均优且性能稳定的黑色阳离子染料组合物。The invention provides a black cationic dye composition with excellent level dyeing property, compatibility value of 5, excellent rubbing fastness, washing fastness, perspiration fastness and other fastnesses and stable performance.
一种黑色阳离子染料组合物，其原料重量百分比组成为：A kind of black cationic dye composition, its raw material weight percentage consists of:
组分A 20%～51%Component A 20%～51%
组分B 10%～22%Component B 10%～22%
组分C 13%～21%Component C 13%～21%
组分D 8.0%～20%Component D 8.0%～20%
组分E 4.5%～16%Component E 4.5%～16%
其余为助剂；The rest are additives;
其中，组分A为如式（1）所示化合物中的一种：Wherein, component A is one of the compounds shown in formula (1):
组分B为如式（2）所示化合物中的一种：Component B is one of the compounds shown in formula (2):
组分C为如式（3）所示化合物中的一种：Component C is one of the compounds shown in formula (3):
组分D为如式（4）所示化合物中的一种：Component D is one of the compounds shown in formula (4):
组分E为如式（5）所示化合物中的一种：Component E is one of the compounds shown in formula (5):
所述的X-为CH3SO4 -、ZnCl3 -、Br-或Cl-。The X - is CH 3 SO 4 - , ZnCl 3 - , Br - or Cl - .
所述的助剂为元明粉和草酸钠中的一种或两种混合物。The auxiliary agent is one or a mixture of sodium oxalate and sodium oxalate.
综合考虑原料的易得性和成本，优选的黑色阳离子染料组合物的原料重量百分比组成为：Taking into account the ease of availability and cost of raw materials, the weight percent of raw materials of the preferred black cationic dye composition consists of:
组分A 37.4%～51%Component A 37.4%～51%
组分B 10%～12.4%Component B 10%～12.4%
组分C 13%～18.2%Component C 13%～18.2%
组分D 8%～15.3%Component D 8%～15.3%
组分E 4.5%～5.8%Component E 4.5%～5.8%
元明粉 5%～7.3%Yuanmingfen 5%～7.3%
草酸钠 3.6%～8.5%。Sodium oxalate 3.6% to 8.5%.
进一步优选的黑色阳离子染料组合物的原料重量百分比组成为：The raw material weight percentage of further preferred black cationic dye composition consists of:
组分A 20%～41.3%Component A 20%～41.3%
组分B 15%～21%Component B 15%～21%
组分C 14.5%～20%Component C 14.5%～20%
组分D 9.2%～19%Component D 9.2%～19%
组分E 8.7%～15%Component E 8.7%～15%
元明粉 5%～9%。Yuanming powder 5% to 9%.
再进一步优选的黑色阳离子染料组合物的原料重量百分比组成为：The raw material weight percentage of further preferred black cationic dye composition is composed of:
组分A 25%～33%Component A 25%～33%
组分B 14%～17.8%Component B 14%～17.8%
组分C 16.1%～21%Component C 16.1%～21%
组分D 10.6%～20%Component D 10.6%～20%
组分E 11.6%～14%Component E 11.6%～14%
草酸钠 10%～13.4%。Sodium oxalate 10% ~ 13.4%.
上述如式（1）或式（2）所示的化合物为现有的蓝色染料，如式（3）所示化合物为现有的红色染料，如式（4）或式（5）所示的化合物为现有的黄色染料，组分A～E以及助剂均可选用市售产品。The above compound shown in formula (1) or formula (2) is an existing blue dye, and the compound shown in formula (3) is an existing red dye, as shown in formula (4) or formula (5) The compound is the existing yellow dye, and the components A~E and auxiliary agents can be selected from commercially available products.
上述染料组合物可由下述方法制备，将组分A、组分B、组分C、组分D、组分E以及助剂按上述重量百分比称量后经粉碎机粉碎后进入混和机，混和4～8小时即可得到匀染性极佳的黑色阳离子染料组合物。The above-mentioned dye composition can be prepared by the following method. Component A, Component B, Component C, Component D, Component E and auxiliary agents are weighed according to the above-mentioned weight percentage, and then pulverized by a pulverizer and then entered into a mixer, and mixed A black cationic dye composition with excellent level dyeing property can be obtained in 4-8 hours.
本发明的黑色阳离子染料组合物牢度性能优异、色光鲜艳，配伍值为5，具有极佳的匀染性，使用过程中各项牢度性能稳定，能满足所有配伍值为5的使用场合。The black cationic dye composition of the present invention has excellent fastness performance, bright shade, a compatibility value of 5, excellent level dyeing property, stable fastness properties during use, and can satisfy all use occasions with a compatibility value of 5.
具体实施方式Detailed ways
实施例1～9Examples 1-9
按表1所示的原料配比，将组分A、组分B、组分C、组分D、组分E以及助剂经磨粉机磨粉后进入混和机混和4～8小时，得到黑色阳离子染料。其中，如式（1）所示的蓝色染料组分可选用浙江闰土股份有限公司生产的阳离子蓝SD-GSL，如式（2）所示的蓝色染料组分可选用浙江闰土股份有限公司生产的阳离子翠蓝SD-GB，如式（3）所示的红色染料组分可选用浙江闰土股份有限公司生产的阳离子红SD-GRL，如式（4）所示的黄色染料组分可选用浙江闰土股份有限公司生产的阳离子金黄SD-GL，如式（5）所示的黄色染料组分可选用浙江闰土股份有限公司生产的阳离子黄SD-5GL。According to the ratio of raw materials shown in Table 1, component A, component B, component C, component D, component E and additives are pulverized by a mill and mixed in a mixer for 4 to 8 hours to obtain Black cationic dye. Among them, the blue dye component shown in formula (1) can be selected from the cationic blue SD-GSL produced by Zhejiang Runtu Co., Ltd., and the blue dye component shown in formula (2) can be selected from Zhejiang Runtu Co., Ltd. The cationic turquoise blue SD-GB produced by Zhejiang Runtu Co., Ltd., the red dye component shown in formula (3) can be selected from the cationic red SD-GRL produced by Zhejiang Runtu Co., Ltd., the yellow dye group shown in formula (4) The cationic golden yellow SD-GL produced by Zhejiang Runtu Co., Ltd. can be selected for the component, and the cationic yellow SD-5GL produced by Zhejiang Runtu Co., Ltd. can be used for the yellow dye component shown in formula (5).
表1Table 1
对上述实施例1～9配制的黑色阳离子染料组合物进行配伍值检测，The black cationic dye composition of above-mentioned embodiment 1～9 preparation is carried out compatibility value detection,
检测方法为：GB/T2400-2006阳离子染料染腈纶时配伍值指数的测定方法。经检测，实施例1～9配制的黑色阳离子染料组合物的配伍值均为5。The detection method is: GB/T2400-2006 Determination method of compatibility value index when dyeing acrylic fiber with cationic dyes. After testing, the compatibility values of the black cationic dye compositions prepared in Examples 1-9 are all 5.
对上述实施例1～9配制的黑色阳离子染料组合物以及公开号为CN100374510C专利文献中实施例1中的方法制备得到黑色阳离子染料组合物作为对比样品进行性能检测，检测方法为：GB2374染料染色的一般条件规定、GB2399阳离子染料染色色光和强度的测定方法。The black cationic dye composition prepared in the above-mentioned Examples 1 to 9 and the black cationic dye composition prepared by the method in Example 1 in the CN100374510C patent document are used as a comparative sample for performance detection, and the detection method is: GB2374 dyed General Conditions, GB2399 Method for Determination of Shade and Intensity of Cationic Dyes.
观察布样色光并采用国家标准GB3920纺织品耐摩擦色牢度试验方法、GB3921纺织品耐洗色牢度试验方法、GB3922纺织品耐汗渍色牢度试验方法测定其染色牢度。测定结果见表2。Observe the shade of the cloth sample and use the national standard GB3920 Test method for color fastness to rubbing of textiles, GB3921 Test method for color fastness to washing of textiles, GB3922 Test method for color fastness to perspiration of textiles to measure its color fastness. The measurement results are shown in Table 2.
表2Table 2
上述测试结果表明：本发明的阳离子黑色染料在满足配伍性为5的前提下，摩擦牢度、耐洗牢度以及耐汗渍牢度有明显提高，且使用过程中各项牢度性能稳定。The above test results show that the cationic black dye of the present invention has significantly improved rubbing fastness, washing fastness and perspiration fastness under the premise of satisfying the compatibility of 5, and the fastness properties are stable during use.
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| CN103360789B (en) * | 2013-07-24 | 2015-04-22 | 杭州璟江瑞华科技有限公司 | Composite cationic dye composition with high light fastness |
| CN108929565B (en) * | 2018-07-06 | 2020-06-09 | 盐城东吴化工有限公司 | Cationic black dye composition and preparation and application thereof |
| CN110016240B (en) * | 2019-05-20 | 2020-07-17 | 上海贝通色彩科技有限公司 | Cationic black dye composition and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699686A (en) * | 2005-06-07 | 2005-11-23 | 浙江闰土股份有限公司 | White discharge cationic black dye for dyeing and printing |
| CN1699685A (en) * | 2005-06-07 | 2005-11-23 | 浙江闰土股份有限公司 | Cationic black dye for modified polyester dyeing |
| CN1718638A (en) * | 2005-07-08 | 2006-01-11 | 浙江闰土股份有限公司 | High-fastness high-performance cationic black dye |
| CN1724592A (en) * | 2005-07-11 | 2006-01-25 | 浙江闰土股份有限公司 | Cationic black dye with excellent level-dyeing property |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1699686A (en) * | 2005-06-07 | 2005-11-23 | 浙江闰土股份有限公司 | White discharge cationic black dye for dyeing and printing |
| CN1699685A (en) * | 2005-06-07 | 2005-11-23 | 浙江闰土股份有限公司 | Cationic black dye for modified polyester dyeing |
| CN1718638A (en) * | 2005-07-08 | 2006-01-11 | 浙江闰土股份有限公司 | High-fastness high-performance cationic black dye |
| CN1724592A (en) * | 2005-07-11 | 2006-01-25 | 浙江闰土股份有限公司 | Cationic black dye with excellent level-dyeing property |
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