CN101982254A - Yellow soil-base sinter-strippable casting coating and preparation method thereof - Google Patents
Yellow soil-base sinter-strippable casting coating and preparation method thereof Download PDFInfo
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Abstract
本发明涉及一种黄壤土基烧结剥离型铸造涂料及其制备方法,其组分包括:由重量比为6-8∶2-4∶0.5-1.5的黄壤土粉、铅锌矿渣粉、膨润土组成的粉料,以及占粉料总重量3%-6%的硅溶胶。先将黄壤土粉、铅锌矿渣粉按照比例混合后在800℃-1200℃进行焙烧,待其冷却后将膨润土、硅溶胶按照比例加入,与水搅拌,即得。本发明的涂料具备良好的悬浮性,浇注后涂料形成易剥离的致密烧结壳,获得的铸件表面光洁,粗糙度低,铸件尺寸精度高,铸件质量良好;制备方法工艺简单,原料价格低廉、来源广泛,具有良好的应用前景。
The invention relates to a yellow loam soil-based sintered stripping type casting paint and a preparation method thereof. Its components include yellow loam powder, lead-zinc slag powder and bentonite with a weight ratio of 6-8:2-4:0.5-1.5. The powder, and the silica sol accounting for 3%-6% of the total weight of the powder. First mix yellow loam powder and lead-zinc slag powder according to the ratio, then roast at 800°C-1200°C, after cooling, add bentonite and silica sol according to the ratio, and stir with water to obtain the product. The coating of the present invention has good suspending property, and after pouring, the coating forms a dense sintered shell that is easy to peel off, and the obtained casting has a smooth surface, low roughness, high dimensional accuracy of the casting, and good quality of the casting; the preparation method is simple, and the raw material is cheap and sourced Wide range, with good application prospects.
Description
技术领域technical field
本发明属于铸造涂料及其制备领域,特别涉及一种黄壤土基烧结剥离型铸造涂料及其制备方法。The invention belongs to the field of casting paint and its preparation, and in particular relates to a yellow loam soil-based sintered stripping casting paint and a preparation method thereof.
背景技术Background technique
随着国民经济以及人类生产生活水平的不断提高,对铸件的尺寸精度和表面质量要求也在不断提高。在砂型铸造工艺中,最常见的铸件缺陷是粘砂,而使用涂料能较好的解决这一缺陷,涂料涂敷在型腔表面形成一道隔离层,能防止铸件产生粘砂等缺陷。With the continuous improvement of the national economy and human production and living standards, the requirements for dimensional accuracy and surface quality of castings are also increasing. In the sand casting process, the most common casting defect is sand sticking, and the use of coatings can better solve this defect. The coating forms an isolation layer on the surface of the cavity, which can prevent castings from sand sticking and other defects.
耐火粉料是铸造涂料中的基本组成部分,常用的耐火粉料石英粉、锆英粉、铬铁矿粉等。涂料在进入工作状态前是一种胶状分散体系,因此需在涂料中需加入悬浮剂、粘结剂等保证涂料的一致性以及使涂料具有一定的粘结力,良好的悬浮性除了能保证涂料的一致性外,还能保证有良好的涂覆性能。常用的悬浮剂有膨润土、凹凸棒土、羧甲基纤维素钠(CMC)等,常见的粘结剂有粘土、水玻璃、硅溶胶等。优质的涂料还要具备良好的渗透能力,能完全填充型腔的孔隙,因此要求粉料的粒度要足够细。涂料载体的主要作用是运载耐火粉料、粘结剂、悬浮剂等物质,以便能将涂料涂敷于铸型表面,按照载体的类型分类,主要有水和有机溶剂,以水为载体时,去除的方法是烘干或者晾干;以醇类作为载体时,去除的方法是用火点燃烧掉,然而醇类点燃后会产生一系列的气体。Refractory powders are the basic components of casting coatings, commonly used refractory powders are quartz powder, zircon powder, chromite powder, etc. The paint is a colloidal dispersion system before it enters the working state, so it is necessary to add suspending agent, binder, etc. to the paint to ensure the consistency of the paint and to make the paint have a certain cohesion. Good suspension can not only ensure In addition to the consistency of the coating, it can also ensure good coating performance. Commonly used suspending agents include bentonite, attapulgite, sodium carboxymethylcellulose (CMC), etc., and common binders include clay, water glass, and silica sol. High-quality coatings also have good penetration ability and can completely fill the pores of the cavity, so the particle size of the powder is required to be fine enough. The main function of the paint carrier is to carry refractory powder, binder, suspending agent and other substances so that the paint can be applied to the surface of the mold. According to the type of carrier, there are mainly water and organic solvents. When water is used as the carrier, The removal method is to dry or dry; when alcohol is used as the carrier, the removal method is to burn it with a fire, but a series of gases will be produced after the alcohol is ignited.
发明内容Contents of the invention
本发明所要解决的技术问题是提供一种黄壤土基烧结剥离型铸造涂料及其制备方法,该涂料具备良好的悬浮性,浇注后涂料形成易剥离的致密烧结壳,获得的铸件表面光洁,粗糙度低,铸件尺寸精度高,铸件质量良好;制备方法工艺简单,原料价格低廉、来源广泛,具有良好的应用前景。The technical problem to be solved by the present invention is to provide a yellow loam soil-based sintered stripping casting coating and its preparation method. The coating has good suspension properties. After pouring, the coating forms a dense sintered shell that is easy to peel off. The surface of the obtained casting is smooth and rough. The casting has low degree of precision, high dimensional accuracy and good casting quality; the preparation method is simple, the raw material price is low, and the source is wide, so it has a good application prospect.
本发明的一种黄壤土基烧结剥离型铸造涂料,其组分包括:由重量比为6-8∶2-4∶0.5-1.5的黄壤土粉、铅锌矿渣粉、膨润土组成的粉料,以及占粉料总重量3%-6%的硅溶胶。A kind of yellow loam soil-based sintering stripping casting coating of the present invention, its component comprises: the powder material that is made up of yellow loam soil powder, lead-zinc slag powder, bentonite that is 6-8: 2-4: 0.5-1.5 by weight ratio, And silica sol accounting for 3%-6% of the total weight of the powder.
所述黄壤土粉的粒度为270-350目,铅锌矿渣粉的粒度为270-350目,膨润土的粒度为180-220目。The particle size of the yellow loam powder is 270-350 mesh, the particle size of the lead-zinc slag powder is 270-350 mesh, and the particle size of the bentonite is 180-220 mesh.
本发明的一种黄壤土基烧结剥离型铸造涂料的制备方法,包括:A kind of preparation method of yellow loam soil-based sintering peel-off casting coating of the present invention comprises:
(1)将黄壤土粉、铅锌矿渣粉按6-8∶2-4混合后于800℃-1200℃进行焙烧,冷却;(1) Roasting at 800°C-1200°C after mixing yellow loam powder and lead-zinc slag powder according to 6-8:2-4, and cooling;
(2)在经焙烧、冷却后的黄壤土粉、铅锌矿渣粉混合物中加入与黄壤土粉重量比为0.5-1.5∶6-8的膨润土和占粉料总重量3%-6%的硅溶胶,加水搅拌均匀,即得,加入少量的水,利用搅拌机进行缓慢搅拌,使得原料充分溶于水中,随后缓慢增加适量的水,此时可以提高搅拌机的转速,待所有原料搅拌均匀后,保持搅拌机的转速继续搅拌15分钟,即得。(2) Adding bentonite with a weight ratio of 0.5-1.5:6-8 to the yellow loam powder and 3%-6% of the total weight of the powder into the roasted and cooled yellow loam powder and the mixture of lead-zinc slag powder Sol, add water and stir evenly, that is, add a small amount of water, use a mixer to stir slowly, so that the raw materials are fully dissolved in water, and then slowly add an appropriate amount of water. At this time, you can increase the speed of the mixer. After all the raw materials are stirred evenly, keep The speed of the mixer continued to stir for 15 minutes, and it was ready.
本发明的涂料除了满足铸造涂料的基本性质外,本涂料还可以在浇注温度之下50℃-100℃熔融烧结,本发明的涂料在浇注过程中烧结,能屏蔽气孔和型砂渗入到铸件表面,在冷却过程中形成致密的烧结壳,保证了铸件尺寸精度,形成的烧结壳在完全冷却后容易剥离铸件表面,防止了粘砂,提高了铸件表面质量;在使用过程中有良好的涂刷性,并且铸件可以在较高温度下打箱取出,提高了铸件的生产效率。In addition to satisfying the basic properties of casting coatings, the coatings of the present invention can also be melted and sintered at 50°C-100°C below the pouring temperature. The coatings of the present invention are sintered during the pouring process and can shield pores and molding sand from penetrating into the casting surface. A dense sintered shell is formed during the cooling process to ensure the dimensional accuracy of the casting. The formed sintered shell is easy to peel off the surface of the casting after complete cooling, preventing sand sticking and improving the surface quality of the casting; it has good paintability during use. , and the castings can be taken out of the box at a higher temperature, which improves the production efficiency of the castings.
有益效果Beneficial effect
(1)本发明的涂料具备良好的悬浮性,在使用过程中能很好的保证涂料的一致性,存储方便;(1) The coating of the present invention possesses good suspending property, can well guarantee the consistency of coating during use, and storage is convenient;
(2)浇注后涂料形成易剥离的致密烧结壳,获得的铸件表面光洁,粗糙度低,铸件尺寸精度高,铸件质量良好;(2) After pouring, the coating forms a dense sintered shell that is easy to peel off, and the obtained casting has a smooth surface, low roughness, high dimensional accuracy of the casting, and good quality of the casting;
(3)本发明的制备方法工艺简单,原料价格低廉、来源广泛,具有良好的应用前景。(3) The preparation method of the present invention has simple process, low raw material price and wide sources, and has good application prospects.
附图说明Description of drawings
图1为实施例1的浇注铸件实物图;Fig. 1 is the physical figure of pouring casting of embodiment 1;
图2为实施例2的浇注铸件实物图。Fig. 2 is the physical figure of pouring casting of embodiment 2.
具体实施方式Detailed ways
下面结合具体实施例,进一步阐述本发明。应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解,在阅读了本发明讲授的内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。Below in conjunction with specific embodiment, further illustrate the present invention. It should be understood that these examples are only used to illustrate the present invention and are not intended to limit the scope of the present invention. In addition, it should be understood that after reading the teachings of the present invention, those skilled in the art can make various changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the appended claims of the present application.
实施例1Example 1
(1)将黄壤土粉、铅锌矿渣粉按重量比3∶1混合后于800℃进行焙烧,冷却;(1) Roasting at 800°C after mixing yellow loam powder and lead-zinc slag powder in a weight ratio of 3:1, cooling;
(2)在经焙烧、冷却后的黄壤土粉、铅锌矿渣粉混合物中加入与黄壤土粉重量比为1∶12的膨润土和占粉体总重量3%的硅溶胶,加入少量的水,利用搅拌机进行缓慢搅拌,使得原料充分溶于水中,随后缓慢增加适量的水,此时可以提高搅拌机的转速,待所有原料搅拌均匀后,保持搅拌机的转速继续搅拌15分钟,即得。(2) in the yellow loam powder, lead-zinc slag powder mixture after roasting, cooling, add the bentonite that is 1: 12 with the yellow loam powder weight ratio and account for the silica sol of powder gross weight 3%, add a small amount of water, Use a mixer to stir slowly to make the raw materials fully dissolve in water, then slowly add an appropriate amount of water, at this time, you can increase the speed of the blender, and after all the raw materials are evenly stirred, keep the speed of the blender and continue stirring for 15 minutes to obtain the product.
将配制出的涂料涂刷在φ150mm×20mm的型腔表面,涂料涂刷性能良好,涂料能完全充分的填充型腔表面的孔隙,将涂刷有涂料的型腔烘干后按照正常的浇注铸铁的方法进行浇注,浇注温度为1300℃-1500℃,当铁水凝固后打箱发现,涂层均已烧结,形成的烧结壳在铸件冷却的过程中剥离铸件表面。将铸件表面烧结壳清理后发现,铸件表面光洁,粗糙度较低,并未出现粘砂现象。由涂层形成的铸件表面如图一所示。Brush the prepared paint on the surface of the cavity of φ150mm×20mm. The coating performance is good, and the paint can fully fill the pores on the surface of the cavity. After drying the cavity coated with the paint, pour the cast iron according to the normal method. pouring method, the pouring temperature is 1300°C-1500°C, when the molten iron is solidified, it is found that the coating has been sintered, and the formed sintered shell peels off the surface of the casting during the cooling process of the casting. After cleaning the sintered shell on the surface of the casting, it was found that the surface of the casting was smooth and the roughness was low, and there was no sand sticking phenomenon. The casting surface formed by the coating is shown in Fig. 1.
实施例2Example 2
(1)将黄壤土粉、铅锌矿渣粉按重量比2∶1混合后于1200℃进行焙烧,冷却;(1) Roasting at 1200°C after mixing yellow loam powder and lead-zinc slag powder in a weight ratio of 2:1, and cooling;
(2)在经焙烧、冷却后的黄壤土粉、铅锌矿渣粉混合物中加入与黄壤土粉重量比为1.5∶8的膨润土和占粉体总重量6%的硅凝胶,加入少量的水,利用搅拌机进行缓慢搅拌,使得原料充分溶于水中,随后缓慢增加适量的水,此时可以提高搅拌机的转速,待所有原料搅拌均匀后,保持搅拌机的转速继续搅拌15分钟,即得。(2) In the mixture of yellow loam powder and lead-zinc slag powder after roasting and cooling, add bentonite with a weight ratio of 1.5:8 and silica gel accounting for 6% of the total weight of the powder with the yellow loam powder, add a small amount of water , use a mixer to stir slowly, so that the raw materials are fully dissolved in water, and then slowly add an appropriate amount of water. At this time, the speed of the mixer can be increased. After all the raw materials are stirred evenly, keep the speed of the mixer and continue stirring for 15 minutes.
将配制出的涂料涂刷在φ80mm×150mm的砂芯表面,将涂层经过烘干后进行浇注,浇注试样尺寸为:外径φ150mm,内径φ80mm,高度150mm。当铁水凝固后打箱发现,涂层均已烧结,形成的烧结壳在铸件冷却的过程中剥离铸件表面。将铸件表面烧结壳清理后发现,铸件表面光洁,粗糙度较低,并未出现粘砂现象。由涂层形成的铸件内表面如图二所示。Brush the prepared paint on the surface of the φ80mm×150mm sand core, dry the coating and pour it. The pouring sample size is: outer diameter φ150mm, inner diameter φ80mm, height 150mm. When the molten iron solidified, it was found that the coating had been sintered, and the formed sintered shell peeled off the surface of the casting during the cooling of the casting. After cleaning the sintered shell on the surface of the casting, it was found that the surface of the casting was smooth and the roughness was low, and there was no sand sticking phenomenon. The inner surface of the casting formed by the coating is shown in Fig. 2.
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CN107414015A (en) * | 2017-08-08 | 2017-12-01 | 合肥正明机械有限公司 | A kind of method for improving Iron Casting Surface quality |
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CN1082466A (en) * | 1993-02-15 | 1994-02-23 | 大连冷冻机厂 | Resin sand mould (core) or cast part type (core) is used water based paint |
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