CN101967756B - Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof - Google Patents
Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof Download PDFInfo
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- CN101967756B CN101967756B CN2010105092675A CN201010509267A CN101967756B CN 101967756 B CN101967756 B CN 101967756B CN 2010105092675 A CN2010105092675 A CN 2010105092675A CN 201010509267 A CN201010509267 A CN 201010509267A CN 101967756 B CN101967756 B CN 101967756B
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Abstract
The invention discloses an anti-mosquito water-proof air permeability wear-resisting resin used for synthetic leather, which comprises the following components in parts by weight: 30-40 parts of polyether polyurethane resin, 5-10 parts of polyester polyurethane resin, 50-55 parts of water, 4-5 parts of silicon dioxide extinction powder, 2-4 parts of anti-mosquito assistant, 2-4 parts of oxidized polyethlene wax, 1-3 parts of modified amino siloxane, 1-3 parts of fluorocarbon surfactant, 1-2 parts of organosilicon flatting agent and 0.5-1 part of fluorine drying agent. The invention also discloses a preparation method of the anti-mosquito water-proof air permeability wear-resisting resin used for synthetic leather; the anti-mosquito water-proof air permeability wear-resisting resin for the synthetic leather has gloss, softness and smooth handfeel, waterproof property and air permeability, wear resistance and scrape resistance, has high-efficiency and rapid striking and killing effect and good repellent effect on mosquitoes, flies, fleas, cooties and moths and the like.
Description
Technical field
The present invention relates to a kind of use for synthetic leather resin, particularly a kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin that is used for synthetic leather rear section technology the invention also discloses the preparation method of this use for synthetic leather mosquito proof waterproof and breathable wear resistant resin simultaneously.
Background technology
Synthetic leather is widely used in interior decoration, mattress, sofa and the automobile substitute as corium; But present synthetic leather is prone to exist following problem: function is perfect inadequately in some range of application, and comfortableness and practicality are outstanding inadequately, and feel is jerky; Water proofing property is poor; Gas permeability is poor, not wear-resisting scratch resistance, and storage is prone to damage by worms the time.
Summary of the invention
Goal of the invention: the present invention provides a kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin that is used for synthetic leather rear section technology and preparation method thereof in order to solve the deficiency of prior art.
Technical scheme: in order to realize above purpose, a kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin of the present invention, its parts by weight proportioning is following: polyethers is 30 parts～40 parts of polyurethane resins; Polyester is 5 parts～10 parts of polyurethane resins, 50 parts～55 parts in water, 4 parts～5 parts of silica flatting silicas; 2 parts～4 parts of mosquito proof auxiliary agents; 2 parts～4 parts of OPEs, 1 part～3 parts of modified amido siloxanes, 1 part～3 parts of fluorocarbon surfactants; 1 part～2 parts of organosilicon levelling agents, 0.5 part～1 part of fluouine water extraction agent.
The invention also discloses the preparation method of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, the concrete steps of this method are following:
(1) is that polyurethane resin and polyester are that polyurethane resin mixes and obtains mixture A by the mass fraction proportioning prescription of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin with polyethers, takes out then and obtain mixture B after 1/3 mixture A and silica flatting silica stir, grind, filter in water;
(2) mixture B is added mosquito proof auxiliary agent, OPE, modified amido siloxanes, fluorocarbon surfactant, organosilicon levelling agent and fluouine water extraction agent, obtain mixture C after stirring;
(3) mixture C is added remaining 2/3 mixture A, filter after the mixing and stirring and can obtain described use for synthetic leather mosquito proof waterproof and breathable wear resistant resin.
Beneficial effect: use for synthetic leather mosquito proof waterproof and breathable wear resistant resin of the present invention compared with prior art has the following advantages:
1, the synthetic leather behind the employing use for synthetic leather mosquito proof waterproof and breathable wear resistant resin of the present invention: gloss is soft; Feel is smooth; Waterproof and breathable, wear-resisting scratch resistance, and can have efficiently, knock down fast insect killing effect and good repellent action to mosquito, fly, flea, lice, moth etc.;
2, use for synthetic leather mosquito proof waterproof and breathable wear resistant resin of the present invention is solvent with water, does not contain poisonous harmful substance, and its synthetic leather of processing is a Green Product; Simultaneously because the synthetic leather that adopts the present invention to process has the feature of environmental protection, multifunctionality; Enlarged the scope of application of synthetic leather; Not only can be used for conventional interior decoration leather, mattress leather, sofa artificial leather and automobile leather etc., also can be widely used in outdoor goods such as tent, sleeping bag, the clothing of charging, the knapsack;
3, use for synthetic leather mosquito proof waterproof and breathable wear resistant resin of the present invention can be used on existing synthetic leather production line, and technology is simple, and need not to change production equipment increases cost.
The invention also discloses the preparation method of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, this preparation method compared with prior art has the following advantages:
Use for synthetic leather mosquito proof waterproof and breathable wear resistant resin production technology of the present invention is simple, is easy to the batch production operation.
The specific embodiment:
Below in conjunction with specific embodiment; Further illustrate the present invention; Should understand these embodiment only be used to the present invention is described and be not used in the restriction scope of the present invention; After having read the present invention, those skilled in the art all fall within the application's accompanying claims institute restricted portion to the modification of the various equivalent form of values of the present invention.
Embodiment 1
A kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, its parts by weight are formed as follows: polyethers is 30 parts of polyurethane resins, and polyester is 8 parts of polyurethane resins; 50 parts in water, 4.5 parts of silica flatting silicas, 2 parts of mosquito proof auxiliary agents; 2 parts of OPEs, 1 part of modified amido siloxanes, 1 part of fluorocarbon surfactant; 1 part of organosilicon levelling agent, 0.8 part of fluouine water extraction agent.
The preparation method of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, concrete steps are following:
(1) by the prescription of above-mentioned parts by weight proportioning; With 30 parts of polyethers is that polyurethane resin and 8 parts of polyester are that polyurethane resin mixes the mixture A that obtains 38 parts, takes out then to obtain mixture B after 1/3 mixture A and 4.5 parts of silica flatting silicas stir, grind, filter in 50 parts of water;
(2) mixture B is added 2 parts of mosquito proof auxiliary agents, 2 parts of OPEs, 1 part of modified amido siloxanes, 1 portion of fluorocarbon surfactant, 1 part of organosilicon levelling agent and 0.8 part of fluouine water extraction agent, obtain mixture C after stirring;
(3) mixture C is added remaining 2/3 mixture A, filter after the mixing and stirring and can obtain described use for synthetic leather mosquito proof waterproof and breathable wear resistant resin.
The technical performance index of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin sees the following form:
| Project | Index | Testing result |
| PH value | 6.5-8.5 | 7 |
| Outward appearance | Translucent milky white liquid | Translucent milky white liquid |
| Stability | There are not deposition, nondiscolouring | There are not deposition, nondiscolouring |
| Viscosity (cps) | 3000±2 | 3000 |
| Solid content (%) | 30±2 | 31 |
Embodiment 2
A kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, its parts by weight are formed as follows: polyethers is 40 parts of polyurethane resins, and polyester is 10 parts of polyurethane resins; 55 parts in water, 5 parts of silica flatting silicas, 4 parts of mosquito proof auxiliary agents; 3.8 parts of OPEs, 3 parts of modified amido siloxanes, 2 parts of fluorocarbon surfactants; 2 parts of organosilicon levelling agents, 1 part of fluouine water extraction agent.
The preparation method of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, concrete steps are following:
(1) by the prescription of above-mentioned parts by weight proportioning; With 40 parts of polyethers is that polyurethane resin and 10 parts of polyester are that polyurethane resin mixes the mixture A that obtains 50 parts, takes out then to obtain mixture B after 1/3 mixture A and 5 parts of silica flatting silicas stir, grind, filter in 55 parts of water;
(2) mixture B is added 4 parts of mosquito proof auxiliary agents, 3.8 parts of OPEs, 3 parts of modified amido siloxanes, 4 portions of fluorocarbon surfactants, 2 parts of organosilicon levelling agents and 1 part of fluouine water extraction agent, obtain mixture C after stirring;
(3) mixture C is added remaining 2/3 mixture A, filter after the mixing and stirring and can obtain described use for synthetic leather mosquito proof waterproof and breathable wear resistant resin.
The technical performance index of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin sees the following form:
| Project | Index | Testing result |
| PH value | 6.5-8.5 | 8.3 |
| Outward appearance | Translucent milky white liquid | Translucent milky white liquid |
| Stability | There are not deposition, nondiscolouring | There are not deposition, nondiscolouring |
| Viscosity (cps) | 3000±2 | 3002 |
| Solid content (%) | 30±2 | 32 |
Embodiment 3
A kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, its parts by weight are formed as follows: polyethers is 36 parts of polyurethane resins, and polyester is 5 parts of polyurethane resins; 52 parts in water, 4 parts of silica flatting silicas, 3 parts of mosquito proof auxiliary agents; 4 parts of OPEs, 2 parts of modified amido siloxanes, 3 parts of fluorocarbon surfactants; 1.7 parts of organosilicon levelling agents, 0.5 part of fluouine water extraction agent.
The preparation method of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, concrete steps are following:
(1) by the prescription of above-mentioned parts by weight proportioning; With 36 parts of polyethers is that polyurethane resin and 5 parts of polyester are that polyurethane resin mixes the mixture A that obtains 41 parts, takes out then to obtain mixture B after 1/3 mixture A and 4 parts of silica flatting silicas stir, grind, filter in 52 parts of water;
(2) mixture B is added 3 parts of mosquito proof auxiliary agents, 4 parts of OPEs, 2 parts of modified amido siloxanes, 3 portions of fluorocarbon surfactants, 1.7 parts of organosilicon levelling agents and 0.5 part of fluouine water extraction agent, obtain mixture C after stirring;
(3) mixture C is added remaining 2/3 mixture A, filter after the mixing and stirring and can obtain described use for synthetic leather mosquito proof waterproof and breathable wear resistant resin.
The technical performance index of above-mentioned use for synthetic leather mosquito proof waterproof and breathable wear resistant resin sees the following form:
| Project | Index | Testing result |
| PH value | 6.5-8.5 | 6.8 |
| Outward appearance | Translucent milky white liquid | Translucent milky white liquid |
| Stability | There are not deposition, nondiscolouring | There are not deposition, nondiscolouring |
| Viscosity (cps) | 3000±2 | 3000 |
| Solid content (%) | 30±2 | 29 |
Claims (2)
1. use for synthetic leather mosquito proof waterproof and breathable wear resistant resin, it is characterized in that: its parts by weight proportioning is following: polyethers is 30 parts～40 parts of polyurethane resins, polyester is 5 parts～10 parts of polyurethane resins; 50 parts～55 parts in water, 4 parts～5 parts of silica flatting silicas, 2 parts～4 parts of mosquito proof auxiliary agents; 2 parts～4 parts of OPEs, 1 part～3 parts of modified amido siloxanes, 1 part～3 parts of fluorocarbon surfactants; 1 part～2 parts of organosilicon levelling agents, 0.5 part～1 part of fluouine water extraction agent.
2. the preparation method of a kind of use for synthetic leather mosquito proof waterproof and breathable wear resistant resin according to claim 1 is characterized in that the concrete steps of this method are following:
(1) is that polyurethane resin and polyester are that polyurethane resin mixes and obtains mixture A by prescription with polyethers, takes out then and obtain mixture B after 1/3 mixture A and silica flatting silica stir, grind, filter in water;
(2) mixture B is added mosquito proof auxiliary agent, OPE, modified amido siloxanes, fluorocarbon surfactant, organosilicon levelling agent and fluouine water extraction agent, obtain mixture C after stirring;
(3) mixture C is added remaining 2/3 mixture A, filter after the mixing and stirring and can obtain described use for synthetic leather mosquito proof waterproof and breathable wear resistant resin.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105092675A CN101967756B (en) | 2010-10-15 | 2010-10-15 | Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof |
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| CN2010105092675A CN101967756B (en) | 2010-10-15 | 2010-10-15 | Anti-mosquito water-proof airpermeability wear-resisting resin used for synthesizing leather and preparation method thereof |
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| CN101967756A CN101967756A (en) | 2011-02-09 |
| CN101967756B true CN101967756B (en) | 2012-01-25 |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102330337A (en) * | 2011-07-28 | 2012-01-25 | 吴江征明纺织有限公司 | Finishing agent for anti-mosquito waterproof and moisture permeable fabric |
| CN102493200B (en) * | 2011-12-05 | 2013-08-28 | 辽宁恒星精细化工有限公司 | Waterproof ventilating anti-mosquito coating glue for textile and preparation method |
| CN102978939A (en) * | 2012-08-21 | 2013-03-20 | 江苏宝泽高分子材料股份有限公司 | Aqueous crystal effect ironing brightening treatment agent for synthetic leather, and preparation method thereof |
| CN104294597B (en) * | 2013-03-23 | 2016-04-20 | 广东德美精细化工股份有限公司 | A kind of preparation method of content of wax water and oil repellent agent |
| CN103835145B (en) * | 2014-03-04 | 2016-04-20 | 合肥市科天化工有限公司 | A kind of environmental protection ventilation clothing leather and preparation method thereof |
| CN104480731A (en) * | 2014-10-23 | 2015-04-01 | 合肥金伶俐服饰有限公司 | Air-permeable PU synthetic leather and producing method thereof |
| CN106521984A (en) * | 2016-11-04 | 2017-03-22 | 南平博士达节能科技有限公司 | Additive for polyurethane synthetic leather and preparation method thereof |
| CN110951033A (en) * | 2019-12-19 | 2020-04-03 | 超然(福建)新材料科技有限公司 | Hydrolysis-resistant polyurethane resin and preparation method thereof |
| WO2024234223A1 (en) * | 2023-05-15 | 2024-11-21 | 福建百宏聚纤科技实业有限公司 | Novel waterproof breathable fabric and preparation method therefor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0609600A1 (en) * | 1993-02-01 | 1994-08-10 | Graniteville Company | Fabrics with insect repellent and a barrier |
| CN1640972A (en) * | 2004-11-04 | 2005-07-20 | 深圳市展辰达化工有限公司 | Water-based termite-proof insect-protected enclosed paint |
| CN1640970A (en) * | 2004-02-26 | 2005-07-20 | 深圳市展辰达化工有限公司 | Polyurethane termite-proof insect-protected enclosed primping paint |
| CN101649552A (en) * | 2009-08-25 | 2010-02-17 | 江苏宝泽高分子材料股份有限公司 | Waterborne PU high smooth wax resin for synthetic leather |
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2010
- 2010-10-15 CN CN2010105092675A patent/CN101967756B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0609600A1 (en) * | 1993-02-01 | 1994-08-10 | Graniteville Company | Fabrics with insect repellent and a barrier |
| CN1640970A (en) * | 2004-02-26 | 2005-07-20 | 深圳市展辰达化工有限公司 | Polyurethane termite-proof insect-protected enclosed primping paint |
| CN1640972A (en) * | 2004-11-04 | 2005-07-20 | 深圳市展辰达化工有限公司 | Water-based termite-proof insect-protected enclosed paint |
| CN101649552A (en) * | 2009-08-25 | 2010-02-17 | 江苏宝泽高分子材料股份有限公司 | Waterborne PU high smooth wax resin for synthetic leather |
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