CN101963359A - Energy-saving device of incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur - Google Patents
Energy-saving device of incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur Download PDFInfo
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- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000011593 sulfur Substances 0.000 title claims abstract description 19
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 title abstract description 9
- 238000000746 purification Methods 0.000 claims abstract description 14
- 239000003344 environmental pollutant Substances 0.000 claims abstract description 8
- 231100000719 pollutant Toxicity 0.000 claims abstract description 8
- 230000006698 induction Effects 0.000 claims description 12
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 9
- 238000006477 desulfuration reaction Methods 0.000 claims description 5
- 230000023556 desulfurization Effects 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 5
- 230000001172 regenerating effect Effects 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 8
- 238000003795 desorption Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 239000007789 gas Substances 0.000 description 6
- 229910052815 sulfur oxide Inorganic materials 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000003915 air pollution Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
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Abstract
Description
技术领域technical field
本发明涉及一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置。The invention relates to an energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur.
背景技术Background technique
生活和生产中广泛应用的有机溶剂,在室温下易挥发成气体,故又名挥发性有机物(Volatile Organic Compounds,VOCs),而多数的VOCs对人体有一定毒性,必须加以处理;另,由空气品质监测资料显示,VOCs及Nox等臭气前驱物质与光反应所产生的臭氧,有取代悬浮微粒成为影响空气污染指数(PSI)的主要污染物的现象,故加强管制VOCs排放乃为目前空气污染防治重点之一;然而,使用焚化炉焚化为VOCs废气处理方式的一种,在适当条件下的VOCs去除率可达99%以上,燃烧后的产物通常为水、二氧化碳、氮氧化物、硫氧化物等,故为一种可有效处理废气中所含的VOCs及臭气的方法。Organic solvents widely used in life and production are easy to volatilize into gases at room temperature, so they are also called Volatile Organic Compounds (VOCs), and most VOCs are toxic to the human body and must be treated; Quality monitoring data show that ozone produced by the reaction of odor precursors such as VOCs and NOx with light has replaced suspended particles as the main pollutant affecting the Air Pollution Index (PSI). Therefore, strengthening the control of VOCs emissions is the current air pollution One of the key points of prevention and control; however, using an incinerator to incinerate is one of the VOCs waste gas treatment methods. Under appropriate conditions, the VOCs removal rate can reach more than 99%, and the products after combustion are usually water, carbon dioxide, nitrogen oxides, and sulfur oxides. Therefore, it is a method that can effectively treat VOCs and odor contained in exhaust gas.
其次,若使用焚化炉焚化含氮或/及含硫的挥发性有机物(诸如下表所列),则必须如图1所示,而于焚化炉10的下游端加设用以脱硝或/及脱硫的再净化单元20,将焚化燃烧后的衍生污染物(氮氧化物(NOx)或/及硫氧化物(SOx)),予以再净化后才对大气排放;但由于用以脱硝或/及脱硫的再净化单元20,其工作温度有最低温度的限制,一般必须在200℃以上(较佳为300℃~400℃之间),才能得到较佳的净化效率,尤其若衍生污染物为硫氧化物(SOx),则另有酸腐蚀露点的问题必须注意;而此衍生污染物的再净化技术为公知公用的技术,在此不再赘述;然而,流经该再净化单元20的气流,通常将焚化炉10的出口气流温度控制在该再净化单元20所需的工作温度(如前述的200℃)以上,以达到再净化的功效;故经由该再净化单元20所排放的净化气流温度仍甚高(可能在200℃~400℃之间),完全能够再加以热回收利用。Secondly, if an incinerator is used to incinerate nitrogen-containing or/and sulfur-containing volatile organic compounds (such as listed in the table below), it must be shown in Figure 1, and a denitrification or/and The desulfurization re-purification unit 20 is used to re-purify the derived pollutants (nitrogen oxides (NOx) or/and sulfur oxides (SOx)) after incineration and combustion before being discharged into the atmosphere; however, due to denitrification or/and The repurification unit 20 for desulfurization has a minimum temperature limit, which generally must be above 200°C (preferably between 300°C and 400°C) to obtain better purification efficiency, especially if the derived pollutant is sulfur For oxides (SOx), there is another problem of acid corrosion dew point that must be paid attention to; and the re-purification technology of this derived pollutant is a well-known and public technology, so it will not be described in detail here; however, the airflow flowing through the re-purification unit 20, Usually the temperature of the outlet airflow of the
再者,为了预防焚化炉入口侧高沸点挥发性有机物残留,而产生停机闷燃问题或结焦(Tar)现象,一般焚化炉(特别是蓄热式焚化炉)均需定期针对焚化炉借由提升气流温度以进行高温热烘模式(Bake out process),将残留的高沸点挥发性有机物加以热烘脱附。Furthermore, in order to prevent volatile organic compounds with high boiling point from remaining on the inlet side of the incinerator, which may cause smoldering or tar formation during shutdown, general incinerators (especially regenerative incinerators) need to regularly upgrade the incinerator The temperature of the airflow is used for high-temperature baking mode (Bake out process), and the residual high-boiling volatile organic compounds are heated and desorbed.
发明内容Contents of the invention
本发明所要解决的主要技术问题在于,克服现有技术存在的上述缺陷,而提供一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,具有增设一热交换器以节能的功效,且能提高再净化效能及热烘脱附净化的效果。The main technical problem to be solved by the present invention is to overcome the above-mentioned defects in the prior art, and provide an energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur, which has the function of adding a heat exchanger to save energy Efficacy, and can improve the performance of repurification and the effect of heat drying desorption purification.
本发明解决其技术问题所采用的技术方案是:The technical solution adopted by the present invention to solve its technical problems is:
一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于,包括:一焚化炉,连接有引气管与排气管;一再净化单元,设置于该焚化炉的排气管下游,将经由该焚化炉焚化燃烧后的衍生污染物进行再净化处理,并由排放管把净化气流排放至大气;一热交换器,令该引气管由该排放管回收热能。An energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur, which is characterized in that it includes: an incinerator connected with an air induction pipe and an exhaust pipe; Downstream of the air pipe, the derivative pollutants after being incinerated and burned by the incinerator are repurified, and the purified airflow is discharged to the atmosphere through the discharge pipe; a heat exchanger enables the air induction pipe to recover heat energy from the discharge pipe.
前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中焚化炉为恢复式焚化炉、蓄热式焚化炉或回转式蓄热焚化炉。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the incinerator is a recovery type incinerator, a regenerative incinerator or a rotary regenerative incinerator.
前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中焚化炉将一风机设置于该引气管或排气管。The aforementioned energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds, wherein the incinerator installs a fan in the air induction pipe or exhaust pipe.
前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中热交换器为管壳式或板式热交换器。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the heat exchanger is a shell-and-tube or plate heat exchanger.
前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中再净化单元为脱硝或/及脱硫设备之一或组合。The aforementioned energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds, wherein the repurification unit is one or a combination of denitrification and/or desulfurization equipment.
前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中引气管或该排放管择一设置避开该热交换器的旁通管,且设置第一温度计与第二温度计于该焚化炉的入口与出口,并借所侦测的温度讯号经由一控制器调整该旁通管控制阀的开度。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the induction pipe or the discharge pipe is selected to avoid the bypass pipe of the heat exchanger, and the first thermometer and the second thermometer are arranged At the inlet and outlet of the incinerator, the opening degree of the bypass pipe control valve is adjusted through a controller by means of the detected temperature signal.
本发明的有益效果是,具有增设一热交换器以节能的功效,且能提高再净化效能及热烘脱附净化的效果。The beneficial effect of the present invention is that it has the effect of adding a heat exchanger to save energy, and can improve the repurification efficiency and the effect of thermal drying, desorption and purification.
附图说明Description of drawings
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
图1是现有含氮或/及含硫的挥发性有机物焚化处理系统的结构示意图。Fig. 1 is a structural schematic diagram of an existing incineration system for volatile organic compounds containing nitrogen or/and sulfur.
图2是本发明的结构示意图。Fig. 2 is a structural schematic diagram of the present invention.
图中标号说明:Explanation of symbols in the figure:
10 焚化炉10 incinerators
11 风机11 fans
12 引气管12 bleed pipe
121 旁通管121 Bypass pipe
122 控制阀122 control valve
13 排气管13 exhaust pipe
20 再净化单元20 repurification unit
21 排放管21 discharge pipe
211 旁通管211 bypass pipe
212 控制阀212 control valve
22 烟囱22 chimney
30 热交换器30 heat exchanger
31 第一温度计31 first thermometer
32 第二温度计32 second thermometer
33 控制器33 controller
具体实施方式Detailed ways
首先,请参阅图2所示,本发明包括有:At first, referring to shown in Fig. 2, the present invention includes:
一焚化炉10,连接有引气管12与排气管13,并将一风机11设置于该引气管12或排气管13,用以将挥发性有机物引入并进行焚化处理;而该焚化炉10为恢复焚化炉(Recuperative Thermal Oxidizer)、蓄热式焚化炉(Regenerative Thermal Oxidizer)或回转式蓄热焚化炉;An
一再净化单元20,设置于该焚化炉10的排气管13下游,用以将经由该焚化炉10焚化燃烧后的衍生污染物(氮氧化物或/及硫氧化物)进行再净化处理,并由排放管21与烟囱22把净化气流排放至大气,而该再净化单元20为脱硝或/及脱硫设备之一或组合;A purification unit 20 is arranged downstream of the
一热交换器30,可为管壳式或板式热交换器,而令该引气管12由该排放管21回收热能。A heat exchanger 30 can be a shell-and-tube heat exchanger or a plate heat exchanger, so that the
此外,该引气管12或该排放管21择一设置避开该热交换器30的旁通管(121或211),而用以控制流经该旁通管(121或211)的气流量,调节进入该热交换器30进行热回收的气流量,以调整引入该焚化炉10的废气气流温度,亦即可进一步限制该焚化炉10的入口与出口温度的高低值;因此,可设置第一温度计31与第二温度计32于该焚化炉10的入口与出口,侦测该焚化炉10的入口与出口温度,并借此温度讯号经由一控制器33调整该旁通管(121或211)的控制阀(122或212)的开度,调节进入该热交换器30进行热回收的气流量,进而将焚化炉10的出口温度控制在300℃~400℃之间。In addition, the
基于上述结构,本发明较现有技术所增设的热交换器30,是将经该再净化单元20净化后的净化气流,进行热回收后再对大气排放;然而,根据实际的测试结果,可将净化气流最终的排放温度,再增设该热交换器30之后,由原本的350℃降低至170℃,而把引入该焚化炉10的废气气流温度,由原本的50℃升温至230℃,进而节省该焚化炉10所需耗费的燃料(能源),具有节能的功效;并可进一步控制焚化炉10的入口与出口温度的高低值,进而增进该再净化单元20的再净化效能,并预防焚化炉10入口侧高沸点挥发性有机物的残留问题,具有增进再净化效能且热烘脱附净化的功效。Based on the above-mentioned structure, the heat exchanger 30 added by the present invention compared with the prior art is to discharge the purified air stream purified by the re-purification unit 20 to the atmosphere after heat recovery; however, according to actual test results, it can be After adding the heat exchanger 30, the final discharge temperature of the purified gas flow is reduced from the original 350°C to 170°C, and the temperature of the exhaust gas flow introduced into the
以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制,凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention in any form. Any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention still belong to within the scope of the technical solutions of the present invention.
综上所述,本发明在结构设计、使用实用性及成本效益上,完全符合产业发展所需,且所揭示的结构亦是具有前所未有的创新构造,具有新颖性、创造性、实用性,符合有关发明专利要件的规定,故依法提起申请。In summary, the present invention fully meets the needs of industrial development in terms of structural design, practicability and cost-effectiveness, and the disclosed structure also has an unprecedented innovative structure, novelty, creativity and practicability, and meets the requirements of relevant According to the requirements of the invention patent requirements, the application is filed according to law.
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Cited By (3)
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CN107763639A (en) * | 2016-08-17 | 2018-03-06 | 中国石化工程建设有限公司 | A kind of method for handling volatile organic matter |
CN108452637A (en) * | 2017-02-17 | 2018-08-28 | 杰智环境科技股份有限公司 | Serial-type rotating wheel high-efficiency purification system and serial-type rotating wheel high-efficiency purification method |
CN109893994A (en) * | 2017-12-07 | 2019-06-18 | 张荣兴 | Handle the accumulation of heat regenerative catalytic oxidizer of VOCs exhaust gas |
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CN2426571Y (en) * | 2000-06-20 | 2001-04-11 | 广西绿洲热能设备有限公司 | Organic waste liquid heat-pipe evaporating concentrating burning boiler |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107763639A (en) * | 2016-08-17 | 2018-03-06 | 中国石化工程建设有限公司 | A kind of method for handling volatile organic matter |
CN108452637A (en) * | 2017-02-17 | 2018-08-28 | 杰智环境科技股份有限公司 | Serial-type rotating wheel high-efficiency purification system and serial-type rotating wheel high-efficiency purification method |
CN109893994A (en) * | 2017-12-07 | 2019-06-18 | 张荣兴 | Handle the accumulation of heat regenerative catalytic oxidizer of VOCs exhaust gas |
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