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CN101963359A - Energy-saving device of incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur - Google Patents

Energy-saving device of incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur Download PDF

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CN101963359A
CN101963359A CN2009101582884A CN200910158288A CN101963359A CN 101963359 A CN101963359 A CN 101963359A CN 2009101582884 A CN2009101582884 A CN 2009101582884A CN 200910158288 A CN200910158288 A CN 200910158288A CN 101963359 A CN101963359 A CN 101963359A
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CN101963359B (en
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张丰堂
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JG Environmental Technology Co Ltd
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Abstract

An energy-saving device of a nitrogen or/and sulfur-containing volatile organic compound incineration treatment system comprises: an incinerator connected with a gas-guiding pipe and an exhaust pipe; a repurification unit arranged at the downstream of the exhaust pipe of the incinerator, repurifies the derived pollutant incinerated and burned by the incinerator, and discharges the purified air flow to the atmosphere through the exhaust pipe; a heat exchanger, which makes the air-bleed pipe recover the heat energy from the exhaust pipe. The invention has the effect of saving energy by additionally arranging the heat exchanger, and can improve the re-purification efficiency and the thermal drying desorption purification effect.

Description

含氮或/及含硫的挥发性有机物焚化处理系统的节能装置 Energy-saving device for nitrogen-containing and/or sulfur-containing volatile organic compounds incineration treatment system

技术领域technical field

本发明涉及一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置。The invention relates to an energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur.

背景技术Background technique

生活和生产中广泛应用的有机溶剂,在室温下易挥发成气体,故又名挥发性有机物(Volatile Organic Compounds,VOCs),而多数的VOCs对人体有一定毒性,必须加以处理;另,由空气品质监测资料显示,VOCs及Nox等臭气前驱物质与光反应所产生的臭氧,有取代悬浮微粒成为影响空气污染指数(PSI)的主要污染物的现象,故加强管制VOCs排放乃为目前空气污染防治重点之一;然而,使用焚化炉焚化为VOCs废气处理方式的一种,在适当条件下的VOCs去除率可达99%以上,燃烧后的产物通常为水、二氧化碳、氮氧化物、硫氧化物等,故为一种可有效处理废气中所含的VOCs及臭气的方法。Organic solvents widely used in life and production are easy to volatilize into gases at room temperature, so they are also called Volatile Organic Compounds (VOCs), and most VOCs are toxic to the human body and must be treated; Quality monitoring data show that ozone produced by the reaction of odor precursors such as VOCs and NOx with light has replaced suspended particles as the main pollutant affecting the Air Pollution Index (PSI). Therefore, strengthening the control of VOCs emissions is the current air pollution One of the key points of prevention and control; however, using an incinerator to incinerate is one of the VOCs waste gas treatment methods. Under appropriate conditions, the VOCs removal rate can reach more than 99%, and the products after combustion are usually water, carbon dioxide, nitrogen oxides, and sulfur oxides. Therefore, it is a method that can effectively treat VOCs and odor contained in exhaust gas.

其次,若使用焚化炉焚化含氮或/及含硫的挥发性有机物(诸如下表所列),则必须如图1所示,而于焚化炉10的下游端加设用以脱硝或/及脱硫的再净化单元20,将焚化燃烧后的衍生污染物(氮氧化物(NOx)或/及硫氧化物(SOx)),予以再净化后才对大气排放;但由于用以脱硝或/及脱硫的再净化单元20,其工作温度有最低温度的限制,一般必须在200℃以上(较佳为300℃~400℃之间),才能得到较佳的净化效率,尤其若衍生污染物为硫氧化物(SOx),则另有酸腐蚀露点的问题必须注意;而此衍生污染物的再净化技术为公知公用的技术,在此不再赘述;然而,流经该再净化单元20的气流,通常将焚化炉10的出口气流温度控制在该再净化单元20所需的工作温度(如前述的200℃)以上,以达到再净化的功效;故经由该再净化单元20所排放的净化气流温度仍甚高(可能在200℃~400℃之间),完全能够再加以热回收利用。Secondly, if an incinerator is used to incinerate nitrogen-containing or/and sulfur-containing volatile organic compounds (such as listed in the table below), it must be shown in Figure 1, and a denitrification or/and The desulfurization re-purification unit 20 is used to re-purify the derived pollutants (nitrogen oxides (NOx) or/and sulfur oxides (SOx)) after incineration and combustion before being discharged into the atmosphere; however, due to denitrification or/and The repurification unit 20 for desulfurization has a minimum temperature limit, which generally must be above 200°C (preferably between 300°C and 400°C) to obtain better purification efficiency, especially if the derived pollutant is sulfur For oxides (SOx), there is another problem of acid corrosion dew point that must be paid attention to; and the re-purification technology of this derived pollutant is a well-known and public technology, so it will not be described in detail here; however, the airflow flowing through the re-purification unit 20, Usually the temperature of the outlet airflow of the incinerator 10 is controlled above the required working temperature (as mentioned above 200°C) of the repurification unit 20 to achieve the effect of repurification; It is still very high (maybe between 200°C and 400°C), and it can be fully recycled by heat.

再者,为了预防焚化炉入口侧高沸点挥发性有机物残留,而产生停机闷燃问题或结焦(Tar)现象,一般焚化炉(特别是蓄热式焚化炉)均需定期针对焚化炉借由提升气流温度以进行高温热烘模式(Bake out process),将残留的高沸点挥发性有机物加以热烘脱附。Furthermore, in order to prevent volatile organic compounds with high boiling point from remaining on the inlet side of the incinerator, which may cause smoldering or tar formation during shutdown, general incinerators (especially regenerative incinerators) need to regularly upgrade the incinerator The temperature of the airflow is used for high-temperature baking mode (Bake out process), and the residual high-boiling volatile organic compounds are heated and desorbed.

发明内容Contents of the invention

本发明所要解决的主要技术问题在于,克服现有技术存在的上述缺陷,而提供一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,具有增设一热交换器以节能的功效,且能提高再净化效能及热烘脱附净化的效果。The main technical problem to be solved by the present invention is to overcome the above-mentioned defects in the prior art, and provide an energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur, which has the function of adding a heat exchanger to save energy Efficacy, and can improve the performance of repurification and the effect of heat drying desorption purification.

本发明解决其技术问题所采用的技术方案是:The technical solution adopted by the present invention to solve its technical problems is:

一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于,包括:一焚化炉,连接有引气管与排气管;一再净化单元,设置于该焚化炉的排气管下游,将经由该焚化炉焚化燃烧后的衍生污染物进行再净化处理,并由排放管把净化气流排放至大气;一热交换器,令该引气管由该排放管回收热能。An energy-saving device for an incineration treatment system for volatile organic compounds containing nitrogen or/and sulfur, which is characterized in that it includes: an incinerator connected with an air induction pipe and an exhaust pipe; Downstream of the air pipe, the derivative pollutants after being incinerated and burned by the incinerator are repurified, and the purified airflow is discharged to the atmosphere through the discharge pipe; a heat exchanger enables the air induction pipe to recover heat energy from the discharge pipe.

前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中焚化炉为恢复式焚化炉、蓄热式焚化炉或回转式蓄热焚化炉。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the incinerator is a recovery type incinerator, a regenerative incinerator or a rotary regenerative incinerator.

前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中焚化炉将一风机设置于该引气管或排气管。The aforementioned energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds, wherein the incinerator installs a fan in the air induction pipe or exhaust pipe.

前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中热交换器为管壳式或板式热交换器。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the heat exchanger is a shell-and-tube or plate heat exchanger.

前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中再净化单元为脱硝或/及脱硫设备之一或组合。The aforementioned energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds, wherein the repurification unit is one or a combination of denitrification and/or desulfurization equipment.

前述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其中引气管或该排放管择一设置避开该热交换器的旁通管,且设置第一温度计与第二温度计于该焚化炉的入口与出口,并借所侦测的温度讯号经由一控制器调整该旁通管控制阀的开度。The aforementioned energy-saving device for the incineration treatment system of volatile organic compounds containing nitrogen and/or sulfur, wherein the induction pipe or the discharge pipe is selected to avoid the bypass pipe of the heat exchanger, and the first thermometer and the second thermometer are arranged At the inlet and outlet of the incinerator, the opening degree of the bypass pipe control valve is adjusted through a controller by means of the detected temperature signal.

本发明的有益效果是,具有增设一热交换器以节能的功效,且能提高再净化效能及热烘脱附净化的效果。The beneficial effect of the present invention is that it has the effect of adding a heat exchanger to save energy, and can improve the repurification efficiency and the effect of thermal drying, desorption and purification.

附图说明Description of drawings

下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.

图1是现有含氮或/及含硫的挥发性有机物焚化处理系统的结构示意图。Fig. 1 is a structural schematic diagram of an existing incineration system for volatile organic compounds containing nitrogen or/and sulfur.

图2是本发明的结构示意图。Fig. 2 is a structural schematic diagram of the present invention.

图中标号说明:Explanation of symbols in the figure:

10   焚化炉10 incinerators

11   风机11 fans

12   引气管12 bleed pipe

121  旁通管121 Bypass pipe

122  控制阀122 control valve

13   排气管13 exhaust pipe

20   再净化单元20 repurification unit

21   排放管21 discharge pipe

211  旁通管211 bypass pipe

212  控制阀212 control valve

22   烟囱22 chimney

30   热交换器30 heat exchanger

31   第一温度计31 first thermometer

32   第二温度计32 second thermometer

33   控制器33 controller

具体实施方式Detailed ways

首先,请参阅图2所示,本发明包括有:At first, referring to shown in Fig. 2, the present invention includes:

一焚化炉10,连接有引气管12与排气管13,并将一风机11设置于该引气管12或排气管13,用以将挥发性有机物引入并进行焚化处理;而该焚化炉10为恢复焚化炉(Recuperative Thermal Oxidizer)、蓄热式焚化炉(Regenerative Thermal Oxidizer)或回转式蓄热焚化炉;An incinerator 10 is connected with an air induction pipe 12 and an exhaust pipe 13, and a fan 11 is arranged on the air induction pipe 12 or the exhaust pipe 13 to introduce and incinerate volatile organic compounds; and the incinerator 10 is a Recuperative Thermal Oxidizer, a Regenerative Thermal Oxidizer or a Rotary Thermal Oxidizer;

一再净化单元20,设置于该焚化炉10的排气管13下游,用以将经由该焚化炉10焚化燃烧后的衍生污染物(氮氧化物或/及硫氧化物)进行再净化处理,并由排放管21与烟囱22把净化气流排放至大气,而该再净化单元20为脱硝或/及脱硫设备之一或组合;A purification unit 20 is arranged downstream of the exhaust pipe 13 of the incinerator 10, and is used for repurifying the derivative pollutants (nitrogen oxides or/and sulfur oxides) after incineration and combustion of the incinerator 10, and The purified gas flow is discharged to the atmosphere through the discharge pipe 21 and the chimney 22, and the repurification unit 20 is one or a combination of denitrification and/or desulfurization equipment;

一热交换器30,可为管壳式或板式热交换器,而令该引气管12由该排放管21回收热能。A heat exchanger 30 can be a shell-and-tube heat exchanger or a plate heat exchanger, so that the air induction pipe 12 recovers heat energy from the discharge pipe 21 .

此外,该引气管12或该排放管21择一设置避开该热交换器30的旁通管(121或211),而用以控制流经该旁通管(121或211)的气流量,调节进入该热交换器30进行热回收的气流量,以调整引入该焚化炉10的废气气流温度,亦即可进一步限制该焚化炉10的入口与出口温度的高低值;因此,可设置第一温度计31与第二温度计32于该焚化炉10的入口与出口,侦测该焚化炉10的入口与出口温度,并借此温度讯号经由一控制器33调整该旁通管(121或211)的控制阀(122或212)的开度,调节进入该热交换器30进行热回收的气流量,进而将焚化炉10的出口温度控制在300℃~400℃之间。In addition, the air induction pipe 12 or the discharge pipe 21 is alternatively arranged to avoid the bypass pipe (121 or 211) of the heat exchanger 30, so as to control the flow of air flowing through the bypass pipe (121 or 211), Adjusting the air flow rate entering the heat exchanger 30 for heat recovery, to adjust the temperature of the exhaust gas flow introduced into the incinerator 10, that is, to further limit the temperature of the inlet and outlet of the incinerator 10; therefore, the first The thermometer 31 and the second thermometer 32 detect the inlet and outlet temperatures of the incinerator 10 at the inlet and outlet of the incinerator 10, and use the temperature signal to adjust the temperature of the bypass pipe (121 or 211) through a controller 33. Control the opening of the valve (122 or 212) to adjust the flow of air entering the heat exchanger 30 for heat recovery, and then control the outlet temperature of the incinerator 10 between 300°C and 400°C.

基于上述结构,本发明较现有技术所增设的热交换器30,是将经该再净化单元20净化后的净化气流,进行热回收后再对大气排放;然而,根据实际的测试结果,可将净化气流最终的排放温度,再增设该热交换器30之后,由原本的350℃降低至170℃,而把引入该焚化炉10的废气气流温度,由原本的50℃升温至230℃,进而节省该焚化炉10所需耗费的燃料(能源),具有节能的功效;并可进一步控制焚化炉10的入口与出口温度的高低值,进而增进该再净化单元20的再净化效能,并预防焚化炉10入口侧高沸点挥发性有机物的残留问题,具有增进再净化效能且热烘脱附净化的功效。Based on the above-mentioned structure, the heat exchanger 30 added by the present invention compared with the prior art is to discharge the purified air stream purified by the re-purification unit 20 to the atmosphere after heat recovery; however, according to actual test results, it can be After adding the heat exchanger 30, the final discharge temperature of the purified gas flow is reduced from the original 350°C to 170°C, and the temperature of the exhaust gas flow introduced into the incinerator 10 is raised from the original 50°C to 230°C, and then Save the fuel (energy) consumed by the incinerator 10, which has the effect of saving energy; and can further control the high and low values of the inlet and outlet temperatures of the incinerator 10, thereby improving the repurification performance of the repurification unit 20 and preventing incineration The residual problem of high-boiling volatile organic compounds on the inlet side of the furnace 10 has the effect of improving the re-purification performance and heat-drying desorption purification.

以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制,凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention in any form. Any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention still belong to within the scope of the technical solutions of the present invention.

综上所述,本发明在结构设计、使用实用性及成本效益上,完全符合产业发展所需,且所揭示的结构亦是具有前所未有的创新构造,具有新颖性、创造性、实用性,符合有关发明专利要件的规定,故依法提起申请。In summary, the present invention fully meets the needs of industrial development in terms of structural design, practicability and cost-effectiveness, and the disclosed structure also has an unprecedented innovative structure, novelty, creativity and practicability, and meets the requirements of relevant According to the requirements of the invention patent requirements, the application is filed according to law.

Claims (6)

1.一种含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于,包括:1. An energy-saving device for a nitrogen-containing or/and sulfur-containing VOC incineration treatment system, characterized in that it comprises: 一焚化炉,连接有引气管与排气管;An incinerator connected with an air induction pipe and an exhaust pipe; 一再净化单元,设置于该焚化炉的排气管下游,将经由该焚化炉焚化燃烧后的衍生污染物进行再净化处理,并由排放管把净化气流排放至大气;The re-purification unit is arranged downstream of the exhaust pipe of the incinerator, and performs re-purification treatment on the derivative pollutants after incineration and combustion of the incinerator, and discharges the purified airflow to the atmosphere through the discharge pipe; 一热交换器,令该引气管由该排放管回收热能。A heat exchanger enables the induction pipe to recover heat energy from the discharge pipe. 2.根据权利要求1所述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于:所述焚化炉为恢复式焚化炉、蓄热式焚化炉或回转式蓄热焚化炉。2. The energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds according to claim 1, wherein the incinerator is a recovery type incinerator, a regenerative incinerator or a rotary storage type Hot incinerator. 3.根据权利要求2所述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于:所述焚化炉将一风机设置于该引气管或排气管。3. The energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds according to claim 2, characterized in that: the incinerator installs a fan in the air induction pipe or exhaust pipe. 4.根据权利要求3所述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于:所述热交换器为管壳式或板式热交换器。4. The energy-saving device for the incineration treatment system of nitrogen-containing and/or sulfur-containing volatile organic compounds according to claim 3, wherein the heat exchanger is a shell-and-tube or plate heat exchanger. 5.根据权利要求4所述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于:所述再净化单元为脱硝或/及脱硫设备之一或组合。5. The energy-saving device for the nitrogen-containing and/or sulfur-containing VOC incineration treatment system according to claim 4, wherein the repurification unit is one or a combination of denitrification and/or desulfurization equipment. 6.根据权利要求1至5中任一项所述的含氮或/及含硫的挥发性有机物焚化处理系统的节能装置,其特征在于:所述引气管或该排放管择一设置避开该热交换器的旁通管,且设置第一温度计与第二温度计于该焚化炉的入口与出口,并借所侦测的温度讯号经由一控制器调整该旁通管控制阀的开度。6. The energy-saving device for the nitrogen-containing and/or sulfur-containing volatile organic compound incineration treatment system according to any one of claims 1 to 5, characterized in that: the air induction pipe or the discharge pipe is set to avoid The bypass pipe of the heat exchanger is provided with a first thermometer and a second thermometer at the inlet and outlet of the incinerator, and the opening degree of the bypass pipe control valve is adjusted through a controller by means of the detected temperature signal.
CN200910158288.4A 2009-07-24 2009-07-24 Energy-saving device for nitrogen-containing and/or sulfur-containing volatile organic compounds incineration treatment system Expired - Fee Related CN101963359B (en)

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CN107763639A (en) * 2016-08-17 2018-03-06 中国石化工程建设有限公司 A kind of method for handling volatile organic matter
CN108452637A (en) * 2017-02-17 2018-08-28 杰智环境科技股份有限公司 Serial-type rotating wheel high-efficiency purification system and serial-type rotating wheel high-efficiency purification method
CN109893994A (en) * 2017-12-07 2019-06-18 张荣兴 Handle the accumulation of heat regenerative catalytic oxidizer of VOCs exhaust gas

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CN2426571Y (en) * 2000-06-20 2001-04-11 广西绿洲热能设备有限公司 Organic waste liquid heat-pipe evaporating concentrating burning boiler

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CN107763639A (en) * 2016-08-17 2018-03-06 中国石化工程建设有限公司 A kind of method for handling volatile organic matter
CN108452637A (en) * 2017-02-17 2018-08-28 杰智环境科技股份有限公司 Serial-type rotating wheel high-efficiency purification system and serial-type rotating wheel high-efficiency purification method
CN109893994A (en) * 2017-12-07 2019-06-18 张荣兴 Handle the accumulation of heat regenerative catalytic oxidizer of VOCs exhaust gas

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